Existence theorem for a minimum problem with free discontinuity set

We study the variational problem Where is an open set in ⁿ ,n2gL ^q () L (), 1q<+, O<, <+ andH _n–1 is the (n–1)-dimensional Hausdorff Measure.     

Classification of linear viscoelastic solids based on a failure criterion

An isotropic, incompressible linear viscoelastic solid subjected to a step shear displacement fails if the relaxation function G(s) is such that 0<G(0)< and –<G(0)0. In this case, the discontinuity in displacement propagates into the interior of the body. The discontinuity will not propagate however if G(0)= or G(0)=–. In the former case there is a diffusion-like smoothening of discontinuous data characteristic of parabolic equations. The case G(0)= may be achieved by composing the kernel as a sum of a smooth kernel and a delta function at the origin times a viscosity coefficient. If the viscosity is small, the smoothing will take place in a propagating layer which scales with the small viscosity. The case of G(0)=– is interesting in the sense that the solution is C smooth but the boundary of the support of the solution propagates at a constant wave spped. If 0<G(0)< and –<G(0)<0, then the material accomodates stress waves under step traction leading to an elastic steady state.     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Two-phase flow in heterogeneous porous media II: Numerical experiments for flow perpendicular to a stratified system

In this work, we make use of numerical experiments to explore our original theoretical analysis of two-phase flow in heterogeneous porous media (Quintard and Whitaker, 1988). The calculations were carried out with a two-region model of a stratified system, and the parameters were chosen be consistent with practical problems associated with groundwater flows and petroleum reservoir recovery processes. The comparison between theory (the large-scaled averaged equations) and experiment (numerical solution of the local volume averaged equations) has allowed us to identify conditions for which the quasi-static theory is acceptable and conditions for which a dynamic theory must be used. Byquasi-static we mean the following: (1) The local capillary pressure,everywhere in the averaging volume, can be set equal to the large-scale capillary pressure evaluated at the centroid of the averaging volume and (2) the large-scale capillary pressure is given by the difference between the large-scale pressures in the two immiscible phases, and is therefore independent of gravitational effects, flow effects and transient effects. Bydynamic, we simply mean a significant departure from the quasi-static condition, thus dynamic effects can be associated with gravitational effects, flow effects and transient effects. To be more precise about the quasi-static condition we need to refer to the relation between the local capillary pressure and the large-scale capillary pressure derived in Part I (Quintard and Whitaker, 1990). Herep _c ¦_y represents the local capillary pressure evaluated at a positiony relative to the centroid of the large-scale averaging volume, and {p _c }¦_x represents the large-scale capillary pressure evaluated at the centroid.In addition to{p _c } ^c being evaluated at the centroid, all averaged terms on the right-hand side of Equation (1) are evaluated at the centroid. We can now write the equations describing the quasi-static condition as , , This means that the fluids within an averaging volume are distributed according to the capillary pressure-saturation relationwith the capillary pressure held constant. It also means that the large-scale capillary pressure is devoid of any dynamic effects. Both of these conditions represent approximations (see Section 6 in Part I) and one of our main objectives in this paper is to learn something about the efficacy of these approximations. As a secondary objective we want to explore the influence of dynamic effects in terms of our original theory. In that development only the first four terms on the right hand side of Equation (1) appeared in the representation for the local capillary pressure. However, those terms will provide an indication of the influence of dynamic effects on the large-scale capillary pressure and the large-scale permeability tensor, and that information provides valuable guidance for future studies based on the theory presented in Part I.Roman Letters A scalar that maps {}*/t onto - A scalar that maps {}*/t onto - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - a vector that maps ({}*/t) onto , m - a vector that maps ({}*/t) onto , m - b vector that maps ({p}– g) onto , m - b vector that maps ({p}– g) onto , m - B second order tensor that maps ({p}– g) onto , m² - B second order tensor that maps ({p}– g) onto , m² - c vector that maps ({}*/t) onto , m - c vector that maps ({}*/t) onto , m - C second order tensor that maps ({}*/t) onto , m² - C second order tensor that maps ({}*/t) onto . m² - D third order tensor that maps ( ) onto , m - D third order tensor that maps ( ) onto , m - D second order tensor that maps ( ) onto , m² - D second order tensor that maps ( ) onto , m² - E third order tensor that maps () onto , m - E third order tensor that maps () onto , m - E second order tensor that maps () onto - E second order tensor that maps () onto - p _c =(), capillary pressure relationship in the-region - p _c =(), capillary pressure relationship in the-region - g gravitational vector, m/s² - largest of either or - - - i unit base vector in thex-direction - I unit tensor - K local volume-averaged-phase permeability, m² - K local volume-averaged-phase permeability in