共查询到18条相似文献,搜索用时 78 毫秒
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利用阴离子交换树脂为催化剂进行了丙烯腈与二醇的Michael加成反应的研究,对影响反应的诸因素进行了讨论,产物收率为70-90%。 相似文献
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Friedel-Crafts酰基化法制备聚苯乙烯型阴离子交换树脂 总被引:6,自引:0,他引:6
提出了一种合成聚苯乙烯型阴离子交换树脂的新方法:通过Friedel-Crafts酰基化反应在交联聚苯乙烯上引入乙酰基,然后经溴化、胺化反应制备阴离子交换树脂。该方法避免了使用氯甲醚等致癌物质,并消除了二次交联等副反应。讨论了溶剂,催化剂,试剂和反应温度及时间等因素对各步反应的影响。测定了产物的基本性能并对所得结果进行了讨论。 相似文献
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为了改进提取甜菊甙(糖)所用的阴离子交换树脂的脱色能力和抗污染能力,作者选用合适的致孔剂进行苯乙烯、二乙烯苯和极性单体的多元悬浮共聚,然后进行氯甲基化和胺化,合成了多种阴离子交换树脂。与D280树脂相对照进行树脂性能测试,筛选出了对甜菊甙脱色容量较大和再生效果较好的E—04树脂。 相似文献
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耐高温强碱阴离子交换树脂研究进展 总被引:1,自引:0,他引:1
羟型强碱阴离子交换树脂的最高使用温度一般为60□,三菱化学公司研究制备了能耐受100□高温的强碱阴离子交换树脂.本文对近年来强碱阴离子交换树脂在热稳定性方面的改进及提高做简要概述. 相似文献
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作者通过对大量树脂的筛选,寻找到了性能优良的脱色树脂D-268,详细研究了D-268树脂的脱色性能和不同再生剂对树脂的再生性能。 相似文献
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阴离子交换树脂提取谷氨酸 总被引:4,自引:0,他引:4
谷氨酸是蛋白质的主要构成成分,具有重要的生理生化功能,其主要应用于食品、医药等工业。目前国内从发酵液中提取谷氨酸普遍采用的步骤是:先用等电法结晶大部分谷氨酸,等电母液采用离子交换法浓缩其中的谷氨酸,此时谷氨酸为阳离子,洗脱高浓度馏分再回入等电罐进行结晶回收[1]。上述工艺的最大缺点是:在结晶和离子交换过程中要使用大量的硫酸调节发酵液和母液的pH,造成环境污染;且提取谷氨酸后产生的废液中其COD和SO2 4和氨态氮含量很高,用常规的方法较难处理[2]。由于谷氨酸发酵液的pH为6 8~7 2,此时,谷氨酸主要以阴离子状态形式存… 相似文献
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本文报导了五种不同品种阴离子交换树脂,在60℃和70℃下热降解性能试验,结果证明大孔强碱Ⅰ型阴离子交换树脂的耐热性能最佳,这为高温凝结水净化处理选用树脂,提供了依据。 相似文献
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大孔阳树脂催化合成苯乙酸酯 总被引:2,自引:0,他引:2
利用D72,D61大孔阳离子交换树脂为催化剂,催化合成苯乙酸异戊酯、苯乙酸丁酯、苯乙酸苄酸、苯乙酸苯乙酯、苯乙酸茴香酯。对影响反应的诸因素进行了讨论,酯收率为90%左右。 相似文献
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Four neutral amino acids (Gly, Ala,.Val and Leu) were separated with ligand exchange resins. The separation capacity of the ligand exchange resins is compared with that of common ion exchange resins. The effects of eluent, column temperature, and central metal ions of the support on the separation are studied. The relationship between matrix structure of resins and their separation capacity is analysed. 相似文献
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Liqiang Yin Dr. Rong Ren Dr. Lanlan He Wentao Zheng Dr. Yu Guo Dr. Linqin Wang Dr. Husileng Lee Dr. Jian Du Dr. Zhiheng Li Dr. Tang Tang Guoheng Ding Prof. Dr. Licheng Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(19):e202400764
Anion exchange membranes (AEMs) are core components in anion exchange membrane water electrolyzers (AEM-WEs). However, the stability of functional quaternary ammonium cations, especially under high temperatures and harsh alkaline conditions, seriously affects their performance and durability. Herein, we synthesized a 1-methyl-3,3-diphenylquinuclidinium molecular building unit. Density functional theory (DFT) calculations and accelerated aging analysis indicated that the quinine ring structure was exceedingly stable, and the SN2 degradation mechanism dominated. Through acid-catalyzed Friedel–Crafts polymerization, a series of branched poly(aryl-quinuclidinium) (PAQ-x) AEMs with controllable molecular weight and adjustable ion exchange capacity (IEC) were prepared. The stable quinine structure in PAQ-x was verified and retained in the ex situ alkaline stability. Furthermore, the branched polymer structure reduces the swelling rate and water uptake to achieve a tradeoff between dimensional stability and ionic conductivity, significantly improving the membrane's overall performance. Importantly, PAQ-5 was used in non-noble metal-based AEM-WE, achieving a high current density of 8 A cm−2 at 2 V and excellent stability over 2446 h in a gradient constant current test. Based on the excellent alkaline stability of this diaryl-quinuclidinium group, it can be further considered as a multifunctional building unit to create multi-topological polymers for energy conversion devices used in alkaline environments. 相似文献
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Fernando J. Ferrer-Gago Li Quan Koh David P. Lane 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(2):379-383
Peptide alcohols are clinically important compounds that are underexplored in structure–activity relationship (SAR) studies in drug discovery. One reason for this underutilization is that current syntheses are laborious and time consuming. Herein, we describe the preparation and utility of Rink, Ramage, and Sieber-chloride resins, which enables the use of a general, easy and practical method for the attachment of fluorenylmethoxycarbonyl (Fmoc)-amino alcohols to a solid support, in the synthesis of peptide alcohols. This method is the first straightforward Fmoc/tBu synthesis of peptide alcohols starting from a pre-loaded resin. The synthesized peptide alcohols can be detached from the linkers through conventional methods. Treatment with trifluoroacetic acid (TFA) (95 %) and scavengers such as triisopropylsilane and water for 2 h is sufficient to obtain a fully deprotected peptide alcohol, while treatment with 20 % hexafluoroisopropanol in dichloromethane renders a fully protected peptide alcohol that can be further modified at the C-terminus. As examples, the new resins were used in straightforward, relatively rapid syntheses of the peptide alcohols octreotide, alamethicin, and a segment of trichogin GA IV, as well as the first synthesis of stapled peptide alcohols. 相似文献
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离子交换树脂在分析化学中的应用 总被引:1,自引:0,他引:1
简要评述了离子交换树脂在分析化学中的应用。包括离子交换树脂预富集技术从稀溶液中浓缩痕量离子,离子交换树脂相分光光度法测定微量离子,离子色谱在无机分析中的应用,以及离子交换树脂在有机分析与生化分析中的应用。 相似文献