Synchrotron x-ray-diffraction study of α-cristobalite at high pressure and high temperature

Abstract

Energy-dispersive x-ray diffraction using synchrotron radiation was carried out on α-cristobalite to 3 GPa and 350°C in a cubic anvil press. A cascading structural phase transition occurred beyond 0.61 GPa at room temperature. The transition was accompanied by a splitting of most of the a-cristobalite reflections: the (111) reflection at 0.61 GPa through the (211) reflections at 2.13 GPa, with many other lines between. The pressure of this transition decreased with increasing temperature.     

Condensed matter chemistry under ‘extreme’ high pressure–high temperature conditions

Improved techniques for high-pressure experiments have led to new studies of the structure and physical properties of materials compressed to extremely high densities. Now we must fully enable the field of condensed matter chemistry under extreme high-pressure conditions. This will require development of strategies for the analysis and control of the chemical composition during reactions between solid, liquid and fluid phases. Such approaches already exist within the fields of experimental geochemistry and petrology, and they can be readily adapted to the wider area of chemistry. The first consideration is the manipulation and determination of stable and metastable pressure–temperature phase diagrams, illustrated here for the one-component system Si. Next, relationships between P, T and the chemical composition, X, expressed in terms of the chemical potential (μ) or the activity–composition relations, can be used to constrain and determine components within the system. This is illustrated by examples drawn from our recent work on high-pressure syntheses of boron suboxides (B₆O_1???δ) and (Si, Ge)₃N₄ nitride spinels.     

Thermoelastic parameter αKT of sodium chloride at high pressure and high temperature

Two different potential models to the molecular dynamics (MD) simulations have been applied to investigate the thermoelastic parameter αK_T of sodium chloride (NaCl) under high pressure and high temperature. The first one is the shell model (SM) potential that due to the short-range interaction when pairs of ions are moved together as is the case in that polarization of a crystal due to the motion of the positive and negative ions, and the second one is the two-body rigid-ion Born–Mayer–Huggins–Fumi–Tosi (BMHFT) potential with full treatment of long-range Coulomb forces. Particular attention is paid to the comparison of the SM- and BMHFT-MD simulations with the Debye model for the first time, and this model combines with ab initio calculations within local density approximation (LDA) and generalized gradient approximation (GGA) using ultrasoft pseudopotentials and a plane-wave basis in the framework of density functional theory (DFT), and it takes into account the phononic effects within the quasi-harmonic approximation. Note that the MD calculated volumes using SM model is somewhat larger than both the DFT and experimental volumes despite not considering the temperature effect. Compared with SM potential, the MD simulated 300 K isotherm of NaCl with BMHFT potential is very successful in reproducing accurately the measured volumes and the GGA calculated volumes. Generally, it is found that there exist minor differences between the LDA and GGA computed the thermoelastic parameter αK_T of NaCl, with both average results giving good agreement with SM-MD simulations. At an extended pressure and temperature ranges, the variation of thermoelastic parameter αK_T which play a central role in the formulation of approximate equations of state has also been predicted. The properties of NaCl are summarized in the pressure range of 0–300 kbar and the temperature up to 2000 K.     

A portable high precision three dimensional trace measuring system for underwater target with high speed

The paper describes a portable high precision three-dimensionaltrace measuring system for underwater target with high speed.Themathematical model for location,the main error sources,the calibrationmethod for the underwater array and the way to correct its state are discussed.Problems about the distance ambiguity and multi-path interference are also an-alyzed.Part of experimental results on lake and at sea are given as well.     

Experimental study on high power all-fiber laser

<正>A high power all-fiber laser is experimentally studied.A monolithic fiber laser system with only one stage of resonator cavity is constructed and 404-W continuous wave(CW) output power is obtained.Its opticalto -optical conversion efficiency is up to 64%.The laser central wavelength is at 1081 nm with the spectral full-width at half-maximum(FWHM) of 2 nm.The laser setup can work with excellent stability;in the long time of high power operation,no thermal distortions or damages are observed.     

