Properties of Graphene/Waterborne Polyurethane Nanocomposites Cast from Colloidal Dispersion Mixtures

Nanocomposites of waterborne polyurethane (WPU) reinforced with functionalized graphene sheets (FGSs) were effectively prepared by casting from a colloidal dispersion of FGS and WPU, and the morphology and physical properties were examined. The finer aqueous FGS dispersions or WPU with smaller particles yielded nanocomposites with enhanced electrical conductivity and thermal resistance due to finely dispersed FGS. The FGS nucleated the crystallization of the polycaprolactone (PCL) segments in WPU and improved its modulus. However, FGS inhibited crystal growth and deteriorated the tensile properties at high deformation, i.e., tensile strength and elongation at break, because the interaction between FGS and WPU hindered the chain rearrangement of WPU in the nanocomposite.     

Structure of Some 4f Rare Earth Liquid Metals - A Charged Hard Sphere Approach

A well-established pseodopotential is used to study the structure of some 4f rare earth liquid metals (Ce,Pr, Eu, Gd, Tb, and Yb). The structure factor S(q), pair distribution function g(r), interatomic distance r1, and coordination number n1 are calculated using Charged Hard Sphere (CHS) reference system. To introduce the exchange and correlation effects, the local field correction due to Sarkar et al. (S) is applied. The present investigation is successful in generating the structural information of Ce, Pr, Eu, Gd, Tb, and Yb 4f rare earth liquid metals.     

高速相干光通信系统中残留色散均衡器研究

在高速相干光通信系统中,完全使用电子色散补偿时会引入均衡增强相位噪声.本文提出在已有10Gbit/s光纤通信链路上使用电子色散补偿来补偿残留色散的混合色散补偿方案,实现了特定通道100Gbit/s以上高速数据传输.使用虚拟光学仪器软件仿真了在112Gbit/s相干光通信系统中,分别采用有限脉冲响应均衡器和重叠频域均衡器对现有光纤信道进行残留色散补偿后的系统性能.仿真结果表明:相同的抽头长度下,有限脉冲响应均衡器相比重叠频域均衡器有更好的残留色散补偿能力,并且有限脉冲响应均衡器均衡性能更稳定而且计算复杂度更低.因而,有限脉冲响应均衡器相较于重叠频域均衡器更适于混合色散补偿.     

Dispersion Characteristics of Coaxial Circular-Arc-Groove Slow-Wave Structure

The coaxial circular-arc-groove periodic slow-wave system for relativestic traveling wave tubes (RTWT) is presented in this paper. To analyze the field in the groove region, the continuous profile of the circular arc is approximately replaced by a series of rectangular steps and the field continuity at the neighboring steps is deduced. The dispersion equation of the coaxial circular-arc-groove slow-wave structure is derived by the matching conditions at the interface between the groove region and central region. The influence of various circuit parameters on the dispersion relation is investigated by the numerical calculation.     

Structure factor of charged colloidal suspensions using Brownian-dynamics simulation: Comparison of Yukawa and Sogami pair potentials

Static structure factorsS(Q) are obtained for dilute charged colloidal systems using Brownian dynamics simulation method for the widely used screened Coulomb repulsive Yukawa potential and the recently proposed Sogami pair potential. The latter potential has, in addition to the usual repulsive part, an attractive term which is necessary to understand the reentrant phase transition reported in these colloids. It is shown for the first time thatS(Q) obtained using the Sogami potential for parameters favourable for liquid-like order agrees well with that measured experimentally. Thus it appears that the Sogami potential explains features of a homogeneous liquid as well as phase separated states, whereas Yukawa potential does not.     

Pattern Structure of Deterministic Displacement in Random Porous Media with Dispersion Effect

A new model-model of random porous mediz degradation via several fluid displacing,freezing,and thawing cycles is introduced and investigated in this paper.The fluid transport is based on the deterministic method with dispersion effect.The result shows that the topology and the geometry of the porous media have a strong effect on displacement processes.The cluster size of viscous fingering (VF) pattern in percolation cluster increases with the increase of iteration parameter n.When iteration parameter n≥10,VF pattern does not change with n.We find that the displacement fluid forms trapping regions in random porous media with dispersion effect.And the trapping regions will expand with the increasing of the iteration parameter n.When r (throat size)→1 and n≥5,the peak value of the distribution Nmat(r) increases as n increases,where Nmat(r) is the normalized distribution of throat sizes after different displacement-damages but before freezing.The peak value of the distribution Ninv(r) reaches a maximum when n≥10 and r=1,where Ninv(r) is the normalized distribution of the size of invaded throat.This result is different from invasion percolation.It is found that the sweep efficiency E increases along with the increasing of iteration parameter n and decreases with the network size L,and E has a minimum as L increases to the maximum size of lattice.The VF pattern in percolation cluster has one frozen zone and one active zone.     

