共查询到20条相似文献,搜索用时 15 毫秒
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Alexander Preinfalk Dr. Antonio Misale Prof. Dr. Nuno Maulide 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(41):14471-14474
The reaction of aryl‐substituted allenes with alcohols under gold catalysis led to highly substituted indenes in good yields, with low catalyst loading and under mild conditions. During this domino transformation, two C?C bonds are formed with water as the only byproduct. 相似文献
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Back Cover: Silver‐Catalyzed Cross‐Coupling of Propargylic Alcohols with Isocyanides: An Atom‐Economical Synthesis of 2,3‐Allenamides (Chem. Eur. J. 8/2014) 下载免费PDF全文
Jianquan Liu Zhenhua Liu Nannan Wu Dr. Peiqiu Liao Prof. Xihe Bi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(8):2388-2388
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Back Cover: Organomagnesium‐Catalyzed Isomerization of Terminal Alkynes to Allenes and Internal Alkynes (Chem. Eur. J. 22/2015) 下载免费PDF全文
Dr. Raphaël Rochat Koji Yamamoto Michael J. Lopez Haruki Nagae Dr. Hayato Tsurugi Prof. Dr. Kazushi Mashima 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(22):8300-8300
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Ana M. Sanjuán Dr. Muhammad A. Rashid Dr. Patricia García‐García Dr. Alberto Martínez‐Cuezva Dr. Manuel A. Fernández‐Rodríguez Dr. Félix Rodríguez Prof. Dr. Roberto Sanz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):3042-3052
Indenes and related polycyclic structures have been efficiently synthesized by gold(I)‐catalyzed cycloisomerizations of appropriate ortho‐(alkynyl)styrenes. Disubstitution at the terminal position of the olefin was demonstrated to be essential to obtain products originating from a formal 5‐endo‐dig cyclization. Interestingly, a complete switch in the selectivity of the cyclization of o‐(alkynyl)‐α‐methylstyrenes from 6‐endo to 5‐endo was observed by adding an alcohol to the reaction media. This allowed the synthesis of interesting indenes bearing an all‐carbon quaternary center at C1. Moreover, dihydrobenzo[a]fluorenes can be obtained from substrates bearing a secondary alkyl group at the β‐position of the styrene moiety by a tandem cycloisomerization/1,2‐hydride migration process. In addition, diverse polycyclic compounds were obtained by an intramolecular gold‐catalyzed alkoxycyclization of o‐(alkynyl)styrenes bearing a nucleophile in their structure. Finally, the use of a chiral gold complex allowed access to elusive chiral 1H‐indenes in good enantioselectivities. 相似文献
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Meeting the Challenge of Intermolecular Gold(I)‐Catalyzed Cycloadditions of Alkynes and Allenes 下载免费PDF全文
Dr. Michael E. Muratore Anna Homs Carla Obradors Prof. Antonio M. Echavarren 《化学:亚洲杂志》2014,9(11):3066-3082
The development of gold(I)‐catalyzed intermolecular carbo‐ and hetero‐cycloadditions of alkynes and allenes has been more challenging than their intramolecular counterparts. Here we review, with a mechanistic perspective, the most fundamental intermolecular cycloadditions of alkynes and allenes with alkenes. 相似文献
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Gold(I)‐Catalyzed Enantioselective Desymmetrization of 1,3‐Diols through Intramolecular Hydroalkoxylation of Allenes 下载免费PDF全文
Dr. Weiwei Zi Prof. Dr. F. Dean Toste 《Angewandte Chemie (International ed. in English)》2015,54(48):14447-14451
A gold(I)‐catalyzed enantioselective desymmetrization of 1,3‐diols was achieved by intramolecular hydroalkoxylation of allenes. The catalyst system 3‐F‐dppe(AuCl)2 /(R)‐C8‐TRIPAg proved to be specifically efficient to promote the desymmetrizing cyclization of 2‐aryl‐1,3‐diols, which have proven challenging substrates in previous reports. Multisubstituted tetrahydrofurans were prepared in good yield with good enantioselectivity and diastereoselectivity by this method. 相似文献
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Hiroaki Chiba Yuki Sakai Ayako Ohara Dr. Shinya Oishi Prof. Dr. Nobutaka Fujii Prof. Dr. Hiroaki Ohno 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(27):8875-8883
The total synthesis of the pentacyclic tetrahydroisoquinoline alkaloid quinocarcin, which possesses intriguing structural and biological features, has been achieved through a gold(I)‐catalyzed regioselective hydroamination reaction. It is noteworthy that the regioselectivity of the intramolecular hydroamination of an unsymmetrical alkyne could be completely switched through substrate control. Other key features of this synthesis include the highly stereoselective synthesis of 2,5‐cis‐pyrrolidine through the intramolecular amination of the bromoallene and the Lewis acid mediated ring opening of dihydrobenzofuran. 相似文献
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Back Cover: Highly Regio‐, Diastereo‐, and Enantioselective Gold(I)‐Catalyzed Intermolecular Annulations with N‐Allenamides at the Proximal CC Bond (Angew. Chem. Int. Ed. 49/2015) 下载免费PDF全文
Yidong Wang Peichao Zhang Deyun Qian Prof. Dr. Junliang Zhang 《Angewandte Chemie (International ed. in English)》2015,54(49):14980-14980
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Inside Back Cover: A Convenient Palladium‐Catalyzed Carbonylative Suzuki Coupling of Aryl Halides with Formic Acid as the Carbon Monoxide Source (Chem. Eur. J. 49/2015) 下载免费PDF全文
Dr. Xinxin Qi Li‐Bing Jiang Hao‐Peng Li Prof. Dr. Xiao‐Feng Wu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(49):17987-17987
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