共查询到10条相似文献,搜索用时 234 毫秒
1.
P. H. McCluskey G. S. Fischman R. L. Snyder 《Journal of Thermal Analysis and Calorimetry》1988,34(5-6):1441-1448
A new process for the production of advanced ceramic powders has been studied. The process involves the chelation of a metal ion in solution by an organic acid polymer. Using FTIR, TG, DTG and DTA, the process for the formation of the organo-metallic complex and the decomposition to the metal oxide is reported. Effects of packing density on DTA are also discussed.
The authors would like to acknowledge the BF Goodrich Co. for supplying the polyacrylic acid used in this study. Rong Sheng Zhou is also acknowledged for his assistance using the GRAFIT plotting program. 相似文献
Zusammenfassung Ein neues Verfahren zur Herstellung von Keramikpulvern wurde untersucht. Das Verfahren beinhaltet die Chelatisierung eines in Lösung befindlichen Metallions mittels einer polymeren organischen Säure. Unter Zuhilfenahme von FTIR, TG, DTG und DTA wurde der Vorgang der organometallischen Komplexbildung und der Zersetzung zu Metalloxid beschrieben. Der Einfluss der Packungsdichte auf die DTA wird ebenfalls beschrieben.
, - . - , , , - . .
The authors would like to acknowledge the BF Goodrich Co. for supplying the polyacrylic acid used in this study. Rong Sheng Zhou is also acknowledged for his assistance using the GRAFIT plotting program. 相似文献
2.
《Reaction Kinetics and Catalysis Letters》1981,16(2-3):195-200
2- (403 , --) 0.1 500 - , . , . - C–O 11 3/.
In the products of transformation of 2-cyclohexyloxytetrahydropyrane (403 K, initiator di-t-butyl peroxide), the amount of -valerolactone and cyclohexane increases but that of cyclohexyl valerate decreases as the pressure is increased from 0.1 to 500 MPa. The pressure does not affect the reactivity of the substrate; its conversion decreases due to the rate of initiation. The difference between the activation volumes of endo- and exocyclic C–O bond rupture is 11 cm3/mol.相似文献
3.
A. Inglot 《Reaction Kinetics and Catalysis Letters》1989,40(2):241-246
The existence of a linear correlation between the apparent activation energy of benzene disappearance and the primary selectivity was demonstrated for a series of vanadia based catalysts. Analysis of this correlation leads to the conclusion that the activation energies of reaction 1 as well as activation energies of reaction 2 in benzene oxidation scheme do not differ significantly over a series of these catalysts.
. , 1, 2 .相似文献
4.
The physico-chemical characterization of magnesium-modified ZSM-5 zeolite catalysts has been performed by differential scanning calorimetry. Evidence has been found of the formation of magnesium oxide and the magnesium spinel phase in alumina-bonded ZSM-5 catalysts. DSC proved a suitable technique for characterization of these systems.
This work was carried out within the Progetto finalizzato Energetica 2 of the National Research Council of Italy. 相似文献
Zusammenfassung Mg-modifizierte ZSM-5-Zeolithkatalysatoren wurden durch DSC charakterisiert. Es wurden Beweise für die Bildung von Magnesiumoxid und Magnesiumspinell in ZSM-5/Aluminiumoxid-Katalysatoren gefunden. DSC hat sich zur Characterisierung dieser Systeme als geeignet erwiesen.
- 3CM-5, . - - . .
This work was carried out within the Progetto finalizzato Energetica 2 of the National Research Council of Italy. 相似文献
5.
Z. V. Gryaznova G. V. Tsitsishvili N. N. Naskidashvili 《Reaction Kinetics and Catalysis Letters》1977,7(1):59-64
It is shown that Gd-zeolites have a catalytic activity towards ethylene hydrogenation at 1 atm. This activity decreases with an increase in the SiO2/Al2O3 ratio from 2.2 to 6.1 and 4.1, i.e. upon going from an X type zeolite to Y and L. For these types of zeolite the activity grows with an increase in Gd3+ content from 50 to 80%. Oxygen addition to the reaction mixture stabilizes the catalytic activity of zeolites.