Fracture toughness evaluation of WC–10 wt% Co hardmetal sintered under high pressure and high temperature

This work focused on fracture toughness studies of WC–10?wt% Co hardmetal fabricated through the high pressure/high-temperature technique. A powder mixture of WC–10?wt% Co was sintered at 1500–1900°C under a pressure of 7.7?GPa for 2 and 3?min. Vickers hardness test at two different loads of 15 and 30?kgf was done and fracture toughness of the sintered bodies was measured using the indentation method to obtain the effect of sintering parameters. Structural analyses were also performed via X-ray diffraction to investigate structure-related properties. Full density was achieved for high sintering temperature along with abnormal grain growth that reduced hardness. High hardness was observed ranging from 1200 to 1670?HV and fracture toughness increased with increasing sintering temperature up to the highest value of 17.85?MPa/m^1/2.     

Output beam analysis of high power COIL

As the output power of a chemical oxygen iodine laser (COIL) increases, the output laser beam instability appears as the far-field beam spot drift and deformation for the large Presnel number unstable resonator. In order to interpret this phenomenon, an output beam mode simulation code was developed with the fast Fourier transform method. The calculation results show that the presence of the nonuniform gain in COIL produces a skewed output intensity distribution, which causes the mirror tilt and bulge due to the thermal expansion. With the output power of COIL increases, the mirror surfaces, especially the back surface of the scraper mirror, absorb more and more heat, which causes the drift and deformation of far field beam spot seriously. The initial misalignment direction is an important factor for the far field beam spot drifting and deformation.     

Ti:sapphire laser pumped high average power laser crystal Nd:GGG with high efficiency output

High-quality neodymium doped GGG laser crystals have been grown by Czochralski (Cz) method. Results of Nd:GGG thin chip laser operating at 1.064 μm pumped by Ti:sapphire laser operating at 808 nm were reported. The slop efficiency was as high as 20%.     

Compact oscillator-amplifier XeCl laser with high brightness

In this work we present the behavior of a very compact XeCl laser system.Itconsists of an oscillator and an amplifier,both with lateral UV-preionization.Both dischargeelectrodes are contained in a single vessel.An unstable optical cavity is applied to the oscilla-tor.An output beam of 105 mJ,with a brightness of 5.5× 10~(l3)Wcm~(-2)Sr~(-1) and with a diver-gence of 0.9 mrad has been obtained.     

Fiber Bragg grating hydrophone with high sensitivity

A fiber Bragg grating(FBG)hydrophone with high sensitivity was demonstrated.This hydrophone used a rubber diaphragm and a copper hard core as the sensing element.To compensate the hydrostatic pressure, a capillary tube was fixed at the end of the hydrophone.Theoretical analysis of the acoustic pressure sensitivity was given in this letter.Experiments were carried out to test the frequency response of the hydrophone.The result shows that when the Young's modulus of the diaphragm is higher,a flatter frequency response will be obtained.     

Double-sided laser heating system for in situ high pressure–high temperature monochromatic x-ray diffraction at the esrf

A new double-sided laser heating system optimized for monochromatic X-ray diffraction at high pressure and high temperature has been developed at beamline ID27 of the European Synchrotron Radiation Facility (ESRF). The main components of this system including optimized focusing optics to produce a large and homogenous heated area, optimized mirror optics for temperature measurements and a state-of-the-art diffraction setup are described in details. Preliminary data collected at high pressure and high temperature on tungsten and iron are presented.     

Laser-diode-pumped Cr4+, Nd3+:YAG self-Q-switched laser with high repetition rate and high stability

A diode end-pumped self Q-switched Cr⁴⁺, Nd³⁺: YAG laser was established with 30-ns pulse width (FWHM) and 0.5-μJ pulse energy output. In normal pulse pumping operation, the lasing threshold changed greatly from 122 mJ to 2.4 mJ as the pump pulse frequency varied from 1 Hz to 500 Hz due to pumping-induced thermal effect. A pre-pumping method was proposed and the change of the lasing threshold was reduced; programmable Q-pulse output with maximum frequency of 16 kHz and high stability was achieved. Received: 16 January 2001 / Revised version: 21 May 2001 / Published online: 19 September 2001     

500-W high average power,high beam quality Nd:YAG solid-state laser with one focusing reflector

In order to explore a 56-J high energy,high frequency lamp-pumped pulsed Nd:YAG solid-state laser, the main factors influencing the higher laser output energy are analyzed,the relation between output power and input power and reflectivity is simulated theoretically,and the effective measures to improve the efficiencies of the laser are brought forward.As a result,pulse width is tunable between 0.1 and 10 ms,frequency between 1 and 1000 Hz.When the input electrical power is 12 kW,the laser can output maximum single pulse energy of 56 J and average power of 500 W with the beam quality of 16.5 mm·mrad, total electro-optic efficiency of 4.2%,and the in stability of±2% output power.It is indicated that the parameters corresponds with the results of theoretical analysis and simulation.     

