SiO2脊形条波导热极化引起的电光效应

通过理论模拟对具有上覆盖层的SiO₂脊形条波导结构进行了优化，在此基础上利用微电子工艺制作了SiO₂脊形波导Mach-Zehnder型电光调制器，并进行热极化引起的电光和非线性效应的研究.热极化过程大幅增强了样品的电光及非线性效应，二次电光系数由热极化前的1.56×10^-22(m/V)²提高到热极化后的8.50×10^-22(m/V)²，极化后得到了0.093pm/V的线性电光系数，对热极化的物理机理进行了理论分析. 关键词： 电光调制器 2光波导')" href="#">SiO₂光波导 电光效应 热极化     

Thermal nonlinear effects in hybrid silica/polymer microdisks

The linear and thermal nonlinear spectral responses of silica and hybrid silica/polymer microdisk resonators are investigated. Both types of resonators can be fabricated using the same technological procedure with only slight modification. An extra polymer layer results in opposite sign of the nonlinear thermal optical response of the hybrid microdisks compared to the pure silica ones, which can be explained by the different thermorefractive coefficients of silica and polymer. A full compensation of eigen frequency shift, caused by thermal nonlinearity, has been demonstrated experimentally.     

Sol–gel combustion synthesis of magnetic MnFe2O4 oxide and FeNi alloy: product dependence on the reduction ability

We report on fabrication of on-chip calcium fluoride (CaF₂) microdisk resonators using water-assisted femtosecond laser micromachining. Focused ion beam (FIB) milling is used to create ultra-smooth sidewalls. The quality (Q) factors of the fabricated microresonators are measured to be 4.2 × 10⁴ at wavelengths near 1,550 nm. The Q factor is mainly limited by the scattering from the bottom surface of the disk whose roughness remains high due to the femtosecond laser micromachining process. This technique facilitates the formation of on-chip microresonators on various kinds of bulk crystalline materials, which can benefit a wide range of applications such as nonlinear optics, quantum optics, and chip-level integration of photonic devices.     

Silica-based microcavity fabricated by wet etching

Silica whispering gallery mode(WGM) microcavities were fabricated by the buffered oxide etcher and potassium hydroxide wet etching technique without any subsequent chemical or laser treatments. The silicon pedestal underneath was an octagonal pyramid, thus providing a pointed connection area with the top silica microdisk while weakly influencing the resonance modes. The sidewalls of our microdisks were wedge shaped, which was believed to be an advantage for the mode confinement. Efficient coupling from and to the 60 μm diameter microdisk structure was achieved using tapered optical fibres, exhibiting a quality factor of 1.5×10~4 near a wavelength of 1550 nm. Many resonance modes were observed, and double transverse electric modes were identified by theoretical calculations. The quality factor of the microdisks was also analysed to deduce the cavity roughness. The wet etching technique provides a more convenient avenue to fabricate WGM microdisks than conventional fabrication methods.     

The sol-gel glass transformation of silica

Abstract

Large monolithic xerogel silica glasses were successfully made from tetramethyl-orthosilicate and distilled water using the combination of an acidic drying control chemical additive (DCCA) and a specially designed drying chamber. The acidic DCCA increases the gel strength by formation of a fibrillar ultrastructure, and the drying chamber reduces the catastrophic capillary forces inside the wet gel body.

Partially densified monolithic gels up to 850°C were routinely made for physical property tests and compared to commercial fused silicas. Although the mechanical properties of the porous gel-silica monoliths such as microhardness, Young's modulus, toughness, flexural strength, density are relatively lower than fused silica, the optically transparent porous gel silica has a UV cut-off ranging from 250–300 nm. Such a porous gel with excellent optical transmission and a highly uniform pore radius of 10–50 Å offers a unique, chemically stable matrix for impregnation with a second phase of optically active organic or inorganic compounds.

The processing and properties of Types I and II fused quartz optics and Types III and IV synthetic fused silica optics are compared with the new organometallic sol-gel derived gel-silica optics. Fully dehydrated and densified gel-silica has excellent transmission from 165 nm to 4400 nm with no OH absorption peaks. This optical transmission is equivalent to the best Type IV fused silica. The other physical properties and structural characteristics of the dehydrated dense gel-silica are similar to fused quartz and fused silica. However, the dense gel-silica has a lower coefficient of thermal expansion of 2.0 × 10^?7 cm/cm compared with 5.5 × 10^?7 cm/cm for standard vitreous silicas. The CTE value is temperature independent from 80 K to 500 K. Sol-gel silica optics can be made as complex shapes by casting of the sol into inexpensive plastic molds.     

