Theory of the relaxation pressure in a dissociating gas

The influence of a slow dissociation reaction (the reaction rate is much lower than the rate of energy exchange between the translational and internal degrees of freedom of the gas particles) on the transfer coefficients is studied using the Chapman—Enskog method. It is shown that changes occur only in the diagonal part of the pressure tensor, where an additional coefficient, the so-called relaxation pressure, appears.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 101–107, March–April, 1978.The author thanks A. S. Pleshanov for useful discussions and valuable comments.     

The noneouilibrium dissociation of diatomic molecules in a boundary layer

A study is made of the influence of the process of diffusion of diatomic molecules on the rate of their thermal dissociation. On the basis of the ladder model of the dissociation of molecules — truncated harmonic oscillators — an expression is obtained for the macroscopic reaction rate which depends explicitly and exponentially on the square of the gradient of the gas temperature. The molecules constitute a small admixture in a monatomic inert gas. The effect of the diffusion on the rate of dissociation is illustrated by the results of numerical calculation of the flow in the boundary layer around the stagnation point of a blunt body.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Shidkosti i Gaza, No. 1, pp. 161–170, January–February, 1985.     

Determination of the constants of electrochemical reactions and the ion mobility coefficients in weakly conducting liquids from an analysis of the current—voltage characteristics

The problem is considered of the passage of a direct current through a solution of a weak electrolyte in a two-dimensional cell. Allowance is made for the electrochemical reactions of dissociation and reconbination which take place in the electrolyte when the rate of dissociation of the molecules is regarded as dependent on the electric field intensity [1–3]. For electrolytes whose recombination coefficient is of the order of magnitude of the Langevin coefficient, theoretical current—voltage characteristics are given for the limiting cases of large and small values of the characteristic times for the ion concentrations to be changed by electrochemical reactions and the transport of ions by the electric field. A method of determining the dissociation rate, the recombination coefficient, and the ion mobility coefficients is proposed on the basis of comparison of the theoretical and experimental current—voltage characteristics.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6. pp. 113–120, November–December, 1984.     

Model of the physico-chemical kinetics behind the front of a very intense shock wave in air

A model of the physico-chemical kinetics of the reactions taking place behind the front of an intense shock wave propagating in air with a speed of 9–14 km/s is proposed. The problem of describing the chemical reactions, namely, molecular dissociation and exchange reactions involving vibrationally excited molecules in the absence of vibrational equilibrium, is solved. The vital role of the vibrational excitation delay in the dissociation of oxygen and nitrogen is established. The rate of the exchange reaction between nitrogen molecules and oxygen atoms in the shock wave depends only slightly on the vibrational excitation level. It is demonstrated that the rate constants for thermally nonequilibrium dissociation reactions can be represented within the framework of the one-temperature approximation at constant vibrational temperatures of the dissociating species satisfying quasi-stationary conditions.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 169–182, March–April, 1995.     

Numerical investigation of supersonic viscous gas flow over long blunt cones with allowance for equilibrium physicochemical effects

Supersonic axisymmetric viscous heat-conducting gas flow over long spherically biunted cones is considered over a broad range of Reynolds numbers on the basis of the complete system of viscous shock layer equations. An economical numerical method based on global iterations is used to solve the viscous shock layer equations. The general influence of the second-approximation effects of boundary layer theory and the influence of equilibrium physicochemical processes on the heat loads are determined for bodies with a large aspect ratio.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 1, pp. 202–205, January–February, 1993.The author wishes to thank S. A. Vasil'evskii and I. A. Sokolova for providing the tables used to calculate the transport coefficients and G. A. Tirskii for his constant interest and useful discussions.     

Nonequilibrium dissociation of diatomic molecules in flows with convective and diffusive particle transport

The nonequilibrium effects in the kinetics of the thermal dissociation which occurs in a streaming gas of diatomic molecules are investigated. Expressions are obtained for the macroscopic reaction rate and the vibrational energy distribution of the molecules, taking into account the influence of the gas motion. Cases of flows with convective and diffusive particle transport are considered. The dissociating molecules are simulated by cutoff harmonic oscillators. The vibrational kinetics is described in the framework of the so-called diffusion approximation.Translated fron Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 147–153, November–December, 1985.     

