低温高压液态空气储能系统分析

压缩空气储能是一种极具潜力的大规模储能技术,传统的压缩空气储能技术存在储能密度低、储存容积大等缺点,应用推广受到很大限制。液态空气储能技术是一种新兴的压缩空气储能技术,相比于传统压缩空气储能技术,能量储存密度显著提高。因此,基于低温空气液化原理,提出一种液态空气储能系统,其核心热力学过程为将空气降温液化后以高压状态存储,通过节流后的空气实现冷量回收,使得系统不需引入额外冷量。对该系统进行热力学分析和参数优化,结果表明系统效率可达50%以上。     

Acoustic characteristics of a rocket combustion chamber: Radial baffle effects

This paper describes methods used for determining the characteristic acoustic modes and frequencies of a liquid-propellant rocket-motor combustion chamber and effects of radial baffles on the chamber’s acoustic field. A multi-point sensing experimental setup, including stationary and moving sensors, was used to measure characteristic frequencies and mode shapes of a combustion chamber. A new technique based on the comparison of signal phase angles from stationary sensors to that of a moving sensor was used to map complex characteristic mode shapes of a combustor. A three-dimensional Helmholtz acoustic solver was also developed using an efficient finite volume approach for complex geometries to simulate the acoustic field inside a combustor. Using this approach the effects of the convergent section of the nozzle and the number of radial baffles on the chamber’s dominant acoustic modes with no mean flow were investigated. We have shown that the classical reduction of characteristic frequency of tangential modes caused by radial baffles is due to longitudinalization of tangential modes and is a function of the blade length and weakly dependent on the number of blades. Also, conjugate spinning modes are decoupled and do not spin in any baffled combustor, independent of the number of blades. On the other hand the converging nozzle section of a combustion chamber modifies pure longitudinal modes in the radial direction and pure tangential modes in the longitudinal direction. Existence of some mixed tangential-longitudinal modes in a combustor is dependent on the ratio of the nozzle throat diameter to the combustor head plate diameter.     

Holographic Investigations of a Diesel Jet injected into a high-pressure test chamber

A Diesel spray injected into a high-pressure test chamber was investigated with two different holographic techniques. The usual off-axis recording geometry was used to investigate the very early beginning of the injection. Double pulsing of the recording laser facilitated velocity measurements. By using two different reference angles for the two recording the two images can be separated upon reconstruction of the holograms. Thus superior image quality could be achieved. Processes leading to jet formation could be identified: the spray tip is periodically axially decelerated and radially accelerated. Consequently, liquid moves at the tip off axis. The spray consists of fast central region surrounded by a slower outer jet region. The outer jet region exhibits periodic droplet concentration fluctuations which are interpreted as a result of the periodic processes at the spray tip. Some high concentration regions in the outer jet region were investigated using a dark-field holographic technique. This technique permits single droplet velocity measurements and local droplet concentration determination at extremely high droplet concentrations. The most important result of these investigations is that no correlation between the local droplet concentration and the droplet velocity could be found.     

Auditory-nerve response from cats raised in a low-noise chamber

A litter of four cats, born and raised in a soundproofed chamber, was studied in an attempt to determine which, if any, features of the auditory-nerve response from routinely available cats might be due to the chronic effects of noise exposure. Two features of routine-normal response were especially suspect in this regard: (1) a "notch" in the distribution of single-unit thresholds centered at characteristic frequencies (CF's) near 3 kHz and (2) a compression of the distribution of rates of spontaneous discharge for units with CF above 10 kHz. A third feature of response in routine animals was the presence of a small number (roughly 10%) of units with virtually no spontaneous discharge and very high thresholds, sometimes 80 dB less sensitive than high-spontaneous units of similar CF. In the data from chamber-raised animals, the high-spontaneous units showed exceptionally low thresholds at all CF regions, however, there were signs of the midfrequency notch in the threshold distribution of at least two of these animals. The compression of the spontaneous rate distribution was not seen in any of the three most sensitive animals. The data suggest that there is a significant amount of "normal pathology" in the high-CF units from routine animals. Low-spontaneous, high-threshold units were present in all four chamber-raised ears with the same characteristics as in routine animals (exceptionally narrow tuning curves and exceptionally low maximum discharge rates) and at roughly the same percentage of the unit sample. A class of units with medium spontaneous rates and intermediate thresholds could also be identified. The possible significance of a classification of auditory-nerve units according to spontaneous rate is discussed.     

