首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 46 毫秒
1.
A new 2D pulse sequence HMSC (heteronuclear multiple-bond and single-bond coupling connectivities) for the simultaneous detection of long-range and one-bond heteronuclear connectivities is proposed which allows the two types of responses to be separated and the corresponding (n)J(CH) and (1)J(CH) connectivity maps to be calculated. (n)J(CH) coherences are selectively labeled in the course of the pulse sequence, the correspondingly acquired data are separately stored, and a simple add/subtract procedure is applied to disentangle and edit (n)J(CH) and (1)J(CH) responses prior to final data processing. Unlike standard methods, which are designed to measure one single type of heteronuclear spin-spin interactions and to efficiently suppress the other, both (n)J(CH) and (1)J(CH) are measured simultaneously in a single experiment with the HMSC pulse sequence. Compared to the common strategy with two standard experiments applied one after the other, e.g., HMBC and HMQC, valuable measuring time may be saved with this single experiment approach. The efficiency of the new pulse sequence and the quality of the corresponding spectra are demonstrated using strychnine. Features such as sensitivity, lineshapes, and the suppression of (1)J(CH) residual peaks in the final (n)J(CH) subspectra are investigated and compared with the corresponding results obtained with standard methods. The attractive and unique single experiment approach, its high efficiency, and its easy experimental setup together with straightforward data processing make HMSC a valuable experimental alternative for the today's more time-consuming "two-step" practice and makes it suitable for standard routine applications.  相似文献   

2.
Scaling of directed dynamical small-world networks with random responses   总被引:1,自引:0,他引:1  
A dynamical model of small-world networks, with directed links which describe various correlations in social and natural phenomena, is presented. Random responses of sites to the input message are introduced to simulate real systems. The interplay of these ingredients results in the collective dynamical evolution of a spinlike variable S(t) of the whole network. The global average spreading length (s) and average spreading time (s) are found to scale as p(-alpha)ln(N with different exponents. Meanwhile, S(t) behaves in a duple scaling form for N>N(*): S approximately f(p(-beta)q(gamma)t), where p and q are rewiring and external parameters, alpha, beta, and gamma are scaling exponents, and f(t) is a universal function. Possible applications of the model are discussed.  相似文献   

3.
Vortexlike turbulent structures in hot-ion mode plasmas with several keV are observed in the case with a radially produced weak shear of electric fields E(r). However, a strong E(r) shear formation due to a high ion-confining potential phi(c) production clears up these vortices together with plasma-confinement improvement and disappearance of both drift-wave and turbulencelike Fourier spectral signals. These findings are based on three-time progress in phi(c) in comparison to phi(c) attained 1992-2002. The significant advance of phi(c) is well extended in line with proposed potential-formation physics scalings.  相似文献   

4.
H(2)-broadening coefficients have been measured for 66 rovibrational lines of NH(3) at room temperature in the (P)P and (R)P branches of the nu(4) band in the range 1470-1600 cm(-1), using a high-resolution Fourier transform spectrometer. The collisional widths are obtained by fitting Voigt profiles to the measured shapes of the lines. The broadening coefficients are found to decrease on the whole as J increases and they increase with K for a given J value. The results are compared with those calculated from a semiclassical model in which the inversion vibration of NH(3) and collision-induced transitions with DeltaK = 0 and DeltaK = +/- 3 are taken into account. The intermolecular potential used includes electrostatic, induction, and dispersion energy contributions. The calculations performed by considering only DeltaK = 0 transitions provide significantly lower broadenings but with a satisfactory J and K dependence. The same trends are obtained for the broadening coefficients in inversion-rotation transitions and in the Q branch of the nu(1) parallel band of NH(3). Copyright 2001 Academic Press.  相似文献   

5.
The (2)H(d,p)(3)H, (2)H(d,n)(3)He, and (2)H(d,γ)(4)He reactions are studied at low energies in a multichannel ab initio model that takes into account the distortions of the nuclei. The internal wave functions of these nuclei are given by the stochastic variational method with the AV8' realistic interaction and a phenomenological three-body force included to reproduce the two-body thresholds. The obtained astrophysical S factors are all in very good agreement with the experiment. The most important channels for both transfer and radiative capture are identified by comparing to calculations with an effective central force. They are all found to dominate thanks to the tensor force.  相似文献   

6.
Jing-Peng Song 《中国物理 B》2022,31(3):37401-037401
Introducing metal thin films on two-dimensional (2D) material may present a system to possess exotic properties due to reduced dimensionality and interfacial effects. We deposit Pb islands on single-crystalline graphene on a Ge(110) substrate and studied the nano- and atomic-scale structures and low-energy electronic excitations with scanning tunneling microscopy/spectroscopy (STM/STS). Robust quantum well states (QWSs) are observed in Pb(111) islands and their oscillation with film thickness reveals the isolation of free electrons in Pb from the graphene substrate. The spectroscopic characteristics of QWSs are consistent with the band structure of a free-standing Pb(111) film. The weak interface coupling is further evidenced by the absence of superconductivity in graphene in close proximity to the superconducting Pb islands. Accordingly, the Pb(111) islands on graphene/Ge(110) are free-standing in nature, showing very weak electronic coupling to the substrate.  相似文献   

