Anisotropic distributions of electrical currents in high-<Emphasis Type="Italic">T</Emphasis><Subscript><Emphasis Type="Italic">c</Emphasis></Subscript> grain-boundary junctions

We developed a self-consistent method for the calculation of spatial current distributions in high-T _c grain-boundary junctions. It is found that crystallographic anisotropy of high-T _c superconducting electrodes results in the effects, which previously were not taken into account for interpretations of experimental data. Among them is a significant redistribution of electrical currents in superconducting electrodes in the vicinity of a grain boundary. In particular in the case of [100]-tilt bicrystal junctions, this current redistribution results in a substantial focusing to the top or bottom part of a thickness of the grain boundary, depending on “roof”- or “valley”-type of the grain boundary. This redistribution is accompanied by generation of vortex currents around the grain boundary, which leads to self-biasing of grain-boundary junctions by magnetic field nucleated by these vortex currents. It is shown that twinning or variation of geometrical shape of the high-T _c electrode may also result in intensive redistribution of electrical currents and nucleation of local magnetic fields inside a high-T _c superconducting electrodes.     

Disordering effects in superconductors with anisotropic pairing: From Cooper pairs to compact bosons

In the weak-coupling BCS-theory approximation, normal impurities do not influence the superconducting transition temperature T _c in the case of isotropic s pairing. In the case of d pairing they result in a rapid destruction of the superconducting state. This is at variance with many experiments on the disordering of high-T _c superconductors, assuming that d pairing is realized in them. As the interelectronic attraction in a Cooper pair increases, the system transforms continuously from a BCS-type superconductor with “loose” pairs to a picture of superconductivity of “compact,” strongly coupled bosons. Near such a transition substantial deviations can be expected from the universal disorder dependence of T _c , as determined by the Abrikosov-Gor’kov equation, and T _c becomes more stable against disordering. Since high-T _c super-conducting systems fall into the transitional region from BCS-type pairs to compact bosons, these results can explain their relative stability against disordering. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 3, 258–262 (10 February 1997)     

Coated conductors containing grains with big aspect ratios

It is shown that the critical currents of high‐T_csuperconducting tapes fabricated by the coated conductor technologies are enhanced considerably if grain arrangements with large effective grain boundary areas are used. Increasing the aspect ratios of the grains reduces the deleterious effects of the grain boundaries. A practical road to competitive high‐T_ccables is proposed.     

Chiral superconducting phase transition in 3-K phase of Sr2RuO4

We have investigated the transports of micro-fabricated sample of 3-K phase superconductivity (T_c  3 K) in Sr₂RuO₄–Ru eutectic system in order to clarify the pairing symmetry. Up to now, pure Sr₂RuO₄ (T_c = 1.5 K: 1.5-K phase) is widely recognized to be a spin-triplet odd-parity superconductor. However, the enhancement mechanism of T_c up to 3 K and the pairing symmetry of the 3-K phase have not been cleared yet. By using micro fabrication technique with focused ion beam, we have succeeded to extract individual superconducting channels for the 3-K phase in which only a few pieces of Ru inclusions are contained. Multiple kink structures observed in differential resistance–current (dV/dI − I) characteristics indicate serially connected superconducting filaments in the 3-K phase. We confirm that the 3-K phase is an odd-parity superconductor similar to pure Sr₂RuO₄ from the monotonous temperature dependence of the critical currents. In addition, we observed a quite unusual hysteresis in dV/dI − I below 2 K, which suggests the internal degrees of freedom in the superconducting state: the most probably the chiral p-wave state.     

High-T c superconducting Bi−Sr−Ca−Cu−O thin films prepared by laser-induced plasma deposition

High-T _c superconducting thin films of Bi–Sr–Ca–Cu oxides were prepared by laser-induced plasma deposition of high-T _c superconducting Bi₂Sr₂Ca₁Cu₂O_x and Bi₂Sr₂Ca₂Cu₃O_x targets in vacuum and a short post-annealing in air at 875°C. Thin films (thickness <500 nm) with a critical temperatureT _c -onset of 95 K can be prepared on silicon substrate material with a SrTiO₃ interface layer. The thin films were completely superconducting between 80 and 90 K. The stoichiometry transfer of superconducting target material by laser-induced plasma deposition was investigated.     

