基于金属型碳纳米管在电场中变形的柱壳理论

提出了关于金属型碳纳米管在电场中变形的柱壳理论．借助于半球模型,得到了金属型碳纳米管在电场中的电荷与电场分布的解析解．将带电碳原子所受的电场力看作是碳纳米管的内力,根据柱壳理论碳纳米管在电场中的变形被解析地给出．结果表明:碳纳米管的长径比对碳纳米管在电场中的变形有重大影响,长径比越大,碳纳米管的变形越明显;碳纳米管的径向变形沿轴向是不均匀的,最大的径向变形出现于碳纳米管的端部;更为有意义的是,即使外加电场不够大,对于长径比很大的碳纳米管仍然可以表现出明显的变形．     

Vibration characteristics of single-walled carbon nanotubes based on an anisotropic elastic shell model including chirality effect

Single-walled carbon nanotubes (SWCNTs) exhibit remarkable chirality-dependent mechanical phenomena. In present paper, an anisotropic elastic shell model is developed to study the vibration characteristics of chiral SWCNTs. Analytical solution is presented by using the Flügge shell theory and complex method. The suggested model is justified by a good agreement between the present results and some experimental and numerical available data in literature. Furthermore, the model is used to elucidate the effect of tube chirality on the frequencies of SWCNTs. Finally, the influences of the externally applied mid-face axial force and torque on longitudinal, radial and torsional frequencies of SWCNTs are investigated.     

Torsional vibration of single-walled carbon nanotubes using doublet mechanics

This paper investigates the torsional vibration of single-walled carbon nanotubes (SWCNTs) using a new approach based on doublet mechanics (DM) incorporating explicitly scale parameter and chiral effects. A fourth-order partial differential equation that governs the torsional vibration of nanotubes is derived. Using DM, an explicit equation for the natural frequency in terms of geometrical and mechanical property of CNTs is obtained for both the Zigzag and Armchair nanotube for the torsional vibration mode. It is shown that chiral effects along with the scale parameter play a significant role in the vibration behavior of SWCNTs in torsional vibration mode. Such effects decrease the natural frequency obtained by DM compared to the classical continuum mechanics and nonlocal theory predictions. However, with increase in the length and/or the radius of the tube, the effect of the chiral and scale parameter on the natural frequency decreases.     

Fabrication of Pt deposited on carbon nanotubes and performance of its polymer electrolyte membrane fuel cells

A new method of depositing nano-sized Pt particles on the surface of the carbon nanotubes was introduced, and the performance of Pt/carbon nanotube compound on polymer electrolyte membrane fuel cells was measured. The experimental results show that the fine platinum particles (about 3 nm) were well dispersed on carbon nanotubes, which demonstrates the excellent catalytic properties of the Pt/CNTs compound in polymer electrolyte membrane fuel cells.     

Small scale effect on vibrational response of single-walled carbon nanotubes with different boundary conditions based on nonlocal beam models

The free vibration response of single-walled carbon nanotubes (SWCNTs) is investigated in this work using various nonlocal beam theories. To this end, the nonlocal elasticity equations of Eringen are incorporated into the various classical beam theories namely as Euler-Bernoulli beam theory (EBT), Timoshenko beam theory (TBT), and Reddy beam theory (RBT) to consider the size-effects on the vibration analysis of SWCNTs. The generalized differential quadrature (GDQ) method is employed to discretize the governing differential equations of each nonlocal beam theory corresponding to four commonly used boundary conditions. Then molecular dynamics (MD) simulation is implemented to obtain fundamental frequencies of nanotubes with different chiralities and values of aspect ratio to compare them with the results obtained by the nonlocal beam models. Through the fitting of the two series of numerical results, appropriate values of nonlocal parameter are derived relevant to each type of chirality, nonlocal beam model, and boundary conditions. It is found that in contrast to the chirality, the type of nonlocal beam model and boundary conditions make difference between the calibrated values of nonlocal parameter corresponding to each one.     