Transport coefficients for a partially ionized two-temperature plasma with ions and neutral particles having different masses

The viscosity, heat-conduction, and diffusion coefficients are calculated for a two-temperature three-component plasma composed of ions, neutral particles and electrons when the masses of the ions m_i and neutral particles m_a are different. Similar transport coefficients for m_i=m_a were calculated in [1–3]. The numerical values obtained for the transport coefficients are compared with the values calculated from the formulas of [1–3]. Numerical calculations are carried out for helium with a cesium additive (m_i>m_a) and for krypton with a lithium additive (m_ia).Finally, the author is grateful to V. V. Gogosov, under whose direction this work was carried out.     

Parametric excitation of waves at an interface

Experiments on the parametric excitation of waves at a fluid interface show a strong disagreement with theoretical results [1–3], since the latter do not take into account the influence of the second medium. This proves to be especially important at low frequencies. Thus, for a water-air interface with an excitation frequency = 60 sec^–1 the contribution amounts to 10%,and with = 30 sec^–1, even 20%. In this paper the stability of the interface of two viscous, incompressible fluids of finite depth in a variable gravity field is considered. The problem is put in the linear form by making an expansion with respect to the small viscosity and is solved by taking the Laplace transform with respect to time. A second-order integrodifferential equation with periodic coefficients is obtained for the deviation of the interface from the equilibrium position; its solution is sought by the method of averaging [4]. It is shown that the presence of the second fluid significantly raises the threshold of instability.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 167–170, March–April, 1977.     

Stability of quasistatic equilibrium state of an inhomogeneous viscous layer on an inclined plane

A study is made of the stability against small perturbations [1] of a slow flow of an incompressible inhomogeneous linearly viscous liquid under the influence of a force of gravity on an unbounded inclined plane. Problems of such kind arise in glaciology when one estimates the stability of snow on mountain slopes or determines the catastrophic movement of a glacier; the results can also be applied to solifluction phenomena [2, 3]. Equations for perturbations of parallel flows of linearly viscous fluids in the case of a continuous variation of the viscosity and density across the flow were derived in [4]. An attempt to solve the hydrodynamic problem with allowance for a perturbation of the viscosity was made in [5]; however, in the equations for the perturbations, simplifications resulted in the neglect of terms that take into account perturbations of the viscosity. In the quasistatic formulation considered here in the case when allowance is made for perturbation of the density and viscosity, the equation for the perturbation amplitudes is an ordinary differential equation with variable coefficients; analytic solution of the equation is very difficult, even for long-wave perturbations. In this connection a study is made of the stability of a laminar model; the viscosity and density are constant within each layer. A similar hydrodynamic problem in the long-wave approximation was considered in [6]. In the present paper an exact solution is constructed in the quasistatic formulation for a two-layer model; the solution shows that the viscosity of the lower layer has an important influence on the stability. Essentially, instability is observed when the lower layer acts as a lubricant.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 20–24, November–December, 1973.     

Boundary layer on a flat plate with strong longitudinal magnetic field

The influence of a magnetic field on the boundary layer on a flat plate in a sufficiently strongly ionized gas stream is studied. The magnetic field is parallel to the plate and to the velocity of the free stream, and it is so strong that the transport coefficients become anisotropic (the cyclotron rotation frequency of the charged particles is greater than or equal to the order of the frequency of the particle collisions). Using the results of [1–3] it is shown that the effect of the strong longitudinal magnetic field with a sufficiently high degree of gas ionization leads to a reduction in the thermal flux to the plate. For low degrees of ionization this effect is very small, since the viscosity and heat conduction in this case are determined by the neutral component of the gas.Results are presented of numerical calculations of the considered problem with account for the dependence of the transport coefficients on the thermodynamic parameters. It is assumed throughout that the magnetic Reynolds number is small (R_m1).     

Effect of rotational degrees of freedom of molecules on energy flux in attenuated gas

On the basis of model kinetic equations a solution is obtained by a numerical method for the flow of attenuated gas around a sphere. The effect of rotational degrees of freedom on the energy flux to the body is investigated. Values of the ratio between the energy flux Q and its free-molecular value Q* for monatomic and diatomic gases are compared; for the comparison, the dimensionless temperature of the body, the gas velocity at infinity, and the law of viscosity must be the same in the two cases. For sufficiently cold bodies (when the body temperature is below the equilibrium temperature for a diatomic gas) the difference between Q/Q* for monatomic and diatomic gases is insignificant. For a diatomic gas when the body temperature is close to equilibrium, the ratio Q/Q* is found to have a nonmonotonic dependence on the Knudsen force.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 119–124, September–October, 1977.     