Peak effect in surface resistance at microwave frequencies in Dy-123 thin films

A pronounced peak in the microwave (at frequency 9.55 GHz) surface resistance, R _s vs. T plot (where T is the temperature) has been observed in epitaxial DyBa₂Cu₃O_7−y superconducting thin films in magnetic fields (parallel to c-axis) in the range 2 to 8 kOe, and temperatures close to the superconducting transition temperature T _c(H). Our data suggest that the nature of peaks observed in the two films is different, thereby indicating different defect structures in the films.     

Role of anisotropy of the coupling constant in a superconductor model with singularities near the Fermi surface

The role of anisotropy of the coupling constant in the influence of nonmagnetic impurities on the behavior of the superconducting transition temperature T _c is investigated in the high-temperature superconductor (HTSC) model, where high values of T _c result from an increase in the density of states near the Fermi surface. It is shown that this model is more sensitive to impurities than the BCS model; Anderson compensation does not occur in the HTSC model, even for identical distributions of the densities of states in the superconducting and impurity channels, and the impurity contributions are no longer linear with respect to the impurity concentration in the vicinity of T _c. Anisotropy of the superconducting gap Δ and the possibility of its disappearance at certain points on the Fermi surface due to various types of pairing are manifested in the stability of the superconducting phase against the influence of impurities. Fiz. Tverd. Tela (St. Petersburg) 39, 1940–1942 (November 1997)     

Thin film synthesis and the influence of irradiation-induced defects on the superconductivity of La1.8Sr0.2CuO4

Thin superconducting films of La_1.8Sr_0.2CuO₄ have been prepared by magnetron sputter deposition and subsequent temperature treatment. The composition of the films has been determined by Rutherford backscattering and the structure by thin film X-ray diffraction. The onset of superconductivity was about 32 K and the midpoint near 28 K. Defect production in the films by He ion bombardment revealed a drasticT _c reduction with a sensitivity similar to that observed in the Chevrel phases. Oxygen implantation and subsequent annealing led to an enhancement of theT _c onset.     

Arrays of interacting ferromagnetic nanofilaments: Small-angle neutron diffraction study

Magnetic properties of spatially ordered arrays of interacting nanofilaments have been studied by means of small-angle diffraction of polarized neutrons. Several diffraction maxima or rings that correspond to the scattering of the highly ordered structure of pores/filaments with hexagonal packing have been observed in neutron scattering intensity maps. The interference (nuclear-magnetic) and pure magnetic contributions to the scattering have been analyzed during the magnetic reversal of the nanofilament array in a field applied perpendicular to the nanofilament axis. The average magnetization and the interference contribution proportional to it increase with the field and are saturated at H = H _S . The magnetic reversal process occurs almost without hysteresis. The intensity of the magnetic contribution has hysteresis behavior in the magnetic reversal process for both the positive and negative fields that form the field dependence of the intensity in a butterfly shape. It has been shown that this dependence is due to the magnetostatic interaction between the filaments in the field range of H ≤ H _S . A theory for describing the magnetic properties of the arrays of interacting ferromagnetic nanofilaments in the magnetic field has been proposed.     

The effect of dielectric coating on the superconductivity of aluminum films

We report measurements on the changes of the superconducting transition temperatureT _c and the normal resistanceR _n of quench condensed aluminum films during dielectric coating. N₂ and noble gas coatings result in an exponential change of the superconducting properties due to the modification of the phonon spectrum. O₂ and Se coatings result in a nonmonotonic change ofT _c andR _n due to charge transfer processes and resonance scattering of the electrons into localized states within the coating layers.     

On the preparation and the characterization of superconducting thin films of YBa2Cu3O7−x

The results of our initial efforts to deposit thin films of YBa₂Cu₃O_7−x system on sapphire substrate are described. The deposited films are shiny black in appearance and are of quite uniform chemical composition. The annealed films exhibit zero resistance superconducting transition temperatureT _c(R=0) ranging between 23 K and 30 K.     

Direct angle resolved photoemission spectroscopy and superconductivity of strained high-T c films

