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1.
极性分子型电流变液是一种新型的电流变材料.其介电颗粒上吸附极性分子,极性分子在颗粒间强局域电场作用下发生取向是产生巨电流变效应的关键.通过对Ca—Ti—O(CTO)体系极性分子型电流变液电流密度的测量发现,其导电行为遵从Poole-Frenkel效应的规律,这是极性分子型电流变液的重要特征之一.而500 ℃处理过的CTO粉体不含极性分子,所配制的电流变液无巨电流变效应,其电流密度随外电场强度近似地呈线性关系,显示出传统电流变液特性. 相似文献
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利用石英晶体微天平(quartz crystal microbalance,QCM)研究了电场对5CB液晶分子的近壁面层黏弹性的影响.对QCM结果的分析发现,电场作用对液晶的黏度影响分为两部分,通过建立含吸附膜的双层膜模型,分析了QCM的两部分结果,发现电场对近壁面吸附层及体相层的影响是不同的.根据QCM的双层膜模型,对近壁面层液晶分子的黏弹性及膜厚进行了定量的分析计算,结果表明5CB在石英晶体上电极附近有一层约100nm厚的近壁面吸附层,其复剪切黏度随电场强度的增加而减小,这与5CB液晶的体相黏度变化规
关键词:
5CB液晶
石英晶体微天平
近壁面
黏弹性 相似文献
3.
极性分子型电流变液 总被引:2,自引:0,他引:2
电流变液在电场作用下软硬连续可调的奇特性质具有广泛和重要的应用价值。传统电流变液是基于颗粒极化产生的相互作用,根据介电理论预测,其剪切屈服强度的上限约为10 kPa。电流变液被发明50年来,阻碍其应用的主要原因是剪切强度低。近年来发明的“极性分子型电流变液”是一类新型电流变液,其屈服强度比传统电流变液大一个数量级以上,且与电场强度呈线性关系,这一点和传统电流变液中的平方关系也明显不同。文章作者提出了极性分子在颗粒间强局域电场中的取向并与极化电荷作用的模型,成功地解释了观察到的实验现象。根据这一原理,有可能制备出屈服强度高达MPa的电流变液。 相似文献
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手性反铁电液晶分子中的各个不同片段、不同基团在电场诱导下展现不同的取向与取向分布.在交变电场的作用下,分子中各个部分的翻转动力学行为也表现的不同. 相似文献
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一般液体在温度降低到凝固点时发生液 -固转变 .而电流变液则是在电场作用下可从液体转变成固体的物质 ,其剪切强度随电场的增加而变大 ,这种变化快速、可逆 .它是独一无二的软硬程度可调节的智能材料 ,有重要应用价值 .最近温维佳博士等研究成功具有巨电流变效应的材料 ,是电流变液研究的重大突破 .封面示意此种电流变液在不同电场强度时 ,剪切强度值所相应的物质 ,分别相当于硅油、豆腐、硬泡沫、硬橡胶和塑料 .封面右下角图中为巨电流变流体 .详细报道见本期第 777— 779页 .电流变液研究获重大突破——发现巨电流变效应$中国科学院物理… 相似文献
10.
运用Landau-Devonshire热力学唯像理论,考虑铁电相和铁磁相的电致伸缩、磁致伸缩效应以及产生于铁电/铁磁和薄膜/基底界面的弹性应力作用,两次重整介电和磁作用系数得到了这种多铁系统在Landau自由能函数下的本征二次方磁电耦合形式,从而研究了外延1-3型纳米多铁复合薄膜中极化、磁化随薄膜厚度、温度的变化以及该薄膜中外加电场诱导的磁化变化.结果表明薄膜平面内的应压力的弛豫使得磁化强度和极化强度随薄膜厚度的增加而减少,外加电场不仅能诱导铁电相极化场翻转,而且由于铁电和铁磁相界面竖直方向的弹性耦合导致
关键词:
多铁
磁电效应
磁致伸缩
薄膜 相似文献
11.
