Evidence for new meson resonances from the reaction pp → K−K+

The differential cross sections for $\text{p}\text{p}\text{→}\text{K}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}$ provide new evidence for mesons with masses between 2.1 and 2.5 GeV/c². The zeros of the cross sections suggest the existence of J^P = 3^? states with both I = 1 and I = 0 at masses between 2.1 and 2.18 GeV/c². The results also support a J^P = 4⁺ state near 2.34 GeV and are consistent with 5^? states in both I = 1 and I = 0 close to 2.5 GeV. This analysis confirms the I = 1 3^?, 5^? and I = 0 4⁺ states seen previously in $\text{p}\text{p}\text{→ π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$ and is in agreement with the existing data for the non-annihilation processes.     

Comparative SNMS and SIMS studies of oxidized Ce and Gd

Polycrystalline Ce and Gd surfaces of various oxidation states have been investigated in situ and alternately by Sputtered Neutral Mass Spectrometry SNMS and by SIMS. For the bombardment with 4 keV Ar⁺ ions the dominating peaks in the mass spectra of postionized sputtered neutrals and positive secondary ions refer to metal atoms Me and monoxide molecules MeO. At oxygen concentrations of several atomic percent the sensitivity of SNMS and SIMS are of the same order. Characteristic differences are found between the behaviour of corresponding SNMS and SIMS signals: For SNMS the intensitiesI(MeO⁰) and I(Me⁰) in general vary complementarily when the oxygen is removed from the surface. The intensity ratios $\text{I(MeO}{}^0\text{)}\text{I(Me}{}^0\text{)}$ decrease monotonously by 1 to 2 orders of magnitude. With SIMS both I(MeO⁺) and I(Me⁺) are found to decrease with the oxygen content. The SIMS ratios $\text{I(MeO}{}^{\mathrm{+}}\text{I(Me}{}^{\mathrm{+}}\text{)}$ display an oscillatory behaviour with only little variation of their absolute values. As an example, quantitative results for the behaviour of the ionisation probability α⁺_Me for the secondary ions Ce⁺ and Gd⁺ are derived for low oxygen concentrations.     

Spin determination of states with stretched configurations in 16N and 32P via the (d, α) reaction at 52 MeV

The reactions ${}^{12}\text{C}\text{(}\text{d}\text{, α)}{}^{10}\text{B}\text{,}{}^{18}\text{O}\text{(}\text{d}\text{, α)}{}^{16}\text{N and}{}^{34}\text{S}\text{(}\text{d}\text{, α)}{}^{32}\text{P}$ have been investigated at E_d = 52 MeV. Vector analyzing powers as large as $\text{¦iT}{}_{11}\text{¦=0.85}$ are observed. They exhibit patterns characteristic for final spins I = |L?1|, L or L + 1 and provide spin determinations at least for states of unique L-transfer. Local, zero-range DWBA calculations assuming deuteron-cluster pick-up reproduce qualitatively the observed effects. The method has been tested for states of known spin, and then has been applied to determine spins of states with stretched coupling in ¹⁶N: J^π = 3⁺(3.96 MeV), 4^?(6.17 MeV) and in ³²P: J^π = 5⁺(4.75 MeV). There is strong evidence for further 5⁺ states in ³²P at 6.43, 7.96, 8.09 and 8.54 MeV.     

Stereoelectronic properties of photosynthetic and related systems: Ab initio configuration interaction calculations on the ground and lower excited singlet and triplet states of magnesium chlorin and chlorin