the-region, m² - K local volume-averaged-phase permeability in the-region, m² - {K } large-scale intrinsic phase average permeability for the-phase, m² - K –{K }, large-scale spatial deviation for the-phase permeability, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K ^* large-scale permeability for the-phase, m² - L characteristic length associated with local volume-averaged quantities, m - characteristic length associated with large-scale averaged quantities, m - I _i i = 1, 2, 3, lattice vectors for a unit cell, m - l characteristic length associated with the-region, m - ; characteristic length associated with the-region, m - l _H characteristic length associated with a local heterogeneity, m - - n unit normal vector pointing from the-region toward the-region (n =–n ) - n unit normal vector pointing from the-region toward the-region (n =–n ) - p pressure in the-phase, N/m² - p local volume-averaged intrinsic phase average pressure in the-phase, N/m² - {p } large-scale intrinsic phase average pressure in the capillary region of the-phase, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - P _c p –{p }, capillary pressure, N/m² - {p_c}^c large-scale capillary pressure, N/m² - r ₀ radius of the local averaging volume, m - R ₀ radius of the large-scale averaging volume, m - r position vector, m - , m - S /, local volume-averaged saturation for the-phase - S ^* {}*{}*, large-scale average saturation for the-phaset time, s - t time, s - u , m - U , m² - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - {v } large-scale intrinsic phase average velocity for the-phase in the capillary region of the-phase, m/s - {v } large-scale phase average velocity for the-phase in the capillary region of the-phase, m/s - v –{v }, large-scale spatial deviation for the-phase velocity, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - V local averaging volume, m³ - V volume of the-phase in, m³ - V large-scale averaging volume, m³ - V capillary region for the-phase within, m³ - V capillary region for the-phase within, m³ - V _c intersection of m³ - V volume of the-region within, m³ - V volume of the-region within, m³ - V () capillary region for the-phase within the-region, m³ - V () capillary region for the-phase within the-region, m³ - V () , region in which the-phase is trapped at the irreducible saturation, m³ - y position vector relative to the centroid of the large-scale averaging volume, m Greek Letters local volume-averaged porosity - local volume-averaged volume fraction for the-phase - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region (This is directly related to the irreducible saturation.) - {} large-scale intrinsic phase average volume fraction for the-phase - {} large-scale phase average volume fraction for the-phase - {}* large-scale spatial average volume fraction for the-phase - –{}, large-scale spatial deviation for the-phase volume fraction - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - a generic local volume-averaged quantity associated with the-phase - mass density of the-phase, kg/m³ - mass density of the-phase, kg/m³ - viscosity of the-phase, N s/m² - viscosity of the-phase, N s/m² - interfacial tension of the - phase system, N/m - , N/m - , volume fraction of the-phase capillary (active) region - , volume fraction of the-phase capillary (active) region - , volume fraction of the-region ( + =1) - , volume fraction of the-region ( + =1) - {p }– g, N/m³ - {p }– g, N/m³     

Flow in porous media II: The governing equations for immiscible,two-phase flow

The Stokes flow of two immiscible fluids through a rigid porous medium is analyzed using the method of volume averaging. The volume-averaged momentum equations, in terms of averaged quantities and spatial deviations, are identical in form to that obtained for single phase flow; however, the solution of the closure problem gives rise to additional terms not found in the traditional treatment of two-phase flow. Qualitative arguments suggest that the nontraditional terms may be important when / is of order one, and order of magnitude analysis indicates that they may be significant in terms of the motion of a fluid at very low volume fractions. The theory contains features that could give rise to hysteresis effects, but in the present form it is restricted to static contact line phenomena.Roman Letters (, = , , and ) A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - g gravity vector, m²/s - H mean curvature of the- interface, m^–1 - H area average of the mean curvature, m^–1 - H – H , deviation of the mean curvature, m^–1 - I unit tensor - K Darcy's law permeability tensor, m² - K permeability tensor for the-phase, m² - K viscous drag tensor for the-phase equation of motion - K viscous drag tensor for the-phase equation of motion - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - n unit normal vector pointing from the-phase toward the-phase (n = –n ) - p _c p – P , capillary pressure, N/m² - p pressure in the-phase, N/m² - p intrinsic phase average pressure for the-phase, N/m² - p – p , spatial deviation of the pressure in the-phase, N/m² - r ₀ radius of the averaging volume, m - t time, s - v velocity vector for the-phase, m/s - v phase average velocity vector for the-phase, m/s - v intrinsic phase average velocity vector for the-phase, m/s - v – v , spatial deviation of the velocity vector for the-phase, m/s - V averaging volume, m³ - V volume of the-phase contained within the averaging volume, m³ Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m² - surface tension of the- interface, N/m - viscous stress tensor for the-phase, N/m² - / kinematic viscosity, m²/s     

