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1.
We report on the formation of a novel ternary compound Ce2PdIn8 that is isostructural with the heavy-fermion superconductors Ce2CoIn8 and Ce2RhIn8. Its magnetic, electrical transport and thermodynamic properties were studied on polycrystalline samples in wide ranges of temperature and magnetic field strength. The results revealed Ce2PdIn8 to be a paramagnetic Kondo lattice with a coherence temperature of about 12 K. The C/T ratio of the specific heat reaches at 350 mK a strongly enhanced magnitude of about per Ce-atom, thus clearly indicating a heavy-fermion nature of this material. Moreover, a logarithmic divergence of C/T vs. T, observed below 3 K, which is accompanied by a linear temperature dependence of the electrical resistivity below 6 K, hint at a non-Fermi liquid character of the electronic ground state in the new compound reported.  相似文献   

2.
Magnetic phase transitions in rare earth intermetallic compound Nd7Rh3 have been investigated using a single crystal. Measurement results of magnetization, magnetic susceptibility, specific heat, and electrical resistivity reveal that Nd7Rh3 has two magnetic phase transitions at TN=34 K, Tt2=9.1 K and a change of the magnetic feature at Tt1=6.8 K in the absence of an external magnetic field. Antiferromagnetic orderings exist in all the three magnetic states; a large magnetic anisotropy between the c-axis and the c-plane is observed. In the magnetic phase below Tt2, an irreversible field-induced magnetic phase transition takes place in the c-plane; after removing external magnetic field, a coexistence state of ferro- and antiferromagnetic ordering or a ferrimagnetic state having a remanent magnetization MR is stabilized. The MR decays to a certain value for several hours after the first process; a magnetic field cooling effect was also observed in the c-plane below Tt2. In the antiferromagentic state above Tt2, the irreversibility disappears and an ordinary antiferromagnetic state takes place. As the origin of this phenomenon, a kind of martensitic structural transition that is observed in Gd5Ge4 can be considered.  相似文献   

3.
霍德璇  廖罗兵  李领伟  李妙  钱正洪 《中国物理 B》2013,22(2):27502-027502
The magnetocaloric effect(MCE) in EuCu1.75P2 compound is studied by the magnetization and heat capacity measurements.Magnetization and modified Arrott plots indicate that the compound undergoes a second-order phase transition at TC ~ 51 K.A large reversible MCE is observed around TC.The values of maximum magnetic entropy change(-△SxMma) reach 5.6 J·kg-1·K-1 and 13.3 J·kg-1·K-1 for the field change of 2 T and 7 T,respectively,with no obvious hysteresis loss in the vicinity of Curie temperature.The corresponding maximum adiabatic temperature changes(△Tadmax) are evaluated to be 2.1 K and 5.0 K.The magnetic transition and the origin of large MCE in EuCu1.75P2 are also discussed.  相似文献   

4.
In this work, the technique of electron magnetic resonance (EMR) is used to measure the magnetic resonant spectra of La0.7Sr0.3MnO3 nanoparticles synthesized by sol–gel routes with three different gelation agents (S1: Urea+citric acid; S2: citric acid, and S3: Urea+tri-sodium citrate). The purpose of this study is to investigate the influence of synthesis conditions on the magnetic properties of nanoparticles. Our ESR results show that Curie temperatures of La0.7Sr0.3MnO3 nanoparticles with different gelation agents are slightly different (Tc∼340 to 360 K) and possess both paramagnetic (PM) and ferromagnetic (FM) phases in the temperature below Tc. Besides, a sharp FM–PM transition indicates that the combined agent of Urea+tri-sodium citrate creates a better quality in CMR nanomagnets.  相似文献   

5.
The LaFe11.5Si1.5H1.3 interstitial compound has been prepared. Its Curie temperature TC (288 K) has been adjusted to around room temperature, and the maximal magnetic entropy change (|ΔS|~17.0 J·kg-1·K-1 at TC) is larger than that of Gd (|ΔS|~9.8 J·kg-1·K-1 at TC=293 K) by ~73.5% under a magnetic change from 0 to 5 T. The origin of the large magnetic entropy change is attributed to the first-order field-induced itinerant-electron metamagnetic transition. Moreover, the magnetic hysteresis of LaFe11.5Si1.5H1.3 under the increase and decrease of the field is very small, which is favourable to magnetic refrigeration application. The present study suggests that the LaFe11.5Si1.5H1.3 compound is a promising candidate as a room-temperature magnetic refrigerant.  相似文献   