Ab initio configuration interaction wavefunctions and energies are reported for the ground state and many low-lying singlet and triplet states of magnesium chlorin and chlorin, and are employed in an analysis of the electronic absorption spectra of these systems.In chlorin, the calculated visible spectrum consists of two ${}^1\text{(π, π}{}^1\text{)}$ states, the lower energy, y-polarized state exhibiting moderate absorption intensity in contrast to the very weak absorption of the higher energy x-polarized state. The configurational composition of both states is well described by the four-orbital model. Five ${}^1\text{(π, π}{}^1\text{)}$ states are responsible for the Soret band envelope. A moderately intense y-state lies under the low energy edge of the band envelope, while two x-polarized states of moderate and strong intensity, respectively, are responsible for the band maximum. The final two ${}^1\text{(π, π}{}^1\text{)}$ states lie at the high energy edge of the Soret band and introduce a measure of asymmetry into the band envelope. Two ${}^1\text{(n, π}{}^1\text{)}$ states of very weak oscillator strength are also found in this region of the spectrum. All the Soret states are of complex configurational composition, and several of the higher lying states contain contributions from doubly excited configurations.The calculated visible spectrum of magnesium chlorin also consists of two ${}^1\text{(π, π}{}^1\text{)}$ states, with the weakly absorbing x-polarized state lying approximately 200 cm^?1 lower in energy than the moderately intense y-polarized state. The configurational composition of both states is well described by the four-orbital model. Four ${}^1\text{(π, π}{}^1\text{)}$ states constitute the bulk of the intensity in the Soret band envelope. In distinction to chlorin, the moderately intense ${}^1\text{(π, π}{}^1\text{)}$ state at the low energy edge of the band envelope is x-polarized. Two intense ${}^1\text{(π, π}{}^1\text{)}$ states of y- and x-polarization, respectively, constitute the band maximum region, and a single x-polarized state of moderately strong intensity can be assigned to the high energy shoulder of the band envelope. Two other weakly absorbing ${}^1\text{(π, π}{}^1\text{)}$ states are also found in this region, along with another weakly absorbing state of mixed in-plane and out-of-plane polarization. No clearly defined ${}^1\text{(n, π}{}^1\text{)}$ states are observed. As was the case for chlorin, all the Soret states are of complex configurational composition, and some of the higher energy states contain significant contributions from doubly excited configurations.Chlorin and magnesium chlorin both possess three ${}^3\text{(π, π}{}^1\text{)}$ states which lie below S₁ and a single ${}^3\text{(π, π}{}^1\text{)}$ which lies slightly above S₂. All four of the low-lying ${}^3\text{(π, π}{}^1\text{)}$ states in each molecule are well described by the four-orbital model, with T₁ being essentially a single configuration in each case. The remainder of the ${}^3\text{(π, π}{}^1\text{)}$ states are clustered in the same energetic region as the comparable ${}^1\text{(π, π}{}^1\text{)}$ Soret states, with comparably complex configurational compositions.Dipole moments and charge distributions for low-lying singlet and triplet states are also reported, and are used to rationalize chemical reactivity characteristics.     

Electron-phonon coupling and phonon generation in normal-metal microbridges

The second derivative of current—voltage characteristic, $\text{d}{}^2\text{I}\text{d}\text{V}{}^2$, of a small orifice connecting two pieces of normal metals is shown to be proportional to the function $\text{G(ω) =}\text{α}\text{?}{}^2\text{(ω)F(ω)}$ at ω = eV, where F(ω) is the phonon density of states, and α̃² (ω) the square of the electron—phonon matrix element averaged over the Fermi surface and multiplied by the additional structure factor taking into account the geometry of the orifice. The constriction is shown to work, in a current-carrying state, as a source of non-equilibrium phonons emitted in the immediate vicinity of the orifice.     

Analysis of the 2770-Å emission system in I2

A weak emission spectrum of I₂ near 2770 Å is reanalyzed and found to to minate on the A(1u³Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward $\text{I}{}^{\mathrm{?}}\text{(}{}^1\text{S) +}\text{I}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_1\text{)}$. In combination with other results for the A state, the analysis yields the following spectroscopic constants: T″_e = 10 907 cm^?1, $\text{D}$″_e = 1640 cm^?1, ω″_e = 95 cm^?1, $\text{R″}{}_{\mathrm{e}}\text{= 3.06}\text{A}\text{?}$; T′_e = 47 559.1 cm^?1, ω′_e = 106.60 cm^?1, $\text{R′}{}_{\mathrm{e}}\text{= 3.53}\text{A}\text{?}$.     

Spin-parity analysis of the nπ+ system produced in the reaction π+p → π+π+n at 16GeV/c

A spin-parity analysis of the nπ⁺ system produced in the reaction π⁺p → π⁺π⁺n at 16 MeV/c has shown apart from the mass enhancements associated with the known resonances Δ⁺(1238), N¹(1520) and N¹(1688) there is an enhancement peaked at M(nπ⁺) ? 1.35 GeV, ∑0.2 GeV wide. For masses below M(nπ⁺) ? 1.35 GeV this enhancement is predominantly due to $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states, predominate. The presence of $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states indicates that the rule ΔP = (?1)^ΔJ is strongly violated in the diffractive process N → Nπ, and hence it cannot be considered a specific characteristic of all diffractive processes.     