Green's functions,bi-linear forms,and completeness of the eigenfunctions for the elastostatic strip and wedge

The bi-harmonic Green's functionG(r,r) for the infinite strip region -1y1, -<x<, with the boundary conditionsG=G/y ony=±1, is obtained in integral form. It is shown thatG has an elegant bi-linear series representation in terms of the (Papkovich-Fadle) eigenfunctions for the strip. This representation is then used to show that any function bi-harmonic in arectangle, and satisfying the same boundary conditions asG, has a unique representation in the rectangle as an infinite sum of these eigenfunctions. For the case of the semi-infinite strip, we investigate conditions on sufficient to ensure that is exponentially small asx. In particular it is proved that this is so, solely under the condition that be bounded asx.A corresponding pattern of results is established for the wedge of general angle. The Green's function is obtained in integral form and expressed as a bilinear series of the (Williams) eigenfunctions. These eigenfunctions are proved to be complete for all functions bi-harmonic in anannular sector (and satisfying the same boundary conditions as the Green's function). As an application it is proved that if an elastostatic field exists in a corner region with free-free boundaries, and with either (i) the total strain energy bounded, or (ii) the displacement field bounded, then this field has a unique representation as a sum of those Williams eigenfunctions whichindividually posess the properties (i), (ii).The methods used here extend to all other linear homogeneous boundary conditions for these geometries.On leave of absence at the University of British Columbia, Vancouver, B.C. Canada, during 1977–79. This work was supported in part by N.R.C. grants Nos. A9259 and A9117.     

Asymptotic analysis of equilibrium states for rotating turbulent flows

The equilibrium states of homogeneous turbulence simultaneously subjected to a mean velocity gradient and a rotation are examined by using asymptotic analysis. The present work is concerned with the asymptotic behavior of quantities such as the turbulent kinetic energy and its dissipation rate associated with the fixed point (/kS)=0, whereS is the shear rate. The classical form of the model transport equation for (Hanjalic and Launder, 1972) is used. The present analysis shows that, asymptotically, the turbulent kinetic energy (a) undergoes a power-law decay with time for (P/)<1, (b) is independent of time for (P/)=1, (c) undergoes a power-law growth with time for 1<(P/)<(C ₂–1), and (d) is represented by an exponential law versus time for (P/)=(C ₂–1)/(C ₁–1) and (/kS)>0 whereP is the production rate. For the commonly used second-order models the equilibrium solutions forP/,II, andIII (whereII andIII are respectively the second and third invariants of the anisotropy tensor) depend on the rotation number when (P/kS)=(/kS)=0. The variation of (P/kS) andII versusR given by the second-order model of Yakhot and Orzag are compared with results of Rapid Distortion Theory corrected for decay (Townsend, 1970).     

Das erweiterte Korrespondenzgesetz für die dynamische Idealviskosität und die Idealwärmeleitfähigkeit reiner Stoffe

Zusammenfassung Zur Berechnung der dynamischen Idealviskosität Ideal (T) und der Idealwärmeleitfähigkeit ideal (T) benötigt man die kritische TemperaturT _kr, das kritische spezifische Volum _kr, die MolmasseM, den kritischen Parameter _kr und die molare isochore WärmekapazitätC _v(T). Sowohl das theoretisch, als auch das empirisch abgeleitete erweiterte Korrespondenzgesetz ergeben eine für praktische Zwecke ausreichende Genauigkeit für die Meßwertwiedergabe, die bei den assoziierenden Stoffen und den Quantenstoffen jedoch geringer ist als bei den Normalstoffen.

