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1.
Paal-Knorr condensation of 2,5-hexandione with primary amines was successfully carried out in ionic liquids. Through investigating different ionic liquids, different reaction times, the reaction, using ionic liquids as solvent, exhibited simple product isolation procedure, improved yields and exclusive selectivity and the mild conditions and the avoidance of using toxic catalysts are also its special features. Recovery and reuse of ionic liquid are also satisfactory. 相似文献
2.
纳米二氧化钛催化苯乙烯环氧化反应的研究 总被引:5,自引:0,他引:5
通过烯烃的环氧化反应 ,可制得活泼的有机合成中间体——环氧化物 ,再通过选择性开环或功能团转化 ,可以方便地合成多种有价值的化合物 .因此 ,催化烯烃环氧化的反应得到广泛的研究 ,其中含钛催化剂具有较好的催化性能 ,如 Ti- ZSM- 5沸石 [1,2 ] 、Ti- ZSM- 1 1沸石[3 ,4 ] 在 H2 O2 存在下就有高的催化活性 ;α-和β- [Si W9Ti3 O4 0 ]10 -也有一定的催化活性 [5] ;Sharpless等人 [6]采用 Ti[OCH( CH3 ) 2 ]4和酒石酸二乙酯诱导体 ,可高选择性催化烯丙醇的不对称环氧化反应 .纳米 Ti O2 ,由于颗粒小 ,处于固体表面的原子多 ,表… 相似文献
3.
氯铝酸室温离子液体中缩醛和缩酮反应 总被引:16,自引:0,他引:16
以取代硫酸等无机酸,实现清洁合成为目的,在1-烷基吡啶和1-甲基-3- 烷基咪唑季胺盐与无水AlCl_3构成的室温离子液体为催化剂和反应介质中,尝试了 醛和酮与甲醇的缩合反应。醛与甲醇反应,产物以缩醛为主,酮与甲醇反应则有相 当量的Aldol缩合产物。依反应底物不同,可获得中至高的转化率和选择性。同时 ,一些产物因不溶于离子液体中而分层,便于产物分离。 相似文献
4.
Silica-gel-confined ionic liquids: a new attempt for the development of supported nanoliquid catalysis 总被引:8,自引:0,他引:8
A new concept of designing and synthesizing highly dispersed ionic-liquid catalysts was developed through physical confinement or encapsulation of ionic liquids (with or without metal complex) in a silica-gel matrix through a sol-gel process. We studied ionic liquids such as EMImBF4, BuMImBF4, DMImBF4, CMImBF4, BuMImPF6, either with or without [Pd(PPh3)2Cl2] and [Rh(PPh3)3Cl], in a silica-gel matrix (E = ethyl, Bu = butyl M = methyl, D = decyl, C = cetyl and Im = imidazolium). The contents of ionic liquids and loadings of Pd or Rh were 8-53 wt % and 0.1 approximately 0.15 wt %, respectively. Analyses of FT-Raman spectra showed that abnormal Raman spectra of the confined ionic liquids were observed in comparison with the bulk and pure ionic liquids. EMImBF4 and BuMImBF4 ionic liquids could be completely washed out from the silica-gel matrix under vigorous reflux conditions, but ionic liquids with larger molecular size, for example, DMImBF4 or CMImBF4, could be confined into the silica-gel nanopores relatively firmly. These results suggested that the ionic liquids were physically confined or encapsulated into the silica gel. The N2 adsorption measurements indicated that the silica-gel skeleton was mesoporous with 50-110 A pore size after the BuMImBF4 ionic liquid was removed completely. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) analysis showed that the silica-gel matrix was amorphous and non-uniformly mesoporous. Carbonylation of aniline and nitrobenzene for synthesis of diphenyl urea, carbonylation of aniline for synthesis of carbamates, and oxime transformation between cyclohexanone oxime and acetone were used as test reactions for these catalysts. Catalytic activities were remarkably enhanced with much lower amounts of ionic liquids needed with respect to bulk ionic-liquid catalysts or silica-supported ionic-liquid catalysts prepared with simple impregnation, in which the ionic liquid may be deposited as a thin layer on the support. Such unusual enhancement in catalytic activities may be attributed to the formation of nanoscale and high-concentration ionic liquids due to the confinement of the ionic liquid in silica gel; this results in unusual changes in the symmetry and coordination geometry of the ionic liquids. 相似文献
5.