7.
Antikaon condensation and kaon and antikaon production in protoneutron stars are investigated in a chiral hadronic model (also referred to as the FST model in this paper). The effects of neutrino trapping on protoneutron stars are analyzed systematically. It is shown that neutrino trapping makes the critical density of K^- condensation delay to higher density and fifo condensation not occur. The equation of state (EOS) of (proto)neutron star matter with neutrino trapping is stiffer than that without neutrino trapping. As a result, the maximum masses of (proto)neutron stars with neutrino trapping are larger than those without neutrino trapping. If hyperons are taken into account, antikaon does not form a condensate in (proto)neutron stars. Meanwhile, the corresponding EOS becomes much softer, and the maximum masses of (proto)neutron stars are smaller than those without hyprons. Finally, our results illustrate that the Q values for K^+ and K^- production in (proto)neutron stars are not sensitive to neutrino trapping and inclusion of hyperons.  相似文献   

8.
Particlelike static spherically symmetric solutions to massless scalar and electromagnetic field equations combined with gravitational field equations are considered. Two criteria for particlelike solutions are formulated: the strong one (solutions are required to be singularity free) and the weak one (singularities are admitted but the total energy and material field energy should be finite). Exact solutions for the following physical systems are considered with their own gravitational field: (i) linear scalar (minimally coupled or conformal) plus electromagnetic field; (ii) the same fields with a bare mass source in the form of charged incoherent matter distributions; (iii) nonlinear electromagnetic field with an arbitrary dependence on the invariant FαβFαβ; and (iv) directly interacting scalar and electromagnetic fields. Case (i) solutions are not particlelike (except those with horizons, in which static regions formally satisfy the weak criterion). For systems (ii), examples of nonsingular models are constructed, in particular, a model for a particle-antiparticle pair of a Wheeler-handle type, without scalar field and explicit electric charges. Besides, a number of limitations upon nonsingular model parameters is indicated. Systems (iii) are proved to violate the strong criterion for any type of nonlinearity but can satisfy the weak criterion (e.g., the Born-Infeld nonlinearity). For systems (iv) some particlelike solutions by the weak criterion are constructed and a regularizing role of gravitation is demonstrated. Finally, an example of a field system satisfying the strong criterion is given.  相似文献   

9.
We present a systematic method to construct the spin models of Heisenberg type in higher dimensions with nearesband non-nearest neighbour interactions. These models constructed in this way are of Temperley-Lieb-Jones (TLJ) algebraic structures and SU(2)-invariances. The TLJ algebra is generalized to adjusting the lattice spin models. The Hamiltonians of Heisenberg spin models in one dimension (including second nearest neighbour interactions) and in two-dimensional triangular lattice (with nearest interaction) are constructed explicitly. The hidden symmetries are shown to be the SU(2) group, and the terms in Ilamiltonian for different lattice cells are explicitly shown to be the representations of elements of (TLJ) algebra.  相似文献   

10.
To evaluate individual expansion coefficients composing fitting parameters of the Born-Oppenheimer corrections to Dunham's coefficients Y(ij) that have been given analytically with the Delta(B) and Delta(omega) formalism, we examined the consistency of analytic expressions for those corrections with Watson's assertion of the experimental inseparability of nonadiabatic corrections Q(a, b)(r) for a molecule AB. Derived analytic expressions in terms of optimal fitting parameters for the corrections are essential to evaluate individual expansion coefficients. These expressions also reveal redundancies between empirical correction parameters Delta(ij). A method of evaluating nonadiabatic vibrational corrections Q(a, b)(r) and adiabatic corrections S(a, b)(r) separately consistent with Watson's assertion of inseparability is presented and is applied to an analysis of spectral data of LiH. Functions Q(a, b) and S(a, b) for LiH are thus successfully evaluated; S(H, Li)(r) values agree well with those predicted simply by wobble-stretch theory. Experimental values for optimal fitting parameters r(H)(1q) and r(H)(2q) are nearly equal to those of r(Li)(1q) and r(Li)(2q), respectively, in agreement with a theoretical relation r(a)(iq)=r(b)(iq). Copyright 2001 Academic Press.  相似文献   