Radiative and convective heat transfer in hypersonic flow around a blunt body

The heat transfer in the vicinity of the critical point is investigated for hypersonic air flow around a blunt body. The gas-dynamical conservation equations are solved simultaneously with the radiative transport equation in integral form. Allowance is made for the viscosity, heat conduction, and the actual radiation parameters of air, including spectral line emission. Profiles are obtained for the thermodynamic variables along the critical line. The dependence of the radiative and convective components of the aerodynamic heating on the velocity and pressure ahead of the shock front as well as the radius of curvature of the blunt nose section is discussed. Approximate relations having the form of similarity laws are derived for the heat fluxes in the vicinity of the critical point. The limits of applicability of the thermodynamic equilibrium approximation in the shock-compressed layer are discussed. The influence of absorption of radiation from the compressed layer by the cold freestream on the aerodynamic heating is considered. Attention is given in this case to the dependence of the spectral absorption coefficient for the cold air on the intensity of the radiation incident upon it.Moscow. Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 5, pp. 112–123, September–October, 1972.     

Flow and Mixing Fields for Transported Scalar PDF Simulations of a Piloted Jet Diffusion Flame (‘Delft Flame III’)

Numerical simulation results are presented for ‘Delft Flame III’, a piloted jet diffusion flame with strong turbulence–chemistry interaction. While pilot flames emerge from 12 separate holes in the experiments, the simulations are performed on a rectangular grid, under the assumption of axisymmetry. In the first part of the paper, flow and mixing field results are presented with a non-linear first order k–ε model, with the transport equation for ε based on a modeled enstrophy transport equation, for cold and reactive flows. For the latter, the turbulence model is applied in combination with pre-assumed β-PDF modeling for the turbulence–chemistry interaction. The mixture fraction serves as conserved scalar. Two chemistry models are considered: chemical equilibrium and a steady laminar flamelet model. The importance of the turbulence model is highlighted. The influence of the chemistry model is noticeable too. A procedure is described to construct appropriate inlet boundary conditions. Still, the generation of accurate inlet boundary conditions is shown to be far less important, their effect being local, close to the nozzle exit. In the second part of the paper, results are presented with the transported scalar PDF approach as turbulence–chemistry interaction model. A C₁ skeletal scheme serves as chemistry model, while the EMST method is applied as micro-mixing model. For the transported PDF simulations, the model for the pilot flames, as an energy source term in the mean enthalpy transport equation, is important with respect to the accuracy of the flow field predictions. It is explained that the strong influence on the flow and mixing field is through the turbulent shear stress force in the region, close to the nozzle exit.     

Estimation of the effect of vibrational excitation of diatomic molecules on their diffusional transport and dissociation in a boundary layer

Relations for the diffusion fluxes of vibrationally highly excited diatomic molecules are found by means of the Chapman-Enskog method. On the basis of these relations a quantitative estimate of the changes in the diffusion coefficients under vibrational excitation and the corresponding changes in the macroscopic dissociation rate is obtained under conditions of disequilibrium of the upper vibrational levels of the dissociating molecules caused by the diffusion processes. The diffusion relations obtained are used in deriving the boundary conditions for the equations of level vibrational kinetics. A simplified version of this derivation is presented for noncatalytic and catalytic surfaces.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 1, pp. 169–182, January–February, 1996.     

Theory of cooled electric probes in a dense plasma. Influence of thermal diffusion

The problem of an electric probe in the shape of a sphere in a weakly ionized three-component plasma at rest is studied. It is assumed that the probe diameter is appreciably larger than the mean free path of the charged particles and that the temperature of the probe surface differs from the temperature of the undisturbed plasma. The contribution of thermal-diffusion mass transport is taken into account in the expressions for the densities of the electric currents of the components. A new numerical method is developed to obtain a solution of the problem in a wide range of the determining parameters. The current-voltage characteristics are constructed. The influence of the probe temperature, the transport coefficients, and other parameters on the current-voltage characteristics is analyzed.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 103–112, March–April, 1979.     

