Solvent extraction of microamounts of europium and americium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and 1,2-(diphenylphosphino)ethylene dioxide

Extraction of microamounts of strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of dibenzo-24-crown-8 (DB24C8, L) has been investigated. The equilibrium data have been explained assuming that the species HL⁺, HL₂ ⁺, ML²⁺, ML₂ ²⁺ and MHL₂ ³⁺ (M²⁺ = Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the complexes in nitrobenzene saturated with water have been determined. It was found that the stability constants of the cationic complex species BaL²⁺ and BaL₂ ²⁺ in the considered nitrobenzene medium are somewhat higher than those of the corresponding complexes SrL²⁺ and SrL₂ ²⁺.     

Solvent extraction of strontium and barium into nitrobenzene by using synergistic mixture of hydrogen dicarbollylcobaltate and dibenzo-24-crown-8

Extraction of microamounts of strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B^?) in the presence of dibenzo-24-crown-8 (DB24C8, L) has been investigated. The equilibrium data have been explained assuming that the species HL⁺, HL₂ ⁺, ML²⁺, ML₂ ²⁺ and MHL₂ ³⁺ (M²⁺ = Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the complexes in nitrobenzene saturated with water have been determined. It was found that the stability constants of the cationic complex species BaL²⁺ and BaL₂ ²⁺ in the considered nitrobenzene medium are somewhat higher than those of the corresponding complexes SrL²⁺ and SrL₂ ²⁺.     

Extraction of microamounts of strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dicyclohexyl-18-crown-6

Summary Extraction of microamounts of strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B^-) in the presence of dicyclohexyl-18-crown-6 (DCH18C6, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, HL, SrL²⁺and SrL are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Extraction of microamounts of calcium,strontium and barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dibenzo-18-crown-6

Extraction of microamounts of calcium, strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of dibenzo-18-crown-6 (DB18C6, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, ML²⁺, ML₂²⁺ and MHL₂³⁺ (M²⁺ = Ca²⁺, Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Solvent extraction of strontium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of 12-crown-4

Extraction of microamounts of strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B^-) in the presence of 12-crown-4 (12C4,L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, HL₂ ⁺, SrL²⁺ and SrL₂ ^+2- are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Extraction of microamounts of calcium and strontium into nitrobenzene using synergistic mixture of hydrogen dicarbollylcobaltate and 2,3-naphtho-15-crown-5

Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of 2,3-naphtho-15-crown-5 (N15C5, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, HL₂ ⁺, CaL²⁺, CaL₂ ²⁺ and SrL₂ ²⁺ are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It has been found that in water saturated nitrobenzene the stability constant of the SrL₂ ²⁺ cationic complex species is substantially higher than that of the complex CaL₂ ²⁺.     

Extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of 1,2-(diphenylphosphino)ethylene dioxide

Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of 1,2-(diphenylphosphino)ethylene dioxide (DPPEDO, L) has been investigated. The equilibrium data have been explained assuming that the species HL⁺, HL₂ ⁺, CaL₂ ²⁺, CaL₃ ²⁺, CaL₄ ²⁺, SrL₂ ²⁺ and SrL₃ ²⁺ are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the CaL _n ²⁺ complexes, where n = 2, 3 and L is DPPEDO, are somewhat higher than those of the corresponding complex species SrL _n ²⁺.     

Extraction of barium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of dibenzo-18-crown-6

Summary Extraction of microamounts of barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B^-) in the presence of dibenzo-18-crown-6 (DB18C6, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, BaL²⁺, BaL, BaHL³⁺and BaHL are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Extraction of 85Sr by a nitrobenzene solution of bis-1,2-dicarbollylcobaltate in the presence of p-nonylphenylnonaethylene glycol and its use for the determination of nonionic surfactants

The equilibrium data and the typical maxima concerning the dependences of the Sr distribution ratios on the analytical concentration of p-nonylphenylnonaethylene glycol in the system under study can be explained assuming that the HL⁺, HL₂ ⁺, SrL²⁺ and SrL₂ ²⁺ particles are extracted into the nitrobenzene phase. The values of the corresponding extraction and stability constants of the extracted species in nitrobenzene saturated with water have been determined. The possibility of the use of this system for the determination of nonionic surfactants by the method of concentration dependence of strontium is discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Extraction of microamounts of calcium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of dibenzo-21-crown-7 and dibenzo-24-crown-8

Extraction of microamounts of calcium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of dibenzo-21-crown-7 (DB21C7) and dibenzo-24-crown-8 (DB24C8) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, CaL²⁺, CaL₂²⁺ and CaHL₂³⁺ (L = DB21C7, DB24C8) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Extraction of microamounts of strontium by a nitrobenzene solution of bis-1,2-dicarbollylcobaltate in the presence of 15-crown-5

Extraction of⁸⁵Sr by a nitrobenzene solution of bis-1,2-dicarbollylcobaltate in the presence of 15-crown-5 (15C5, L) has been investigated. The equilibrium data and the typical maxima concerning the dependencies of the Sr distribution ratios on the analytical concentration of 15C5 in the system under study can be explained assuming that the HL⁺, HL₂ ⁺ and SrL₂ ²⁺ species are extracted into the nitrobenzene phase. The values of the corresponding extraction and stability constants of the extracted species in nitrobenzene saturated with water have been determined.     

Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide

Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of N,N,N′,N′-tetraisobutyl-2,6-dipicolinamide [T(iBu)DPA, L] has been investigated. The equilibrium data have been explained assuming that the species HL⁺, HL₂ ⁺, CaL₂ ²⁺, SrL₂ ²⁺ and SrL₃ ²⁺ are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined.     

