Phase transitions and hysteresis in nonlocal and order-parameter models

The paper describes two types of regularization to the basic quasistatic double-well potential problem in one space dimension. One model features a spatially nonlocal term while the other incorporates the use of an order parameter. Some basic existence and regularity results for these modified models are derived and some numerical calculations that show hysteresis and motion of phase boundaries are presented.

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Sommario Il lavoro descrive due tipi di regolarizzazione del problema quasistatico per un potenziale con due minimi in una dimensione. Un modello evidenzia caratteri di non località spaziale, mentre l'altro conduce ad una teoria con parametro d'ordine. Si derivano alcuni risultati di esistenza e regolarità e si presentano alcuni studi numerici che mostrano l'isteresi e il moto delle frontiere tra le fasi.

     

The influence of surface energy on stress-free microstructures in shape memory alloys

Certain alloys such as In-Tl, Ni-Ti, Ag-Cd or Cu-Al-Ni display remarkable mechanical properties such as the shape memory effect or pseudo-elasticity. This behaviour is related to a solid-solid phase transformation which leads to a complicated microscopic arrangement of different phases. In recent studies such microstructures have been analyzed by the minimization of elastic energy. We discuss the influence of additional surface energy terms on the existence of stress-free microstructures both in the nonlinear and a geometrically linear setting.

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Sommario Certe leghe come quelle di In-Tl, Ni-Ti, Ag-Cd o Cu-Al-Ni mostrano proprietà meccaniche notevoli quali la memoria di forma o la pseudoelasticità. Questo comportamento è determinato da una trasformazione di fase solido-solido che conduce a complicati arrangiamenti a livelo microscopico. In studi recenti tali microstrutture sono state analizzate attraverso la minimizzazione dell'energia elastica. Noi discutiamo l'influenza di termini addizionali di energia superficiale sull'esistenza di microstrutture in uno stato naturale sia in un contesto lineare che non lineare.

     

A semi-analytical approach to Biot instability in a growing layer: Strain gradient correction,weakly non-linear analysis and imperfection sensitivity

Many experimental works have recently investigated the dynamics of crease formation during the swelling of long soft slabs attached to a rigid substrate. Mechanically, the spatially constrained growth provokes a residual strain distribution inside the material, and therefore the problem is equivalent to the uniaxial compression of an elastic layer.The aim of this work is to propose a semi-analytical approach to study the non-linear buckling behaviour of a growing soft layer. We consider the presence of a microstructural length, which describes the effect of a simple strain gradient correction in the growing hyperelastic layer, considered as a neo-Hookean material. By introducing a non-linear stream function for enforcing exactly the incompressibility constraint, we develop a variational formulation for performing a stability analysis of the basic homogeneous solution. At the linear order, we derive the corresponding dispersion relation, proving that even a small strain gradient effect allows the system to select a critical dimensionless wavenumber while giving a small correction to the Biot instability threshold. A weakly non-linear analysis is then performed by applying a multiple-scale expansion to the neutrally stable mode. By applying the global conservation of the mechanical energy, we derive the Ginzburg–Landau equation for the critical single mode, identifying a pitchfork bifurcation. Since the bifurcation is found to be subcritical for a small ratio between the microstructural length and the layer׳s thickness, we finally perform a sensitivity analysis to study the effect of the initial presence of a sinusoidal imperfection on the free surface of the layer. In this case, the incremental solution for the stream function is written as a Fourier series, so that the surface imperfection can have a cubic resonance with the linear modes. The solutions indicate the presence of a turning point close to the critical threshold for the perfect system. We also find that the inclusion of higher modes has a steepening effect on the surface profile, indicating the incipient formation of an elastic singularity, possibly a crease.     