Comparison of laser-induced and planar laser-induced fluorescence measurements of nitric oxide in a high-pressure, swirl-stabilized, spray flame

We report spatially resolved linear laser-induced fluorescence (LIF) and planar laser-induced fluorescence (PLIF) measurements of nitric oxide (NO) in a pre-heated, high-pressure (4.27 atm), lean direct-injection (LDI) spray flame. The feasibility of using PLIF in lieu of LIF is assessed with respect to measuring NO concentrations in high-pressure LDI spray flames. NO is excited via the resonant Q₂(26.5) transition of the γ(0,0) band while a non-resonant wavelength is employed to subtract background interferences. LIF detection is performed in a 2-nm region centered on the γ(0,1) band. PLIF detection is performed in a 68-nm window that captures fluorescence from several vibrational bands. An in situ NO doping scheme for fluorescence calibration is successfully employed to quantify the LIF signals. However, a similar calibration scheme for the reduction of PLIF images to quantitative field measurements is plagued by the laser-excited background. Excitation scans and calibration comparisons have been performed to assess the background contribution for PLIF detection. Quantitative radial NO profiles measured by LIF are presented and analyzed so as to correct the PLIF measurements to within the accuracy bars of the LIF measurements via a single-point scaling of the PLIF image. Received: 23 November 1999 / Revised version: 17 January 2000 / Published online: 27 April 2000     

Impact of nitric oxide on n-heptane and n-dodecane autoignition in a new high-pressure and high-temperature chamber

A New One Shot Engine (NOSE) was designed to simulate the thermodynamic conditions at High Pressure-High Temperature like an actual common-rail diesel engine in order to study the compression ignition of spray. The volume of the combustion chamber provided with large optical windows simplified the implementation of various optical diagnostics. The advantage of this kind of set-up in comparison to pre-burn or flue chambers is that the initial gas mixture can be well controlled in terms of species and mole fraction. The purpose of this work was to investigate the impact of nitric oxide (NO) on ignition delay (ID) for two fuels with different cetane numbers: n-heptane, and n-dodecane. In the thermodynamic conditions chosen (60?bar and over 800–900?K), NO had a strong effect on ID, with increases in NO tending to reduce the ignition delay. Results showed that ID and Lift-Off Length (LOL) presented the same trend as a function of temperature and NO concentration. Experimentally, at 900?K the ignition of n-dodecane was promoted by NO up to 100?ppm, whilst higher NO levels did not further promote ignition and a stabilization of the value has been noticed. For n-heptane, stronger promoting effects were observed in the same temperature conditions: the ignition delays were monotonically reduced with up to 200?ppm NO addition. At a lower temperature (800?K) the inhibiting effect was observed for n-dodecane for [NO] greater than 40?ppm, whereas only a promoting effect was observed for n-heptane. The experimental results of LOL showed that NO shortened LOL in almost all cases, and this varied with both the NO concentration and the mixture temperature. Thus, fuels with shorter ignition delays produce shorter lift-off lengths.     

Comparison of dose measurements in CT using a photodiode and a small ion chamber

Owing to the advance of multislice computed tomography (CT), the dosimetric protocol currently used in CT has become inadequate. Instead of dosimetry based on the measurement of the Computed Tomography Dosimetry Index (CTDI) using a pencil ion chamber (IC) 100 mm in length, the use of a short IC and the calculation of the dose equilibrium (D_eq) at the location of the chamber are proposed. The objective of this work was to compare the performance of a short IC and a commercial photodiode (BPW34FS) to measure the accumulated dose at the center of the scan length L, D_L(0), and to obtain the equilibrium dose D_eq using the two detectors. The result for L = 100 mm was compared with the result of the pencil chamber. The results indicate that the commercial photodiode is suitable to measure the accumulated dose at the center of the scan length L as compared with the ICs. This methodology allows measurements of the accumulated dose for any desired scan length, allowing measurement of the equilibrium dose D_eq if the phantom is long enough to allow it.     

Structure,thermal stability,and state of grain boundaries of copper subjected to high-pressure torsion at cryogenic temperatures

Evolution of the structure of tough-pitch copper upon severe deformation by high-pressure torsion at room temperature and in liquid nitrogen is studied. The thermal stabilities of the resulting structures are investigated. The state of grain boundaries is examined by means of Mössbauer emission spectroscopy. Factors that hamper the formation of a nanostructured state and the possibility of eliminating the effect of these factors are analyzed.     

Transient thermal analysis of a cryogenic oxidizer tank in the liquid rocket propulsion system during the prelaunch helium gas pressurization

The transient thermal behavior in the cryogenic oxidizer tank for the liquid propulsion system of the KSLV-I satellite launching space vehicle is theoretically investigated for the pressurization process by gaseous helium injection followed by the readiness check stage. The numerical model is established using the transient mass and energy conservation of oxygen/helium mixtures both in ullage and liquid regions. At the liquid-gas interface, various modes of heat and mass transfer are considered, including the liquid evaporation and the helium absorption. The present study focuses on the effects of the increasing pressurization level on some of important properties that should be considered in the propulsion system design, such as tank pressure, ullage gas temperature, and evaporation of liquid oxygen. Particularly, the tank pressure drop after the pressurization is investigated in the proposed design of propulsion system. Also, the effect of the initial loading of liquid oxygen in the oxidizer tank is studied and discussed. As for the helium absorption into the liquid region, its mass is negligibly small and it should not be the concern in design and operation of the oxidizer tank system.     