Zhi-Dong Zhang 《Physics letters. A》2008,372(4):498-509
A nematic liquid crystal slab composed of N molecular layers is investigated using a simple cubic lattice model, based upon the molecular pair potential which is spatially anisotropic and dependent on elastic constants of liquid crystals. A perfect nematic order is assumed in the theoretical treatment, which means the orientation of the molecular long axis coincides with the director of liquid crystal and the total free energy equals to the total interaction energy. We present a modified Gruhn-Hess model, which is relative to the splay-bend elastic constant K13. Furthermore, we have studied the free nematic interfacial behavior (intrinsic anchoring) by this model in the assumption of the perfect nematic order. We find that the preferred orientation at the free interface and the intrinsic anchoring strength change with the value of modification, and that the director profile can be determined by the competition of the intrinsic anchoring with external forces present in the system. Also we simulate the intrinsic anchoring at different temperatures using Monte Carlo method and the simulation results show that the intrinsic anchoring favors planar alignment and the free interface is more disordered than the bulk. 相似文献
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A piezoelectric effect has been observed in a cholesteric liquid crystal layer (an electric field effect type, a mixture of cholesteryl oleyl carbonate, cholesteryl chloride and cholesteryl nonanoate) [1]. The layer, subjected to shear vibration, generates an alternating electric potential of the same frequency as the exciting vibration. In the present paper an extension of these investigations is reported to cases with various mixing ratios and also to one of smectic liquid crystals (lecithin with water). For a cholesteric liquid crystal of a particular mixing ratio, the strength of the electric generation is found to reach as high as 450 mV(p-p) for a vibratory shear displacement of 1 μm(p-p) under a certain molecular orientation preparation. Small electric generation is also observed for the above smectic liquid crystal but not for the nematic liquid crystals (MBBA and EBBA). A simple continuum elasticity model can qualitatively explain the behaviour of this electric potential generation. 相似文献
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Based on the fact that rubbed groove patterns also affect the anchoring of liquid crystals at substrates,a quartic coupling is included in constructing the surface energy for a liquid crystal cell.The phase diagram and the wetting behaviors of the liquid crystal cell,bounded by surfactant-laden interfaces in a magnetic field perpendicular to the substrate are discussed by taking the quartic coupling into account.The nematic order increases at the surface while it decreases in the bulk as a result of the introduction of quartic substrate-liquid crystal coupling,indicating that the groove anchoring makes the liquid crystal molecules align more orderly near the substrate than away from it.This causes a different wetting behavior:complete wetting. 相似文献
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Theoretical analysis of the influence of flexoelectric effect on the defect site in nematic inversion walls 下载免费PDF全文
Based on the experimental phenomena of flexoelectric response at defect sites in nematic inversion walls conducted by Kumar et al., we gave the theoretical analysis using the Frank elastic theory. When a direct-current electric field normal to the plane of the substrate is applied to the parallel aligned nematic liquid crystal cell with weak anchoring, the rotation of ± 1 defects in the narrow inversion walls can be exhibited. The free energy of liquid crystal molecules around the +1 and-1 defect sites in the nematic inversion walls under the electric field was formulated and the electric-field-driven structural changes at the defect site characterized by polar and azimuthal angles of the local director were simulated. The results reveal that the deviation of azimuthal angle induced by flexoelectric effect are consistent with the switching of extinction brushes at the +1 and-1 defects obtained in the experiment conducted by Kumar et al. 相似文献
15.
A. L. Andreev I. N. Kompanets T. B. Andreeva Yu. P. Shumkina 《Physics of the Solid State》2009,51(11):2415-2420
The director reorientation in smectic liquid crystals with ferroelectric properties has been considered in the case where
the interaction of liquid-crystal molecules with the surface leads to a partial unwinding of the helical structure of the
liquid crystal and the reorientation occurs as a result of the domain-wall motion. The dependences of the velocity of domain-wall
motion on the electric field strength, electric field variation frequency, boundary conditions, spontaneous polarization,
and viscosity of the liquid crystal have been determined. It has been demonstrated that an increase in the electric field
variation frequency or the polar part of the anchoring energy and the spontaneous polarization of the liquid crystal at a
constant field frequency results in an increase of the velocity of domain-wall motion. As a consequence, the time of the electro-optic
response of the liquid crystal in weak electric fields (from 0.4 to 2.0 V/μm) decreases by a factor of more than three. 相似文献
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The effective rotational viscosity and polar anchoring coefficient of a nematic liquid crystal were determined using electro-optical response by changing the frequency of the electric field in the kilohertz range. Both quantities monotonically decreased with an increase in the frequency and converged to a certain value at several tens of kilohertz. The effective rotational viscosity changes more than the order of magnitude in experimental range. On the other hand, the effective value of anchoring coefficient changes several times. We tried to explain the trends with the effect of an electric field induced by the motion of ionic impurity in liquid crystal. 相似文献
17.