The internal redox esterification of α,β-unsaturated aldehydes and alcohols was carried out using different ionic liquids (ILs) as catalysts and reaction solvents. The basic ionic liquid, 1-butyl-3-methylimidazolium acetate ([bmim]OAc), exhibited the best activity for this reaction. The influences of the amount of ionic liquid catalyst and reaction time on yield of saturated ester have been investigated. The results showed that ionic liquid anions have a crucial effect on the redox esterification of α,β-unsaturated aldehydes and alcohols. The nucleophilic carbenes generated in situ from the ionic liquid cation were believed to be actual active species for this reactions. 相似文献
6.
超临界CO2/离子液体体系 总被引:2,自引:0,他引:2
超临界CO2和离子液体是两种具有优异性能的绿色化学试剂,本文介绍了将两者结合反应,分离体系的物化性质和多种绿色化学过程。利用超临界CO2可以广泛地萃取离子液体中的不挥发性化合物而不导致离子液体及其中催化剂的流失,在加氢、醛化、甲酰化等反应,分离过程中的应用表明,过程具有很好的反应分离特性和环境友好性,应用前景广阔。 相似文献
7.
Kulkarni PS Branco LC Crespo JG Afonso CA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(30):8470-8477
A novel study on organic solute absorption from the vapor phase is reported. The organic solutes chosen for the absorption studies include 1,4-benzodioxane, biphenyl, xanthene, and menthol. A series of imidazolium, ammonium, and guanidinium-based ionic liquids (ILs) containing several types of anions were used as absorbents. Absorption of water vapor was also studied along with the organic solutes. Absorption studies of each organic solute were performed by using a specially devised glass apparatus at 50 degrees C. It was observed that the rate of absorption increases with time and is faster in the case of 1,4-benzodioxane (24 h). The absorption process for each organic solute with different classes of ionic liquids was studied and the results were compared with each other. Absorption values of more than 25,000 ppm were observed in some ionic liquids. Distribution ratios of organic solutes in an ionic liquid and in the vapor phase were measured and the selectivity was evaluated by using the distribution ratio values. A remarkable selectivity was observed for some ionic liquids towards a specific organic solute. Importantly, it was observed that the selectivity remained constant, even though a mixture of solute was used for the absorption study. Desorption of organic vapors from ionic liquids was successfully carried out by applying a vacuum. Further, it was observed that the same ionic liquid can be repeatedly reused several times for absorption. These studies reveal that, in future, a task-specific ionic liquid can be prepared and used for specific solute capture from the vapor phase. 相似文献
8.
碱性离子液体催化甘油合成1,2-甘油碳酸酯(英) 总被引:3,自引:0,他引:3
以离子液体为催化剂,在无溶剂体系中,考察了生物质平台化合物甘油转化1,2-甘油碳酸酯的反应.与酸性离子液体和常用无机碱性催化剂相比,碱性离子液体咪唑基1-丁基-3-甲基咪唑([Bmim]Im)、氢氧化1-丁基-3-甲基咪唑([Bmim]OH)、咪唑基1-烯丙基-3-甲基咪唑([Amim]Im)、氢氧化1-烯丙基-3-甲基咪唑([Amim]OH)在甘油与碳酸二甲酯的酯交换反应中表现出优异的活性.其中,以[Bmim]Im离子液体为催化剂时甘油转化率为98.4%和甘油碳酸酯选择性接近100%.另外,该离子液体可以回收重复利用3次后甘油转化率仍可达92%,甘油碳酸酯选择性可近100%.此碱性离子液体催化方法具有反应结果较好、产物分离简单、条件温和以及环境友好等特点. 相似文献
9.
离子液体介质中用Cu/ZrO2-SiO2催化香茅醛加氢合成薄荷醇 总被引:1,自引:0,他引:1
制备了Cu/ZrO2-SiO2双载体催化剂, 并在离子液体介质中研究了香茅醛催化加氢合成薄荷醇的反应. 研究结果表明, 离子液体中的阳离子与香茅醛分子中的羰基形成氢键, 使香茅醛更容易异构化为胡异薄荷醇, 提高了催化剂的选择性; 特别是可调节酸度的[bmim][AlmCln]离子液体, 有效地提供了香茅醛的异构化所需要的路易斯酸条件, 在竞争性加氢中促进了香茅醛向生成薄荷醇的方向转化. 在0.8 MPa, 90 ℃, 2 h的条件下, 香茅醛一锅反应生成薄荷醇的转化率为100%, 对薄荷醇的选择性为91.3%, 而且, 催化剂和离子液体可回收和重复使用. 相似文献
10.