Ethanol ignition in a high-pressure shock tube: Ignition delay time and high-repetition-rate imaging measurements

Ethanol is known to be prone to pre-ignition in internal combustion engines under high-load conditions and its ignition shows large deviations from ideal, spatially, and temporally-homogeneous ignition in shock tubes at moderate temperatures (800–950 K). In this context, the ignition of stoichiometric ethanol/O₂ mixtures with various levels of inert gas dilution was investigated in a high-pressure shock tube at ?20 bar between 800 and 1250 K. Ignition delay times were determined from spatially integral detection of chemiluminescence emission. Additionally, high-repetition-rate color imaging enabled the differentiation of the luminescence in time, space, and spectral range between various ignition modes. In the low-temperature range (800–860 K), different inhomogeneous ignition modes were identified. The addition of small amounts of helium into the undiluted fuel/air mixture was found to be efficient to mitigate pre-ignition, attributed to a variation in heat transfer and thus suppression of the build-up of local temperature inhomogeneities. The experiments in case of spatially homogeneous ignition show very good agreement with the predictions based on three detailed kinetics mechanisms (Zhang et al., CNF 190 (2018) 74, Frassoldati et al., CNF 159 (2012) 2295, and Zhou et al. CNF 197 (2018) 423), inhomogeneities, however, resulted in a shortening of the ignition delay times up to a factor of 2.6.     

PENTATRAP: a novel cryogenic multi-Penning-trap experiment for high-precision mass measurements on highly charged ions

The novel five-Penning-trap mass spectrometer Pentatrap is developed at the Max-Planck-Institut für Kernphysik (MPIK), Heidelberg. Ions of interest are long-lived highly charged nuclides up to bare uranium. Pentatrap aims for an accuracy of a few parts in 10¹² for mass ratios of mass doublets. A physics program for Pentatrap includes Q-value measurements of β-transitions relevant for neutrino physics, stringent tests of quantum electrodynamics in the regime of extreme electric fields, and a test of special relativity. Main features of Pentatrap are an access to a source of highly charged ions, a multi-trap configuration, simultaneous measurements of frequencies, a continuous precise monitoring of magnetic field fluctuations, a fast exchange between different ions, and a highly sensitive cryogenic non-destructive detection system. This article gives a motivation for the new mass spectrometer Pentatrap, presents its experimental setup, and describes the present status.     

Spectroscopic,calibration and RET issues for linear laser-induced fluorescence measurements of nitric oxide in high-pressure diffusion flames

Two different strategies are compared for linear laser-induced fluorescence (LIF) measurements of nitric oxide concentration ([NO]) in counter-flow diffusion flames at high pressures via the A-X(0,0) system. Excitation of NO via a rovibronic transition at 226.03 nm is found to be slightly better compared to a previously utilized excitation wavelength of 225.58 nm. An indirect approach based on the computed spectral overlap fraction is verified and applied to calibrate [NO] measurements in counter-flow diffusion flames at high pressures. A five-level model for NO molecular dynamics is presented and utilized to investigate the effects of rotational energy transfer (RET) on linear LIF measurements of [NO] at pressures up to 15 atm. The results indicate that rotational relaxation effects are essentially negligible under high-pressure conditions at low laser fluences, and thus they need not be accounted for when measuring [NO] using linear LIF. The calibration technique is validated by direct comparisons to [NO] measurements made at pressures up to 5 atm via another calibration method, based on doping NO in counter-flow premixed flames at the same pressure. Using this calibration technique, LIF measurements of [NO] are obtained in a series of counter-flow diffusion flames at pressures up to 15 atm. These measurements are found to be in excellent agreement with previously reported measurements of [NO] in similar flames. PACS 07.35.+k; 33.20.Sn; 42.62.Fi     

Flame-acoustic coupling of combustion instability in a non-premixed backward-facing step combustor: the role of acoustic-Reynolds stress

Combustion instability in a laboratory scale backward-facing step combustor is numerically investigated by carrying out an acoustically coupled incompressible large eddy simulation of turbulent reacting flow for various Reynolds numbers with fuel injection at the step. The problem is mathematically formulated as a decomposition of the full compressible Navier–Stokes equations using multi-scale analysis by recognising the small length scale and large time scale of the flow field relative to a longitudinal mode acoustic field for low mean Mach numbers. The equations are decomposed into those for an incompressible flow with temperature-dependent density to zeroth order and linearised Euler equations for acoustics as a first order compressibility correction. Explicit coupling terms between the two equation sets are identified to be the flow dilatation as a source of acoustic energy and the acoustic Reynolds stress (ARS) as a source of flow momentum. The numerical simulations are able to capture the experimentally observed flow–acoustic lock-on that signifies the onset of combustion instability, marked by a shift in the dominant frequency from an acoustic to a hydrodynamic mode and accompanied by a nonlinear variation of pressure amplitude. Attention is devoted to flow conditions at two Reynolds numbers before and after lock-on to show that, after lock-on, the ARS causes large-scale vortical rollup resulting in the evolution of a compact flame. As compared to acoustically uncoupled simulations at these Reynolds numbers that show an elongated flame with no significant roll up and disturbance in the upstream flow field, the ARS is seen to alter the shear layer dynamics by affecting the flow field upstream of the step as well, when acoustically coupled.