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FU Ding-Wei~a SONG Ji-Rong~a b REN Ying-Hui~a YAN Biao~a Lü Xing-Qiang~a HU Huai-Ming~c a 《结构化学》2008,(5)
A copper(Ⅱ ) complex Cu(L)2(NO3)2 constructed by the L (L = N-(4,6-dime- thoxylpyrimidin)-N'-(ethoxycarbonyl)thiourea) ligand crystallizes in monoclinic, space group C2/c with a = 16.2416(16), b = 9.1385(7), c = 22.0008(18) , β = 108.077(2)o, V = 3104.3(5)3, Dc = 1.627 g/cm3, Z = 4, C20H28CuN10O14S2, Mr = 760.18, μ(MoKα) = 0.920 mm–1, F(000) = 1564, R = 0.0471 and wR = 0.1284 for 2239 observed reflections (I > 2σ(I)). X-ray diffraction shows the existence of weak complementary intramolecular N–H…O (DA) hydrogen bonds which further strengthen the coordination from the two L ligands with the Cu(II) ion, intermolecular C–H…O hydrogen bonds and weak π…π stacking interactions, leading to the formation of a multi-dimen- sional supramolecular network. 相似文献
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A new three-dimensional supramolecule composed of copper-Schiff base complex, [Cu(naphdien)]Cl·H2O, where naphdien is Schiff base of 2-hydroxy-1-naphthaldehyde and diethylenetriamine, has been synthesized and determined by single-crystal X-ray diffraction. It belongs to the monoclinic system, space group P21/c, with a = 7.3490(15), b = 7.0847(16), c = 30.845(3)A, β= 95.33(3)°, V = 1599.0(5)A3, Z = 4, C15 H20ClCuN3O2, Mr = 373.33, De = 1.551 g/cm3, μ = 1.543 mm^-1, F(000) = 772, R = 0.0536 and wR = 0.0927 for 2788 unique reflections with 1659 observed ones (I 〉2σ(I)). In the crystal structure, mononuclear units [Cu(naphdien)]Cl·H2O are linked into a two-dimensional framework via strong hydrogen bonds, and extended into a three-dimensional supramolecular structure through π-π stacking interactions. 相似文献
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1INTRODUCTIONCoppercomplexeshavealargevarietyofstericstructuresandplayanimportantroleincatalysingtheenzymaticactivities,which... 相似文献
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XU Li ZHANG Yan-Ping WANG Li SHI Jun-Yan DONG Wen-Kui ② 《结构化学》2008,27(2):183-186
A new mononuclear Cu(II) complex, [Cu(L)] (H2L = 4,4′,6,6v-tetrabromo-2,2′- [ethylenedioxybis(nitrilomethylidyne)]diphenol), has been synthesized and structurally characterized. X-ray crystal structure of the complex reveals that the Cu(Ⅱ) ion is four-coordinated by two oxygen atoms and two nitrogen atoms from L2- unit. Crystallographic data: monoclinic, space group P21/n with a = 14.076(2), b = 6.9801(14), c = 19.858 (2) A, β= 107.613(2)°, C16n10Br4CuN2O4, Mr = 677.44, V = 1859.6(5) A3, Dc = 2.420 g/cm3,μ = 9.796 mm^-1, F(000) = 1284, Z = 4, the final R = 0.0516 and wR = 0.0938 for 1879 observed reflections with I 〉 2σ(/). The dihedral angel between the two coordination planes of Cu(1)-N(2)--O(4) and Cu(1 )-N( 1 )-O(3)) is 30.08(6)°. 相似文献
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A new complex [Cu(phen)3][(C6H4)2C(OH)COO]2·6H2O was prepared by selfassembly of benzilic acid, 1,10-phenanthroline (phen), and copper perchlorate. It crystallizes in triclinic, space group P1-, with a = 1.14661(17), b = 1.6455(2), c = 1.6457(2) nm, α= 74.779(2), β = 74.904(3), γ = 84.424(3)°, V = 2.8914(7) nm^3, Dc = 1.340 g/cm^3, Z = 2, F(000) = 1218, GOOF = 1.018, the final R = 0.0643 and wR= 0.1633. The crystal structure shows that the copper ion is coordinated with six nitrogen atoms from six 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. 相似文献
