Viscometric properties of viscous theta solutions of monodisperse polystyrene

Theta solvents for polystyrene are prepared from high-viscosity blends of styrene and low-molecular-weight polystyrene, and then used to make dilute solutions with monodisperse polystyrene solutes of high-M = 2.3, 6.0, 9.0, 18.0 · 10⁵. A Weissenberg rheogoniometer is used to measure the non-Newtonian viscosity as a function of shear stress, for low values, and also the complex viscosity components and as functions of frequency. A capillary viscometer is used for high- measurements of(). Viscometric properties, at room temperature, are analyzed as functions of high-molecular-weight solute concentrationc with parameters of constant or to obtain [()], [ ()], and [ ()]. Such a collection of data has apparently not previously been available for polymers in theta solvents (in which Gaussian chain statistics prevail). Also unique is the achievement of high stress ( = 2 10⁴ Pa) at low shear rate, by virtue of high solvent viscosity which is not characteristic of other known theta solvents.     

An extension of Reiner's “Deborah Number” concept to a Wide field of rheological investigations

Summary Reiner defined a numeric, which he called theDeborah Number to represent the ratio of a relaxation time to a natural (observation) time. This implies aMaxwell model but is readily extended to complete relaxation spectra. Similar Numbers are proposed for retardation times and also for some conditions of coagulation thixotropy and for data from certain psychophysical experiments.     

Nonlinear rheological behavior of a concentrated spherical silica suspension

Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G^* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain (0.2) while the nonlinear relaxation modulus G(t, ) characterizing strong stress damping behavior was obtained for large (>0.2). G(t, ) obeyed the time-strain separability at long time scales, and the damping function h() (–G(t, )/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity () for small shear rates (< ^–1; = linear viscoelastic relaxation time) and shear-thickening for larger (>^–1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, + (t, ) and _– (t, ). In the shear-thinning regime, the and dependence of ₊(t,) and _–(t,) as well as the dependence of () were well described by a BKZ-type constitutive equation using the G(t) and h() data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.Dedicated to the memory of Prof. Dale S. Parson     

Hypersonic flow past blunt-edged delta wings

A method is proposed for calculating hypersonic ideal-gas flow past blunt-edged delta wings with aspect ratios = 100–200. Systematic wing flow calculations are carried out on the intervals 6 M 20, 0 20, 60 80; the results are analyzed in terms of hypersonic similarity parameters.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 175–179, September–October, 1990.     

Effect of the specific heat ratio on the stability and laminar-turbulent transition of a supersonic boundary layer

At high supersonic velocities the specific heat ratio of the flow impinging on a body may change in connection with the considerable increase in stagnation temperature and chemical reactions (strictly speaking, in this case the flow can be described by means of the perfect gas model with an effective specific heat ratio _ef; as a rule, _gf<). This may entail a change in the point of laminar-tubulent boundary layer transition on the model. This paper is concerned with the determination of the effect of the specific heat ratio on boundary layer transition.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 179–183, March–April, 1989.The author wishes to thank M. I. Yaroslavtsev and V. A. Dmitriev for assisting with the experiments.     

On the effects of uniform high suction on the rotationally symmetric flow of a conducting liquid near a stationary disc in the presence of a transverse magnetic field

In the present paper an attempt has been made to find out effects of uniform high suction in the presence of a transverse magnetic field, on the motion near a stationary plate when the fluid at a large distance above it rotates with a constant angular velocity. Series solutions for velocity components, displacement thickness and momentum thickness are obtained in the descending powers of the suction parameter a. The solutions obtained are valid for small values of the non-dimensional magnetic parameter m (= 4 _e ² H ₀ ² /) and large values of a (a2).Nomenclature a suction parameter - E electric field - E _r , E , E _z radial, azimuthal and axial components of electric field - F, G, H reduced radial, azimuthal and axial velocity components - H magnetic field - H _r , H , H _z radial, azimuthal and axial components of magnetic field - H ₀ uniform magnetic field - H* displacement thickness and momentum thickness ratio, */ - h induced magnetic field - h _r , h , h _z radial, azimuthal and axial components of induced magnetic field - J current density - m nondimensional magnetic parameter - p pressure - P reduced pressure - R Reynolds number - U ₀ representative velocity - V velocity - V _r , V , V _z radial, azimuthal and axial velocity components - w ₀ uniform suction through the disc. - density - electrical conductivity - kinematic viscosity - _e magnetic permeability - a parameter, (/)^1/2 z - a parameter, a - * displacement thickness - momentum thickness - angular velocity     

Two-dimensional transonic vortex flows of an ideal gas

Equations are obtained for two-dimensional transonic adiabatic (nonisoenergetic and nonisoentropic) vortex flows of an ideal gas, using the natural coordinates (=const is the family of streamlines, and =const is the family of lines orthogonal to them). It is not required that the transonic gas flow be close to a uniform sonic flow (the derivation is given without estimates). Solutions are found for equations describing vortex flows inside a Laval nozzle and near the sonic boundary of a free stream.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 105–109, September–October, 1973.     