6.
Using powder neutron diffraction techniques, we have examined the magnetic order of the pseudoternary compound Ho(Rh0.3Ir0.7)4B4 below the Néel temperature TN=2.7K. The magnetic structure consists of stacked antiferromagnetic basal plane sheets forming a body centered tetragonal unit cell, with a sublattice magnetization corresponding to 9.6±0.6μB per Ho3+ion at 1.5 K. Magnetic intensity versus temperature measurements indicate that the transition is second order and reveal no anomalous effects when the compound becomes superconducting at Tc=1.34K.  相似文献   

7.
Bulk superconducting La2CuO4+δ single crystals are obtained by using electrochemical intercalation technique from the as-grown insulating samples. Oxidation is carried out by constant current I=10μA at temperature T=70℃ and room temperature, respectively. Structure and magnetic properties are studied by low-temperature X-ray diffraction and susceptibility measurements. A superconducting phase with Tc of 19K and δ-0.12 can be attributed to the formation of oxygen clusters. Room temperature oxidation is inhomogeneous: two superconducting phases with Tc1 of 24K and Tc2 of 8K and an antiferromagnetic phase are coexisting in the crystal. It is found that the appearance of Tc in this system has the "step" tendency.  相似文献   

8.
Magnetoelastic properties of Nd6Fe13Cu intermetallic compound are reported. To study the magnetoelastic behaviour of this compound, the thermal expansion as well as the longitudinal (λl) and transverse (λt) magnetostriction were measured by using the strain gauge method in the selected temperature range of 80-500 K under applied magnetic fields up to 1.5 T. An anomaly and invar-type effects are observed in the linear thermal expansion and α(T) curves at the Néel temperature. The linear spontaneous magnetostriction decreases sharply by approaching the Néel temperature and also shows the short-range magnetic ordering effects when antiferromagnetic-paramagnetic transition occurs. In the low field region, the absolute values of the anisotropic magnetostriction are small and then start to increase with applied magnetic field. Each isofield curve of the anisotropic magnetostriction passes through a minimum and then approaches to zero with increasing temperature. This magnetostriction compensation arises from the difference in the magnetoelastic coupling constants of the sublattices in this compound.  相似文献   

9.
The magnetic properties and the magnetic entropy change AS have been investigated for Gd6Co1.67Si3 compounds with a second-order phase transition. The saturation moment at 5 K and the Curie temperature TC are 38.1μB and 298 K, respectively. The AS originates from a reversible second-order magnetic transition around TC and its value reaches 5.2 J/kg.K for a magnetic field change from 0 to 5T. The refrigerant capacity (RC) of Gd6Co1.67Si3 are calculated by using the methods given in Refs.[12] and [21], respectively, for a field change of 0 5T and its values are 310 and 440 J/kg, which is larger than those of some magnetocaloric materials with a first-order phase transition.  相似文献   

10.
The differential thermal analysis, electrical resistivity and thermopower are studied as a function of temperature in the range 300–1100 K. The measurements show two transition points at 905 and 1030 K. The first point is linked with the magnetic transition at the Néel temperature (TN), and the second with the order-disorder phase. The conduction mechanism through the Néel point is discussed using the spin polaron model.  相似文献   

11.
The magnetic ionic liquids (MILs) are considered to open up a wide range of applications because of their magnetic and electrochromic switching. Until recently almost all magnetic ionic liquids containing tetrachloroferrate ion FeCl4 evidenced a paramagnetic temperature dependence of the magnetic susceptibility, with only small deviations from the Curie law at low temperatures. However, 1-ethyl-3-methylimidazolium tetrachloroferrate, Emim[FeCl4], clearly exhibits a long-range antiferromagnetic ordering below the Neel temperature TN≈3.8 K. In addition, the shape of the magnetic ordering depends on the cooling speed, indicating that the magnetic coupling could be modified.  相似文献   

12.
We report the low temperature magnetic properties of Cd-doped single crystals of Ce2RhIn8 grown from In-flux. Measurements of temperature-dependent magnetic susceptibility, heat capacity, electrical resistivity and X-ray magnetic scattering revealed that Cd-doping enhances the antiferromagnetic ordering temperature from for crystals with nominal Cd-concentration of ~20%. Similarly to the pure compound, Cd-doped Ce2RhIn8 presents just below TN a commensurate antiferromagnetic structure with a propagation vector . Comparisons between our results and the general effects of Cd-doping on the single layer related family CeMIn5 (M=Co, Rh and Ir) will also be given.  相似文献   

