锗酸铜晶体压致非晶化的研究

High-pressure Raman spectra of copper metagermanate(CuGeO3) are presented,.Above 70 kbar copper metagermanate becomes amorphous,in the range of 70-125 kbar the transition is veversible,above 141 kbar is irreversible.The recrystallization process of pressure-induced amorphous state were investigated.     

锗酸盐晶体压致非晶化的研究

高压拉曼散射研究表明．ＣｕＧｅＯ３，Ｌｉ２ＧｅＯ３和Ｌｉ６Ｇｅ２Ｏ７三种晶体分别在７，１２和１１ＧＰａ压力下转变为非晶。在高于起始转变压力以上一定范围压致非晶是可逆的，ＣｕＧｅＯ３，Ｌｉ２ＧｅＯ３和Ｌｉ６Ｇｅ２Ｏ７压致非晶的不可逆转变压力分别为１４．１，２０和２０ＧＰａ。压致非晶ＣｕＧｅＯ３的重新晶化温度在６００℃附近。锗酸及系列晶体的压致非晶化与它们的成份和结构有关，随着在这一系列晶体中Ｌｉ２Ｏ含量的增加，压致非晶化的压力趋于减小。     

晶体压致非晶化的拉曼散射研究

本文主要介绍压致非晶化研究的进展，其中包括我们对β—ＢａＢ＿２Ｏ＿４，ＬｉＢ＿３Ｏ＿５，Ｐｂ＿５Ｇｅ＿３Ｏ＿１１和Ｌｉ＿２Ｇｅ＿７Ｏ＿（１５）的拉曼散射研究结果。综述了压致非晶的结构特征，压致非晶转变机制和重新晶化过程。     

二硼酸锂晶体的压致非晶化研究

二硼酸锂晶体的压致非晶化研究李玉栋，扈士芬，蓝国祥（南开大学物理系天津３０００７１）Ｐｒｅｓｓｕｒｅ－ＩｎｄｕｃｅｄＡｍｏｒｐｈｉｓａｔｉｏｎｏｆＬｉｔｈｉｕｍＤｉｂｏｒｉｔｅ￥ＹｕｄｏｎｇＬｉ；ＳｈｉｆｅｎＨｕａｎｄＧｕｏｘｉａｎｇＬａｎ（Ｄｅｐａ...     

压致硼酸盐晶态物质的非晶化现象研究

 本文用X射线衍射、Eu²⁺的发射谱与激发谱、拉曼谱以及扫描电镜（SEM）颗粒形貌，研究了常压下合成的具有正交结构的SrB₂O₄:Eu²⁺晶体在3.0~7.0 GPa压力下的晶态非晶化现象。分析结果表明，压力导致晶粒细化和晶态非晶化。晶粒尺寸由常压下的微米量级细化为几十个纳米量级，随压力的变化为：2 μm（0.1 MPa），49.4 nm（3.0 GPa），29.7 nm（5.0 GPa），25.1 nm（7.0 GPa）。晶态与非晶态体积比随压力增加而减小，分别为：70/30（3.0 GPa），63/37（5.0 GPa），57/43（7.0 GPa）。在压力下Eu²⁺是处在晶态与非晶态两种不同的低对称的环境中。纳米级晶粒是以亚晶粒形式存在于微米级大晶粒中的，压致非晶态可能组成了纳米亚晶粒的界面区。     

锗酸铋晶体的超声特性

本文采用超声脉冲回波法在4.2K—300K温区内测试了锗酸铋晶体[110]和[111]晶向的超声纵波衰减与温度的关系,结果在50K附近均出现由于激活弛豫过程所引起的大的异常衰减峰;本文还用脉冲回波重合法精密测定了[100],[110]和[111]晶向的超声纵波和横波的声速,并由此计算出弹性常数C₁₁,C₄₄和C₁₂。     

锗酸铋晶体的光子探测性能研究

本文报道我们对国产BGO晶体的光子探测性能研究的一些结果:BGO晶体相对于NaI（T1）的发光强度是12％,能量分辨是ΔE/E=14％/E（MeV）^1/2,光输出与入射光子能量之间的线性关系良好.我们还对发光衰减时间及温度效应作了研究.     

