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1.
The Thomas–Fermi approximation gives the Grüneisen parameter γ=γ∞=1/2 for all materials at extreme compression (P→∞ or V→0). After re-analyzing the existing experimental data of volume dependence of Grüneisen parameter γ of hexagonal close-packed (HCP) iron, we find that γ=1/2+a(V/V 0)1/3+b(V/V 0) n , where a, b and n are constants. Based on this new form of γ, the second Grüneisen parameter q, the Debye temperature θD and the shear sound velocity v s of HCP iron are discussed in the present work. It is found that the zero pressure second Grüneisen parameter q 0=0.654, which is consistent with the previously determined value of HCP iron for Earth's core physics from Dubrovinsky et al. The calculations for the Debye temperature and the shear sound velocity are also found to be in good agreement with the experimental data. 相似文献
2.
Semiempirical equations of state (EoS) of Au, Pt, MgO, NaCl-B1, and NaCl-B2 based on expanded Mie–Grüneisen–Debye approach, which are consistent both with the Mie–Grüneisen–Bose–Einstein approach and the thermochemical, X-ray, ultrasonic and shock-wave data in a wide pressure-temperature range, have been constructed. It is shown that to determine the volume dependence of the Grüneisen parameter, not only shock-wave and static compression data, but also experimental information on heat capacity, bulk moduli, volume, and thermal expansion coefficient at zero pressure need to be taken into account. Intrinsic anharmonicity is of great importance at construction of EoS at high temperatures and x=V/V 0>1. Cross-comparison of the current equations of state with independent measurements shows that these EoS may be used as the internally consistent and independent pressure scales in a wide range of temperatures and pressures. 相似文献
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The generalized Grüneisen parameters (γ′
j
) and (γ″
j
) for cadmium and zirconium were calculated from the second- and third-order elastic constants to determine the low temperature
limit of the volume thermal expansion of these metals of hexagonal symmetry. The low temperature limit of cadmium and zirconium
was calculated to be positive values indicating a positive volume expansion down to 0 K even though many Grüneisen gammas
were found to be negative. 相似文献
5.
Litov and Anderson after various considerations suggested a four constant potential function for a-Se as well as a-As2S3. Hence we also used a four constant potential function with the sole purpose of applying this potential function to obtain
several acoustic, thermodynamic and other properties. We calculated several acoustic properties of a-Se like second order
elastic constants (SOECs), their pressure derivatives, the longitudinal and transverse Grüneisen constant by two different
methods, phonon frequencies, absorption band position through the use of Nath-Smith-Delaunay’s equation, and the thermodynamic
properties like heat capacity, bulk modulus, thermal Grüneisen constant, the pressure derivative of the bulk modulus (dK
T/dP=C
1), the pressure derivative ofC
1 which is related to Anderson-Grüneisen parameter, pressure derivative of Grüneisen constant namelyγ′
g
which is related to second Grüneisen constant, characteristics of phonon frequencies, potential energy function through the
use of fitted parameters and third order elastic constants. Finally we calculatedK
T at the reduced density ofρ/ρ
0=1.1.K
T is obtained from the potential function with the fitted parameters. In all the above cases the calculated values are found
to be in good agreement with experiment wherever available. In this connection it is important to point out that we eliminated
‘C’ a constant in the potential function using the equilibrium condition as was done by Litovet al in a-Se and Gerlichet al in the case of a-As2S3 as all amorphous substances are isotropic as mentioned by several authors. We contemplate to calculate several other properties
for a-Se and a-As2S3 and present them at a later stage. 相似文献
6.
Abstract “Regular” linear relations between shock and particle velocities, us = us0, + c · up, imply a divergence of the Hugoniot pressure pH at a critical compression V c/V o = (c-1)/c, where the thermal pressure Δp th = (γ/V)· ΔU th = p H-p T becomes very large with respect to the cold (isothermal) pressure p T at this compression. The Hugoniot relation for the total internal energy U H results in this case in the relation γc = 2(c- 1) for the Grüneisen parameter in this region. Experimental data for the zero pressure value Γo and its derivative Γo together with theoretical data for the limiting value γ∞ = 2/3, and the additional expenmental value γc are then used to determine the thermal (phonon) pressure with the common Mie-Grüneisen assumption. 相似文献
7.
