硅树脂材料热光特性的测试与分析

用激光-V棱镜装置测得耐热型硅树脂在632.8nm和650nm波长上的热光系数分别为-3.3×10-4/℃和-3.6×10-4/℃。以石英玻璃为衬底,用该材料制作了平板波导,用棱镜耦合法测量了不同温度下波导的有效折射率,利用平板波导模式本征方程求解出不同温度下导波层的膜厚与折射率,分析了有效折射率随温度变化的特点。根据导波层折射率与厚度的变化和高分子材料的克劳修斯莫索提公式,分析出该材料的极性分子较大,是引起负热光系数大的原因。该材料适合用于研制低功耗、与塑料光纤匹配的短距离光通信热光开关。     

SOI材料非对称脊型波导结构PDL标准样品研究

通过制备非对称结构SOI脊型波导,设计并优化得到一个偏振相关损耗标准样品,通过与标准单模光纤耦合封装,实现了偏振相关损耗测试仪表的快速校准。该器件偏振相关损耗值为0.58dB,测量重复性相对标准差为0.02,测量不确定度为0.2dB。     

红外波段十字阵列光吸收材料光学特性研究

尺寸为光波长量级的微纳结构材料与电磁波的相互作用,使得其具有许多特殊的光学性能,金属-电介质-金属微纳结构具有电磁波完美吸收特性。基于S参数法,研究十字阵列光吸收材料在红外波段的光学特性参数,分析其谐振吸收机理及光学特性参数调谐性。研究结果表明,十字阵列单元尺寸对其等效光学参数具有调谐作用;当材料表面与入射介质之间满足阻抗匹配条件,以及等效折射率系数虚部值足够大时,可以有效提高其吸收率;经过结构优化的十字阵列光吸收材料在红外波段具有大于95%的吸收率,实验样件测试结果大于80%。十字结构臂长和电介质层厚度决定吸收谱特性,而十字结构臂宽仅仅影响吸收谱峰值大小。十字阵列光吸收材料在红外波段的完美吸收及光谱调谐性特点,使其可用于红外探测和光谱成像等领域。     

硅基二氧化硅光波导器件偏振特性的理论分析

从理论上分析了硅基二氧化硅光波导器件的芯区尺寸、相对折射率差、内应力和弯曲径对器件偏振特性的影响,得出结论：小折射率差的正方形波导的双折射系数小;内应力对双折射的影响比几何参数大;弯曲半径较小时,双折射系数较大,弯曲损耗也较大。     

极化聚合物薄膜波导的光学特性

叙述了键合型ＤＡＮＳ聚合物薄膜波导的制备和极化过程。应用集成光学中的棱镜耦合技术,对ＤＮＡＳ聚合物薄膜波导极化前后以及紫外光照射前后的光学特性分别进行了表征。实验结果表明,极化后波导非寻常光折射率明显增大而波导寻常光折射率减小;经过紫外光照射后,波导折射率降低约０．０２。     

硼酸对KDP晶体光学特性的影响

生长了不同硼酸掺杂浓度的KDP晶体,用超显微镜了晶体内部的散射颗粒,检测了晶体的光损耗和透过率特性。实验结果表明,较高浓度的硼酸对KDP晶体的光学均匀特性有较大影响,并使晶体具有显著的旋光性和波片效应。     

激光多普勒测速仪中散射光特性的研究

后向散射光特性与多普勒信号的质量密切相关。为了设计高性能的激光多普勒测速仪,运用散斑理论详细分析了激光多普勒信号的强度与散射光斑大小的关系,结合泛函理论给出了计算多普勒电流的散斑表达式,并通过实验的方法研究了回波信号的偏振特性及其强度分布。理论分析与实验结果表明,激光多普勒信号的强度与接收器件光敏面的直径成正比,与光斑的直径成反比;选用光斑较小的圆偏振激光束,并用光敏面尺寸较小的探测器在镜面反射方向上接收信号光,可以大大提高多普勒信号的信噪比,增强系统的探测能力,为提高系统的测量精度创造有利的条件。     