锗酸铋晶体二波耦合效应的研究

本文叙述了锗酸铋晶体的生长。采用二波耦合光路测试BGO晶体的衍射效率和增益系数,研究BGO晶体的二波耦合中光波的位相变化。     

锗酸锌钠晶体中锰的发光

Na_2ZnGeO_4相晶体是强碱性锗酸盐中最有趣的一种物质。用锰浓激活的这种晶体具有很亮的光致发光、磨擦发光、阴极射线发光和X射线发光,在其上观察到明显的压电效应,并发现有直流场致发光。 我们测量了掺锰的相晶体的室温和液氮温度下的光致发光光谱。用普通的测量方法:用装有光电倍增管—51的单色仪—2分光,并将光谱自动记录在自记器—09上。激发光波长是365毫微米,激发光源是—4灯。研究了从6种不同实验得来的14个晶体。在晶体的生长过程以     

Theoretical Strength of Face-Centred-Cubic Single Crystal Copper Based on a Continuum Model

The constitutive relation of single crystal copper based on atomistic potential is implemented to capture the nonlinear inter-atomic interactions. Uniaxial loading tests of single crystal copper with inter-atomic potential finite-element model are carried out to determine the corresponding ideal strength using the modified Born stability criteria. Dependence of the ideal strength on the crystallographic orientation is studied, and tension- compression asymmetry in ideal strength is also investigated. The results suggest that asymmetry for yielding strength of nano-materials may result from anisotropic character of crystal instability. Moreover, the results also reveal that the critical resolved shear stress in the direction of slip is not an accurate criterion for the ideal strength since it could not capture the dependence on the loading conditions and hydrostatic stress components for the ideal strength.     

单晶铜中冲击波阵面结构的数值模拟研究

 用分子动力学方法模拟计算了在初始温度为0 K时单晶铜中的冲击波结构,相互作用势采用铜的嵌入原子势（EAM）,模拟计算结果表明即使是在初始温度为0 K的FCC晶体中,冲击波波阵面后的区域也会向平衡态演化。局域分析表明冲击波阵面后区域的压力、粒子速度、应变和温度随时间逐步变化到稳定态,在所研究的冲击波强度（约262 GPa）下,波后区域的平均压力、粒子速度、应变均在约1 ps内逐渐上升并达到稳定值。动能温度在波阵面处始终为最大值,随着冲击波的传播,波后非零温度区域逐渐扩大,不同时刻的粒子速度分布函数说明波后区域逐渐向热力学平衡态演化,并最终达到热力学平衡,进一步的分析说明局域平衡是系统向平衡态演化的基本过程。     

2,2'-联咪唑类离子液体配位的双核铜配合物的合成、光谱表征及晶体结构研究

以2,2'-联咪唑为原料制得离子液体1,3,1'-三丁基-2,2'-联咪唑六氟磷酸盐,将此离子液体与醋酸铜配位得到了1,3,1'-三丁基-2.2'-联咪唑六氟磷酸盐配位的双核铜配合物.采用元素分析,IR,UV,ESI对其结构进行了表征.并用X-ray单晶衍射仪确定了其单晶结构,化合物属三斜晶系,空间群P-1晶胞参数α=0.84507(11)nm,b=1.11663(15)nm,c=1.6262(2)nm.α=96.640(2)°β=11.860(3)°,γ=98.091(3)°;V=1.4760(3)nm3,Dc=1.418g/cm3,Z=1,F(000)=654,μ=0.865mm-1.     

晶体塑性有限元方法研究辐照对多晶铜力学性能的影响

将辐照硬化理论与晶体塑性理论结合, 运用ABAQUS有限元分析软件模拟辐照后多晶铜的拉伸过程。分析辐照效应对材料屈服强度、硬化过程、晶体变形等力学性能的影响, 研究位错密度的演化及空间分布规律。数值模拟表明: 辐照效应提高多晶铜的屈服应力, 影响不同阶段的硬化和软化现象; 辐照剂量增大导致位错密度增殖总体变缓, 空间不均匀度增大; 晶体的塑性变形及晶体转动也受到辐照的影响, 在相同的应变条件下, 辐照剂量越大, 晶体塑性变形程度越小, 塑性变形分布不均匀度变大, 同时晶体转动程度及转动角离散度增大。     