Thermal considerations on the design and operation of lens ducts

In this paper, heat effects due to powerful pump beam in the lens duct delivery system is investigated and subsequent thermal effects are described. Temperature raise in the device, thermal loading, and material considerations for the lens ducts fabrication are reported. For an absorbed intensity of 10 W/cm² in a 4 cm-long lens duct, the temperature difference between the midpoint and its faces, for a lens duct made from borosilicate is 7.05°C, for sapphire 4.01°C, and for synthetic fused silica is the smallest value of 0.54°C. For a typical absorbed intensity of 1.4 W/cm² in a 4 cm-long lens duct, with a steady-state time constant of 120 s, the fractional thermal loading is 1.98% for BK-7, 1.89% for sapphire, and only 0.16% for synthetic fused silica. By considering different glass materials, the overall results show that synthetic fused silica is superior to some other materials for the fabrication of a lens duct. The reported analytical method and the results of parametric studies can be helpful in material selection and construction of an effective lens duct.     

Effect of group velocity dispersion on supercontinuum generation and filamentation in transparent solids

We experimentally investigate the spectral extent and spectral profile of the supercontinuum (SC) generated in transparent solids: barium fluoride, calcium fluoride, and fused silica upon irradiation by intense femtosecond-long pulses of 800, 1,380, and 2,200 nm light. These wavelengths correspond to the normal and anomalous group velocity dispersion (GVD) regimes in fused silica calcium fluoride and barium fluoride. We observe an isolated (anti-Stokes) wing on the blue side most prominently in fused silica but also in CaF₂. The SC conversion efficiency is measured for the long wavelengths used in our experiments. We also present results on filamentation in BaF₂ in the anomalous GVD regime, including visualization of focusing–refocusing events within the crystal; the size of a single filament is also determined. The 15-photon absorption cross section in BaF₂ is deduced to be 6.5 × 10^?190 cm³⁰ W^?15 s^?1.     

Nonlinear refraction of silver nanowires from nanosecond to femtosecond laser excitation

In order to investigate the effect of pulse width and solvent on the nonlinear properties of metal nanostructures, silver nanowires were fabricated in a direct current electric field (DCEF) using a solid-state ionic method and characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The nonlinear refractive index (γ) of silver nanowires suspended in ethanol was measured using the Z-scan technique and laser radiation of various (femto-, pico-, and nanosecond) pulse durations. Experimental results indicated that silver nanowires have obvious positive refractive nonlinearities and γ (the Kerr-induced self-focusing) increases as the pulse duration increases from 7.4×10⁻⁸ cm²/GW at 110 fs to 1.6×10⁻⁴ cm²/GW at 8 ns, due to the additional influence of the atomic reorientational Kerr effect in the case of longer pulses. Due to the solvent dependence of the nonlinear behavior of the silver nanowires, the nonlinear absorption and refraction of silver nanowires suspended in de-ionized water are smaller than those of silver samples suspended in ethanol. The thermal nonlinearities are insignificant in our experimental conditions.     

Modification of the fused silica glass network associated with waveguide fabrication using femtosecond laser pulses

Atomic-scale structural changes have been observed in the glass network of fused silica after modification by tightly focused 800-nm, 130-fs laser pulses at fluences between 5 and 200 J cm^-2. Raman spectroscopy of the modified glass shows an increase in the 490 and 605-cm^-1 peaks, indicating an increase in the number of 4- and 3-membered ring structures in the silica network. These results provide evidence that densification of the glass occurs after exposure to fs pulses. Fluorescence spectroscopy of the modified glass shows a broad fluorescence band at 630 nm, indicating the formation of non-bridging oxygen hole centers (NBOHC) by fs pulses. Waveguides that support the fundamental mode at 633 nm have been fabricated inside fused silica by scanning the glass along the fs laser beam axis. The index changes are estimated to be approximately 0.07×10^-3. Received: 17 December 2001 / Accepted: 9 July 2002 / Published online: 25 October 2002 RID="*" ID="*"Corresponding author. Fax: +1-925/423-2463, E-mail: dmkrol@ucdavis.edu     

Nonlinear optical absorption in Bi3TiNbO9 thin films using Z-scan?technique

Bi₃TiNbO₉ (BTN) thin films with layered perovskite structure were fabricated on fused silica by pulsed laser deposition. The XRD pattern revealed that the films are single-phase perovskite and highly (00l) textured. Their fundamental optical constants, such as band gap, linear refractive index, and linear absorption coefficient, were obtained by optical transmittance measurements. The dispersion relation of the refractive index vs. wavelength follows the single electronic oscillator model. The nonlinear optical absorption of the films was investigated by single beam Z-scan method at a wavelength of 800 nm with laser duration of 80 fs. We obtained the nonlinear absorption coefficient β=1.44×10⁻⁷ m/W. The results show that the BTN thin films are promising for applications in absorbing-type optical devices.     