Since 1997 we systematically perform direct angle resolved photoemission spectroscopy (ARPES) on in-situ grown thin (<30 nm) cuprate films. Specifically, we probe low-energy electronic structure and properties of high-T _c superconductors (HTSC) under different degrees of epitaxial (compressive vs. tensile) strain. In overdoped and underdoped in-plane compressed (the strain is induced by the choice of substrate) ≈15 nm thin La_{2 − x} Sr _x CuO₄ (LSCO) films we almost double T _c to 40 K, from 20 K and 24 K, respectively. Yet the Fermi surface (FS) remains essentially two-dimensional. In contrast, ARPES data under tensile strain exhibit the dispersion that is three-dimensional, yet T _c drastically decreases. It seems that the in-plane compressive strain tends to push the apical oxygen far away from the CuO₂ plane, enhances the two-dimensional character of the dispersion and increases T _c, while the tensile strain acts in the opposite direction and the resulting dispersion is three-dimensional. We have established the shape of the FS for both cases, and all our data are consistent with other ongoing studies, like EXAFS. As the actual lattice of cuprates is like a ‘Napoleon-cake’, i.e. rigid CuO₂ planes alternating with softer ‘reservoir’, that distort differently under strain, our data rule out all oversimplified two-dimensional (rigid lattice) mean field models. The work is still in progress on optimized La-doped Bi-2201 films with enhanced T _c.      

Growth and magnetic characterization of YBCO films

Summary Epitaxial films of YBa₂Cu₃O_7−x were depositedin situ on LaAlO₃ substrates using single-target 90° off-axis sputtering. The films were characterized by magnetization measurements (M vs. T, H), applying the field parallel toc-axis. The observed differences in theT _c andJ _c values are attributed to the different oxygen content in the superconducting films. Paper presented at the ?VII Congresso SATT?, Torino, 4–7 October 1994.     

Theory of superconductivity in strongly correlated materials: Application to cuprate superconductors

A microscopic theory of superconductivity in systems with strong electron correlations is considered within the Hubbard model. The Dyson equation for the matrix Green function in terms of the Hubbard operators is derived and solved in the noncrossing approximation for the self-energy. Two channels of superconducting pairing are revealed: mediated by antiferromagnetic (AFM) exchange and spin-fluctuations. It is proved that AFM exchange interaction results in pairing of all electrons in the conduction band and high T _c proportional to the Fermi energy. T _c dependence on lattice constants (or pressure) and an oxygen isotope shift of T _c are explained. The text was submitted by the author in English.     

Effect of elastic strain and stress on the superconducting transition temperature of quench-condensed films

The volume dependence of the superconducting transition temperatureT _c of amorphous and highly disordered films is investigated by bending the film substrate. The volume coefficientd InT _c /d InV of annealed Sn and Pb films agrees with the volume coefficient known from hydrostatic pressure experiments. This bending technique is applied to superconducting modifications which can be produced only by quench condensation onto a substrate at liquid helium temperature. Amorphous films such as Bi, Ga, Sn₉₀Cu₁₀ and Pb_xBi_1–x, as well as highly disordered Sn and Pb films, are investigated. The relations found between the volume coefficient, the electron-phonon coupling constant and the Grüneisen parameter _G are in reasonable agreement with the volume dependence ofT _c for non-transition metals, obtained on the basis of the McMillan equation. In particular, the results represent an expansion of this kind of investigation to very strong-coupling superconductors.Dedicated to Prof. Dr. W. Buckel on the occasion of his 60th birthdayPaper based in part on a Habilitationsschrift submitted to the Fakultät für Physik, Universität Karlsruhe (TH)     

Metastable phases in YBCO films created by short-term annealings

The effect of short-term low-temperature annealing in air and in vacuum on the properties of HTSC films of YBCO is studied. It is shown that, under certain conditions of preparation of initial samples, a transition from the HTSC phase with the superconducting transition temperature T_c=90 K to a phase with T_c=60 K occurs without a noticeable change in the oxygen content. It is found that, as a result of short-term annealings, a transition from the HTSC phase with T_c=60 K to the phase with T_c=90 K can occur only through the vacuum annealing stage, which converts the sample into the superconducting state. Short-term annealings lead to multiple reversible “switching” of the films from one phase to another. The obtained results are of practical interest, since the proposed method can be used to quickly obtain superconducting YBCO films in various phase states. It is shown, in addition, that the annealing procedure makes it possible not only to increase the oxygen concentration but also to produce a structural rearrangement of a YBCO film.     

Superconductivity of vapour quenched beryllium and beryllium-based alloys

The properties of Be films, quench-condensed upon a³He cooled substrate, have been investigated by resistance and tunneling measurements. The superconducting transition temperature,T _c , of Be films increased with thickness and a thick film limit of 9.95 K could be estimated. Alloying with Al or Pb decreasedT _c. The ratios between energy gaps andT _c 's indicated that Be is a weak coupling superconductor, and no phonon induced structure could be traced in tunneling curves neither in pure Be nor in the Be based alloys. Resistance change during annealing as well as superconducting data indicated that the vapour quenched Be films were amorphous as deposited.