A study of resonance production in the reaction K+p → K0pπ+ from 3 to 16 GeV/c

The reactions $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^{\mathrm{1+}}\text{(890)}\text{p}$, $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^{\mathrm{1+}}\text{(1420)}\text{p}$ and K⁺p → K⁰Δ⁺⁺ have been systematically studied for eleven incident momenta between 3.0 and 16.0 GeV/c. Cross sections, differential cross sections and density matrix elements are presented. For K¹(890) production the contributions from natural and unnatural parity exchanges have also been separated into I = 0 and I = 1 components. Effective trajectories have been extracted in the case of natural parity exchange, and also for Δ⁺⁺ production.     

Observation of interference between Iu=12 and Iu=32 baryon exchange amplitudes in 4 GeV/c backward inelastic scattering

Interference between the $\text{I}{}_{\mathrm{<mtext>u</mtext>}}\text{=}\text{1}\text{2}$ and $\text{I}{}_{\mathrm{<mtext>u</mtext>}}\text{=}\text{3}\text{2}$ baryon exchange amplitudes is observed in the reaction π^?p → pπ^?π⁰, with the proton produced forward with $\text{cos}\text{θ}{}_{\mathrm{p}}{}^1\text{>0.8}$. The Dalitz plot shows that the reaction is dominated by the quasi two body final states ρ^?p(δ exchange) and $\text{N}{}^{10}\text{(1670)π}{}^0\text{(}\text{N exchange}\text{)}$, with δ(1238), N¹(1520) and higher mass N¹'s also produced. The relative phase between the ρ and the N¹(1670) production amplitudes is measured to be 135° ± 10° and is compared with the Regge pole signature factor phase predictions.     

Medium-spin levels and the character of the 20.4 ns 132+ isomer in 145Gd

Levels of the N = 81 nucleus ¹⁴⁵Gd have been investigated by in-beam γ-ray and conversion electron spectroscopy with the ¹⁴⁴Sm(³He, 2n) reaction. Fourteen new low- and medium-spin states between 1.0 and 2.4 MeV excitation, the known yrast levels up to spin $\text{21}\text{2}{}^{\mathrm{+}}$, five other high-spin non-yrast states and a new 20.4 ns $\text{13}\text{2}$ isomer at 2200.2 keV in ¹⁴⁵Gd have been observed. The isomer decays via a fast 927.3 keV E3 transition with B(E3) = 48 ± 7 W.u. Another weaker decay branch is a mixed, strongly hindered E1 + M2 + E3 transition to the $\text{v}\text{h}{}^{\mathrm{?1}}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}$ state. We propose an octupole $\text{v}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{j}{}^{\mathrm{?2}}\text{× 3}{}^{\mathrm{?}}$ main configuration for the isomer, analogous to the 997 keV $\text{13}\text{2}{}^{\mathrm{+}}$ isomer in ¹⁴⁷Gd. The levels of ¹⁴⁵Gd are discussed on the basis of the spherical shell model.     

On the determination of α2F(ω) in metals by measuring I–V characteristics of “wide” (non-ballistic) point-contact junctions

For metals with small electron and phonon mean free paths (alloys, deformed or amorphous materials), there exists a possibility of determining α²F(ω) by measuring the V dependence of $\text{d}{}^2\text{I}\text{d}\text{V}{}^2$ or $\text{d}{}^3\text{I}\text{d}\text{V}{}^3$ of wide (d ? 10³ Å) point contacts (PC) and then inverting the linear equation relating these quantities to α²F(ω). The procedure is elaborated numerically and tested successfully for model electron-phonon interaction spectra.     

Core polarization for M2 transitions in odd-A tin isotopes

The reduced M2 transition probabilities $\text{11}\text{2}{}^{\mathrm{?}}{}_1\text{→}\text{7}\text{2}{}^{\mathrm{+}}{}_1$ in the odd-A isotopes ^109–121Sn are found to reveal a specific behaviour. B(M2) values are calculated in the framework of the quasiparticlephonon model. The coupling of a quasineutron with the 2⁺, 3^? and 2^? one-phonon core excitation is taken into account. Inclusion of all one-phonon 2^? states up to 24 MeV in the wave functions of the excited states $\text{11}\text{2}{}^{\mathrm{?}}{}_1\text{and}\text{7}\text{2}{}^{\mathrm{+}}{}_1$ reduces the theoretical B(M2) values by 3–4 times as compared to the single-particle values. The specific B(M2) dependence on the mass number appears to be due to the pairing effect.     