飞秒激光诱导自组织纳米光栅偏振散射特性研究

实验证实飞秒激光在透明材料内部诱导的周期性纳米条纹具有特殊的光学特性。采用时域有限差分方法(FDTD)分别对单元纳米光栅和纳米光栅阵列的散射特性进行研究,分析结果显示纳米光栅的散射对入射激光的偏振方向敏感;散射强度与入射激光波长相关,波长越长、散射越弱。对于纳米光栅阵列,平行于纳米光栅的散射强度比垂直于纳米光栅的散射强度小两万倍。最后从理论上验证了Ⅱ类波导和纳米光栅偏振导光是由纳米光栅的散射引起的而不是双折射效应。     

同轴波导内金属支撑杆的散射特性研究

对同轴波导内传输TEM模时金属支撑杆的散射特性进行了研究。通过将同轴波导等效为窄边是磁壁的矩形波导,建立了金属支撑杆的散射场计算模型,用积分方程法得到了散射场的计算公式,其计算结果与有限元方法仿真结果吻合良好。分析计算和实验表明：当同轴波导传输TEM模时,n根角向均匀分布的支撑杆在同轴波导内激励起一系列TE(mn)1模式;当n大于同轴波导截面平均周长与波长之比时,金属杆所激励的高阶模截止,输出和反射模式仅为TEM模,其反射系数随支撑杆根数或支撑杆半径的增加而增大,随频率的升高而减小。     

大孔聚丙烯醛-邻羧基苯腙螯合树脂的合成及其性能的初步研究

以大孔聚丙烯醛-苯乙烯-二乙烯苯三元共聚物树脂为高分子骨架,通过其含有的活泼醛基与邻羧基苯肼螯合剂进行高分子反应合成了一种含羧基及氮配位原子的螯合树脂——聚丙烯醛-邻羧基苯腙,用元素分析及红外光谱对其结构进行了鉴定,并用电感耦合等离子体发射光谱研究了其对贵金属离子的吸附性能,结果表明该树脂对金、钯及铂具有选择性吸附作用,吸附容量分别为1.98,0.31及0.16mmol·g~(-1)。     

集成光学平板光盘读出头研制

采用集成光学方法,将非球面消球差双凸波导透镜、双光栅会聚光波导透镜、光波导转向棱镜单片集成在铌酸锂基底上构成光学平板光盘读出头.集成光学平板光盘读出头克服了微透镜光盘读出头体积大、组装复杂的不足,实现了光盘读出头的集成化,提高了系统的可靠性.光斑理论值0.475 μm,实测值0.67 μm.     

Study on the Structure and Properties of UHMWPE/Epoxy Resin Composite Fiber

The preparation, crystallization behavior, and fiber structure and properties of ultrahigh molecular weight polyethylene (UHMWPE) epoxy resin composite fiber were studied by means of differential scanning calorimeter (DSC), X‐ray diffraction (XRD), Scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and tensile testing. The morphology showed a different behavior from pure polyethylene (PE) fiber. The fiber mechanical properties, creep behavior, and thermal properties of UHMWPE fiber can be improved by adding epoxy resin. It's believed that the epoxy can serve as a physical cross‐linking agent to limit the motion or migration of PE molecules and consequently improve the fiber creep property. However, when the content of epoxy resin is higher than 5 wt%, all of the behavior and properties deteriorate.     

激光固化快速成形SL7510型光敏树脂性能研究

利用红外光谱仪、紫外激光固化快速成形设备、旋转黏度计、电子拉力试验机以及热机械性能分析仪对美国Huantsman公司的SL7510型光敏树脂进行了性能研究.实验结果表明,SL7510型光敏树脂是一种环氧树脂-丙烯酸酯混杂型光敏树脂,它在30℃时的黏度为335 mPa·s,临界曝光量为10.9 mJ/cm2,透射深度为0.14 mm,固化体积收缩率为4.03%,固化物托伸强度为40.8 MPa,拉伸弹性模量为2009.2 MPa,断裂伸长率为13.6%,玻璃化温度为62℃.同时,根据所测定的光敏树脂临界曝光量和透射深度数值,选定了紫外激光固化快速成形设备的加工参数,制作了电话机外壳,其制作效果较好.     