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The extended correspondence law for the ideal dynamic viscosity and the ideal thermal conductivity of pure substances

For the calculation of the ideal dynamic viscosity Ideal (T) and the ideal thermal conductivity ideal (T) the critical temperatureT _kr, the critical specific volumev _kr, the molecular massM, the critical parameter _kr, and the molar isochoric heat capacityC _v(T) is needed. Not only the theoretically determined but also the empirically determined extended correspondence law gives for practical use a good representation of the measured data, which for the associating substances and the quantum substances is not so good as for the normal substances.

     

Constituency measurements in the mixing region of a cross flow jet using a laser velocimeter

The velocities in the mixing region of a cross flow jet injected into a freestream were studied in detail with a laser velocimeter. Three jet to freestream momentum ratios were used (3.1, 8.1, 16.2). By purposely seeding the jet and freestream separately (as well as both simultaneously), marking the fluid was feasible. Thus, determining the velocities that emanated from the different streams was possible. By methodically analyzing the three sets of dependent data, the size and location of the mixing region was determined. The mixing regions for the three momentum ratios were found to be of different sizes and at different locations. By proper scaling, however, the regions for the three momentum ratios were found to collapse to one scaled region. Because of the intermittent behavior of the mixing, conventional turbulence models for such mixing may not be applicable; however, detailed velocities and turbulence quantities are included for benchmarking predictions.List of symbols B slot width - H channel height - MR momentum ratio, jet to free stream = _j V _j ²/ U ² - Re _H Reynolds number, U H/v - U free stream velocity - u axial velocity - u rms of axial velocity fluctuation - v transverse velocity - v rms of transverse velocity fluctuation - V _j slot exit transverse velocity - x axial direction (Fig. 3) - x _c x-center of mixing region - scaled value of x, = x/B - y transverse direction (Fig. 3) - y _c y-center of mixing region - scaled value of y, = y/ MRB - _x mixing region width in x-direction - _y mixing region width in y-direction - scaled mixing region width in x-direction, = _x /B - scaled mixing region width in y-direction, = _y / MRB - free stream density - _j slot exit density - v kinematic viscosity of freestream This research was sponsored in part by the Fulbright Commission (Bonn, Germany), the Institut für Thermische Strömungsmaschinen, Universität Karlsruhe (Karlsruhe, Germany), and the Rotating Machinery and Controls Industrial Research Program, University of Virginia (Charlottesville, VA, USA)     

Approximate solutions for drag coefficient of bubbles moving in shear-thinning elastic fluids

The drag coefficient for bubbles with mobile or immobile interface rising in shear-thinning elastic fluids described by an Ellis or a Carreau model is discussed. Approximate solutions based on linearization of the equations of motion are presented for the highly elastic region of flow. These solutions are in reasonably good agreement with the theoretical predictions based on variational principles and with published experimental data. C _D Drag coefficient - E ^* Differential operator [E ^{* 2} = ²/² + (sin/ ²)/(1/sin /)] - El Ellis number - F _D Drag force - K Consistency index in the power-law model for non-Newtonian fluid - n Flow behaviour index in the Carreau and power-law models - P Dimensionless pressure [=(p – p ₀)/₀ (U /R)] - p Pressure - R Bubble radius - Re ₀ Reynolds number [= 2R U /₀] - Re Reynolds number defined for the power-law fluid [= (2R) ⁿ U ^2–n /K] - r Spherical coordinate - t Time - U Terminal velocity of a bubble - u Velocity - Wi Weissenberg number - Ellis model parameter - Rate of deformation - Apparent viscosity - ₀ Zero shear rate viscosity - Infinite shear rate viscosity - Spherical coordinate - Parameter in the Carreau model - ^* Dimensionless time [=/(U /R)] - Dimensionless length [=r/R] - Second invariant of rate of deformation tensors - ^* Dimensionless second invariant of rate of deformation tensors [=/(U /R)²] - Second invariant of stress tensors - ^* Dimensionless second invariant of second invariant of stress tensor [= / ₀ ² (U /R)²] - Fluid density - Shear stress - ^* Dimensionless shear stress [=/ ₀ (U /R)] - _1/2 Ellis model parameter - ₁ ^2/* Dimensionless Ellis model parameter [= _1/2/ ₀(U /R)] - Stream function - ^* Dimensionless stream function [=/U R ²]     

Oscillatory free convection heat transfer along a semi-infinite vertical plate

Summary The fluctuating free convection flow along a semi-infinite vertical plate is considered when the plate temperature is of the form T _p –T =(T ₀ –T ) where 0 < 1, denotes the frequency of oscillation and the mean temperature T ₀–T is proportional to ⁿ (0 n < 1). Flow and temperature fields have been obtained by means of two asymptotic expansions. For small values of the frequency parameter , a regular expansion is obtained while for large the method of matched asymptotic expansion is used. It is found that the skin friction and the rate of heat transfer obtained from two expansions overlap satisfactorily for a certain value of . For n=1 the flow governing equations to a semisimilar form, and have been solved by finite difference method. The results obtained from the series and the finite difference methods are in good agreement.