, qv 1 . , SiO2/Al2O3 2,2 6,1 4,1, .. X Y L. , 50 80%. .相似文献
6.
V. P. Nekhoroshkov G. L. Kamalov V. I. Melnik 《Reaction Kinetics and Catalysis Letters》1984,24(1-2):103-105
Studies of the liquid-phase oxidation of dibenzyl ether in the presence of 12 acetylacetonates of 3d metals and a comparative analysis of the dependence of the catalytic activity and selectivity of chelates on the atomic number and valence state have been carried out.
12 3d . .相似文献
7.
R. Naumann H. -H. Emons K. Köhnke J. Paulik F. Paulik 《Journal of Thermal Analysis and Calorimetry》1988,34(5-6):1327-1333
DTA, DSC and X-ray investigations of Mg(NO3)2 · 6H2O revealed a lattice transformation at (71±2) C withH=12.5 J/g, and congruent melting at 90 C withH=150.3 J/g. The results of the DTA investigations on different Mg(NO3)2-H2O samples are in good agreement with those of solubility investigations. The melting enthalpy of Mg(NO3)3 · 6H2O is lowered considerably by deviation from the stoichiometric water content of the compound. The results allow conclusions as to the application of this salt hydrate as a latent heat-storage material.
We thank Dr. Flammersheim, Department of Chemistry, FSU, Jena, for the DSC measueements. 相似文献
Zusammenfassung DTA-, DSC- und röntgenographische Untersuchungen von Mg(NO3)2 · 6H2O zeigten die Existenz einer Gitterumwandlung bei (71±2) C mitH=12.5 J/g und ein kongruentes Schmelzen bei 90 C mitH=150.3 J/g. Die Ergebnisse der DTA-Untersuchungen an verschiedenen Mg(NO3)2-H2O Proben stehen in guter übereinstimmung mit denen von Löslichkeitsuntersuchungen. Durch ein Abweichen vom stöchiometrischen Wassergehalt der Verbindung wird die Schmelzenthalpie von Mg(NO3)2 · 6H2O beträchtlich vermindert. Die Ergebnisse ermöglichen Aussagen zur Anwendbarkeit dieses Salzhydrates als Wärmespeichermedium.
, 71±2 H=12,5 · 90 H=150,3 ·–1. Mg(NO3)2-H2O . . .
We thank Dr. Flammersheim, Department of Chemistry, FSU, Jena, for the DSC measueements. 相似文献
8.
The H2+CO reaction on silica supported Ru, Fe and RuFe catalysts prepared from metal carbonyl clusters has been investigated under atmospheric and 20 bar pressure. According to the change of selectivity values with temperature and with pressure, the participation of surface carbon proposed earlier by several authors seems to be confirmed by this work.
H2+CO Ru, Fe RuFe, , 20 . , , , .相似文献
9.
It has been shown that hydrogen determined from the TPD curves of platinum saturated with hydrogen sorbed above room temperature is chiefly absorbed and not adsorbed hydrogen; this absorbed hydrogen has no effect on the charging curve.
, , , , ; .相似文献
10.
A. M. Volodin 《Reaction Kinetics and Catalysis Letters》1984,25(3-4):335-338
ESR studies of the thermal stability of anion radicals O– on the MgO surface have revealed that most stable (at T>420 K) are O– with g
2=2.032 and g
3=2.044, whereas anion radicals with g
1=2.042 are destroyed at T<400 K and possess the highest heat of [O–·O2] complex formation.
- O– MgO. , O– g 2=2.032 g 3=2.044, 420 , O– g 1=2.042 400 . , [O–·O2] - O– g 1=2.042.相似文献