Coupled high Q-factor surface nanoscale axial photonics (SNAP) microresonators

We experimentally demonstrate series of identical two, three, and five coupled high Q-factor surface nanoscale axial photonics (SNAP) microresonators formed by periodic nanoscale variation of the optical fiber radius. These microresonators are fabricated with a 100 μm period along an 18 μm radius optical fiber. The axial FWHM of these microresonators is 80 μm and their Q-factor exceeds 10(7). In addition, we demonstrate a SNAP microresonator with the axial FWHM as small as 30 μm and the axial FWHM of the fundamental mode as small as 10 μm. These results may potentially enable the dense integration of record low loss coupled photonic microdevices on the optical fiber platform.     

104 nm period grating fabrication in fused silica by immersion two-beam interferometric laser induced backside wet etching technique

A substantial extension of the method of two-beam interferometric laser induced backside wet etching (TWIN-LIBWE), the immersion TWIN-LIBWE, is used to fabricate fused silica gratings with a 104 nm period. The spatially filtered fourth harmonic of Nd:YAG laser (λ=266 nm, τ_FWHM=8 ns) pulses were split into two parts which then interfered at the backside of the fused silica target in contact with a liquid absorber (naphthalene methyl methacrylate saturated solution with a concentration of 1.85 mol/dm³). The hypotenuse of a rectangular fused silica prism is attached to the fused silica target with the use of distilled water as the immersion liquid. On steering the beams through the sides of the prisms, the angle between the two laser beams has been substantially increased. The resulting period of 104 nm is the minimal grating constant achievable under such experimental conditions and, to our knowledge, the smallest laser generated grating period in fused silica at present. PACS 42.62; 42.79; 81.65     

石英玻璃的电致二阶非线性极化及其热擦除性

本文报导了石英玻璃的电致二阶非线性极化及其热擦除性的实验研究结果。通过电致二次谐波测量发现:在一定的电场极化条件下,石英玻璃的电致二阶非线性极化强度随极化时间的延长而逐渐增强,并渐趋饱和;石英玻璃的电致二阶非线性极化可通过热处理而擦除,并随热擦除时间的延长呈动态衰减趋势。根据玻璃的电致二阶非线性极化的“偶极子取向”模型,对实验结果进行了讨论.     

Backside laser etching of fused silica using liquid gallium

Laser-induced backside wet etching (LIBWE) that is regularly performed with hydrocarbon solutions is demonstrated with the liquid metal gallium as a new class of absorbers for the first time. Well-contoured square etch pits in fused silica with smooth bottoms and well-defined edges were achieved already with the first pulse from a 248 nm excimer laser. The etching is characterized by a threshold fluence of 1.3 J/cm² and a straight proportional etch rate growth with the fluence up to 8.2 J/cm². In addition, the etch depth increases linearly for onward pulsed laser irradiation and gives evidence for an only marginal incubation effect. The high fluences necessary for etching originate from the high reflection losses as well as the high thermal conductivity of the metallic absorber. The suggested etch mechanism comprises the heating of the fused silica up to or beyond the fused silica melting point by the laser heated gallium and the removing of the softened or molten fraction of the material by mechanical forces from shock waves, bubbles, high pressures, or stress fields. PACS 81.65.C; 81.05.J; 79.20.D; 61.80.B; 42.55.L     

Fabrication of Nanoimprint Stamp Using Interference Lithography

Interference lithography is used to fabricate a nanoimprint stamp, which is a key step for nanoimprint lithography. A layer of chromium in thickness of about 20 nm is deposited on the newly cleaned fused silica substrate by thermal evaporation, and a layer of positive resist in thickness of 150nm is spun on the chromium layer. Some patterns, including lines, holes and pillars, are observed on the photoresist film by exposing the resist to interference patterns and they are then transferred to the chromium layer by wet etching. Fused silica stamps are fabricated by reactive ion etching with CHF3/O2 as etchants using the chromium layer as etch mask. An atomic force microscope is used to analyse the pattern transfer in each step. The results show that regular hole patterns of fused silica, with average full width 143nm at half maximum （FWHM）, average hole depth of 76nm and spacing of 450nm, have been fabricated. The exposure method is fast, inexpensive and applicable for fabrication of nanoimprint stamps with large areas.     