11.
The formation of bacterial biofilms on material surfaces is a recurrent problem in public health. Antibacterial nanoparticles (NPs) are promising because pathogens have not yet developed resistance mechanisms and encapsulation of the drug can protect it from the surrounding medium and improve pharmacokinetics. Biocompatible and biodegradable particles of various sizes (nano- and micro-scale) based on poly(lactic-co-glycolic acid) (PLGA) are elaborated using a simple and free toxic nanoprecipitation process. Particles are poly(ethylene glycol) (PEG)-ylated in order to reduce unwanted interactions with biological fluids, or loaded with the large spectrum antibiotic ciprofloxacin (CIP). NPs are studied against Staphylococcus aureus in planktonic and biofilm modes. Empty NPs with smallest size (60 nm) are able to totally eradicate planktonic culture after 24 h, even in the presence of serum proteins. CIP-loaded NPs present slightly lower antimicrobial activity against planktonic microorganisms compared with the free antibiotic, due to progressive release of CIP over time. In biofilm mode, CIP-loaded NPs show a very good antibiofilm activity, much better than free CIP, thanks to NPs penetration within the polymer matrix and a consequent release of the antibiotic close to the embedded bacteria. The present results open the way for widespread applications of PLGA-NPs in the pharmaceutical or medical fields.  相似文献   

12.
This paper reports the analysis of experiments on the r.f. surface impednace of thin slabs of single crystal indium in the presence of a d.c. magnetic field normal to the slab plane. While our experimental results are generally in agreement with thos of Krylov, we diverge on their interpretation. Our analysis is based on a calculated Fermi surface model and on numerical calculations of dispersion relations and the surface impedance. We find for the (001) sample plane a weak Doppler-shifted cyclotron resonance (DSCR) absorption in the propagating helicon regime which provides a sensitive test of the model Fermi surface. For the helicon absorption edges corresponding to relatively strong DSCR absorption, the calculated dispersion and surface impedance results for the edge are compared with experimental results for the (001), (100), (111) and (110) sample planes. For the (001) and (110) planes we also observe oscillations in the DSCR absorption regime which are almost periodic in the applied d.c. field. Our surface impedance calculations indicate that these are not Gantmakher-Kaner oscillations but that they correspond to weak DSCR modes with a circular polarization sense opposite to that of the helicons.  相似文献   

13.
Fast-acting compression has several effects on the envelope of speech signals, especially when a target and a background are mixed together. Three measures of the envelope are described, which can be used to quantify these changes: (1) Within-signal modulation correlation or coherence, the degree of correlation (or coherence) of the envelope (on a dB scale) of a single source across different frequency regions, which is reduced by fast-acting compression; (2) fidelity of envelope shape, the degree to which the envelope shape of the target speech in different frequency channels is preserved following compression; and (3) across-signal modulation correlation or coherence (ASMC), the extent to which the target and background acquire a common component of modulation when they are compressed together, which becomes greater in absolute value (more negative) when the target and background are compressed together. Values of these measures are presented and compared with intelligibility scores obtained using stimuli processed (with a noise-vocoder) so as to preserve mainly envelope cues in a limited number of frequency channels. The results suggest that the dominant factor affecting intelligibility is ASMC.  相似文献   

14.
张杰  陈祥磊  叶邦角 《中国物理 B》2010,19(7):77806-077806
The positron lifetimes of some compounds with NaCl-type crystal structure are calculated with the method of atomic superposition approximation (ATSUP) based on the theories of local-density-approximation (LDA) and generalgradient-approximation (GGA).The systematical results are fitted to a curve as a function of lattice constants.The positron bulk lifetimes of some other compounds with NaCl-type crystal structure,which are deduced from the systematical results,are in agreement with the experimental results given in other literature.  相似文献   

15.
Lightning attachment to vertical grounded conductors are presented with special attention to the lightning attractive radii of vertical conductors as predicted by self consistent leader inception and propagation model (SLIM), Electro Geometrical Model (EGM) and Collection Volume Method (CVM). Moreover, SLIM was utilized to model the attachment of a slanted stepped leader to a tall tower that resulted in a side flash to a point below the top of the tower. The important conclusions to be drawn from the results obtained are the following: (a) The error (caused by neglect of the connecting leader in EGM) in the predicted attractive radii and the striking distance of EGM increases with increasing structure height. However, for structures whose height is shorter than about 30 m the error associated with using EGM is less than about 20%. (b) The attractive radii predicted by the Collection Volume Method (CVM) are much larger than the ones predicted by SLIM and EGM. Thus, the use of CVM to locate the lightning conductors on a structure may undermine its safety. (c) Slanted stepped leader channels can cause side flashes in tall structures even though long connecting leaders are emitted from the top of the structure.  相似文献   