On the sensitive dynamical system and the transition from the apparently deterministic process to the completely random process

The detailed analysis of the dynamical process of coin tossing is made. Through calculations, it is illustrated how and why the result is extremely sensitive to the initial conditions. It is also shown that, as the initial height of the mass center of the coin increases, the final configuration, i.e. head or tail, becomes more and more sensitive to the initial parameters (the initial velocity angular velocity, and the initial orientation), the coefficient of the air drag, and the energy absorption factor of the surface on which the coin bounces. If we keep the head upward initially but allow a small range for the change of some other initial parameters, the frequency that the final configuration is head, would be 1 if the initial height h of the mass center is sufficiently small, and would be clo to 1/2 if h is sufficiently large. An interesting question is how this frequency changes continuously from 1 to 1/2 as h increases. Detailed calculations show that such a transition is very similar to the transition from laminar to turbulent flows. A basic difference between the transition stage and the completely random stage is indicated: In the completely random stage, the deterministic process of the individual case is extremely sensitive to the initial conditions and the dynamical parameters, out the statistical properties of the ensemble are insensitive to the small changes of the initial conditions and the dynamical parameters. On the contrary, in the transition stage, both the deterministic process of the individual case and the statistical properties of the ensemble are sensitive to the initial conditions and the dynamical parameters. The mechanism for this feature of the transition stage is the existence of the long-train structure in the parameter space. The illuminations of this analysis on some other random phenomena are discussed.     

Messung des binären Diffusionskoeffizienten in einem Entmischungssystem mit Hilfe der Photonen-Korrelationsspektroskopie

Zusammenfassung Die dynamische Lichtstreuung in Form der Photonen-Korrelationsspektroskopie wird in einem Entmischungssystem beispielhaft zur Messung des binären Diffusionskoeffizienten eingesetzt. Mit einem Versuchsaufbau wird nahe dem kritischen Entmischungspunkt mit der Homodyn-Methode und weit davon entfernt mit der Heterodyn-Methode gearbeitet. Ein Verfahren ermöglicht die Korrektur der Störeinflüsse des Heterodyn-Anteils bei der Homodyn-Messung. Fürn-Hexan/Nitrobenzol wird der Diffusionskoeffizient für vier unterschiedliche Konzentrationswerte als Funktion der Temperatur ausgemessen. Bei der kritischen Konzentration zeigt er bei gleicher Temperatur den kleinsten Wert und läßt sich nahe dem kritischen Entmischungspunkt durch einen einfachen Potenzansatz mit der reduzierten Temperaturdifferenz =T (– T_c)/T_c ausdrücken. Die statistische Genauigkeit ist besser als 1 %. Die Übereinstimmung mit Literaturwerten ist gut.

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Measuring of the binary diffusion coefficient in a separation system with photon-correlation-spectroscopy

The dynamic light scattering in form of photon-correlation spectroscopy is examplary used in a separation system for measuring the binary diffusion coefficient. In a test setup the homodyntechnique is used near the critical separation point and in distance the heterodyn-technique is used. A special method allows the correction of the disturbing influences of the heterodyn-part using the homodyn-measuring. Forn-hexane/nitrobenzene the diffusion coefficient is measured for four different concentration values as a function of temperature. At the critical concentration with constant temperature the coefficient shows the minimum value and it is expressed near the critical separation point with an elementary exponential equation with the reduced temperature difference =T (– T_c)/T_c. The statistical precision is better than 1%. The conformity with the literature is well.

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Abbreviations

Formelzeichen A Konstante - B Konstante - b Konstante - b ₁ Konstante - b₂ Konstante - C Konstante - c Konzentration - c _c kritische Konzentration - D Konstante - D ₁₂ binärer Diffusionskoeffizient - E ₀ elektrisches Feld des Laserlichts - E _s elektrisches Feld des Streulichts - G () Korrelationsfunktion - I ₀ Intensität des Referenzlichts - _s mittlere Intensität des Streulichts - k ₀ Wellenvektor des Laserlichts - k _s Wellenvektor des Streulichts - n Brechungsindex der zu untersuchenden Flüssigkeit - p Druck - q Streuvektor - R Ortsvektor - r Ortsvektor - T Temperatur, Zeit - t Zeit - x Molenbruch Griechische Buchstaben reduzierte Temperaturdifferenz; Dielektrizität - Frequenz des Laserlichts - statistische Schwankungen der Dielektrizitätskonstante - ₀ Wellenlänge des Laserlichts - Streuwinkel - Zeit - _c Zeitkonstante - kritischer Exponent     