Magnetic moments of isomeric bandheads in transitional nuclei: 119I and 192Tl

Nuclear g-factors of isomeric bandheads in the transition nuclei ¹¹⁹I and ¹⁹²Tl have been measured to be $\text{g[}{}^{119}\text{I}\text{(}\text{9}\text{2}{}^{\mathrm{+}}\text{)] = 1.20(3)}$ and $\text{g[}{}^{192}\text{Tl}\text{(8}{}^{\mathrm{?}}\text{)] = 0.207(5)}$. These values are in agreement with a model of one or two quasiparticles coupled to a deformed core. This interpretation is also supported by a preliminary quadrupole moment determination of $\text{Q[}{}^{192}\text{Tl}\text{(8}{}^{\mathrm{?}}\text{)] = 45(9)}\text{fm}{}^2$. The lifetimes were remeasured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 34.6(5)}\text{ns}$ and $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 296(5)}\text{ns}$ for the ¹¹⁹I and the ¹⁹²Tl isomers, respectively.     

The spectrum of HeNe+

Discharges through mixtures of helium and neon show two band groups near 4250 and 4100 Å as first observed by Druyvesteyn. These bands, assigned to the HeNe⁺ ion by Tanaka, Yoshino, and Freeman, have been studied under high resolution and have been fairly completely analyzed. The upper state of the transition is a very weakly bound state resulting from $\text{He}{}^{\mathrm{+}}\text{(}{}^2\text{S) +}\text{Ne}\text{(}{}^1\text{S}{}_0\text{)}$. There are two lower states resulting from the two components of $\text{Ne}{}^{\mathrm{+}}\text{(}{}^2\text{P) +}\text{He}\text{(}{}^1\text{S}{}_0\text{)}$. The upper of these two (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) is also very weakly bound while the lower of the two, the ²Σ⁺ ground state, has a dissociation energy of 0.69 eV and an r_e value of 1.30 Å. All bands in both band groups show four branches designated R_ff, Q_ef, Q_fe, and P_ee. From their analysis the rotational constants in the various vibrational levels of the three electronic states have been determined. While no spin splitting in the B²Σ⁺ state has been found the ground state X²Σ shows a very large spin splitting and the $\text{A}{}_2{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state a very large $\text{Ω-type}$ doubling. The vibrational numberings in all these states were established by the study of the spectrum of ³HeNe⁺. At the same time the hyperfine structure observed in all lines of ³HeNe⁺ confirmed the nature of the upper state B²Σ⁺ as resulting from He⁺ + Ne, i.e., by charge exchange from the ground state. The ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ component of the ²Π state has not been observed, presumably because of low intensity.     

A new electronic band system of PbO

The chemiluminescence spectrum of atomic Pb reacting with O₃ under single-collision conditions includes a series of 55 bands in the regions 450–850 nm. A vibrational analysis is obtained which shows emission is to the ground state of PbO from excited electronic states not previously analyzed. Forty-nine of the bands are assigned to the a(1)-X(0⁺) transition and the remaining six are tentatively identified as the forbidden b(0^?)-X(0⁺) transition. Both the a and b states are believed to be Hund's case (c) components of the ³Σ⁺ states arising from the configuration $\text{σ}{}^2\text{π}{}^3\text{π}{}^1$. The vibrational parameters of the a state are ν₄ = 16 029 ± 8, ω_e′ = 478.7 ± 1.9, and ω_ex_e′ = 2.292 ± 0.128 cm^?1, where the uncertainties represent two standard deviations of the least-squares fit. Emission is also observed from the PbO B state produced in the reaction of metastable Pb atoms with O₃. Using pulsed laser excitation, an attempt is made to determine radiative lifetimes. We find for the PbO A(0⁺) state τ = 3.74 ± 0.3 μsec, and for the PbO B(1) state τ = 2.58 ± 0.3 μsec, while for the a(1) state τ is estimated to be greater than 10 μsec. From the vibrational analysis, energy conservation arguments place a lower limits to the ground state dissociation energy of $\text{D}{}_0{}^0\text{(}\text{PbO}\text{) ≥ 3.74 ± 0.03}\text{eV}$ (86.2 ± 0.7 kcal/mole). For the Pb + O₃ reaction we find less than 1% of the products are PbO¹ molecules that emit in the visible. Correlations are made with the low-lying states of other Group IV chalconides based on the assignment of the PbO $\text{a}{}^3\text{Σ}{}^{\mathrm{+}}\text{(1)}$ state and the correspondence between the low-lying triplet states of PbO and CO.     