分光计调整方法的改进及白光色散研究

普通物理实验中使用分光计观察白光散射,测量三棱镜顶角,最小偏向角等。但在测量前需借助三棱镜调整分光计,有人通过理论分析发现传统的调节方法存在误调和误差,并提出了改进的实验调整方法。本文我们通过实验来验证该方法是否可行,并在实验中发现了其它的问题。     

FCC结构胶体光子晶体的制备及其带隙特性测量

基于对光纤传输特性和胶体光子晶体制备方法的研究,提出了用外加电场控制的方法制备光子带隙位于通讯波段的FCC结构的胶体光子晶体,并用光纤系统测试胶体光子晶体的带隙特性.采用RSOFT模拟了胶体光子晶体的带隙,分析了带隙位于通讯波段时所需的胶体微球的基本参量(微球折射率和直径).采用自组装的方法,用步进电机控制玻璃基片向上的拉升速率.速率为5 μm/s,同时外加一电场.用扫描电镜观测胶体晶体的表面形貌,并设计了单模光纤系统测量胶体光子晶体的带隙特性.测试的透射谱线表明胶体光子晶体的带隙中心波长为1552 nm.测试结果和模拟结果具有很好的一致性,误差只有2 nm.     

偏振模色散影响色散控制孤子传输的理论研究

采用变分法分析高速色散控制孤子在双折射光纤中的传输规律。首先建立了色散控制孤子在双折射光纤中的扰动传输模型 ,然后解析了偏振模色散影响下色散控制孤子各参量的传输演化规律 ,最后对解析结果进行了计算。研究结果表明 ,偏振模色散参量对色散控制孤子能量、脉宽的演化影响很大 ,当偏振模色散很大时 ,如Dp>0 .3ps/km1/ 2 时 ,必须考虑采用某些在线控制手段来有效抑制偏振模色散对传输系统的影响 ,然而 ,当Dp≤ 0 .1ps/km1/ 2 时 ,系统几乎不受影响 ,同时本文还证明了色散控制孤子抗偏振模色散扰动的能力强的这一特点。为研究偏振模色散对高速非线性传输系统、特别是色散控制孤子传输系统的影响提供了理论依据和研究方法。     

光纤通信系统中偏振模色散自适应补偿实验研究

成功地研制了光纤通信系统偏振模色散的自适应补偿实验系统.实验中采用特定频率分量功率取样作为反馈信号,采用一种名为PSO(Particle Swarm Optimization)的优化方法作为反馈控制算法.偏振模色散的补偿量达30 ps,自动跟踪补偿时间为1～2 s,实现了准实时自动跟踪补偿.     

啁啾光栅色散及时延特性研究

基于耦合模理论，通过对耦合波方程进行相位共轭变换，将反向耦合波方程变换为Ｒｉｃｃａｔｉ微分方程，利用数值解法对常耦合系数和高斯型耦合系数线性啁啾光栅的反射特性、色散特性和时延特性进行了详细分析，为设计具有理想效果的色散补偿器件提供了有效的理论方法。     

Theoretical Investigation of Uniform and Non-uniform Penetrable Sphere Fluid

A bridge function approximation is proposed for a single-component fluid consisting of penetrable sphere interacting via a potential that remains finite and constant for center-center distance smaller than the particle diameter and is zero otherwise. The radial distribution function from the Ornstein-Zernike integral equation combined with the present bridge function approximation is in satisfactory agreement with the corresponding simulation data for all of the investigated state points. The presently calculated excess Helmholtz free energy respectively based on virial route and compressibility route is highly self-consistent, and is in very good agreement with simulational results for the case of low temperatures. The present bridge function approximation, combined with the bridge density functional approximation, can reproduce very accurately density profiles of the penetrable sphere fluid confined in a hard spherical cavity for all the cases where simulational results are available.     