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Oszillierender Wärmeübergang an einer halbunendlichen senkrechten Platte bei freier Konvektion

Übersicht Betrachtet wird die fluktuierende freie Konvektionsströmung längs einer halbunendlichen senkrechten Platte, deren Temperatur dem Gesetz T _p –T =(T ₀–T ) [1+ sin {ie1-03}] folgt, wobei 0 < 1 gelte, {ie1-04} die Frequenz ist und der Temperatur-Mittelwert T ₀–T proportional zu ⁿ (0 n < 1) ist. Mit Hilfe zweier asymptotischer Entwicklungen werden die Strömungs- und Temperaturfelder gewonnen. Für kleine Werte des Frequenzparameters wird eine gewöhnliche Entwicklung benutzt, für große die Methode angepaßter asymptotischer Entwicklungen. Es stellt sich heraus, daß die Oberflächenreibung und die Wärmeübergangsrate aus zwei Entwicklungen für ein bestimmtes zufriedenstellend aufeinander fallen. Für n=1 werden die Grundgleichungen zueinander ähnlich und werden nach der Finite-Differenzen-Methode gelöst. Die Ergebnisse nach den Reihenentwicklungen und der Finite-Differenzen-Methode stimmen gut überein.

     

Dynamic melt viscoelastic behavior of random copolymers

Summary The viscoelastic properties of 65/35 styrenen-butyl methacrylate random copolymers were determined using the Eccentric Rotating Disks device of the Rheometrics Mechanical Spectrometer. Similar to the behavior observed in homopolymers, an increase in the molecular weight of the copolymer resulted in extension of the rubbery plateau and in a reduction in the terminal region. The dynamic complex viscosity showed onset of non-Newtonian flow at higher frequencies, with the non-Newtonian region increasing with increasing molecular weight.The elastic modulus,G, was dependent upon the frequency,, asG ^1.5 in the terminal region, rather than asG ² observed for polystyrene. The viscous modulus,G, was proportional to the frequency,, asG , similar to what is observed for polystyrene. The dynamic viscosity | ^*| at high frequencies showed a region independent of molecular weight where a power law of | ^*| ^0.9 is applicable, consistent with entanglement models. Thy dynamic viscosity at low frequencies in the Newtonian region is related to molecular weight as |^*| . Using WLF equations, the coefficient of expansion, _f , was obtained that, together with glass transition, showed a negative deviation from the Fox-Flory relationship.

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Zusammenfassung Die viskoelastischen Eigenschaften von statistischen 65/35-Styrol/n-Butyl-Methacrylat-Kopolymeren wurden mit Hilfe einer Maxwell-Rheometer-Anordnung in Verbindung mit dem Mechanischen Spektrometer der Fa. Rheometrics bestimmt. Ähnlich dem bei Homopolymeren beobachteten Verhalten ergab sich auch hier mit wachsendem Molekulargewicht eine Verbreiterung des Kautschuk-Plateaus und eine Verkleinerung des Endbereichs. Die komplexe Viskosität zeigte erst bei höheren Frequenzen das Einsetzen nicht-newtonschen Fließens an, wobei der nichtnewtonsche Bereich mit steigendem Molekulargewicht größer wurde.Der SpeichermodulG ergab sich im Endbereich als proportional zu ^1,5, im Unterschied zu der bei Polystyrol beobachteten Proportionalität mit ². Dagegen war der VerlustmodulG der Frequenz direkt proportional, ähnlich wie es auch bei Polystyrol beobachtet worden war. Die dynamische Viskosität | ^*| zeigte unabhängig vom Molekulargewicht bei hohen Frequenzen einen Bereich, in dem eine Potenz-Beziehung | ^*| ~ ^0,9 herrschte, was auf die Wirkung von Verzweigungen hindeutet. Dagegen galt bei den niedrigen Frequenzen des newtonschen Bereichs|^*| ~ . Mit Hilfe der WLF-Gleichung wurde der Ausdehnungskoeffizient _f bestimmt, der ebenso wie der Glasübergang eine negative Abweichung von der Fox-Flory-Beziehung zeigte.