Observation of Kerr nonlinearity in microcavities at room temperature

We have devised and experimentally verified a method for observation of the optical Kerr effect in microcavities at room temperature. The technique discriminates against the much larger and typically dominant thermal component of nonlinearity by using its relatively slow frequency response. Measurement of the Kerr coefficient or equivalently of the third-order nonlinear susceptibility of the cavity material is demonstrated for a silica microcavity. With this approach, useful information about the characteristic thermal response time in microresonators can also be acquired.     

基于交叉偏振波产生的脉冲净化技术研究与应用

本文利用交叉偏振波产生技术(XPW)对800 nm波段钛宝石飞秒激光器输出的激光脉冲进行时域净化, 提高脉冲时域对比度, 并测量验证了10¹¹对比度的脉冲, 达到测量仪器的动态范围极限, 比初始脉冲时域对比度有三个量级的提高, XPW的效率为22%. 同时发现净化后脉冲光谱宽度也得到一定展宽, 进一步利用啁啾镜对和补偿片对净化后的脉冲进行色散补偿, 得到25 fs脉宽的脉冲. 利用该净化后的激光脉冲作为种子注入已有的太瓦级钛宝石啁啾脉冲放大系统中, 在输出脉冲能量250 mJ, 宽度50 fs, 对应峰值功率5 TW的情况下, 在主脉冲前100 ps以外的范围内测量验证了10¹¹的脉冲对比度.     

Efficient Entanglement Concentration Schemes for Separated Nitrogen-Vacancy Centers Coupled to Low-Q Microresonators

We present several efficient entanglement concentration protocols (ECPs) with the nitrogen-vacancy (N-V) centers coupled to low-Q microresonators. Based on the input-output process of ancillary coherent light pulse in low-Q microresonators, we can obtain the maximally entangled states among remote participants via local operations and classical communication. Our protocols use a conventional photon detector to discriminate the two coherent states |α〉 and |?α〉, which is more convenient than homodyne measurement. We discuss the feasibility of our protocols, and they may be beneficial for quantum repeaters and quantum information processing.     

Enhanced nonlinear optical responses in metal-glass nanocomposites

The “engineered” nonlinear nanocomposite materials with extremely large values of optical Kerr susceptibility and fast temporal responses that can be precisely tuned to satisfy the requirements of switching applications is of current interest in photonics. Metal quantum-dot composite glasses can exhibit enhanced optical susceptibility, χ⁽³⁾, whose real and imaginary parts are related to the intensity-dependent refractive index and two-photon absorption coefficient, respectively. Classical (dielectric) and quantum confinement effects come into play in the nonlinear optical responses of these nanocomposites. Metal nanocluster-glass composites have been synthesized by 200 keV Cu⁺ and 1.5 MeV Au⁺ ion implantations in fused silica glasses at a dose of 3 × 10¹⁶ ions/cm², followed by thermal annealing in reducing atmosphere to promote cluster growth. UV-Visible spectroscopy has revealed prominent linear absorption bands at characteristic surface plasmon resonance (SPR) frequencies signifying appreciable formation of copper and gold colloids in glass matrices. Third-order optical properties of the composite materials have been studied by Z-Scan and Anti-Resonant Interferometric Nonlinear Spectroscopy (ARINS) measurements. The sign of nonlinear refraction is readily obtained from the Z-Scan signatures. The ARINS technique utilizes the dressing of two unequal-intensity counter-propagating pulsed light beams with differential nonlinear phases, which occur upon traversing the sample if it exhibits nonlinear optical response. This difference in phase manifests itself in the intensity-dependent transmission. The nonlinear refractive index, nonlinear absorption coefficient, the real and imaginary parts of the third-order optical susceptibility have been extracted.     

Nonlinear Refractive Index of Er3+-Doped Fiber and Its Application to Nonlinear Fiber Coupler

A large change in the refractive index originating in the transition absorption of erbium ions is induced in an Er³⁺-doped fiber. It is shown that the Er³⁺-doped fiber exhibits the nonlinear refractive index of n₂=7.4 × 10⁻¹⁵ m²/W, which is 10⁵−10⁶ times larger than that caused by the optical Kerr effect in a usual silica fiber at the pumping, wavelength of 514.5 nm. The large nonlinear refractive index occurred in a fiber directional coupler fabricated with the Er³⁺-doped fiber optically changes the coupling condition. The coupling ratio changes up to 0.16 by increasing the pumping power up to 0.7 mW.