共查询到20条相似文献,搜索用时 171 毫秒
1.
2.
SynthesisandStructureof4,5-bis(2,4-Dinitrophenylthio)-1,3-Dithiole-2-ThioneQuZheng;CaiJing-Hua;FangQi;YouXiao-Zeng(Coordinati... 相似文献
3.
StudiesonAcylthiosemicarbazidesandRelatedHeterocycle(XXIII)──SynthesisandBactericidalActivityOf5-(5-(3-pyridyl)-2H-tetrazole-... 相似文献
4.
WANG Xi-Cun WANG Fang QUAN Zheng-Jun ZHANG Zhang 《结构化学》2009,28(8):957-962
The synthesis for acyliminothiazolines by treatment of N, N□-substituted thioureas with α-bromoacetophenone under aqueous media was described. 2-(2-Benzofuroylimino)-3-aryl- 4-phenyl-1,3- thiazolines were characterized by infrared, NMR spectroscopy and elemental analysis. The single crystals of compounds 4a and 4b were grown by slow evaporation of 80% ethanol solution at room temperature. Compounds 4a and 4b crystallize in triclinic space group P1 and monoclinic space group P21/c, respectively. 相似文献
5.
6.
SONG Zhe LI Guang-hua YU Yang SHI Zhan FENG Shou-hua College of Chemistry State Key Laboratory of Inorganic Synthesis Preparative Chemistry Jilin University Changchun P.R.China 《高等学校化学研究》2009,25(1)
Hydrothermal reaction between mixed ligand(1,2,4-triazole and benzoic acid) and Zn(NO3)2·6H2O afforded a three-dimensional(3D) metal-organic framework Zn3(C2H2N3)2(C7H5O2)4(C2H2N3=1,2,4-triazole,C7H5O2=benzoic acid).The compound was crystallized in the hexagonal system with space group R3:a=2.90234(9) nm,b=2.90234(9) nm,c=1.08597(5) nm,γ=120°,V=7.9222(5) nm3,Mr=816.68,Dc=1.541 g/cm3,Z=9,F(000)=3708,R=0.0636,and wR=0.1777.Its structure consists of ZnN2O2 tetrahedron and ZnN2O4 octahedron,which are connected ... 相似文献
7.
SynthesisandCrystalStructureof3,3-Diphenylnaphtho[1,2-b]furan-2(3H)-oneMengJi-Ben;WenZhong;WangYong-Mei;WangRu-Ji;WangHong-Ge... 相似文献
8.
CrystalandMolecularStructureof5,6,7,8,9,10-Hexahydro-3-(4-methylphenylamino)-2-thioxoquinoxalineSunDa-Qing;LangJian-Ping;LuZh... 相似文献
9.
StructuralStudiesofComplexesof1-phenyl-3-methyl-4-benzoyl-5-pyrazolonewithMetalIons(Ⅲ)(Ⅱ)CrystalStructureof〔Nd(C_(17)H_(13)N_2?.. 相似文献
10.
A new ruthenium complex trans-RuCl2(COD)Py2 has been synthesized and characterized by elemental analysis, IR, IH NMR and single-crystal X-ray diffraction. Crystal data: trans- RuCl2(COD)Py2, Mr = 438.35, monoclinic, space group P21/c, a = 8.9116(9), b = 14.6175(15), c = 13.7582(14)A, β = 101.994(1)°, V= 1753.1(3)A^3, Z= 4, Dc= 1.661 g/cm^3, F(000)= 888,μ = 1.199 mm^-1, R = 0.0376 and wR = 0.0789 for 2492 observed reflections with I 〉 2σ(I). 相似文献
11.
lmTR0DUCTI0NSincetheseleniumcoronandswereachivevedin1989tli,thesynthesisandcoor-dinationchemistrystudyofthismacrocycliccomPOundshavereceivedwideattentionowingtotheirstrongcomplexingabilitiestowardssoft.transiti0nandheavymetals.InourprevibuspaPer,wereP0rtedthecrystalstructureoftw0selenacrownethers(2'3)andaPd(1)complexwith10'selenabenzo-15-crown-5t4i.Duetothedifficultyofthepreparationsofselenium-nitr0genmixeddonorc0n-..tainingmacrocycles,thestudyontheseligandsisconsiderablyscarce.Thesynthes… 相似文献
12.
