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1.
The title C, O -dialkylated resorcinols have seldom been prepared. We have developed a practical synthesis of this class of compounds starting with cyclohexane-1,3-dione. The key features of the synthesis are mono-O-alkylation of a 2-alkyl cyclohexane-1,3-dione and Pd-C catalyzed or NBS/DBU annuitization of the resultant O-alkyl-2-alkyl cyclohexane-1,3-dione. The use of cyclohexane-1,3-dione allows regioselective alkylations that would not be possible with resorcinol itself. A convenient synthesis of 2-alkyl resorcinols from cyclohexane-1,3-dione has also been achieved. 相似文献
2.
CO2/H2和(CO/CO2)+H2低压合成甲醇催化过程的本质 总被引:8,自引:0,他引:8
通过在Cu/ZnO/Al2O3催化剂上CO2+H2,CO+H2和(CO/CO2)+H2催化反应动力学研究对合成甲醇动力学和反应机理进行了细致分析,提出合成甲醇的反应机理,解释了在(CO/CO2)+H2合成甲醇过程中少量CO2的作用及合成甲醇的直接碳源。 相似文献
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The highly enantioselective synthesis of 2-aryl- and 2-vinyl-piperidines has been accomplished through a catalytic dynamic resolution (CDR) of N-Boc-2-lithiopiperidine. The method has been applied to the synthesis of both enantiomers of the tobacco alkaloid anabasine. 相似文献
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An efficient and practical isatin-based oxidative domino protocol has been developed for the facile synthesis of 2-aminobenzamides and 2-aminobenzoates. The robust nature of this reaction system is reflected by accessible starting materials, room temperature and high-yield gram-scale synthesis. 相似文献
5.
The synthesis of nitroanilines catalyzed by horseradish peroxidase(HRP) in the presence of sodium nitrite and hydrogen peroxide was investigated, o-Nitroaniline and p-nitroaniline were found in the nitrated products. 2-Aminotoluene and 4-aminotoluene could also be nitrated to give corresponding nitrated products. This protocol has great potentials to open new avenues useful for the synthesis of nitroaniline and its derivatives. 相似文献
6.
Barclay TM Hicks RG Lemaire MT Thompson LK Xu Z 《Chemical communications (Cambridge, England)》2002,(16):1688-1689
The synthesis of a verdazyl radical with a carboxylate substituent renders the radical highly soluble in water, thereby permitting the aqueous synthesis of Ni(II) and Co(II) verdazyl complexes which have been structurally and magnetically characterized. 相似文献
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Generally, synthesis of hydantoin derivatives involve use of carbonyl compounds which in turn require multistep synthesis. Here, we report a new approach to assemble spirohydantoins via [2+2+2] cyclotrimerization reaction using commercially available, inexpensive hydantoin as a starting material. 相似文献
9.
Chemistry of Heterocyclic Compounds - The microreview considers recent methodologies for the synthesis of 2H-thiochromenes including enantioselective synthesis, multistep synthesis,... 相似文献
10.
A. A. Tolmachev V. S. Tolmacheva L. I. Shevchuk A. V. Turov É. S. Kozlov F. S. Babichev 《Chemistry of Heterocyclic Compounds》1990,26(11):1245-1249
A method is developed for the synthesis of 5,6-disubstituted nitroamino- and nitromethylamino-2-methyl- and-2-methyleneindolines. These are starting compounds for the synthesis of 2-methyleneindolines condensed with some heterocycle.See [1] for Communication 2.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1495–1499, November, 1990. 相似文献
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[structure: see text]. The first synthesis of 2'-C-beta-trifluoromethyl pyrimidine ribonucleosides is described. 1,2,3,5-Tetra-O-benzoyl-2-C-beta-trifluoromethyl-alpha-D-ribofuranose (3) is prepared from 1,3,5-tri-O-benzoyl-alpha-D-ribofuranose (1) in three steps and converted to 3,5-di-O-benzoyl-2-C-beta-trifluoromethyl-alpha-D-1-ribofuranosyl bromide (5). The 1-bromo derivative (5) is found to be a powerful reaction intermediate for the synthesis of ribonucleosides. The reaction of silylated pyrimidines with (5) in the presence of HgO/HgBr2 affords exclusively the beta-anomers (6-8). Deprotection of (6-8) with ammonia in methanol yields the 2'-C-beta-trifluoromethyl nucleosides (9-11). 相似文献
13.
Otto A. Gansow A. Rashid Kausar Kelly B. Triplett 《Journal of heterocyclic chemistry》1981,18(2):297-302
Methods for the synthesis of aromatic substituted diaza-polyoxamacrobicyclic compounds (benzocryptands) are described. New synthetic routes to cryptand precursors are developed and improvements in eryptand synthesis discussed and employed to prepare some bifunctional cryptands. 相似文献
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The synthesis and thermal decomposition of Na2(SO4)2·2H2O in both air and nitrogen are described. The synthesis was performed by two different procedures, but in both cases the same product was obtained, corresponding to the general formula given above. The crystals obtained were investigated by methods of X-ray powder diffraction, and chemical and thermal analysis. The differences in thermal decomposition in air and nitrogen are discussed. 相似文献
16.
The first enantioselective synthesis of (+)-allocyathin was achieved. The synthesis features a Pd-catalyzed asymmetric allylic alkylation to install the first quaternary center, a Ru-catalyzed diastereoselective cycloisomerization to construct the six-membered ring, and a diastereoselective hydroxylative Knoevenagel reaction to introduce the final hydroxyl group. The unusual olefin isomerization of the Ru-catalyzed cycloisomerization was discussed and exploited for the synthesis. 相似文献
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[reaction: see text] A series of 2-bromo- and 2-iodo-galactopyranosyl acetates and trichloroacetimidates were evaluated as glycosyl donors for the synthesis of 2-deoxygalactopyranosides. The best selectivity for the beta-glycosidic linkage was achieved by using 6-deoxy-3,4-carbonate-protected galactosyl donors. 相似文献
19.
In connection with natural products synthesis, we had need of 2-acetylindene (IV). The only reported synthesis of this compound is by Rupe and Müller in 1921.1 These workers formylated benzylacetone (I) and cyclized the major compound (assumed to be II) with acid to give a solid, mp 122°, reported to be IV. 相似文献
20.
Bo-Han Liu Xian-Sheng Luo Han-Lin Deng Zhi-Hao Zhang Wen-Hao Fan Qi Zhang Mu-Hua Huang 《Journal of polymer science. Part A, Polymer chemistry》2024,62(8):1706-1713
Since the initial introduction of porous C2N-h2D materials by the Baek group in 2015, these materials have exhibited highly promising applications in fields such as semiconductor devices, heterogeneous catalysis, gas storage and separation, biomedicine, and more. However, much of the existing research on C2N materials has been based on theoretical calculations due to the challenges associated with their synthesis. In this study, an enhanced synthesis method for porous C2N materials has been successfully developed, involving the innovative and nonexplosive synthesis of hexaaminobenzene trihydrochloride (HAB·3HCl) as a crucial intermediate, as well as a time-efficient synthesis of C2N. Rigorous structural characterizations have been conducted, including solid-state NMR analysis, among others. The resultant C2N material has been effectively employed to improve the efficiency of CO2 conversion reactions. This straightforward protocol for synthesizing C2N materials is poised to stimulate further exploration and application of this promising 2D material in the near future. 相似文献