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A novel coordination polymer [Mg(L)(H2O)2]·H2O] (LH2=L-cysteic acid) has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction.The crystal crystallizes in orthorhombic system, space group P212121, with a=5.962(3), b=11.224(6), c=13.664(7)(A), V=914.3(8) (A)3, Z=4, Mr=245.50, Dc=1.783 g/cm3,μ=0.445 mm-1,flack parameter=0.32(16), F(000)=512, the final R=0.0458 and wR=0.1172 for 1578 observed reflections with I > 2σ(Ⅰ). The Mg(Ⅱ) atom shows an octahedral geometry defined by two carboxyl O atoms from two different L-cysteic acid ligands, one carboxyl O atom and one amino N atom from the adjacent ligand, and two aqua ligands. The Mg(Ⅱ) atoms are bridged by L-cysteic acid ligands, leading to a 1D infinite zigzag chain. In the structure there are extensive hydrogen bonds,through which the complex completes its 3D framework structure. 相似文献
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HUANG Zun-Xing WANG Xiu-Li LIU Shi-Xiong 《结构化学》2002,21(5):505-508
1 INTRODUCTION Transition metal complexes with ferrocene are of considerable interest in the past fifty years because of their novel structures and special properties[1, 2]. The chemistry of ferrocene and its derivatives has become richer and richer in the last decade. Many complexes containing ferrocenyl have been synthesized and characterized[3~5]. Recently we have reported the synthesis and crystal structure of dibromo[1,1?bis(diphenylphosphino)- ferrocene]cadmium (Ⅱ)[6]. Herein we… 相似文献
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1 INTRODUCTION In recent years, coordination polymeric frame- works have attracted great attention not only due to their potential applications in the areas of magnetism, nonlinear optics, electronics, catalysis, and molecu- lar recognition and sorption but also to their intri- guing structure topologies[1~8]. The coordination polymers can be specially designed by careful selec- tion of the metal ions with definite coordination geometry, the structure of the connecting ligands, the nature… 相似文献
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DU Qiao-Yun MA Liang QIN Jian-Hua 《结构化学》2007,26(3):347-351
A new acetate radical bridged dinuclear copper(Ⅱ ) complex (C8H9NO2)2-Cu2(CH3COO)4 has been synthesized by the reaction of Cu(OAc)2 with pyridine-3-ethyl formate and further characterized by X-ray single-crystal diffraction. Crystal data for the title compound: triclinic system,space group P1,with a=8.1654(14),b=9.7010(16),c=9.9005(17) ,α= 83.266(2),β=78.887(2),γ=72.881(2)o,V=733.9(2) 3,Mr=665.58,Z=1,Dc=1.506 g/cm3,F(000)=342,μ=1.510 mm-1,the final R=0.0392 and wR=0.1005. According to the structural determination,each unit of the title compound is composed of two Cu(Ⅱ) atoms,two pyridine-3-ethyl formate molecules and four acetate ions. Each Cu(Ⅱ) coordinates to oxygen atoms of acetate and nitrogen atoms of pyridine-3-ethyl formate ligand to give a six-coordinate distorted octahedral geometry. It is worth mentioning that strong Cu–Cu bond can be observed in the title compound. 相似文献
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A New Dinuclear Cu(Ⅱ) Complex of a Ligand with Benzimidazole Group - Synthesis and Crystal Structure
LI Qing-Xiang WANG Xiu-Feng YANG Xiang-Liang XU Hui-Bi 《结构化学》2007,26(6):707-710
A new dinuclear copper complex, [Cu(C9H11N3)Cl2]2(C18H22Cl4Cu2N6), has been synthesized and characterized by X-ray structure determination. It crystallizes in the triclinic P1^- space group with a = 7.526(3), b = 9.473(4), c = 9.535(3)A, α = 117.214(10), β = 108.251(9), γ = 91.560(6)°, V = 562.3(4)A^3, Z = 1, Mr = 591.30, F(000) = 298, Dc = 1.746 g/cm^3, μ(MoKα) = 2.385 mm^-1, the final R = 0.0577 and wR = 0.1248 for 2188 unique reflections with 1629 observed ones (Ⅰ〉 2σ(Ⅰ)). In the title complex, each copper(Ⅱ) atom is located at the center of a distorted trigonal bipyramid of five coordination atoms (two nitrogen and three chlorine atoms). Two copper(Ⅱ) atoms were bridged by two chlorine anions (Cl(2) and Cl(2a)) to form a Cu(Ⅱ)-Cu(Ⅱ) binuclear entity with the distance between two copper(Ⅱ) atoms of 3.398 (A). 相似文献
