共查询到19条相似文献,搜索用时 93 毫秒
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测定了酸性水溶液中甘氨酸、丝氨酸和天冬氨酸稀土络合物(Ln=La、Pr、Nd、Eu、Tb、Dy、Ho、Er、Tm和Yb)的13C诱导位移。对位移试剂的分析指出,三种氨基酸通过α-羧基以双齿形式配位于稀土,配位键长为0.23nm~0.25nm,天冬氨酸的γ-羧基也是配位基团。由本文与文献中已报道的各种氨基酸稀土络合物的13C诱导位移的系统分析表明,配体13C超精细偶合常数A值和结构因子G值有如下规律:(1)│A(C0)│<│A(Cα)│;A(C0)为正,A(Cα)为负;(2)│G(C0)│>│G(Cα)│;配体碳核的G均为负值。 相似文献
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本文的工作在于,利用49°Y旋转铌酸锂基片,在其基片的表面激励表面漏波,利用其机电耦合系数k_s~2比较高;短路金属反射条声阻抗变化比较大的特点,成功地研制了表面漏波谐振滤波器(Surface Leaky waves resonators简称SLWR)。这种谐振滤波器的突出优点是所占的基片面积小,仅为同频率的声表面波谐振滤波器(SAWR)的1/4—1/5,50Q系统中的插入损耗仅2—5dB。 本文在实验上,测定了49°Y旋转LiNbO_3基片表面的机电耦合系数k_s~2及声阻抗失配比│8│,从而计算了不同短路金属反射条时的反射系数。利用等效电路模型定性分析了它在50Q系统中的插入损耗。并介绍了典型的实验数据。 相似文献
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利用动态光散射技术系统地研究了不同化合价的平衡离子氯化钠 (Na+)、氯化镁 (Mg2+)、三氯六氨络合钴 ([Co(NH3)6]3+) 和精胺 ([C10N4H30]4+) 与DNA之间的相互作用. 实验结果显示, 当缓冲液中只包含Na+ 或Mg2+, 且浓度c≥ 5 mM时, DNA电泳迁移率之比约为2:1; 当缓冲液单独包含Na+或[Co(NH3)6]3+, 且浓度c≥ 5 mM时, DNA 的电泳迁移率之比约为4.5:1. 而当平衡离子的化合价为4时, 观察到DNA的电泳迁移率由负变正, 意味着发生了电荷反转. 在平衡离子浓度c<5 mM时, 随着离子浓度的增大, 迁移率之比逐渐增大. 对于一价或二价平衡离子情形, 实验结果与Manning的平衡离子凝聚理论的预言相符. 对于三价平衡离子, 实验结果与理论值有明显偏离. 而对于四价离子, 由于发生了DNA电荷逆转, 基于平均场的平衡离子凝聚理论失效. 另外, 通过原子力显微镜观察到当平衡离子的化合价大于等于3 时, DNA分子的构型发生变化. 因此, 自由溶液中的聚电解质的构型和离子关联效应在聚电解质迁移过程中起重要作用.
关键词:
电泳迁移率
平衡离子
动态光散射
DNA 相似文献
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利用WS2的可饱和吸收特性,在激光二极管侧面抽运Nd:YAG固体激光器Z型腔结构中分别实现了被动调Q和被动调Q锁模运转。实验表明:当泵浦电流为9.5 A时,开始启动调Q运转,当泵浦电流大于9.8 A时,调Q激光脉冲趋于稳定。当泵浦电流为12.8 A时,被动调Q输出的最大平均功率为466 mW,最窄脉冲宽度为3.205 μs,对应的重复频率为71.70 kHz,此时最大单脉冲能量为6.5 μJ。当泵浦电流达到13.4 A时,激光器实现调Q锁模运转。调Q锁模的最高输出功率为590 mW,调Q包络频率为71.98 kHz,单个调Q包络内的脉冲串重复频率123.1 MHz,每个调Q包络中包含369个脉冲,单脉冲能量为22.2 nJ。结果表明WS2材料可以作为可饱和吸收体用于固体激光器中。 相似文献
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依据离化杂质散射、声学声子散射和谷间散射的散射模型,在考虑电子谷间占有率的基础上,通过求解玻尔兹曼方程计算了不同锗组分下,不同杂质浓度时应变Si/(001)Si1-xGex的电子迁移率.结果表明:当锗组分达到0.2时,电子几乎全部占据Δ2能谷;低掺杂时,锗组分为0.4的应变Si电子迁移率与体硅相比增加约64%;对于张应变Si NMOS器件,从电子迁移率角度来考虑不适合做垂直沟道.选择相应的参数,该方
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电子谷间占有率
散射模型
锗组分
电子迁移率 相似文献
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《Solid State Communications》1987,64(1):27-29
The Stanford studies include a remarkable dI/dV versus voltage curve with not just one BCS-like peak on each of the positive and negative voltage curves, but with three peaks on the positive-V side, and almost the same structure on the negative-V side. This structure may be caused by an incommensurate spin density wave (SDW) with TCSCW comparable to 125 K. Incommensurability of the SDW would replicate the usual structure at EF with two peaks at the edges of a 2Δ gap centred not at EF, but at displaced positions ± 2vFδQ away from EF, where δQ is the incommensurability of the SDW wave vector. 相似文献
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研究了在一维势场Vn=λcos(Qn+anv)(0<v<1)中运动的电子状态,计算了本征能量和本征态的局域化指数。对Q=2π/3,系统的能带由三个子能带构成。当λ小于2时,每个子带中有两个迁移率边界。研究了扩展态、局域态以及迁移率边界随参数λ,ν,α的变化。
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In this paper, the influence of SiO2 buffer layer on electrical and structural properties of AZO films on soda lime glasses has been investigated. The results showed that the Hall mobility and carrier concentration of AZO films deposited on soda lime glasses at high temperature could be enhanced by introducing SiO2 layers. The optical absorption edges of AZO films with SiO2 buffer layer are blue shifted compared with that of buffer layer free due to the increase of carrier concentration. SiO2 layers prepared at 400 °C more effectively suppress the diffusion of Na atoms into AZO films compared with that prepared at room temperature. On the other hand, the in-plane stress dependence of optical band gap is linear for AZO films deposited on quartz glass substrates, but is deviated from linearity in the case of soda lime glass substrates. 相似文献
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The dependence of the Hall-current on energy of a 2-D electron system in a strong perpendicular magnetic field is studied using sum rule arguments. It turns out that, in a finite system, this dependence is determined to a large extent by the states at the edges of the system. As a consequence the distance between the mobility edges is considerably smaller than the width of the density of states. In fact the mobility edges are essentially the same as in the unperturbed system. 相似文献
