共查询到20条相似文献,搜索用时 0 毫秒
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Bashkirov AG 《Physical review letters》2004,93(13):130601
The Renyi distribution ensuring the maximum of Renyi entropy is investigated for a particular case of a power-law Hamiltonian. Both Lagrange parameters alpha and beta can be eliminated. It is found that beta does not depend on a Renyi parameter q and can be expressed in terms of an exponent kappa of the power-law Hamiltonian and an average energy U. The Renyi entropy for the resulting Renyi distribution reaches its maximal value at q=1/(1+kappa) that can be considered as the most probable value of q when we have no additional information on the behavior of the stochastic process. The Renyi distribution for such q becomes a power-law distribution with the exponent -(kappa+1). When q=1/(1+kappa)+epsilon (0相似文献
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Elwood T. Olsen 《Foundations of Physics Letters》1993,6(4):327-337
This note addresses a problem of nineteenth century applied mathematics—is it possible in the context of Hamiltonian mechanics to define a functionS of the generalized coordinates and momenta which is monotonically increasing along orbits? The question is of interest, because, for a sytem not in thermodynamic equilibrium, entropy should increase strictly monotonically along an orbit, and a negative answer implies that mechanical principles different from those of Hamiltonian mechanics must be introduced to explain thermodynamics. This note answers the question rigorously for Hamiltonian systems confined to an invariant region of finite volume in phase space; it is not possible to define a continuous function which increases monotonically along orbits. An appendix gives a translation of an 1889 paper of Poincaré addressing the same issue. 相似文献
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We study a discrete dynamical system whose evolution is governed by rules similar to those of Conway's game of Life but also include a stochastic element (parametrized by a temperature). Statistical properties that are examined are density as a function of temperature and entropy (suitably defined). A phase transition and a certain thermodynamic constant of the motion are observed.Lady Davis Visiting Scientist at the Technion 1974–75. 相似文献
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We construct an entropy function such that statistical inference with respect to a partial measurement and a given a priori distribution is characterized by maximal entropy. 相似文献
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François Bavaud 《Journal of statistical physics》1987,46(3-4):753-775
A unified treatment of viscoelasticity is developed in the framework of non-equilibrium classical statistical mechanics. An exact correspondence between Mori's continued-fractions formalism and rheological circuits is shown. 相似文献
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J. S. Høye 《Journal of statistical physics》1987,49(1-2):297-317
On the basis of van der Waals theory for interfaces we evaluate explicitly the small-wavevector behavior of the pair correlation function along an interface. A correction to the density profile is also found. The results obtained are in full accord with capillary wave theory when wave amplitudes are regarded as small. 相似文献
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Irwin Oppenheim 《Journal of statistical physics》1996,82(1-2):455-456
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G. A. Lassner 《Czechoslovak Journal of Physics》1979,29(3):304-307
In this paper mathematical properties of local observables leading to well-defined entropy are discussed. Especially for the Bose-lattice-gas the finiteness and continuity of the local entropy is shown for every strong positive state.Talk given at the Symposium on Mathematical Methods in the Theory of Elementary Particles, Liblice castle, Czechoslovakia, June 18–23, 1978. 相似文献
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We present the statistical-mechanical theory of semiflexible polymers based on the connection between the Kratky-Porod model and the quantum rigid rotator in an external homogeneous field, and treatment of the latter using the quantum mechanical propagator method. The expressions and relations existing for flexible polymers can be generalized to semiflexible ones, if one replaces the Fourier-Laplace transform of the end-to-end polymer distance, 1/(k
2/3 + p), through the matrix
, where D and M are related to the spectrum of the quantum rigid rotator, and considers an appropriate matrix element of the expression under consideration. The present work provides also the framework to study polymers in external fields, and problems including the tangents of semiflexible polymers. We study the structure factor of the polymer, the transversal fluctuations of a free end of the polymer with fixed tangent of another end, and the localization of a semiflexible polymer onto an interface. We obtain the partition function of a semiflexible polymer in half space with Dirichlet boundary condition in terms of the end-to-end distribution function of the free semiflexible polymer, study the behaviour of a semiflexible polymer in the vicinity of a surface, and adsorption onto a surface.Received: 23 March 2004, Published online: 23 July 2004PACS:
36.20.-r Macromolecules and polymer molecules - 61.41. + e Polymers, elastomers, and plastics - 82.35.Gh Polymers on surfaces; adhesion 相似文献
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R. G. Zaripov 《Russian Physics Journal》1980,23(6):462-466
An algebra of thermodynamic operators of the fluctuations of physical quantities in classical statistical mechanics is found and its properties studied. A method is proposed for obtaining equations that describe the equilibrium and nonequilibrium statistical ensembles of classical systems.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 6–11, May, 1980. 相似文献
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K.K Singh 《Annals of Physics》1973,75(1):38-55
It is shown that the equilibrium thermodynamic properties of some superfluid models can be calculated by using density matrices defined in suitable irreducible representations. The approach enables one to introduce in a fundamental manner temperature-dependent order parameters and can be used to obtain general formulations of the problems of superfluids. 相似文献
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J. R. HENDERSON 《Molecular physics》2013,111(10):677-681
The wetting of chemically heterogeneous surfaces is typically discussed in terms of Cassie's law (1948, Discuss. Faraday Soc., 3, 11), which defines the cosine of the contact angle in terms of an average over the different chemical regions, weighted by their relative surface coverage. This paper derives an exact formulation of Cassie's law, in the context of the wetting of chemically patterned substrates. Deviations from Cassie's law arise from quasi-two-dimensional fluid-mediated interactions, analogous to solvation forces. 相似文献
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Based on the Klimontovich method of construction of a relativistic statistical mechanics the binary correlation function of a relativistic plasma is considered. Up to the order e4 for spatially homogeneous systems the relativistic binary correlation function can be expressed by the relativistic dielectric tensor, where higher-order correlation functions are neglected.In the case of thermodynamic equilibrium the relativistic dielectric tensor is calculated. The corresponding binary correlation function is determined up to the first relativistic order. The result is compared with those of Trubnikov/Kosachev (1968) and Krizan (1969). 相似文献
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F. Bavaud 《Journal of statistical physics》1989,57(5-6):1059-1068
The difficulties inherent in the construction of two-dimensional pressure ensembles are discussed, and are tackled by defining an energy cost depending on the convex hull of the set of particles. An energy proportional to the area of the convex hull is not able to prevent evaporation of the system, whereas an energy proportional to the area of the circumcircle of the convex hull ensures a thermodynamic behavior. In the latter model, which turns out to be exactly solvable, various characterizations are given of the geometry of a typical state. 相似文献
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