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With 10 figures and 1 table     

Two-phase flow in heterogeneous porous media III: Laboratory experiments for flow parallel to a stratified system

Two-phase flow in stratified porous media is a problem of central importance in the study of oil recovery processes. In general, these flows are parallel to the stratifications, and it is this type of flow that we have investigated experimentally and theoretically in this study. The experiments were performed with a two-layer model of a stratified porous medium. The individual strata were composed of Aerolith-10, an artificial: sintered porous medium, and Berea sandstone, a natural porous medium reputed to be relatively homogeneous. Waterflooding experiments were performed in which the saturation field was measured by gamma-ray absorption. Data were obtained at 150 points distributed evenly over a flow domain of 0.1 × 0.6 m. The slabs of Aerolith-10 and Berea sandstone were of equal thickness, i.e. 5 centimeters thick. An intensive experimental study was carried out in order to accurately characterize the individual strata; however, this effort was hampered by both local heterogeneities and large-scale heterogeneities.The theoretical analysis of the waterflooding experiments was based on the method of large-scale averaging and the large-scale closure problem. The latter provides a precise method of discussing the crossflow phenomena, and it illustrates exactly how the crossflow influences the theoretical prediction of the large-scale permeability tensor. The theoretical analysis was restricted to the quasi-static theory of Quintard and Whitaker (1988), however, the dynamic effects described in Part I (Quintard and Whitaker 1990a) are discussed in terms of their influence on the crossflow.Roman Letters A interfacial area between the -region and the -region contained within V, m² - a vector that maps onto , m - b vector that maps onto , m - b vector that maps onto , m - B second order tensor that maps onto , m² - C second order tensor that maps onto , m² - E energy of the gamma emitter, keV - f fractional flow of the -phase - g gravitational vector, m/s² - h characteristic length of the large-scale averaging volume, m - H height of the stratified porous medium , m - i unit base vector in the x-direction - K local volume-averaged single-phase permeability, m² - K - {K}, large-scale spatial deviation permeability - { K} large-scale volume-averaged single-phase permeability, m² - K ^* large-scale single-phase permeability, m² - K ^** equivalent large-scale single-phase permeability, m² - K local volume-averaged -phase permeability in the -region, m² - K local volume-averaged -phase permeability in the -region, m² - K - {K } , large-scale spatial deviation for the -phase permeability, m² - K ^* large-scale permeability for the -phase, m² - l thickness of the porous medium, m - l characteristic length for the -region, m - l characteristic length for the -region, m - L length of the experimental porous medium, m - characteristic length for large-scale averaged quantities, m - n outward unit normal vector for the -region - n outward unit normal vector for the -region - n unit normal vector pointing from the -region toward the -region (n = - n ) - N number of photons - p pressure in the -phase, N/m² - p ₀ reference pressure in the -phase, N/m² - local volume-averaged intrinsic phase average pressure in the -phase, N/m² - large-scale volume-averaged pressure of the -phase, N/m² - large-scale intrinsic phase average pressure in the capillary region of the -phase, N/m² - - , large-scale spatial deviation for the -phase pressure, N/m² - p_c , capillary pressure, N/m² - p _c capillary pressure in the -region, N/m² - p capillary pressure in the -region, N/m² - {p _c } ^c large-scale capillary pressure, N/m² - q -phase velocity at the entrance of the porous medium, m/s - q -phase velocity at the entrance of the porous medium, m/s - S_wi irreducible water saturation - S /, local volume-averaged saturation for the -phase - S _i initial saturation for the -phase - S _r residual saturation for the -phase - S ^* { }^*/}^*, large-scale average saturation for the -phase - S saturation for the -phase in the -region - S saturation for the -phase in the -region - t time, s - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the -phase, m/s - {v } large-scale averaged velocity for the -phase, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v local volume-averaged phase average velocity for the -phase in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - v -{v } , large-scale spatial deviation for the -phase velocity in the -region, m/s - V large-scale averaging volume, m³ - y position vector relative to the centroid of the large-scale averaging volume, m - {y}^c large-scale average of y over the capillary region, m Greek Letters local porosity - local porosity in the -region - local porosity in the -region - local volume fraction for the -phase - local volume fraction for the -phase in the -region - local volume fraction for the -phase in the -region - {}^* { }^*+{ }^*, large-scale spatial average volume fraction - { }^* large-scale spatial average volume fraction for the -phase - mass density of the -phase, kg/m³ - mass density of the -phase, kg/m³ - viscosity of the -phase, N s/m² - viscosity of the -phase, Ns/m² - V /V , volume fraction of the -region ( + =1) - V /V , volume fraction of the -region ( + =1) - attenuation coefficient to gamma-rays, m^-1 - -      