16.
Modeling and fast reanalysis techniques are proposed for predicting the dynamic response of complex structures with uncertainty represented by parameter variability (in geometric and material properties) at component-level. The novel models allow for accurate reanalyses and are useful in many applications where the model of the pristine structure may not capture the changes in the system-level response due to component-level parameter variations. Herein, such models are obtained by using a novel approach based on a modified concept of component mode synthesis. The novel models, referred to as parametric reduced-order models, are developed for the general case of multiple substructures with parameter variabilities. Three types of parameteric variabilities are considered: (a) geometric (thickness) variability, (b) structural deformations (dents), and (c) cracks. For the first case, a novel parametrization of component-level mass and stiffness matrices is employed to predict the system-level response. For the second case, a novel approximate method based on static mode compensation is implemented. For the third case (cracks), a generalized formulation for the bi-linear frequency approximation is used. The predicted vibration responses of complex structures are shown to agree very well with results obtained using a much more computationally expensive commercial tool.  相似文献   

17.
(57)Fe M?ssbauer and magnetic measurements are reported on Taylor phase compounds T-Al(3)(Mn,Fe), which can be seen as complex metallic alloys. The orthorhombic unit cell contains 156 atoms. These investigations are further extended to Al(71)Mn(19)Fe(10) crystallizing as a decagonal quasicrystal. Common to both structures are layers, which are oriented perpendicular to the b axis in the crystalline or to the periodic axis in the quasicrystalline compound, allowing the formation of characteristic building blocks. At low temperatures for all samples spin glass behavior is observed with freezing temperatures T(f) increasing with Fe content. Above T(f) the (57)Fe M?ssbauer spectra were analyzed by a superposition of two subspectra with intensity ratio around 75:25, which can be allocated to Fe substituted on Mn sites surrounded either by Al and Mn or solely by Al with Mn only at the edge of the nearest neighbor shell. For both subspectra quadrupole splitting and center shift do not change significantly with Fe content and with structure. Below T(f) broad hyperfine field distributions with non-vanishing contributions at zero hyperfine field are present. Magnetic and electrostatic hyperfine interactions are governed by length scales which are determined by the very similar interatomic configurations forming the T-Al(3)Mn phase as well as the decagonal compound. The presence of long range atomic order is of less importance.  相似文献   

18.
The interaction of noise with a variety of other agents and with some physical characteristics of the individual to produce noise-induced hearing loss is reviewed critically. The review is restricted, for the most part, to publications since 1970. Other agents interacting with steady-state noise that are reviewed here include: (1) ototoxic drugs (kanamycin, neomycin, ethacrynic acid, furosemide, and salicylates), (2) impulse noise, and (3) whole-body vibration. Physical characteristics of the individual that are reviewed are: (1) age, (2) presence of previous hearing loss from prior noise exposure, (3) eye color, and (4) race. Suggestions for future research in this general area are also made. Some of these suggestions are as follows: (1) to extend studies of the interaction of steady-state noise with impulse noise, salicylates, and whole-body vibration to encompass a broader range of exposure conditions, including exposure conditions typically encountered by the worker, (2) to develop an animal model of presbycusis to explore the interactions of noise-induced hearing loss and presbycusis, and (3) to explore the potential interactions resulting from concurrent exposure to multiple agents, such as impulse noise and ototoxic drugs, in younger, more susceptible animals.  相似文献   

19.
Ultrafine ?-SiC powders are synthesized in thermal plasmas by a reaction between methane and silicon monoxide. The reaction is carried out in an unconfined plasma jet (22.5 kW) operating at atmospheric Ar pressure. High temperatures (> 10 000 K) combined with ultrarapid quench rates (? 106 K/s) of the plasma lead to a high degree of supersaturation of the chemical vapor, resulting in homogeneous nucleation of ultrafine particles. Product characterizations are pursued with X-ray diffraction analysis, X-ray photoelectron spectroscopy (XPS), scanning, and transmission electron microscopy. The maximum SiC yield determined by thermogravimetric analysis (TGA) is 97.3 percent. Particle size analyses show a bimodal distribution with the majority of the particles falling in a size range from 2 to 40 nm. Triangular and hexagonal SiC particles are observed throughout this work and the nucleation and growth of these particles are discussed.  相似文献   

20.
Line positions and intensities belonging to the vibrational system 2nu(2)/nu(4) of ammonia (14)NH(3) are measured and analyzed between 1200 and 2200 cm(-1) in order to improve the molecular database. For this, laboratory spectra are obtained at 0.006 and 0.011 cm(-1) unapodized resolution and with 4% precisions for the intensities using Fourier transform spectrometers located at the Kitt Peak National Observatory and the Jet Propulsion Laboratory. The observed data contain transitions of the nu(4) fundamental band near 1626.276(1) and 1627.375(2) cm(-1) (for s and a inversion upper states, respectively) and the 2nu(2) overtone band near 1597.470(3) and 1882.179(5) cm(-1) (for s and a inversion states, respectively). A total of 2345 lines with J' 相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号