Vibration of carbon nanotube reinforced composite beams based on the first and third order beam theories

This paper investigates the linear free vibration of nanocomposite beams reinforced by single-walled carbon nanotubes (SWCNTs). Two types of CNT reinforced beams, namely uniformly distributed CNT reinforced (UD-CNT) beams and functionally graded CNT reinforced (FG-CNT) beams, are considered. It is assumed that the SWCNTs are aligned along the beam axial direction and the distribution of the SWCNTs may vary through the thickness of the beam. The virtual strain and kinetic energies of the FG-CNT composite beam are obtained using the classic variational method of Hamilton’s principle and then solved by the p-Ritz method. Vibration frequency parameters for the FG-CNT beams based on the first order and third order beam theories are presented and the effects of CNT filler volume fraction, distribution, beam span to depth ratio and end support conditions on the free vibration characteristics of the beams are discussed. Comparison studies for UD-CNT and FG-CNT beams based on the first order and the third order beam theories are also performed and the differences in vibration frequencies between these two theories are highlighted.     

A finite difference scheme for solving a nonlinear hyperbolic two-step model in a double-layered thin film exposed to ultrashort-pulsed lasers with nonlinear interfacial conditions

Hyperbolic two-step microscale heat transport equations have attracted attention in thermal analysis of thin metal films exposed to ultrashort-pulsed lasers. Exploration of temperature-dependent thermal properties is absolutely necessary to advance our fundamental understanding of microscale (ultrafast) heat transport. In this article, we develop a finite difference scheme, by obtaining an energy estimate, for solving the hyperbolic two-step model with temperature-dependent thermal properties in a double-layered microscale thin film with nonlinear interfacial conditions irradiated by ultrashort-pulsed lasers. The method is illustrated by investigating the heat transfer in a gold layer on a chromium layer.     

Dynamic analysis of functionally graded nanocomposite beams reinforced by randomly oriented carbon nanotube under the action of moving load

This work deals with a study of the vibrational properties of functionally graded nanocomposite beams reinforced by randomly oriented straight single-walled carbon nanotubes (SWCNTs) under the actions of moving load. Timoshenko and Euler-Bernoulli beam theories are used to evaluate dynamic characteristics of the beam. The Eshelby-Mori-Tanaka approach based on an equivalent fiber is used to investigate the material properties of the beam. An embedded carbon nanotube in a polymer matrix and its surrounding inter-phase is replaced with an equivalent fiber for predicting the mechanical properties of the carbon nanotube/polymer composite. The primary contribution of the present work deals with the global elastic properties of nano-structured composite beams. The system of equations of motion is derived by using Hamilton’s principle under the assumptions of the Timoshenko beam theory. The finite element method is employed to discretize the model and obtain a numerical approximation of the motion equation. In order to evaluate time response of the system, Newmark method is also used. Numerical results are presented in both tabular and graphical forms to figure out the effects of various material distributions, carbon nanotube orientations, velocity of the moving load, shear deformation, slenderness ratios and boundary conditions on the dynamic characteristics of the beam. The results show that the above mentioned effects play very important role on the dynamic behavior of the beam and it is believed that new results are presented for dynamics of FG nano-structure beams under moving loads which are of interest to the scientific and engineering community in the area of FGM nano-structures.     

Morphology, structure and Raman scattering of carbon nanotubes produced by using mesoporous materials

Carbon nanotubes were prepared by chemical vapor deposition (CVD) of hydrocarbon gas on various substrates. The effect of substrates on the growth, morphology and structure of carbon nanotubes were investigated. Aligned carbon nanotubes with high density and purity were achieved by CVD on mesoporous silica substrate. The Raman scattering of aligned carbon nanotubes was carried out, and the dependence of the phonon properties on the microstructure of the nanotubes has been discussed.     

Dynamic stability of carbon nanotubes reinforced composites

Based on an effective model of multi-walled carbon nanotubes and Donnell-shell theory, an analytical method is presented to study dynamic stability characteristics of multi-walled carbon nanotubes reinforced composites considering the surface effect of carbon nanotubes. From obtained results it is seen that carbon nanotubes composites, under combined static and periodic axial loads, may occur in a parametric resonance, the parametric resonance frequency of dynamic instability regions of CNTs reinforced composites under axially oscillation loading enhances as the stiffness of matrix surrounding CNTs increases, and the surface effective modulus and residue stress of carbon nanotubes make the parametric resonance frequency and the region breadth of dynamic instability of carbon nanotubes reinforced composites increase.     