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以EDTA为螯合剂,加入MX2结构化合物NiSe2作为晶种,水热合成了FeS2纳米晶. x射线衍射分析结果表明产物为单一相黄铁矿型FeS2(pyrite),平均粒径约40—50nm.丝网印刷成膜且高温退火后FeS2薄膜光学直接带隙变宽.随晶种量的增加,吸收边在紫外—可见光谱区红移、方块电阻升高、霍尔迁移率上升和载流子浓度下降,实现了n型掺杂.并且对FeS2的形成机理进行了讨论.
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2纳米晶')" href="#">FeS2纳米晶
水热
诱导结晶
直接禁带宽度 相似文献
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Yucheng Wang Gao Xianlong Shu Chen 《The European Physical Journal B - Condensed Matter and Complex Systems》2017,90(11):215
We study a one-dimensional quasiperiodic system described by the Aubry–André model in the small wave vector limit and demonstrate the existence of almost mobility edges and critical regions in the system. It is well known that the eigenstates of the Aubry–André model are either extended or localized depending on the strength of incommensurate potential V being less or bigger than a critical value V c , and thus no mobility edge exists. However, it was shown in a recent work that for the system with V < V c and the wave vector α of the incommensurate potential is small, there exist almost mobility edges at the energy E c±, which separate the robustly delocalized states from “almost localized” states. We find that, besides E c±, there exist additionally another energy edges E c′±, at which abrupt change of inverse participation ratio (IPR) occurs. By using the IPR and carrying out multifractal analyses, we identify the existence of critical regions among |E c±|?≤?|E|?≤?|E c′±| with the mobility edges E c± and E c′± separating the critical region from the extended and localized regions, respectively. We also study the system with V > V c , for which all eigenstates are localized states, but can be divided into extended, critical and localized states in their dual space by utilizing the self-duality property of the Aubry–André model. 相似文献
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I. Gutman S. Goldberg Y. Segev T. Tamegai 《Physica C: Superconductivity and its Applications》2010,470(19):963-966
This work focuses on differential magneto-optical two-dimensional imaging of the current distribution in a high-Tc superconducting Bi2Sr2CaCu2O8 crystal having a region of 170 × 170 μm2 patterned with periodic blind antidots. By measuring the self-induced field of an applied current, we can map the current flow distribution within and at the edges of the patterned region. We detected three separate types of current flow within the patterned region, which correspond to three different arrangements of pancake vortices within and at the edges of the patterned region. At high temperatures the vortices delocalize from the antidots, presumably due to thermal fluctuations. However, at lower temperatures vortex pinning mechanisms become prominent, lowering the vortex mobility in the patterned region. There are two contributing mechanisms: bulk pinning by the patterned antidots and interface pinning due to an entry barrier into the patterned region. Each mechanism is dominant at different temperatures. From our experiments we see that the T–H transition line from the bulk to the interface pinning and the vortex melting line in the pristine region coincide. 相似文献
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We investigate numerically the quantum discord and the classical correlation in a one-dimensional slowly varying potential model and a one-dimensional Soukoulis–Economou ones, respectively. There are well-defined mobility edges in the slowly varying potential model, while there are discrepancies on mobility edges in the Soukoulis–Economou ones. In the slowly varying potential model, we find that extended and localized states can be distinguished by both the quantum discord and the classical correlation. There are sharp transitions in the quantum discord and the classical correlation at mobility edges. Based on these, we study “mobility edges” in the Soukoulis–Economou model using the quantum discord and the classical correlation, which gives another perspectives for these “mobility edges”. All these provide us good quantities, i.e., the quantum discord and the classical correlation, to reflect mobility edges in these one-dimensional aperiodic single-electron systems. Moreover, our studies propose a consistent interpretation of the discrepancies between previous numerical results about the Soukoulis–Economou model. 相似文献