结晶紫.溴酚蓝等色染料离子对浮选光度法测定铜

用ＰＨ＝１０的ＮａＯＨ水溶液解析铜－２,２’－联喹啉－溴酚蓝（ＢＰＢ）三元络合物,使ＢＰＢ进入水相,向其中加入与ＢＰＢ颜色相近的碱性染料结晶紫（ＣＶ）,形成等色染普等离子对ＣＶ·ＢＰＢ而被苯浮选,将浮选物溶于忆际最大吸收波长５９０ｎｍ处进行光度测定。由于两种染产等色并同时参与显色,使本方法具有较高的灵敏度。２,２‘－联喹啉为铜的特效试验,因此方法选择性亦好。ε＝１．４５×１０＾５Ｌ·ｍｏｌ＾－１·     

基于晶体劈的电光晶体半波电压测量

通过测量外加电压下电光晶体的相位延迟来获取半波电压.基于双折射晶体劈的偏光干涉法,将通过电光晶体后的偏振光相位延迟量转化为干涉条纹的平移,通过定位暗纹位置进行精密的线性测量.实验结果表明:偏光干涉法测量铌酸锂晶体相位延迟的测量准确度为4.4×10-3 rad,所测量铌酸锂晶体的半波电压为480.0V,其测量误差为0.10%,远小于极值法0.96%的测量误差.偏光干涉法光路结构简单、测量准确度高、测量结果不受光功率波动的影响,且电光晶体相位延迟量的测量范围不受限制.     

Synthesis, Crystal Structure, DNA-binding Properties and Cytotoxic Activity of the Copper (II) Complex Involving Xanthone

1, 8-(3, 6, 9-Trioxaundecane-1, 11-diyldioxy)xanthone (L), and its new Cu (II) complex [Cu·L·(CH₃CN)₂](ClO₄)₂ have been synthesized and characterized by ¹H NMR, electrospray mass spectra (ESI-MS), elemental analyses, infrared spectra (IR) and X-ray single crystal diffraction. The crystal structure of complex shows that Cu (II) ion is encapsulated within the macrocycle of L. The geometry around copper is a distorted square bipyramid with two acetonitrile molecules at axial position, and four macrocyclic oxygens including the carbonyl oxygen on the equatorial positions. The interaction of Cu (II) complex with calf thymus DNA (ct DNA) has been investigated by spectrophotometric titrations, ethidium bromide (EB) displacement experiments, circular dichroism (CD) spectra and viscosity measurements. Rresults indicate that Cu (II) complex can intercalate into the DNA base pairs by the plane of xanthone ring. Furthermore, the Cu (II) complex was tested against tumor cell lines including ECA109, SGC7901and GLC-82 by MTT (microculture tetrazolium) method. The studies of DNA-binding agree with the effects on the inhibition of tumor cells in vitro.     

Synthesis,Crystal Structures and Photo- and Electro-Luminescence of Copper(I) Complexes Containing Electron-Transporting Diaryl-1,3,4-Oxadiazole

Two mononuclear Cu(I) complexes based on 2-(2-pyridyl)benzimidazolyl derivative ligand containing electron-transporting 1,3,4-oxadiazole group (L), [Cu(L)(PPh₃)₂](BF₄) and [Cu(L)(DPEphos)](BF₄), where L?=?1-(4-(5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl)benzyl)-2-(pyridin-2-yl)benzimidazole and DPEphos?=?bis[2-(diphenylphosphino)phenyl]ether, have been successfully synthesized and characterized. The X-ray crystal structure analyses of the ligand L and the complex [Cu(L)(PPh₃)₂](BF₄) were described. The photophysical properties of the complexes were examined by using UV–vis, photoluminescence spectroscopic analysis. The doped light-emitting devices using the Cu(I) complexes as dopants were fabricated. With no electron transporting layers employed in the devices, yellow electroluminescence from Cu(I) complexes were observed. The devices based on the complex [Cu(L)(DPEphos)](BF₄) possess better performance as compared with the devices fabricated by the complex [Cu(L)(PPh₃)₂](BF₄). The devices with the structure of ITO/MoO₃ (2 nm)/NPB (40 nm)/CBP:[Cu(L)(DPEphos)](BF₄) (8 wt%, 30 nm)/BCP (30 nm)/LiF (1 nm)/Al (150 nm) exhibit a maximum efficiency of 3.04 cd/A and a maximum brightness of 4,758 cd/m².     

碘量法测定铜精矿中的铜

碘量法是利用碘和碘离子的氧化还原性进行滴定的分析方法.在传统碘量法的基础上,对分析过程进行了简化及改进,已达到迅速测定铜精矿中铜的目的,实验证明,结果可靠,方法快捷.