Whose Thoughts Are They, Anyway? Dimensionally Exploding Bion's “Double-Headed Arrow” into Coadapting, Transitional Space

The physics and biology that found psychoanalysis account for discontinuous experience only in the presence of nonmeasurable, metaphysical operators; these include the ego and its subsystems as well as biological experience inherited through Lamarckian principles. Complex, self-organizing systems, however, can link biology to experience without metaphysics. They can also account for psychoanalytically relevant behaviors without appealing to stable internal representations. These behaviors include what W. R. Bion called transformation in O and its corollary, the appearance of the selected fact. By dimensionally exploding the double-headed arrow that he used to link the states Ps and D in his model for thinking (Ps D), we can generate a space that is, at once, psychoanalytically imaginal and dynamically coadapting. Isomorphic to D. W. Winnicott's transitional space, it is self-organizing. It is describable according to dynamics formulated by W J. Freeman, S. Kauffman and C. Langton and it can generate instantaneous conscious contents by way of a selective process analogous to spatio-temporal binding. As a whole, this model supports a clinical stance advanced by D. W. Winnicott as play, within transitional space.     

Experimental study of mutual interference between two spheres placed on a plane boundary

This paper describes an experimental study of the mutual interference between two spheres placed on a plane boundary. The experiment was carried out in an N. P. L. type wind-tunnel having a working section of 500×500×2000 mm³ in size at a Reynolds number of 4.74×10⁴. The surface-pressure distributions of two spheres were measured for the various relative positions of two spheres and the drag, side-force, and lift coefficients were determined from surface-pressure distributions. The separation of the flow and the formation of vortices were observed by the method of visualization. The distributions of velocities, and turbulent intensities of the flow past two spheres were measured. The experimental results for two spheres were compared with those of a single sphere.List of symbols C _D drag coefficient - C _L lift coefficient - C _p surface-pressure coefficient of sphere=(P-P )(qU ² ) - C _s coefficients of side force - D diameter of sphere [mm] - P static pressure [Pa] - P static pressure in free stream [Pa] - Re Reynolds number= DU/v - S spacing between the centers of two adjoining spheres in plane view [mm] - U time-mean velocity in X-direction [m/s] - [m/s] free stream velocity [m/s] - u, v, w X, Y and Z-components of velocity fluctuation [m/s] - X, Y, Z coordinate axes with origin at the bottom center of test sphere, X, Y, Z axis being taken in the streamwise, lateral and vertical directions respectively [mm] (Fig. 1) - latitude angle [°] - longitude angle [°] - angle between the line connected with the centers of two spheres and wind direction [°] (Fig. 2) - kinematic viscosity of air [m²/s] - density of air [N/m³] This paper was presented at the 10th Symposium on Turbulence, University of Missouri-Rolla, Sept. 22–24, 1986     

On the evolutions of the discontinuities of orders ⩾ m in solutions for quasi-linear systems of PDEs of order m,or for the linearizations of these systems

Summary One considers a system L[u]=0 of PDEs, quasi-linear (according to [1]) and of order m, which possesses a bicharacteristic line , as it happens in the hyperbolic case. For v=0, , –m (>0) let u(^v) be a discontinuity wave of order m+v that solves the system above and whose discontinuity hypersurface includes . The corresponding transport equations along are considered. Furthermore some interesting cases are pointed out, in which these equations turn out to be mutually equivalent in a suitable sense. Some theorems are stated to compare the transport equations for the discontinuities of the above kinds, that are connected with the systems d^hL[u]/dt^h=0 (h=0, , –m) and/or the linearization of the system L[u]=0 around any regular solution of it.

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Sommario Si considera un sistema L[u]=0 di equazioni alle derivate parziali, quasi lineare (secondo [1]) e di ordine m, il quale sia dotato di qualche bicaratteristica , come accade nel caso iperbolico. Per v=0, , –m(>0) sia u(^v) un'onda di discontinuità di ordine m+v risolvente il detto sistema e avente ipersuperficie di discontinuità contenente Si considerano le relative equazioni di trasporto lungo e si determinano casi interessanti in cui queste equazioni sono mutuamente equivalenti in senso opportuno. Si stabiliscono teoremi di confronto per il trasporto delle discontinuità del tipo suddetto, relative ai sistemi d^hL[u]/dt^h=0 (h=0, , –m) e/o alla linearizazione del sistema L[u]=0 attorno a qualche sua soluzione regolare.