The continuous dehydration of D-glucose into 5-hydroxymethylfurfural(HMF) was carried out under mild conditions,using SO3H-functionalized acidic ionic liquids as catalysts and H2O-4-methyl-2-pentanone(MIBK) biphasic system as solvent.High glucose conversion of 97.4% with HMF yield of 75.1%was obtained at 120 8C for 360 min,also,small amounts of levulinic acid(LA) and formic acid were generated.Generally,the dosage of catalyst and the initial content of glucose influenced the reaction significantly; the HMF selectivity decreased with the excessive elevation of temperature and prolonging of time; and water content in the system had a negative effect on the reaction.The ionic liquid catalyst could be recycled and exhibited constant activity for five successful runs.This paper provided a new strategy for HMF production from glucose. 相似文献
11.
离子液体中V2O5催化环己烯选择氧化合成 2-环己烯酮 总被引:1,自引:0,他引:1
研究了以V2O5为催化剂,H2O2为氧化剂,在室温离子液体中环己烯氧化制备2-环己烯酮的反应.考察了离子液体种类、反应温度、催化剂用量和氧化剂用量等因素对2-环己烯酮产率的影响.结果表明,在H2O2用量为110 mmol,V2O5/环己烯摩尔比为2%,反应温度为313 K的条件下,在[bmim]BF4离子液体中反应10 h后,环己烯的转化率和2-环己烯酮选择性分别为88.7%和91.1%.对含离子液体的催化体系的重复使用性能进行了考察.结果发现,随着使用次数的增加,环己烯的转化率以及2-环己烯酮的选择性有所下降. 相似文献
12.
改性离子液体中异丁烷与丁烯的烷基化反应 总被引:16,自引:2,他引:16
向由无水三氯化铝和盐酸三乙基胺合成的离子液体中溶入不同过渡金属(铜、铁、锌等)离子,考察它们对离子液体催化异丁烷与丁烯烷基化反应性能的影响。结果表明:过渡金属离子的加入能不同程度地影响离子液体的催化性能。溶入Cu2+和Cu+后,离子液体的催化性能有显著的改善,当Cu2+的摩尔加入量为三氯化铝的5%时,烷基化油收率达到丁烯体积的178%,对C8的选择性为75%,烷基化油辛烷值(RON)为92.2,并且离子液体可以重复使用。 相似文献
13.
Earle MJ Hakala U McAuley BJ Nieuwenhuyzen M Ramani A Seddon KR 《Chemical communications (Cambridge, England)》2004,(12):1368-1369
A range of metal bis[(trifluoromethyl)sulfonyl]amide complexes, including many unreported ones, have been synthesised, most of which have been found to be excellent Friedel-Crafts acylation catalysts in the absence of solvent; these reactions have also been carried out in ionic liquids, which allow the catalysts to be recycled and reused. 相似文献
14.
Wenkang Lei Zaikun Wu Jie Ma Ping Yu Yunbai Luo 《Research on Chemical Intermediates》2016,42(9):6893-6905
Two routes to 1,2-cyclohexanediol were studied. Specifically: (a) the hydrolysis of cyclohexene oxide and (b) the direct dihydroxylation of cyclohexene with aqueous hydrogen peroxide. Both reactions were carried out with zeolites as catalysts under solvent-free conditions, aiming to establish green routes for the synthesis of 1,2-cyclohexanediol. In the first route, H-Beta and H-ZSM-5 zeolites were used as catalysts, respectively. According to the results, H-ZSM-5 was a suitable catalyst for the hydrolysis of cyclohexene oxide. A 88.6 % yield of 1,2-cyclohexanediol could be obtained at a 96.2 % conversion of cyclohexene oxide under mild conditions, and the catalyst could be reused for three times. Compared with H-ZSM-5, H-Beta gave a much lower selectivity (63 %), although it was more active. In the second route, Ti-Beta zeolites with three different Ti loadings prepared via a simple two-step strategy were characterized and used. The results indicated that it was the framework Ti species which was responsible for the catalytic activity. The resultant Ti-Beta-3 % could give a 90.2 % cyclohexene conversion at a 66.2 % selectivity of 1,2-cyclohexanediol. 相似文献
15.
Alexandre A.M. Lapis Jackson D. Scholten Marcos N. Eberlin 《Tetrahedron letters》2006,47(38):6775-6779
Intermolecular hydroamination or hydroarylation reactions of norbornene and cyclohexadiene performed with catalytic amounts of Brönsted or Lewis acid in ionic liquids were found to provide higher selectivity and yields than those performed in classical organic solvents. The ionic liquid increases the acidity of the media and stabilizes ionic intermediates through the formation of supramolecular aggregates. 相似文献
16.