13.
We carefully studied the nonsuperconducting sample of the magneto-superconducting RuSr2(Eu1−xCex)Cu2O10−δ series with composition RuSr2EuCeCu2O10−δ. This compound seems to exhibit a complex magnetic state as revealed by host of techniques like resistivity, thermopower, magnetic susceptibility, and MR measurements. The studied compound exhibited ferromagnetic like M(H) loops at 5, 20, and 50 K, and semiconductor like electrical conduction down to 5 K, with −MR7 T of up to 4% at low temperatures. The −MR7 T decreases fast above 150 K and monotonically becomes close to zero above say 230 K. Below, 150 K −MR7 T decreases to around 3% monotonically down to 75 K, with further increase to 4% at around 30 K and lastly having a slight decrease below this temperature. The thermopower S(T) behavior closely followed the −MR7 T steps in terms of d(S/T)/dT slopes. Further, both MR7 T steps and d(S/T)/dT slopes are found in close vicinity to various magnetic ordering temperatures (Tmag) of this compound.  相似文献   

14.
沈俊  王芳  李养贤  孙继荣  沈保根 《中国物理》2007,16(12):3853-3857
Magnetic properties and magnetocaloric effects of Tb6Co1.67Si3 have been investigated by magnetization measurement. This compound is of a hexagonal Ce$_{6}$Ni$_{2}$Si$_{3}$-type structure with a saturation magnetization of 187\,emu/g at 5\,K and a reversible second-order magnetic transition at Curie temperature $T_{\rm C} = 186$\,K. A magnetic entropy change $\Delta S = 7$\,J\,$\cdot$\,kg$^{-1}$\,$\cdot$\,K$^{-1}$ is observed for a magnetic field change from 0 to 5\,T. A large value of refrigerant capacity (RC) is found to be 330\,J/kg for fields ranging from 0 to 5\,T. The large RC, the reversible magnetization around $T_{\rm C}$ and the easy fabrication make the Tb6Co1.67Si3 compound a suitable candidate for magnetic refrigerants in a corresponding temperature range.  相似文献   

15.
MnFe2O4 nano-particles with an average size of about 7 nm were synthesized by the thermal decomposition method. Based on the magnetic hysteresis loops measured at different temperatures the temperature-dependent saturation magnetization (MS) and coercivity (HC) are determined. It is shown that above 20 K the temperature-dependence of the MS and HC indicates the magnetic behaviors in the single-domain nano-particles, while below 20 K, the change of the MS and HC indicates the freezing of the spin-glass like state on the surfaces. By measuring the magnetization–temperature (MT) curves under the zero-field-cooling (ZFC) and field-cooling procedures at different applied fields, superparamagnetism behavior is also studied. Even though in the ZFC MT curves peaks can be observed below 160 K, superparamagnetism does not appear until the temperature goes above 300 K, which is related with the strong inter-particle interaction.  相似文献   

16.
The phase relation of LaFe11.5Si1.5 alloys annealed at different high-temperature from 1223 K (5 h) to 1673 K (0.5 h) has been studied. The powder X-ray diffraction (XRD) patterns show that large amount of 1:13 phase begins to form in the matrix alloy consisting of α-Fe and LaFeSi phases when the annealing temperature is 1423 K. In the temperature range from 1423  to 1523 K, α-Fe and LaFeSi phases rapidly decrease to form 1:13 phase, and LaFeSi phase is rarely observed in the XRD pattern of LaFe11.5Si1.5 alloy annealed at 1523 K. With annealing temperature increasing from 1573  to 1673 K, the LaFeSi phase is detected again in the LaFe11.5Si1.5 alloy, and there is La5Si3 phase when the annealing temperature reaches 1673 K. There almost is no change in the XRD patterns of LaFe11.5Si1.5 alloys annealed at 1523 K for 3-5 h. According to this result, the La0.8Ce0.2Fe11.5−xCoxSi1.5 (0≤×≤0.7) alloys are annealed at 1523 K (3 h). The analysis of XRD patterns shows that La0.8Ce0.2Fe11.5xCoxSi1.5 alloys consist of the NaZn13-type main phase and α-Fe impurity phase. With the increase of Co content from x=0 to 0.7, the Curie temperature TC increases from 180 to 266 K. Because the increase of Co content can weaken the itinerant electron metamagnetic transition, the order of the magnetic transition at TC changes from first to second-order between x=0.3 and 0.5. Although the magnetic entropy change decreases from 34.9 to 6.8 J/kg K with increasing Co concentration at a low magnetic field of 0-2 T, the thermal and magnetic hysteresis loss reduces remarkably, which is very important for the magnetic refrigerant near room temperature.  相似文献   