     

On-board facility vibration-proofing system

Various methods of vibration proofing on-board technical equipment and the results of the Vibration experiment on board the Mir manned orbital station are analyzed.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 5, pp. 15–21, September–October, 1994.     

Effect of Porous Coatings on Stability of Hypersonic Boundary Layers

The influence of ultrasoundabsorbing coatings on stability of hypersonic boundary layers is considered. Two types of coatings were used in experiments: feltmetal with a random porous microstructure and a sheet perforated by blind cylindrical microchannels. The experiments were performed in a wind tunnel at a Mach number M = 5.95 on sharp cones with a 7° apex halfangle. Evolution of natural disturbances and artificially induced wave packets in the boundary layer was studied with the help of hotwire anemometry. Spatial characteristics of artificial disturbances were obtained. It is demonstrated that such coatings exert a stabilizing effect on secondmode disturbances.     

Fixed point theorem of nonexpansive mappings in convex metric spaces

Let X be a convex metric space with the property that every decreasing sequence of nonenply dosed subsets of X with diameters tending to has menemptyintersection. This paper proved that if T is a mapping of a elosed conver nonempty subset K of X into itself satisfying the inequality:d(T_x,T_y)≤ad(x,t)+b{d(x,T_x)+d(y,T_y)}+c{d(x,T_x)+d(y,T_y)}for all x,y in K,where 0≤a<1,b≥0,c≥0,a+c≠0 and a+2b+3c≤1, then T has a unique fixed point in K.     

Parameter identification in a soil with constant diffusivity

We consider infiltration into a soil that is assumed to have hydraulic conductivity of the form K = K = K_se^h and water content of the form = K – _r. Here h denotes capillary pressure head while K_s, , and _r represent soil specific parameters. These assumptions linearize the flow equation and permit a closed form solution that displays the roles of all the parameters appearing in the hydraulic function K and . We assume K_s and _r to be known. A measurement of diffusivity fixes the product of and resulting in a parameter identification problem for one parameter. We show that this parameter identification problem, in some cases, has a unique solution. We also show that, in some cases, this parameter identification problem can have multiple solutions, or no solution. In addition it is shown that solutions to the parameter identification problem can be very sensitive to small changes in the problem data.     

On the Ellipticity of the Middle Surface of a Shell and its Application to the Asymptotic Analysis of ‘Membrane’ Shells

We consider a surface S = (), where ² is a bounded, connected, open set with a smooth boundary and : ³ is a smooth map; let () denote the components of the two-dimensional linearized strain tensor of S and let 0 with length 0 > 0. We assume the the norm ,|| ()||0, in the space V0() = { H¹() × H¹() × L²(); = 0 on 0 } is equivalent to the usual product norm on this space. We then establish that this assumption implies that the surface S is uniformly elliptic and that we necessarily have 0 = .     

Lp-estimates for the nonlinear spatially homogeneous Boltzmann equation

This paper studies L^p-estimates for solutions of the nonlinear, spatially homogeneous Boltzmann equation. The molecular forces considered include inverse k^th-power forces with k > 5 and angular cut-off.The main conclusions are the following. Let f be the unique solution of the Boltzmann equation with f(v,t)(1 + ¦v²¦)^(s ₁ ^{+ /p)/2} L¹, when the initial value f ₀ satisfies f ₀(v) 0, f ₀(v) (1 + ¦v¦²)^(s ₁ ^{+ /p)/2} L¹, for some s₁ 2 + /p, and f ₀(v) (1 + ¦v¦²)^s/2 L^p. If s 2/p and 1 < p < , then f(v, t)(1 + ¦v¦²)^{(s s} ₁)^/2 L^p, t > 0. If s >2 and 3/(1+ ) < p < , thenf(v,t) (1 + ¦v¦²)^(s(s ₁ ^{+ 3/p))/2} L^p, t > 0. If s >2 + 2C₀/C₁ and 3/(l + ) < p < , then f(v,t)(1 + ¦v¦²)^s/2 L^p, t > 0. Here 1/p + 1/p = 1, x y = min (x, y), and C₀, C₁, 0 < 1, are positive constants related to the molecular forces under consideration; = (k – 5)/ (k – 1) for k^th-power forces.Some weaker conclusions follow when 1 < p 3/ (1 + ).In the proofs some previously known L-estimates are extended. The results for L^p, 1 < p < , are based on these L-estimates coupled with nonlinear interpolation.     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²