Solvent extraction of microamounts of strontium from water into nitrobenzene by using cesium dicarbollylcobaltate in the presence of 15-crown-5

Extraction distribution of microamounts of strontium in the water-CsCl-15-crown-5 (15C5,L)-nitrobenzene-cesium dicarbollylcobaltate system has been investigated. The equilibrium data have been explained assuming that the CsL⁺, CsL₂ ⁺ and SrL₂ ²⁺ complexes are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Solvent extraction of calcium and strontium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and diphenyl-<Emphasis Type="Italic">N,N</Emphasis>-dibutylcarbamoylmethyl phosphine oxide

Extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of diphenyl-N,N-dibutylcarbamoylmethyl phosphine oxide (DPDBCMPO, L) has been investigated. The equilibrium data have been explained assuming that the species HL⁺, \textHL₂ ⁺ {\text{HL}}_{2}^{ + } , CaL²⁺, \textCaL ₂ ^{2 +} {\text{CaL}}_{ 2}^{{ 2 { + }}} , \textCaL ₃ ^{2 +} {\text{CaL}}_{ 3}^{{ 2 { + }}} , SrL²⁺, \textSrL ₂ ^{2 +} {\text{SrL}}_{ 2}^{{ 2 { + }}} , \textSrL ₃ ^{2 +} {\text{SrL}}_{ 3}^{{ 2 { + }}} and \textSrL ₄ ^{2 +} {\text{SrL}}_{ 4}^{{ 2 { + }}} are extracted into the organic phase. The values of extraction and stability constants of the cationic complexes in nitrobenzene saturated with water have been determined. In the considered nitrobenzene medium, it was found that the stability constants of the complexes CaL²⁺, \textCaL ₂ ^{2 +} {\text{CaL}}_{ 2}^{{ 2 { + }}} and \textCaL ₃ ^{2 +} {\text{CaL}}_{ 3}^{{ 2 { + }}} , where L is DPDBCMPO, are somewhat higher than those of the corresponding complex species SrL²⁺, \textSrL ₂ ^{2 +} {\text{SrL}}_{ 2}^{{ 2 { + }}} and \textSrL ₃ ^{2 +} {\text{SrL}}_{ 3}^{{ 2 { + }}} .     

Solvent extraction of microamounts of strontium and barium into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of polyethylene glycol PEG 600

Extraction of microamounts of strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of polyethylene glycol PEG 600 (L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, H₂L²⁺, ML²⁺ and MHL³⁺ (M²⁺ = Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It was found that in water-saturated nitrobenzene the stability constant of the BaL²⁺ cationic complex species is essentially higher than that of the complex SrL²⁺.     

Extraction distributions of microamounts of strontium and barium in the two-phase water-HCl-nitrobenzene-dibenzo-21-crown-7-hydrogen dicarbollylcobaltate system

Extraction of microamounts of strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻) in the presence of dibenzo-21-crown-7 (DB21C7, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL⁺, ML²⁺, ML₂²⁺ and MHL₂³⁺ (M²⁺ = Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Solvent extraction of microamounts of strontium and barium from water into nitrobenzene using hydrogen dicarbollylcobaltate in the presence of benzo-18-crown-6

Extraction of microamounts of strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B⁻¹) in the presence of benzo-18-crown-6 (B18C6, L) has been investigated. The equilibrium data been explained assuming that the complexes HL⁺, ML²⁺, ML₂²⁺ and MHL₂³⁺ (M²⁺ = Sr²⁺, Ba²⁺) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.     

Stability of the valinomycin - strontium complex in water saturated nitrobenzene

Summary From extraction experiments and<span style='font-size:12.0pt;font-family:Symbol; mso-bidi-font-family:Symbol'>g-activity measurements, the extraction constant corresponding to the equilibrium Ba²⁺(aq)+SrL²⁺(nb)?BaL²⁺(nb)+Sr²⁺(aq) taking place in the two-phase water-nitrobenzene system (L= valinomycin; aq= aqueous phase,</o:p>nb= nitrobenzene phase) was evaluated as logK_ex(Ba²⁺, SrL²⁺)=1.3. Furthermore, the stability constant of the valinomycin-strontium complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: logb_nb(SrL²⁺)=5.4.     

Synergistic extraction of calcium and strontium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol

Solvent extraction of microamounts of calcium and strontium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H⁺B^?) in the presence of dodecaethylene glycol (DDEG, L) has been investigated. The equilibrium data have been explained assuming that the species HL⁺, H₂L²⁺, ML²⁺ and MHL³⁺ (M²⁺ = Ca²⁺, Sr²⁺; L = DDEG) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water have been determined. It was found that in this nitrobenzene medium, the stability constant of the SrL²⁺ complex is somewhat higher than that of CaL²⁺.     

Distribution of Strontium in the System Water — Ca(NO3)2 — Nitrobenzene — Strontium Dicarbollylcobaltate — 18-crown-6

From several strontium distribution experiments with ⁸⁵Sr tracer, the extraction constant corresponding to the equilibrium Ca²⁺(aq)+SrL²⁺(nb) CaL²⁺(nb)+Sr²⁺ (aq) in the two-phase water-nitrobenzene system (L = 18-crown-6; aq = aqueous phase, nb = nitrobenzene phase) was tentatively evaluated as log K _ex (Ca²⁺,SrL²⁺) = –1.9±0.1. Furthermore, the stability constant of the calcium — 18-crown-6 complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log _nb(Cal²⁺) = 10.1±0.1.