Frequency-stabilized semimonolithic frequency doubler with high output power

The frequency-doubled Nd:YAP laser with high out- put power is an important pumping source for quan- tum information, quantum optics, and nonlinear optics experiments[1-6]. Intracavity frequency-doubled[7-11] and external frequency-doubled lasers[12-18] are two usual methods to generate continuous second harmonic wave. For the former, the frequency-doubling nonlinear crystal and the active medium of the laser are put in the same resonant cavity, thus the process of frequency doubling possibly…     

AμSR apparatus with high time resolution

A high time resolutionSR apparatus is described. The set up is mainly used for precision measurements of the muonium hyperfine interaction.     

Ceramic synthesis of 0.08BiGaO_3–0.90BaTiO_3–0.02LiNbO_3 under high pressure and high temperature

In this paper, the preparation of 0.08BiGaO_3–0.90BaTiO_3–0.02LiNbO_3 is investigated at pressure 3.8 GPa and temperature 1100–1200?C. Experimental results indicate that not only is the sintered rate more effective, but also the sintered temperature is lower under high pressure and high temperature than those of under normal pressure. It is thought that the adscititious pressure plays the key role in this process, which is discussed in detail. The composition and the structure of the as-prepared samples are recorded by XRD patterns. The result shows that the phases of Ba TiO_3, BaBiO_(2.77), and Ba_2Bi_4Ti_5O_(18) with piezoelectric ceramic performance generate in the sintered samples. Furthermore, the surface morphology characteristics of the typical samples are also investigated using a scanning electron microscope. It indicates that the grain size and surface structure of the samples are closely related to the sintering temperature and sintering time. It is hoped that this study can provide a new train of thought for the preparation of lead-free piezoelectric ceramics with excellent performance.     

Effects of Mg on diamond growth and properties in Fe–C system under high pressure and high temperature condition

Diamond crystal crystallized in Fe–Mg–C system with Archimedes buoyancy as a driving force is established under high pressure and high temperature conditions. The experimental results indicate that the addition of the Mg element results in the nitrogen concentration increasing from 87 ppm to 271 ppm in the diamond structure. The occurrence of the {100}plane reveals that the surface character is remarkably changed due to the addition of Mg. Micro-Raman spectra indicate that the half width of full maximum is in a range of 3.01 cm~(-1)–3.26 cm~(-1), implying an extremely good quality of diamond specimens in crystallization.     

Crystal structure of the high pressure phases of bismuth bi iii and bi iii′ by high energy synchrotron x-ray diffraction

Abstract

This paper reports the results of a synchrotron X-ray diffraction study on the crystal structures of Bi 111 and Bi 111′ which have been known to form under high pressure but have, for a long time, been unsolved. Powdered samples were compressed in a cubic-type multi-anvil press, MAXID, and diffraction data were collected using an Imaging Plate with monochromatized radiation of an energy of 49.7 keV. It was possible to identify at 3.8 GPa forty-eight reflections for Bi I11 in the sin θ / δ range from 1.6 nm^?1 to 5.6 nm^?1, which were indexed in terms of a tetragonal unit cell with a=0.8659 nm and c═ O·4238 nm (2=10). Analysis based on the observed intensities of the reflections led to a structure in which atoms form a distorted body-centered cubic lattice. It is of the same type as the structure of the high pressure phase of antimony Sb 11. When pressure was increased across the suggested transition pressure 4.3 GPa between Bi III and Bi III′ to 6.6 GPa, no change in the diffraction pattern was observed, indicating that there is no distinction between the two phases as long as the crystal structure is concerned. Discussion is given on the sequence of high pressure phase transitions in the Group Vb elements.