Rheology of molten polymers

Summary TheCross equation describes the flow of pseudoplastic liquids in terms of an upper and a lower Newtonian viscosity corresponding to infinite and zero shear, and ₀, and of a third material constant related to the mechanism of rupture of linkages between particles in the intermediate, non-Newtonian flow regime, Calculation of of bulk polymers is important, since it cannot be determined experimentally. The equation was applied to the melt flow data of two low density polyethylenes at three temperatures.Using data in the non-Newtonian region covering 3 decades of shear rate to extrapolate to the zero-shear viscosity resulted in errors amounting to about onethird of the measured ₀ values. The extrapolated upper Newtonian viscosity was found to be independent of temperature within the precision of the data, indicating that it has a small activation energy.The ₀ values were from 100 to 1,400 times larger than the values at the corresponding temperatures.The values of were large compared to the values found for colloidal dispersions and polymer solutions, but decreased with increasing temperature. This shows that shear is the main factor in reducing chain entanglements, but that the contribution of Brownian motion becomes greater at higher temperatures.

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Zusammenfassung Die Gleichung vonCross beschreibt das Fließverhalten von pseudoplastischen Flüssigkeiten durch drei Konstante: Die obereNewtonsche Viskosität (bei sehr hohen Schergeschwindigkeiten), die untereNewtonsche Viskosität ₀ (bei Scherspannung Null), und eine Materialkonstante, die vom Brechen der Bindungen zwischen Partikeln im nicht-Newtonschen Fließbereich abhängt. Die Berechnung von ist wichtig für unverdünnte Polymere, wo man sie nicht messen kann.Die Gleichung wurde auf das Fließverhalten der Schmelzen von zwei handelsüblichen Hochdruckpolyäthylenen bei drei Temperaturen angewandt. Die Werte von ₀, durch Extrapolation von gemessenen scheinbaren Viskositäten im Schergeschwindigkeitsbereich von 10 bis 4000 sec^–1 errechnet, wichen bis 30% von den gemessenen ₀-Werten ab. Die Aktivierungsenergie der war so klein, daß die-Werte bei den drei Temperaturen innerhalb der Genauigkeit der Extrapolation anscheinend gleich waren. Die ₀-Werte waren 100 bis 1400 mal größer als die-Werte.Im Verhältnis zu kolloidalen Dispersionen und verdünnten Polymerlösungen war das der Schmelzen groß, nahm aber mit steigender Temperatur ab. Deshalb wird die Verhakung der Molekülketten hauptsächlich durch Scherbeanspruchung vermindert, aber der Beitrag derBrownschen Bewegung nimmt mit steigender Temperatur zu.

     

A general model for the effective viscosity of pseudoplastic and dilatant fluids

Summary A new and very general expression is proposed for correlation of data for the effective viscosity of pseudoplastic and dilatant fluids as a function of the shear stress. Most of the models which have been proposed previously are shown to be special cases of this expression. A straightforward procedure is outlined for evaluation of the arbitrary constants.

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Zusammenfassung Eine neue und sehr allgemeine Formel wird für die Korrelation der Werte der effektiven Viskosität von strukturviskosen und dilatanten Flüssigkeiten in Abhängigkeit von der Schubspannung vorgeschlagen. Die meisten schon früher vorgeschlagenen Methoden werden hier als Spezialfälle dieser Gleichung gezeigt. Ein einfaches Verfahren für die Auswertung der willkürlichen Konstanten wird beschrieben.