Shift of chemical equilibrium in a binary reacting mixture of molecular gases under the action of resonance laser radiation

At the present time, great attention is being paid to the problem of the final state of molecular gas systems originating from a steady external effect. This is associated, first of all, with intensive investigations of the properties of molecular gas lasers and also laser initiation of chemical reactions and the isotope separation. The theoretical feasibility is shown in [1, 2] for effectively shifting the chemical equilibrium in dissociation—three-particle recombination reactions, initiated in a single-component gas by resonance laser radiation. The purpose of this paper is to analyze the shift of chemical equilibrium in a binary mixture of molecular gases as a function of the intensity and nature of the laser pumping. It is well known [3] that the equilibrium constant of a chemical reaction can be expressed in terms of the dissociation equilibrium constant of the molecules participating in the reaction This factor permits the problem to be reduced to calculation of the dissociation equilibrium constants.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 1, pp. 3–9, January–February, 1978.The authors express thanks to B. F. Gordiets for numerous discussions of the results obtained and also to R. V. Khokhlov and P. K. Khabibullaev for support and interest in the work.     

Small vibrations of a sphere in a spherical volume of viscous fluid

Problems of the vibration of bodies in confined viscous fluids have been solved to determine the added masses and damping coefficients of rods [1–3] and floats [4–5]. The solutions of these problems, based on the use of simplifications of the boundary-layer method [4–6], are obtained analytically in general form and are in good agreement with the experimental data. However, in each specific case the possibility of using such solutions for given values of the fluid viscosity and vibration frequency must be justified either experimentally [2, 4, 5] or theoretically as, for example, in [1], where an analytic solution was obtained for concentric cylinders. The present paper offers a general solution of the problem of the small vibrations of a sphere in a spherical volume of fluid valid over a broad range of variation of the dimensionless kinematic viscosity. The limiting cases of this solution for both high and low viscosity are considered. The asymptotic expressions obtained are compared with calculations based on the analytic solution.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 29–34, March–April, 1986.     

Bending of an Anisotropic Elliptic Plate on an Elastic Foundation

An approach is proposed to solve a stress–strain problem for anisotropic rigidly fixed plates on an elastic foundation. The problem is solved by the method of successive approximations. At each approximation, the deflection is represented as polynomials whose coefficients are determined from a system of linear algebraic equations. Study is made of the influence of the reinforcement angle and the modulus of subgrade reaction on the deflections and the bending moments in an orthotropic plate.     

Transport properties of nonequilibrium polyatomic gas mixtures

It is shown that the well-known Hirschfelder-Euken correction to the thermal conductivity of a polyatomic gas mixture given by the first approximation in Sonine polynomials can be less than the corresponding exact value (for a Lorentz mixture of light and heavy molecules interacting in accordance with Coulomb's law) by a factor of 3.4. Fairly high accuracy is achieved in the second approximation in Sonine polynomials. Within the framework of the latter, similar corrections to the nonequilibrium heat and diffusion fluxes are found. On the basis of the generalized Chapman-Enskog method a more general case is studied. In this case some of the nonelastic collision integrals is also taken into account in calculating the transport coefficients. The transport coefficients are either represented in terms of the well-known formulas for fast and retarded internal molecular energy exchange or convenient approximate expressions are obtained.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 183–189, March–April, 1995.     

Viscosity of some clay-based coating colors at high shear rates

The shear viscosity of clay-based coating colors containing latex and carboxymethyl cellulose (CMC) has been measured over a relatively large shearrate region. In the shear-rate range of 50–1500 s^–1 the measurements were performed using a rotational viscometer and, at higher shear rates extending into the region 10⁵ – 10⁶ s^–1, a high pressure capillary viscometer was employed. The viscosity of the clay colors increased with increasing CMC-concentration, but the influence of the CMC-content was less pronounced at higher shear rates. The apparent shear-thinning behavior of the investigated colors could, in part, be attributed to the shear-thinning of the corresponding polymer (CMC) solution constituting the liquid phase of the color, but the influence of another factor was also indicated. At low shear rates, the interaction between the color components can produce relatively high viscosity levels, but in the high shear rate region these interactions appear to be less important for the viscosity level. It is also of interest to note that the viscosity dependence on the solids content in the high shear-rate region could be described with reasonable accuracy using an empirical equation neglecting interactions between the color components.