17.
通过对EuSr2Ru1-xTaxCu2O8 (x=0.0, 0.1, 0.2, 0.5和1.0)体系的结构、电阻和磁化强度的观测,发现EuSr2RuCu2O8(x=0.0)样品在130.2K以下呈现铁磁有序,在35K时发生了超导转变,并呈现典型的欠掺杂高温超导体特征;随着Ta对Ru替代浓度x值的增加,铁磁相变温度和超导临界温度均下降 关键词: 高温超导电性 铁磁有序 Ru-Cu氧化物  相似文献   

18.
In continuous magnetic fields H up to 28 T, we have studied the out-of-plane transport properties and tunneling characteristics of high-quality nondoped single crystals of the Bi-cuprate family: Bi2Sr2CuO6+δ (Bi2201), Bi2Sr2CaCu2O8+δ (Bi2212) and Bi2Sr2Ca2Cu3O10+δ (Bi2223) grown by an identical method. For all compounds the out-of-plane magnetotransport ρc(H) is negative in the temperature region where ρc(T) shows in the normal state a semiconducting-like temperature dependence. The negative magnetoresistance of ρc corresponds to the suppression of the semiconducting temperature dependence of ρc(T) which is found to be isotropic. For the Bi2201 compound, where the normal state can be reached in the available magnetic fields (28 T), a nearly complete suppression of the low-temperature upturn in ρc(T) is observed in the highest magnetic fields with a tendency towards a metallic behavior down to the lowest temperatures (0.4 K). Using the break-junction technique, especially for the Bi2212 and Bi2232 compounds, a clear superconducting gap structure can be observed. Both for temperatures above the critical temperature and for magnetic fields above the upper critical field, a pseudogap structure remains present in the tunneling spectra. The applied magnetic fields yield a stronger suppression of the superconducting state compared to that of the normal-state gap structures as manifested in ρc(T) transport and tunneling.  相似文献   

19.
In this work the Mn5Si3 and Mn5SiB2 phases were produced via arc melting and heat treatment at 1000 °C for 50 h under argon. A detailed microstructure characterization indicated the formation of single-phase Mn5Si3 and near single-phase Mn5SiB2 microstructures. The magnetic behavior of the Mn5Si3 phase was investigated and the results are in agreement with previous data from the literature, which indicates the existence of two anti-ferromagnetic structures for temperatures below 98 K. The Mn5SiB2 phase shows a ferromagnetic behavior presenting a saturation magnetization Ms of about 5.35×105 A/m (0.67 T) at room temperature and an estimated Curie temperature between 470 and 490 K. In addition, AC susceptibility data indicates no evidence of any other magnetic ordering in 4-300 K temperature range. The magnetization values are smaller than that calculated using the magnetic moment from previous literature NMR results. This result suggests a probable ferrimagnetic arrangement of the Mn moments.  相似文献   

20.
Magnetoresistances and magnetic entropy changes in NaZn13-type compounds La(Fel-xCox)11.9Si1.1 (x=0.04, 0.06, and 0.08) with Curie temperatures of 243 K, 274 K, and 301 K, respectively, are studied. The ferromagnetic ordering is accompanied by a negative lattice expansion. Large magnetic entropy changes in a wide temperature range from ~230 K to ~320 K are achieved. Raising Co content increases the Curie temperature but weakens the magnetovolume effect, thereby causing a decrease in magnetic entropy change. These materials exhibit a metallic character below Tc, whereas the electrical resistance decreases abruptly and then recovers the metal-like behaviour above Tc. Application of a magnetic field retains the transitions via increasing the ferromagnetic ordering temperature. An isothermal increase in magnetic field leads to an increase in electrical resistance at temperatures near but above Tc, which is a consequence of the field-induced metamagnetic transition from a paramagnetic state to a ferromagnetic state.  相似文献   

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