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Nomenclature b arbitrary constant inSisko model (eq. [5]) - n arbitrary exponent in eq. [1] - x independent variable - y(x) dependent variable - y ₀(x) limiting behavior of dependent variable asx 0 - y(x) limiting behavior of dependent variable asx - z original dependent variable - arbitrary constant inSisko model (eq. [5]) andBird-Sisko model (eq. [6]) - arbitrary exponent in eqs. [2] and [8] - effective viscosity = shear stress/rate of shear - _A effective viscosity at = _A - _B empirical constant in eqs. [2] and [8] - ₀ limiting value of effective viscosity as 0 - ₀() limiting behavior of effective viscosity as 0 - limiting value of effective viscosity as - () limiting behavior of effective viscosity as - rate of shear - arbitrary constant inBird-Sisko model (eq.[6]) - shear stress - _A arbitrary constant in eqs. [2] and [8] - ₀ shear stress at inBingham model - _1/2 shear stress at = ( ₀ + )/2 With 8 figures     

Viscometric properties of viscous theta solutions of monodisperse polystyrene

Theta solvents for polystyrene are prepared from high-viscosity blends of styrene and low-molecular-weight polystyrene, and then used to make dilute solutions with monodisperse polystyrene solutes of high-M = 2.3, 6.0, 9.0, 18.0 · 10⁵. A Weissenberg rheogoniometer is used to measure the non-Newtonian viscosity as a function of shear stress, for low values, and also the complex viscosity components and as functions of frequency. A capillary viscometer is used for high- measurements of(). Viscometric properties, at room temperature, are analyzed as functions of high-molecular-weight solute concentrationc with parameters of constant or to obtain [()], [ ()], and [ ()]. Such a collection of data has apparently not previously been available for polymers in theta solvents (in which Gaussian chain statistics prevail). Also unique is the achievement of high stress ( = 2 10⁴ Pa) at low shear rate, by virtue of high solvent viscosity which is not characteristic of other known theta solvents.     

Finite-difference analysis of MHD Stokes problem for a vertical infinite plate in dissipative fluid

Finite-difference solution of MHD flow past an impulsively started vertical infinite plate in an electrically conducting fluid has been presented on taking into account the viscous dissipative heat. Results for velocity and temperature are shown graphically whereas the numerical values of the skin-friction and the rate of heat transfer are entered in the table. The results are discussed in terms of the parameters M (the Hartmann number), G (the Grashof number, G>0, cooling of the plate by free convection, G<0, heating of the plate by free convection currents), E (the Eckert number) and P (the Prandtl number).Nomenclature B ₀ applied magnetic field - c _p specific heat at constant pressure - g acceleration due to gravity - k thermal conductivity - t time - T temperature of the fluid near the plate - T temperature of the fluid far away from the plate - U ₀ velocity of the plate - u velocity of the fluid - coefficient of volume expansion - kinematic viscosity - scalar electrical conductivity - coefficient of viscosity - density of the fluid     

Versuche zu einem „shear-rate-blockage“-Effekt am Protoplasma zentrifugierter Gewebe

Ohne ZusammenfassungI thank Mr.Scott Blair for his answer reserving the term dilatancy for cases of real dilatation. Now it's only to wish that this terminology is used according to his Report on the principles of rheological nomenclature (Amsterdam 1949).     

About the Regularized Navier–Stokes Equations

The first goal of this paper is to study the large time behavior of solutions to the Cauchy problem for the 3-dimensional incompressible Navier–Stokes system. The Marcinkiewicz space L^3, is used to prove some asymptotic stability results for solutions with infinite energy. Next, this approach is applied to the analysis of two classical regularized Navier–Stokes systems. The first one was introduced by J. Leray and consists in mollifying the nonlinearity. The second one was proposed by J.-L. Lions, who added the artificial hyper-viscosity (–)^{/ 2}, > 2 to the model. It is shown in the present paper that, in the whole space, solutions to those modified models converge as t toward solutions of the original Navier–Stokes system.     

Concentration dependence of the critical viscoelastic properties of gelatin at the gel point

Gelatin gel properties have been studied through the evolution of the storage [G()] and the loss [G()] moduli during gelation or melting near the gel point at several concentrations. The linear viscoelastic properties at the percolation threshold follow a power-law G()G() and correspond to the behavior described by a rheological constitutive equation known as the Gel Equation. The critical point is characterized by the relation: tan = G/G = cst = tan ( · /2) and it may be precisely located using the variations of tan versus the gelation or melting parameter (time or temperature) at several frequencies. The effect of concentration and of time-temperature gel history on its variations has been studied. On gelation, critical temperatures at each concentration were extrapolated to infinite gel times. On melting, critical temperatures were determined by heating step by step after a controlled period of aging. Phase diagrams [T = f(C)] were obtained for gelation and melting and the corresponding enthalpies were calculated using the Ferry-Eldridge relation. A detailed study of the variations of A with concentration and with gel history was carried out. The values of which were generally in the 0.60–0.72 range but could be as low as 0.20–0.30 in some experimental conditions, were compared with published and theoretical values.