13.
Mao Jiang-Gao 《结构化学》1994,(5)
CrystalStructureof1,5-Bis(Ts),1,5-diaza-13-crown-4(Ts=p-methylphenylsulfonyl)MaoJiang-Gao(FujianInstituteofResearchontheStruc... 相似文献
14.
用凝胶法生长了标题配合物[NH_4(B15C5)_2][Cd(SCN)_3]的晶体,并对其进行了红外光谱,元素分析等各项物理性质的测试。经X射线单晶结构分析得到了配合物的全部晶体学数据:M_r=841.31,正交晶系,空间群P2_12_12_1,晶胞常数a=10.970(3),b=21.834(3),c=15.563(4),V=3727(3),Z=4,D_x=1.50g/cm ̄3,F(000)=1736,μ=7.09cm ̄(-1),R=0.070,R_w=0.063。结构分析结果表明,配阳离子[NH_4(B15C5)_2] ̄+和配阴离子[Cd(SCN)_3] ̄-间靠静电力结合成配合物。 相似文献
15.
CrystalStructureof[La(NO_3)_3(12-crown-4)-(H_2O)](12-crown-4)MaoJiang-Gao;JinZhong-Sheng;YuFeng-Lan(LaboratoryofRareEarthChemi?.. 相似文献
16.
合成了六种轻希土硫氰酸盐与标题不饱和冠醚的新固体配合物,进行了元素分析,摩尔电导率、DTA、UV、IR和XPS等表征.对Ln(NCS)3·L和Ln(NCS)3的XPS研究中,得到它们组成原子芯能级电子(Ln3d5/2,Ols,Nls,S2p)的结合能信息;观察到除Y3d5/2外Ln3d5/2(Ln=La、Ce、Pr、Nd、和Sm)的伴峰结构,Ln3d5/2结合能与原子序数呈线性关系,并推断类似化合物Pm3d5/2结合能在1035eV附近. 相似文献
17.
CrystalStructuresofLn(NO_3)_3(Ln=La,Yb)Complexeswith12-crown-4MaoJiang-Gao;JinZhong-Sheng;YuFeng-Lan(LaboratoryofRareEarthChem... 相似文献
18.
1 INTRODUCTIONCrownandazacrownetherhavebeenusedwidelyashostsforrecognizingguestmetalions.[1~ 4] Thiacrownethersincorporatingonlysulfuratomsinringalsohavebeenstudiedasextractingreagentsforsomesoftmetalions.[5] On lyfewstudiesonmixed donorcrownethercontain ing… 相似文献
19.
SynthesisandCrystalStructureof[Na(DB18C6)(CH_3OH)]_2Mo_6O_(19)·(DB18C6)·(CH_3OH)¥ZhouYin-Zhuang;TuShu-Jie;JinXiang-Lin;LiuShun-... 相似文献
20.
合成并测定了2,11,14-三氯-5,8-二氧-3,4,9,10-双(4,4’-三氟甲苯并)-13,15-(2’,6’)吡啶环十五-1,12-二烯酮的单晶结构。晶体分子式C23H15F6N3O4,Mr=511.38,晶体属单斜晶系,空间群P21/c,晶胞参数a=6.732(2),b=15.751(4),c=20.420(8)A,β=96.54(3)°,V=2151.6A3,Z=4,Dc=1.579g/cm3,μ(MOKO)=1.360cm-1,F(000)=1040。分子含有A、B、C、D四个环,D、C苯环对称连有2个三氟甲基,中间A环为含氧、氮的十五员王冠大杂环,整个分子为近平面结构。 相似文献