Study of the Kππ system produced in K−p → KππN reactions at 14.3 GeV/c

We have studied the $\text{K}\text{ππ}$ system in the 14.3 GeV/c reactions K^?p → K^?π⁺π^?p, $\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^0\text{π}{}^{\mathrm{?}}\text{π}{}^0\text{and}\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^0\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{n}$. The data have been obtained from a 500 000 picture exposure of the CERN 2m HBC. The first two final states are dominated by Q-production in the Kππ system; there is also an L-signal at M (Kππ) ～ 1.75 GeV. The reaction cross sections are compared to K^?p data at other energies. We discuss the Kππ mass dependence of the diffractive production slope. Evidence is presented for a Q^?p versus Q⁺p differential cross section cross-over around |t| = 0.17 GeV². A t-channel isospin analysis for the $\text{KN}\text{→}\text{K}\text{1(890)π}\text{N}$ channels in the Q-region shows that the I = 1 exchange amplitude is $\text{? 10\%}$ of the dominant I = 0 exchange amplitude. The Kππ decay distributions indicate a predominant J^P = 1⁺ state in the Q-region, and an important J^P = 2^? contribution in the L-region. We find neither s-channel nor t-channel helicity conservation at the meson vertex in the Q- or L-regions. The Kπ angular correlation moments within the Kππ diffractive system are characteristic of Kπ elastic scattering, suggesting a π-exchange Deck-type production mechanism. There is evidence for a Kf⁰ and κπ contribution (where κ is the J^P(Kπ) = 0⁺ state) to the diffractive Kππ system. A fit to the $\text{K}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{and}\text{K}{}^0\text{π}{}^{\mathrm{?}}\text{π}{}^0$ Dalitz-plot distributions for the Q-re gion indicates that the ratio of $\text{K}\text{?}\text{to K}{}^1\text{π}$ decay amplitudes decreases with increasing Kππ mass.     

Investigation of level energies and B(E2) values for rotation-aligned bands in Hg isotopes

High spin states in ^{191, 192, 193, 195, 197, 199}Hg were investigated by observing γ-rays and conversion electrons in the compound reactions ${}^{\mathrm{192,\; 194,\; 198}}\text{Pt(α, x}\text{n}\text{)}\text{and}{}^{192}\text{Pt}\text{(}{}^3\text{He}\text{, 4}\text{n}\text{)}$. In ¹⁹⁷Hg the decoupled band built on the $\text{13}\text{2}{}^{\mathrm{+}}$ state and the semi-decoupled negative-parity band are observed up to $\text{I}{}^{\mathrm{\pi }}\text{=}\text{41}\text{2}{}^{\mathrm{+}}\text{and}\text{33}\text{2}{}^{\mathrm{?}}$, respectively. A careful investigation of ¹⁹⁹Hg revealed no new high spin states above the previously known levels with $\text{I}{}^{\mathrm{\pi }}\text{=}\text{25}\text{2}{}^{\mathrm{+}}\text{and}\text{31}\text{2}$^?. Half-lives were determined for the 10⁺, 7^?, 8^? and 16^? states in ¹⁹²Hg, the if$\text{33}\text{2}{}^{\mathrm{+}}$$\text{states in}{}^{\mathrm{191,193}}\text{Hg and the}$ (frc states in ^{191, 193, 195, 197}Hg. The systematics of the level energies and B(E2) values for the positive-parity ground and $\text{13}\text{2}{}^{\mathrm{+}}$ bands and the negative-parity semi-decoupled bands in ^190–200Hg is discussed.     

Magnetic moments of (νi132)−n isomers in neutron-deficient lead isotopes

The magnetic moments of the 12⁺ isomers in ^{192, 196, 198, 200, 206}Pb and of the $\text{33}\text{2}{}^{\mathrm{+}}$ isomer in ²⁰⁵Pb have been measured using the PAD technique. The results for the g-factors are: g(192) = ?0.173(2), g(196) = ?0.1600(15), g(198) = ?0.1552(15), g(200) = ?0.1512(15), g(206) = ?0.1496(18), and g(205) = ?0.148(5). As all states have a rather pure $\text{(νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?n}}$ configuration, the values reflect directly the $\text{νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ orbital. They show a decrease towards the more neutron-deficient isotopes attributed to the reduced core polarisation as a result of decreasing occupation of the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ neutron shell. The measured systematics are discussed regarding core polarisation, mesonic corrections, and small admixtures of core-excited states to the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ wave function.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.