A new form of the coherency energy in pseudoelasticity

In some previous papers [1], [2] pseudoelasticity in tensile experiments has been treated thermodynamically under the assumption that the relevant constitutive ingredients are

Nonlinear dynamics and stability of microstructures in a lattice model for ferroelastic materials

With the view of understanding how precise macroscopic properties of a material emerge from the underlying physics of homogeneous microstructures, a lattice model which can describe complex non-linear patterns made of elastic domains and interfaces is proposed. On the basis of a two-dimensional lattice model involving non-linear and competing interactions the dynamics of microstructure formation is examined. The emphasis is placed especially on an instability mechanism of a strain band producing localized domains. The influence of applied forces and dissipative effects on the dynamics of two perpendicular strain bands is studied. The results are interpreted as a microtwinning in crystalline alloys. The physical conjectures are checked by means of numerical simulations performed directly on the microscopic system.

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Sommario Si propone un modello reticolare che può descrivere complessi arrangiamenti fatti di domini elastici ed interfacce. Sulla base di un modello bidimensionale in cui sono presenti interazioni contrastanti e nonlineari si esamina la dinamica della formazione di microstrutture. L'accento è posto sui meccani'smi di instabilità che determinano bande di deformazione localizzata. Si studia l'influenza delle forze applicate e degli effetti dissipativi sulla dinamica di due bande perpendicolari e si interpretano i risultati come un microtwinning in leghe cristalline. Si verificano le congetture fisiche per mezzo di simulazioni numeriche del modello microscopico.

     

Inertial and self interactions in structured continua: Liquid crystals and magnetostrictive solids

Evolution equations for liquid crystals and for magnetostrictive solids are discussed within the framework of a theory of continua with microstructure that allows for mechanical self-interactions and non-standard inertial terms.

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Sommario Si discutono equazioni di evoluzione per cristalli liquidi e per solidi magnetostrittivi nell'ambito di una teoria dei continui con microstruttura che contempla la possibilità sia di autointerazioni meccaniche che di termini inerziali non standard.

     

Some examples of electron microscopy studies of microstructures and phase transitions in solids

In this contribution the results of some electron microscopy studies on microstructures related with phase transitions in a variety of materials will be presented. The materials include binary and ternary alloys, high T_C superconductors as well as C₆₀ and C₇₀ fullerenes, while the transitions can be diffusional, displacive or both.

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Sommario Si presentano i risultati di alcuni studi fatti attraverso la microscopia elettronica sulle microstrutture relative a transizioni di fase in una varietà di materiali. I casi comprendono leghe binarie e ternarie, superconduttori T_C e materiali C₆₀ e C₇₀; le transizioni esaminate sono diffusionali, displacive o di entrambi i tipi.

     

The issues of the uniqueness and the stability of the homogeneous response in uniaxial tests with gradient damage models

We consider a wide class of gradient damage models which are characterized by two constitutive functions after a normalization of the scalar damage parameter. The evolution problem is formulated following a variational approach based on the principles of irreversibility, stability and energy balance. Applied to a monotonically increasing traction test of a one-dimensional bar, we consider the homogeneous response where both the strain and the damage fields are uniform in space. In the case of a softening behavior, we show that the homogeneous state of the bar at a given time is stable provided that the length of the bar is less than a state dependent critical value and unstable otherwise. However, we also show that bifurcations can appear even if the homogeneous state is stable. All these results are obtained in a closed form. Finally, we propose a practical method to identify the two constitutive functions. This method is based on the measure of the homogeneous response in a situation where this response is stable without possibility of bifurcation, and on a procedure which gives the opportunity to detect its loss of stability. All the theoretical analyses are illustrated by examples.     

Martensitic transformation and phonon localization in Ni-Al alloys by atomistic simulations

We discuss an atomistic model for the potential energy of Ni-Al alloys based on the Embedded Atom Method. The potential is applied in a Molecular Dynamics and Quasi Harmonic investigation of the Martensitic Transformation (MT) that occurs in Ni _x Al_1– x for compositions 0.61<x<0.64 at a temperatureT _M ranging from ~ 0 K atx=0.61 to ~ 400 K atx=0.64. We determine the transition temperature as a function of composition and pressure and we show that our potential reliably reproduces the known properties of the alloy.We exploit the model to investigate the microscopic dynamical properties underlying the transition. Our computation shows that in the austenite the compositional disorder induces several bands of localized phonons, that discontinuously de-localize at the MT. We show that specific localized modes associated with Ni-rich clusters identify regions of incipient lattice instability, and provide favourable sites for the nucleation.