A revised model of volume dependence of Anderson–Grüneisen parameter for lower mantle under adiabatic condition is presented in this study, and the volume dependence of (α T/C P =α ′) is then discussed. It is shown that the results are in good agreement with seismic data of the Earth. 相似文献
8.
基于Gray金属三相状态方程模型,分别采用ργ=常数,Gray,GRIZZLY的Grüneisen系数模型和从头算给出的Grüneisen系数,系统计算了铝的熔化曲线、等熵压缩线、等温压缩线和等熵卸载线,计算结果与实验数据比较表明;在冲击压力约为500GPa的宽广压力范围,GRIZZLY Grüneisen系数模型是最适合描述铝的热力学特性的形式,ργ=常数模型次之,在高压区,Gray和从头算的Grüneisen系数的计算结果与实验值差距较大.
关键词:
Grneisen系数
状态方程
铝 相似文献
9.
在活塞圆筒式p-V关系测量装置上,研究了KH2PO4(KDP)和(CH3NHCH2COOH)CaCl2[Tris-sarcosine calcium chloride(TSCC)]在室温下、4.5 GPa内的p-V关系。实验结果表明:KDP在2.1 GPa左右有一个相变;TSCC在0.8 GPa和3.2 GPa左右各有一个相变。本工作还给出了它们在相变前后的状态方程,以及它们的格临爱森参数γ0、体积模量B0和B0的压力导数B0'。 相似文献
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The general expression for the Anderson-Grüneisen parameterδ recently derived by Gupta and others, has been used to study the variation ofδ with the Grüneisen parameterγ employing the interaction approach. For this purpose four potential energy functions have been selected. It is found thatδ values evaluated by the modified Varshni-Shukla potential are better than other forms of overlap repulsive interaction. The
variation ofδ withγ is also studied by plotting curves betweenδ andγ. The method of least-squares has been employed to yield the best fitted equation. 相似文献
13.
B K Sharma 《Pramana》1980,14(6):477-483
We test the validity of an approximate equation of state of real fluids and the expression for surface tension of hardsphere
liquids with attractive interactions derived by Sharma and others by obtaining expressions for isothermal compressibility,C
1-parameter and acoustical parameter and relate them to microscopic Grüneisen parameter. The calculated values for liquid fluorine
show fair agreement with experimental values. 相似文献
14.
The lattice parameters of CdF2 andβ-PbF2 have been determined over the temperature range 300–670 K. The coefficient of expansion at room temperature is 21·3 × 10−6 K−1 and 25·4 × 10−6 K−1 for CdF2 and PbF2 respectively and it increases linearly with temperature over the range of temperature covered. The Grüneisen parameter decreases
with temperature in both the crystals. 相似文献
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16.
Jeffery L. Tallon 《Journal of Physics and Chemistry of Solids》1980,41(8):837-850
The isobaric and isothermal volume derivatives of In B, In μ and In μ' are investigated, where B, μ and μ' are the isothermal bulk modulus and the two shear moduli, respectively, of a cubic crystal. In the case of the bulk modulus, the temperature independence of αB (where α is the volume thermal expansion) for a large number of materials, ensures that the derivatives are constant and approximately equal, while for the shear moduli, evidence is advanced that the isothermal derivatives are constant along an isotherm, but not along an isobar except at high temperatures near the melting point. The relationships satisfied by the bulk modulus enable the explicit temperature and pressure dependence of the molar volume, V, thermal expansion, and bulk modulus to be determined. The most adequate representation of the volume dependence of the Grüneisen parameter, γ, appears to be that γ/V is independent of volume between the Debye and melting temperatures. 相似文献
17.
A.C. Lawson 《哲学杂志》2013,93(19):2150-2161
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