José C.J.M.D.S. Menezes Ana M.V.M. Pereira Maria G.P.M.S. Neves Artur M.S. Silva Sérgio M. Santos Sabrina T. Martinez Bárbara V. Silva Ângelo C. Pinto José A.S. Cavaleiro 《Tetrahedron》2012,68(39):8330-8339
New porphyrin indolin-2-one conjugates were synthesized via palladium-catalyzed amination reactions of iodinated and dibrominated indolin-2-one derivatives with (2-amino-5,10,15,20-tetraphenylporphyrinato)nickel(II). The combination of palladium catalysts and the phosphine ligand dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl (XPhos) is an effective methodology for catalyzing the coupling of 5-iodo-, 5,7-dibromo- and 4,6-dibromo-1,3,3-trimethylindolin-2-one with 2-aminoporphyrin to give the corresponding mono-(2-aminoporphyrinyl)- and di-(2-aminoporphyrinyl)-substituted indolin-2-ones in satisfactory yields under mild conditions. The mono brominated porphyrinic derivatives also underwent cross-coupling reactions under similar catalytic conditions. The studies also demonstrated that the course of the coupling process depends on factors, such as the catalytic system, number and position of the halogen substituents and the heating condition. Insights into the reactivity trends of the 5-iodo; 4,6- and 5,7-dibrominated indolin-2-one derivatives was carried out using theoretical calculations performed using density-functional theory with the B3LYP functional. 相似文献
17.
Cole AC Jensen JL Ntai I Tran KL Weaver KJ Forbes DC Davis JH 《Journal of the American Chemical Society》2002,124(21):5962-5963
The reaction of triphenylphosphine or N-butylimidazole with cyclic sultones gives zwitterions that are subsequently converted into ionic liquids by reaction with trifluoromethane sulfonic acid or p-toluenesulfonic acid. The resulting ionic liquids have cations to which are tethered alkane sulfonic acid groups. These Br?nsted acidic ionic liquids are useful solvent/catalysts for several organic reactions, including Fischer esterification, alcohol dehydrodimerization and the pinacol rearrangement. The new ionic liquids combine the low volatility and ease of separation from product normally associated with solid acid catalysts, with the higher activity and yields normally found using conventional liquid acids. 相似文献
18.
Alexandra Brown Victoria Hogan Jacob Perry Renuka Manchanayakage 《Tetrahedron letters》2017,58(11):1061-1065
Chiral ionic liquids show promising applications in various different fields. A series of pyrrolidinium-based chiral ionic liquids bearing a chiral cation, a chiral anion or both was prepared in good yields using an efficient, economic and simple pathway. The chirality was introduced using (l)-lactate and (l)-menthol derivatives. The resultant chiral compounds were characterized by both spectroscopy and polarimetry. We envision that these new chiral compounds can serve as effective reaction media and chiral catalysts for asymmetric reactions, which are presently being investigated in our lab. 相似文献
19.
For several decades various chemical industries are involved in environment pollution by using hazardous chemicals or excessive use of solvents or catalysts to get maximum amount of desired product. In this case acidic ionic liquids may act as safer substitute of volatile organic solvents/or traditional Brønsted or Lewis acid catalysts with their unique dual task-specific solvent-catalyst properties. Recent surge in the literature review clearly describes the importance, properties and applications of acidic ionic liquids as solvent and efficient reusable catalyst in organic reactions. This review presents an account of some recent reports indicating the synthesis and uses of –SO3H functionalized ionic liquids(SFILs) as catalyst in organic synthesis. 相似文献
20.
Bini R Chiappe C Mestre VL Pomelli CS Welton T 《Organic & biomolecular chemistry》2008,6(14):2522-2529
The Diels-Alder reaction between cyclopentadiene and three dienophiles (acrolein, methyl acrylate and acrylonitrile) having different hydrogen bond acceptor abilities has been carried out in several ionic liquids and molecular solvents in order to obtain information about the factors affecting reactivity and selectivity. The solvent effects on these reactions are examined using multiparameter linear solvation energy relationships. The collected data provide evidence that the solvent effects are a function of both the solvent and the solute. For a solvent effect to be seen, the solute must have a complimentary character; selectivities and rates are determined by the solvent hydrogen bond donation ability (alpha) in the reactions of acrolein and methyl acrylate, but not of acrylonitrile. 相似文献