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WU Wei JIN Xu-Hui JU Zhang-Feng ZHANG Jie 《结构化学》2008,27(8):949-954
A novel redox-active bipyridinium ligand N-(3-carboxyphenyl)-4,4'-bipyridinium chloride (HCPBPyC1) and its coordination polymer {[Cd2(CPBPy)2(BDC)(H2O)2Cl2]·6H2O}n 1 (H2BDC = benzene-1,4-dicarboxylic acid) were synthesized and characterized. Crystallographic data for 1: C42H44Cd2Cl2N4O16, Mr = 1156.51, monoclinic, space group C2/c, a = 21.046(3), b = 11.0036(15), c = 20.012(3)A, β = 98.694(8)°, Z = 4, V = 4581.1(11)A3, Dc = 1.677 g/cm^3, F(000) = 2280 and μ = 1.120 mm^-1. Complex 1 possesses a thick and undulated two-dimensional layer with (6,3) topology, which interpenetrates with two others (above and below) to extend into a three-dimensional supramolecular framework. 相似文献
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Reaction of cobalt carbonate, pivalic acid and quinoline in a refluxing ethanol solvent yielded the dicobalt(Ⅱ) compound, Co2(O2CCMe3)4(C9H7N)2 (1) (C9H7N is quinoline), which has been characterised by elemental analysis, IR and X-ray diffraction method. Crystallographic data: monoclinic, P21/a, a=9.341(2), b=18.591(4), c=11.822(2)(), β=97.71(2), V=2034(1)()3, Z=2, Mr=918.19, Dc=1.27 g/cm-3, F(000)=820, μ(MoKα)=8.60 cm-1, T=293K, final R=0.049, Rw=0.060 for 2715 observed reflections with I>3.0 σ(I). The centrosymmetric molecule comprises a pair of cobalt(Ⅱ) atoms connected by four pivalate ligands in syn-syn bridging modes. Square pyramidal five-coordination of cobalt(Ⅱ) is further completed by a quimoline molecule. The CoⅡ-CoⅡ distance is 2.784(1)(). 相似文献
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In an attempt to synthesize a new pyrimidine complex of copper(H) in a solution reaction of CuBr2 with 2,2‘-bis(hexahydropydmidine) and hydro-chloric acid, we unexpectedly obtained a bright yellow chip-like crystal of CuCl4(H2tn) [H2tn=(H3NCH2CH2CH2NH3)^2 ]. Its structure was determined by single-crystal X-ray diffraction analysis. The crystal belongs to orthorhombic system, space group Pnma, with cell parameters: a=0.7216(2)nm, b=1.8308(6)nm, c=0.7553(3)nm, V=0.9953(6)nm^3, Z=4, F(000)=564, Mr=281.49, Dc=1.879 g/cm^3. u(Mo Ka)=3.204 mm^-1, R1=0.0248, wR2=0.0575. The analysis of the crystal structure indicates that the complex has a three-dimensional network structure, which is formed by hydrogen bonds and electrostatic interaction. 相似文献
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YUAN Ji-xin ** HU Mao-lin LI Ju-xia SONG Xin-yuan . College of Chemistry Chemical Engineering Donghua University Shanghai P. R. China . Department of Chemistry Wenzhou Normal College Wenzhou P.R.China 《高等学校化学研究》2005,21(1):21-23
IntroductionThe synthesis and characterization of the novelcomplexes with polycarboxylate groups are activefields currently due to their diverse intriguingstructures and potential properties as new materi-als[1_ 3 ] . 1 ,2 ,4,5 - Benzenetetracarboxylic acid( H4tcb) has a versatile coordination behavior sinceit can bridge metal centers in many modes,gener-ating various and sometimes surprising moleculararchitectures. Therefore,numerous complexeswith ligand H4TCB have been extensively stud-ied… 相似文献