Tensile and tribological properties of a short-carbon-fiber-reinforced peek composite doped with carbon nanotubes

The main objective of this paper is to develop a high-wear-resistant short-carbon-fiber-reinforced polyetheretherketone (PEEK) composite by introducing additional multiwall carbon nanotubes (MWCNTs) into it. The compounds were mixed in a Haake batch mixer and fabricated into sheets by compression molding. Samples with different aspect ratios and concentrations of fillers were tested for wear resistance. The worn surfaces of the samples were examined by using a scanning electron microscope (SEM), and the photomicrographs revealed a higher wear resistance of the samples containing the additional carbon nanotubes. Also, a better interfacial adhesion between the short carbon fibers and vinyl ester in the composite was observed.     

Modeling large amplitude vibration of matrix cracked hybrid laminated plates containing CNTR-FG layers

This paper presents the mathematical modeling of the nonlinear vibration behavior of a hybrid laminated plate composed of carbon nanotube reinforced functionally graded (CNTR-FG) layers and conventional fiber reinforced composite (FRC) layers. Three type symmetric distributions of single walled carbon nanotubes (SWCNTs) through the thickness of layers are considered. The cracks are modeled as aligned slit cracks across the ply thickness and transverse to the laminate plane. The distribution of cracks is assumed to be statistically homogeneous corresponding to an average crack density. The obtained partial differential equations are solved by the element-free kp-Ritz method, and the iteration process is dealt with using the linearized updated mode method. Detailed parametric studies are conducted investigate the effects of matrix crack density, CNTs distributions, CNT volume fraction, plate aspect ratio and plate length-to-thickness ratio, boundary conditions and number of layers on the frequency-amplitude responses of hybrid laminated plates containing CNTR-FG layers.     

Frequency analysis of carbon and silicon nanosheet with surface effects

Silicon-based microelectromechanical system (MEMS) and nanoelectromechanical systems (NEMS) have been used to design and fabricate sensitive sensors and actuators. Recent research trends show that graphene and carbon nanotubes (CNTs) have been used to change the surface properties of silicon-based MEMS and NEMS to improve different mechanical, optical and electrical properties of silicon-based composites. In this paper, we focus on analyzing the vibrational characteristics of silicon-based devices when the surface of silicon is coated with single-layer graphene and horizontally aligned carbon nanotubes (HACNTs). To perform the analysis, we use multi-scale finite element approach for developing graphene–silicon nanocomposites (GSNCs) and carbon nanotube-silicon nanocomposites (CSNC) composites in which interface layer of silicon with graphene or CNT is modeled using bonded contact element. Subsequently, we performed modal analysis to find the first transverse mode frequency of GSNC and CSNC composites for beam with smaller as well as longer lengths. The numerical model is compared with classical beam theory with and without surface effect. For GSNCs composites, we take a fixed-free case with lengths in the range of (20 Å–120 Å) and (400 Å–2000 Å), respectively. For CSNC composites, CNT diameter is varied from (5 Å–30 Å) for single walled nanotube. Subsequently, we analyze the influence of HACNTs-on-silicon on its vibrational characteristics. The analysis presented in the paper demonstrate that GSNCs offer a higher bending stiffness compared to single layer graphene (SLGs) and isolated silicon nanosheet which lead to higher natural frequency. A similar trend is found in the case of HACNTs on silicon NS when the number of tubes increases.     

Rotating response on the vibrations of functionally graded zigzag and chiral single walled carbon nanotubes

This study deals with the vibration analysis of zigzag and chiral rotating functionally graded carbon nanotubes (FG-CNT) invoking Love's shell theory using wave propagation approach. The frequency equation is formed in the eigenvalue form. It has been shown that with the increase of angular speed, frequencies of forwarding curve decrease and backward curve increase. The phenomena of frequency versus length-and height-to-radius ratios are noted as decreasing and increasing, respectively, for rotating CNTs. The backward and forward frequency curves of clamped-free are lower throughout the computation than the clamped-clamped zigzag and chiral carbon nanotube depending upon the rotating speed. MATLAB software is used to calculate the rotating (backward and forward) frequencies of SWCNTs and the frequency peaks in the present results show excellent stability across a wide range of parameters. Using geometrical and material parameters, the vibration results are given in tabular and graphical form. It is thus desirable to produce more precise estimations of the vibrational frequencies of CNTs. The present results are compared with earlier literature using simply supported boundary conditions and show a good coincidence.     