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Sommario L'articolo discute un modello Embedded Atom per l'energia potenziale di leghe Ni-Al. Il potenziale viene utilizzato in uno studio di Dinamica Molecolare e nell'approssimazione Quasi Armonica della Transformazione Martensitica (MT) che ha luogo in Ni _x Al_1–x per 0.61<x<0.64 a una temperatutaT _M compresa tra ~ 0 K perx=0.61 e ~ 400 K perx=0.64. La temperature di transizione è determinata in funzione della composizione e della pressione. I risultati dimostrano la validità del potenziale nel riprodurre le proprietà note della lega.Il modello viene utilizzato per studiare la dinamica microscopica alla base della trasformazione. Lo studio mostra che nella austenite il disordine chimico legato alla non-stechiometria induce bande di fononi localizzati che si delocalizzano in modo discontinue allaMT. Viene mostrato che i modi localizzati sono associati a regioni rieche di Ni ed individuano siti di incipiente instabilità reticolare. Tali siti forniscono centri preferenziali per la nucleazione.

     

Finite-scale microstructures and metastability in one-dimensional elasticity

This paper addresses the non-uniqueness pointed out by Ericksen in his classical analysis of the equilibrium of a one-dimensional elastic bar with non-convex energy [1]. Following some previous work in this area, we suitably regularize the problem in order to investigate this degenerancy. Our approach gives an explicit framework for the the study of the rich variety offinite-scale equilibrium microstructures for the bar in a hard loading device, and their stability properties. In this way we clarify the role of interfacial energy in creating finitescale microstructures, by considering the combined effect of the oscillation-inducing and oscillation-inhibiting terms in the energy functional.

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Sommario Il lavoro riguarda la non unicità messa in luce da J.L. Ericksen nella sua analisi dell'equilibrio di barre elastiche con energia non convessa. Seguendo le linee di precedenti lavori, per investigare questa degenerazione si ricorre ad una regolarizzazione del problema e si dà un esplicito quadro di riferimento per lo studio della ricca varietà delle microstrutture di scala finita e della loro stabilità. Si chiarisce in particolare il ruolo dell'energia di interfaccia nella creazione di microstrutture di scala finita considerando l'effetto combinato di termini inibitori e favorevoli all'insorgere di oscillazioni nel funzionale energia.

     

Internal loops in pseudoelastic behaviour of Ti-Ni shape memory alloys: Experiment and modelling

The stress-strain isothermal hysteresis loops due to the incomplete martensitic transformation are analysed for Ti-Ni shape memory alloys. Experiments show the existence of two distinct yield lines for phase transition; one for the forward transformation austenitemartensite (AM), the other for the reverse transformation MA. The tensile behaviour of single crystals with only one yield line (AM) [1] can be considered as an ideal case. An extension of a thermodynamic model for pseudoelasticity [2] allows these two yield lines to be taken into account.

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Sommario Per leghe Ti-Ni con memoria di forma vengono analizzati i cicli di isteresi isotermici tensione-deformazione prodotti da una incompleta trasformazione martensitica. Gli esperimenti mostrano l'esistenza di due distinte linee di snervamento per la transizione di fase, una verso la trasformazione austenitemartensite (AM), l'altra per la trasformazione inversa MA. Il comportamento a trazione di un singolo cristallo con una sola linea di snervamento (AM) [1], può essere considerato un caso ideale. L'estensione ad un modello termodinamico pseudo-elastico [2] consente di analizzare queste due linee di snervamento.