Theoretical Investigation of Uniform and Non-uniform Penetrable Sphere Fluid

A bridge function approximation is proposed for a single-component fluid consisting of penetrable sphere interacting via a potential that remains finite and constant for center-center distance smaller than the particle diameter and is zero otherwise. The radial distribution function from the Ornstein-Zernike integral equation combined with the present bridge function approximation is in satisfactory agreement with the corresponding simulation data for all of the investigated state points. The presently calculated excess Helmholtz free energy respectively based on virial route and compressibility route is highly self-consistent, and is in very good agreement with simulational results for the case of low temperatures. The present bridge function approximation, combined with the bridge density functional approximation,can reproduce very accurately density profiles of the penetrable sphere fluid confined in a hard spherical cavity for all the cases where simulational results are available.     

Structure factor of a hard-core fluid with short-range Yukawa attraction: analytical FMSA theory against Monte Carlo simulations

ABSTRACT

Analytical solution of the first-order Ornstein–Zernike equation known as the first-order mean spherical approximation (FMSA) theory due to Tang and Lu [J. Chem. Phys. 99, 9828 (1993)] is used to write down a closed equation for the static structure factor of the hard-sphere fluid with a short-range Yukawa attraction. Calculations are performed for a Yukawa decay exponent that corresponds to a range of attraction that does not exceed the first coordination shell of Lennard-Jones-like simple fluids. By comparison with Monte Carlo simulation data it is shown that the analytical FMSA equation for the static structure factor is of the same or even of superior accuracy as that within the seminumerical mean spherical approximation theory.     

偏振复用光纤通信系统色散均衡器及算法的研究

设计了一种适用于偏振复用相干解调光纤通信系统的色散均衡器,用于补偿信道传输的色散损伤。该均衡器采用半码元间隔的蝶形有限脉冲响应滤波器结构,与此结构配合的自适应算法分别采用最小均方算法和递归最小二乘算法。通过仿真实验,分析了两种算法对残留色度色散和偏振模色散的补偿容限。仿真结果表明,递归最小二乘算法的补偿效果优于最小均方算法,它可以同时补偿1760ps/nm的残留色度色散和104.9ps偏振模色散引起的差分群时延,比同等条件的最小均方算法提升性能2.23dB。     

通过调节纤芯大小实现接近零色散的色散平坦光子晶体光纤

利用已有文献对光子晶体光纤色散特性的计算结果,分析了色散随光子晶体光纤结构参数变化的趋势,并利用有效折射率方法基于标量近似理论对光子晶体光纤色散特性进行了有目的性的数值模拟,发现通过独立调整纤芯大小,可以在光通信波段实现非常接近零色散的色散平坦光子晶体光纤,其色散系数D的绝对值在1.3 μm～2.0 μm波长范围小于1.5 ps·km-1·nm-1 .     

Hamiltonian Structure for Dispersive and Dissipative Dynamical Systems

We develop a Hamiltonian theory of a time dispersive and dissipative inhomogeneous medium, as described by a linear response equation respecting causality and power dissipation. The proposed Hamiltonian couples the given system to auxiliary fields, in the universal form of a so-called canonical heat bath. After integrating out the heat bath the original dissipative evolution is exactly reproduced. Furthermore, we show that the dynamics associated to a minimal Hamiltonian are essentially unique, up to a natural class of isomorphisms. Using this formalism, we obtain closed form expressions for the energy density, energy flux, momentum density, and stress tensor involving the auxiliary fields, from which we derive an approximate, “Brillouin-type,” formula for the time averaged energy density and stress tensor associated to an almost mono-chromatic wave.     

非接触二次色散法测量人体血糖的初步研究

提出了一种测量血糖浓度的新方法——二次色散法，此方法采用低相干干涉仪来测量时间相干干涉信号，通过傅里叶变换和多项式拟合获得二次色散。初步测量了三种不同浓度的糖溶液在0．55μm到0．8μm之间的二次色散，实验结果发现随着血糖浓度的增加，二次色散也随之增加。研究证明该方法是一种潜在的无接触、无伤害在线探测人体血糖浓度的方法。为设计一种非接触、无伤害在线探测人体血糖浓度的光学医疗仪器奠定基础。最后讨论了采用本方法尚需改进的问题和进一步的工作。     

振动光谱法研究布洛芬及其固体分散体

将拉曼光谱法与红外光谱法相结合,以期获得布洛芬更全面的结构信息.另外,为了验证Raman光谱法验证固体分散体的可行性,采用熔融法制备布洛芬固体分散体,并用Raman光谱法和红外光谱法研究其分散性.两种鉴别方法得到一致的结果——布洛芬与载体之间不存在相互作用,以微晶状态分散在固体分散体中,且拉曼光谱法简单易行、快速直接、...