Theoretical model for swirling thin film flows inside nozzles with converging-diverging shapes

A quasi-one-dimensional model was developed to describe a swirling, thin, liquid film inside nozzles with different wall profiles. The model quantifies the effects of swirl strength, initial film thickness, and Reynolds and Weber numbers on the film thickness along the nozzle surface. Moreover, the model allows for a rapid (at least, qualitative) evaluation of different effects, e.g. of the swirl strength and nozzle geometry, and can serve as a benchmark case for the subsequent more involved numerical simulations. Steady-state solutions are presented as a function of various parameters. The effect of the nozzle geometry on film thickness is explored. As swirling flow entered the expanding (diverging) section of the nozzle, film thickness decreased to satisfy continuity (to conserve mass). Conversely, film thickness increased upon entering the contracting (converging) region of the nozzle. Geometric effects controlled film thicknesses much more than other flow parameters. This quasi-one-dimensional model for a swirling thin film can be useful for designing a swirl jet used in various industrial applications.     

On the behaviour of thin liquid layers at curved solid edges

The knowledge of the behaviour of thin liquid layers on solid surfaces is of fundamental interest as far as basic research and applications like technical covering or lubrication processes are concerned. The subject is currently of increasing importance, particularly due to stronger requirements of thin liquid layer functionalities. We therefore studied the development of the liquid layer thickness distribution field as well as the liquid layer disturbance propagation on a plane solid surface in the vicinity of a curved solid edge experimentally using LIF technique. The investigation focusses on the influence of the initial layer thickness as well as on liquid properties like viscosity and surface tension on the liquid film behaviour, especially close to solid edges. Selected experimental results are shown highlighting relevant quantities with respect to disturbance propagation and validation. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Transient film profile of thin liquid film flow on a stretching surface

In this paper we have studied a non-planar thin liquid film flow on a planar stretching surface. The stretching surface is assumed to stretch impulsively from rest and the effect of inertia of the liquid is considered. Equations describing the laminar flow on the stretching surface are solved analytically. It is observed that faster stretching causes quicker thinning of the film on the stretching surface. Velocity distribution in the liquid film and the transient film profile as functions of time are obtained. (Received: May 4, 2004; revised: February 2/August 24, 2005)     

Change in the Surface Properties of Carbon Fibers as a Result of Plasmochemical Modification

The influence of plasmochemical modification of carbon fibers on their surface properties and compatibility with the PTFE matrix is investigated. It is shown that the thin PTFE coating formed on the carbon fiber surface improves the wetting of the fibers by PTFE. As a result, the mechanical characteristics of PTFE-based composites are improved.     

Leveling a capillary ridge generated by substrate geometry

The formation of capillary ridges is typical of thin viscous films flowing over a topographical feature. This process is studied by using a two-dimensional model describing the slow motion of a thin viscous nonisothermal liquid film flowing over complex topography. The model is based on the Navier-Stokes equations in the Oberbeck-Boussinesq approximation. The density, surface tension, and viscosity of the liquid are linear functions of temperature. For a nonisothermal flow over a planar substrate with a local heater, the influence of the heater on the free surface is analyzed numerically depending on the buoyancy effect, Marangoni stresses, and variable viscosity. The analysis shows that the film can create its own ridges or valleys depending on the heater and the dominating liquid properties. It is shown that the capillary ridges generated by the substrate features can be optimally leveled by using various types of heaters consistent with the dominating liquid properties. Numerical results for model problems are presented.     

A new higher‐order accurate numerical method for solving heat conduction in a double‐layered film with the neumann boundary condition

Heat conduction in multilayered films with the Neumann (or insulated) boundary condition is often encountered in engineering applications, such as laser process in a gold thin‐layer padding on a chromium thin‐layer for micromachining and patterning. Predicting the temperature distribution in a multilayered thin film is essential for precision of laser process. This article presents an accurate finite difference (FD) scheme for solving heat conduction in a double‐layered thin film with the Neumann boundary condition. In particular, the heat conduction equation is discretized using a fourth‐order accurate compact FD method in space coupled with the Crank–Nicolson method in time, where the Neumann boundary condition and the interfacial condition are approximated using a third‐order accurate compact FD method. The overall scheme is proved to be convergent and hence unconditionally stable. Furthermore, the overall scheme can be written into a tridiagonal linear system so that the Thomas algorithm can be easily used. Numerical errors and convergence rates of the solution are tested by an example. Numerical results coincide with the theoretical analysis. © 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 30: 1291–1314, 2014