气相色谱法测定医用高分子材料硅凝胶中环氧乙烷的残留

以 HP- INNOWAX(Crosslinked Polyethlene Glycol交链聚乙二醇 )毛细管柱为固定相 ,使用氢火焰离子化检测器 (FID) ,二阶程序升温 ,外标法定量 ,气相色谱法分析硅凝胶中环氧乙烷的残留量 ,检出限为1ng环氧乙烷 ,相对标准偏差均小于 4 .32 % ,回收率在 98.2 5 %— 10 1.84 %之间 ,该方法操作简便、灵敏、准确、重现性好 ,适用于硅凝胶中环氧乙烷的残留量分析     

光散射PC荧光树脂的制备及光学性能

以聚碳酸酯(PC)粉体、有机硅光扩散剂和YAG∶Ce荧光粉为原料,通过熔融共混法和高温压模法及减薄抛光工艺制备出不同有机硅光扩散剂质量分数的PC/YAG∶Ce光散射荧光树脂样品,通过SEM、XRD、透射光谱和PL的性能分析,表明：荧光树脂样品在500～800 nm光谱范围有较高的透光率,样品的主相都为Y₃Al₅O₁₂,在342和448 nm有两个激发波峰,发射光谱在532 nm有一宽峰,属于Ce3+的5d→4f特征跃迁发射,对应的荧光寿命在61.5 ns左右。把荧光树脂样品应用到白光LED器件的封装获得的光效为81.12 lm/W@100 mA, 说明PC/YAG∶Ce荧光树脂片适用于作白光LED封装的新型荧光材料。     

Effects of Chemical Structure of Phenolic Resin on Damping Properties of Acrylate Rubber-Based Blends

Two types of acrylate rubber (AR)-based damping blends were prepared by using two types of phenolic resins (PF), a resole resin (RR) and a novolac resin (NR), as organic fillers. The structure and damping properties of the AR/RR and AR/NR blends obtained by hot-pressing were characterized and compared by Fourier transform infrared spectrum, scanning electron microscopy, differential scanning calorimetry, and dynamic mechanical analysis. The results showed that the chemical structures of PF and the hot-pressing process had a significant effect on the damping properties of the AR-based composites. The loss peak of AR/RR shifted to a lower temperature accompanied with a gradually reduced peak intensity with the increase of RR content. In contrast, hot-pressed AR/NR showed great improvement in damping properties, which can broaden the effective damping temperature region and an increase in the temperature of the loss peak. It was thus concluded that NR with linear structure and abundant phenolic hydroxyl groups, which can create effective hydrogen bonds with an AR matrix, even after hot-pressing, makes it a promising NR to choose as an organic additive in ARs to prepare advanced damping blends.     

Computation of the scattering matrix of guided acoustical propagation by the Wave Finite Element approach

This work aims to study the guided acoustical propagation. The Wave Finite Element method is applied rather than the classic Finite Element method. Finite Element libraries are used for an elementary portion modelling. The dynamic stiffness matrix is then calculated. Periodicity conditions lead to a simple eigenvalue problem and the wave basis can be extracted. The dynamic stiffness matrix of the coupling elements corresponding to the lined parts can be also calculated considering the acoustical impedance. The use of the coupling’s conditions provides the scattering matrix. Within the framework of this method, the dispersion curves, the evolution of the scattering coefficients and the forced response to pressure excitations for both single and coupled waveguides can be represented, and compared to the FE method. The WFE method, treated in literature, and its main interests are reviewed, while adding the impedance notion into the calculation of the scattering matrix.