共查询到20条相似文献,搜索用时 15 毫秒
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It is shown that oxazolidines derived from racemic unbranched α-acetoxyaldehydes and ?-ephedrine have predictable chromatographic mobilities, with the R-isomer always having a higher Rf-value. This resolution has been used to prepare and -HETE. 相似文献
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Tadashi Nakata Shigeto Nagao Sachiko Takao Tadasu Tanaka Takeshi Oishi 《Tetrahedron letters》1985,26(1):73-74
(1,3,5)-1,3-Dimethyl]-2,9-dioxabicyclo[3.3.1]nonane has been stereoselectively synthesized based on a highly stereoselective method for the synthesis of 1,3--polyol. 相似文献
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An asymmetric synthesis of both isomers of dimethyl 2-acetoxycitramalate in over 96% enantiomeric excess is described. 相似文献
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All four isomers of substituted 3-alkylthio-4-hydroxybutenes have been synthesised: both the geometry of the double bond and the relative stereochemistry of the two chiral centres are controlled. 相似文献
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We describe a short synthesis of ()-5-hydroxymethyl-(5-furan-2-one and some 5-O-derivatives, which are being used as key starting products for the synthesis of several antileukaemic lignan lactones, from -ribonolactone. 相似文献
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Intermediates in asymmetric hydrogenation by the title phosphine are defined by NMR techniques. 相似文献
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Claudio Fuganti Piero Grasselli Stefano Servi Carlo Zirotti 《Tetrahedron letters》1982,23(41):4269-4272
The C4erythro and threo diols (7) and (8) are converted either into the chiral epoxides (13) and (15) or into the enantiomers (14) and (16); the epoxide (13) is used as chiral synthon for the preparation of (3,4) 4-methyl-3-heptanol (21). 相似文献
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By appropriate choice of reaction conditions, the enantiomerically pure ()-(+)-2-(-tolylsulfinyl)cycloalkenone can be converted into an ()-or an ()-3-substituted cycloalkanone in good to excellent enantiomeric purity. 相似文献
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An asymmetric synthesis of ()-(?)-mevalolactone in over 87% enantiomeric purity is described. 相似文献
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1,3,7,9,11,12,14-Heptazapentacene-2,4,8,10 (14,3,9,12)-tetraones (mixed flavins) were prepared by the cyclization of 1,5-dihydro-8-[N-alkyl-N-(5-nitrouracil-6-yl)-amino-5-deazaflavins with Vilsmeier reagent. The mixed flavins oxidized alcohol under neutral condition in sunlight and a remarkable autorecycling was observed. 相似文献
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Hideo Kigoshi Makoto Ojika Yoshikazu Shizuri Haruki Niwa Kiyoyuki Yamada 《Tetrahedron letters》1982,23(51):5413-5414
From a red alga (10, 11)-(+)-squalene-10, 11-epoxide was isolated and its asymmetric synthesis has been achieved starting from -farnesol. 相似文献
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Non enzymatic hydration of leukotriene A (), the biogenetic precursor of leukotriene B () affords among other products two diastereomeric 6--isomers of 2, the first stereospecific and efficient syntheses of which are recorded herein. 相似文献
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The term MIRC reaction is defined. Examples of the construction of three, five, six and seven membered rings using alkylthiolates and LDA as nucleophiles are presented. 相似文献