The effect of a surface electric field produced by ionic adsorption on the molecular orientation of a nematic liquid crystal
sample is analyzed. The eigenvalue problem for a semi-infinite medium is analytically solved both for strong and weak anchoring
situations. The threshold instabilities are numerically determined and it is shown that the homeotropic pattern can be destabilized
also in the situation of strong anchoring. The dependence of the threshold field on the anchoring strength and on the surface
polarization is determined by taking into account also the coupling of the quadrupolar component of the flexoelectric coefficient
with the field gradient.
Received 4 November 1999 and Received in final form 4 April 2000 相似文献
18.
液晶对微波的调制取决于外加电压作用下液晶分子的取向, 而基板的锚泊对液晶取向有重要影响, 必然导致微波调制的变化. 本文研究了无手性掺杂的弱锚泊90°扭曲向列相液晶的微波调制特性. 基于液晶弹性理论和变分原理得到了液晶盒系统的平衡态方程和边界条件, 采用差分迭代方法数值模拟了不同锚定强度大小和不同预倾角下单位长度相移随电压的变化. 结果表明: 1)预倾角对微波相移的影响与施加电压有关. 当液晶盒施加电压为0.5–1.6 V之间时, 随预倾角增大, 单位长度微波相移及其与强锚泊0°预倾角90°扭曲液晶相移差均增大, 且相移差达到最大时的电压值也随倾角增大而减小; 1.6–3.0 V之间, 单位长度微波相移及相移差随预倾角增大而减小; 1.6 V附近及3.0 V之后, 相移基本没有变化. 2)表面锚定强度大小对微波相移的影响非常大. 随锚定强度减小, 单位长度微波相移及相移差均会增大, 微波相移的可调范围也增大, 且增加越来越明显. 此研究为液晶微波调制器件的设计提供了理论依据. 相似文献
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阐述一种理论模型,讨论共面转换(IPS)模式下横向电场对平面织构胆甾相液晶螺距及扭曲角的影响.利用琼斯矩阵法计算了光正入射情况下未加电场时胆甾相液晶的反射谱.在上述模型基础上,计算了施加电场后胆甾相液晶的反射峰值波长以及反射带宽随场强的变化关系.探讨了忽略锚定与强锚定两种边界条件下横向电场对平面织构胆甾相液晶螺距及反射特性的影响.所得结论在理论上证实:共面转换模式下电场可以调谐胆甾相液晶的反射光颜色,从而为基于电控螺距原理的胆甾相液晶反射式彩色显示方案提供了理论上的依据.
关键词:
胆甾相液晶
电控螺距
共面转换
琼斯矩阵法 相似文献
20.
Threshold and saturation properties of the field-induced twist cell with two parameters weak anchoring boundaries 下载免费PDF全文
On the basis of two-parameter formula of weak surface coupling anchoring
energy of nematic liquid crystals proposed by Zhao et al recently, the general
torque equilibrium equation and boundary conditions of the director have
been obtained and the threshold field as well as the saturation field of the
field-induced twist cell have been analysed for three kinds of
configurations, i.e. homogeneous, splay and Pi cells formed by
different rubbing conditions and pretilt angles. The results
indicated that the polar anchoring has no effect on the threshold field. It
is determined only by the twist anchoring and pretilt angle. But, the polar
anchoring and twist anchoring are coupling with each other and have a great
influence on the saturation field. The formulae for calculating the
threshold field and saturation field are given. These results will be very
useful in understanding surface physics and the design of liquid crystal
cells. 相似文献