无限深势阱中粒子的态密度

对于自由粒子在有限容器中的能态密度,热力学统计教材一般根据半经典量子图像,由驻波条件和德布罗意关系,以动量分立值为基础出发得到;然而根据量子理论,无限深势阱中的粒子存在能量本征态,而非动量本征态.本文以能量本征态为统计对象推导了有限体积中的自由粒子的能态密度,结果与教材一致.但是我们的处理方式显得更为自然.     

Lifshitz tails and long-time decay in random systems with arbitrary disorder

In random systems, the density of states of various linear problems, such as phonons, tight-binding electrons, or diffusion in a medium with traps, exhibits an exponentially small Liftshitz tail at band edges. When the distribution of the appropriate random variables (atomic masses, site energies, trap depths) has a delta function at its lower (upper) bound, the Lifshitz singularities are pure exponentials. We study in a quantitative way how these singularities are affected by a universal logarithmic correction for continuous distributions starting with a power law. We derive an asymptotic expansion of the Lifshitz tail to all orders in this logarithmic variable. For distributions starting with an essential singularity, the exponent of the Lifshitz singularity itself is modified. These results are obtained in the example of harmonic chains with random masses. It is argued that analogous results hoid in higher dimensions. Their implications for other models, such as the long-time decay in trapping problems, are also discussed.     

Ground-state and quenched-state properties of a one-dimensional interacting lattice gas in a random potential

We determine the zero-temperature properties of a one-dimensional lattice gas of particles that interact via a nearest neighbor exclusion potential and are subject to a random external field. The model is a special limiting case of the random field Ising chain. We calculate (1) the energy and density of the ground state as well as the local energy-density correlation and (2) the pair correlation function. The latter calculation gives access to all higher order correlations. The structure factor is shown to be a squared Lorentzian. We also compare the ground state to the quenched state obtained by sequentially filling the lowest available energy levels.     

On the statistical mechanics approach in the random matrix theory: Integrated density of states

We consider the ensemble of random symmetricn×n matrices specified by an orthogonal invariant probability distribution. We treat this distribution as a Gibbs measure of a mean-field-type model. This allows us to show that the normalized eigenvalue counting function of this ensemble converges in probability to a nonrandom limit asn and that this limiting distribution is the solution of a certain self-consistent equation.     

The number of electronic states in metallic nanowires as a function of the electrochemical potential

We derive a mathematical expression for the number of electronic states in metallic nanowires within the electrochemical environment as a function of the electrochemical potential so that the variation of the above number with respect to this potential is discussed within an electron energy range from zero energy up to Fermi energy.     

Mobility of an electron in a Guassian random potential

The mobility of an electron in a Gaussian random potential is evaluated. It is shown that the relaxation time of the electron is found to be proportional to $\text{L}{}^2\text{|}\text{p}\text{|}$ for large and small correlation lengths L where |p| is the electron momentum.     

Lifschitz singularities for periodic operators plus random potentials

UsingX-bounding (lower bounds by Laplacians with mixed boundary conditions and discrete analogs), we obtain the Lifschitz exponent at the bottom of the spectrum for random operators of typeH =T+V , withT a (periodic) generator of a positivity-preserving semigroup, extending results by Kirsch and Simon.     

Almost sure quasilocality in the random cluster model

We investigate the Gibbsianness of the random cluster measures ^{q, p} and , obtained as the infinite-volume limit of finite-volume measures with free and wired boundary conditions. Forq>1, the measures are not Gibbs measures, but it turns out that the conditional distribution on one edge, given the configuration outside that edge, is almost surely quasilocal.     

Polymer localization in random potential

This work re-examines the classical problem of polymer collapse in a random system, using a Gaussian variational formalism to treat the “poor solvent” case. In particular we seek to clarify some of the disputed questions related to symmetry breaking between the replicas used to analyze such quenched systems, and the scaling of the globular collapse with the disorder strength. We map the random system to a chain with attractive interactions in the standard way, and conduct a variational analysis along with a detailed examination of the theory's stability to replica symmetry breaking. The results suggest that replica symmetry is in fact not broken by the collapse of the chain in a random-disordered system, and that inclusion of a positive third, or higher, virial coefficient is crucial to stabilize the theory. For three dimensions, we find the globule square radius falling as (α-2ω)², where α and ω are proportional to the second and third virial coefficients, respectively. This is in keeping with the earliest results of the replica-symmetric argument advanced by Edwards and Muthukumar [J. Chem. Phys. 89 (1988) 2435], but we anticipate a different scaling with dimensionality in other cases, with the globule square radius scaling as l(α,ω)^2/(d-2) for d<4, where l is some linear function. This result agrees a scaling argument regarding the chain in a random potential like that put forth by Cates and Ball [J. Phys. (France) 49 (1988) 2009], but with a repulsive third virial coefficient present.     

On the Lifschitz singularity and the tailing in the density of states for random lattice systems

We prove rigorously the existence of a Lifschitz singularity in the density of states at zero energy in some random lattice systems of noninteracting bosons and fermions in any numberv of dimensions. The basic tool is a simple modification of the method of Fukushima to yield the correct upper and lower bounds for allv. We also comment on the mathematical difference between the models treated and the system of phonons with mass disorder in the harmonic approximation, whose behavior is known to be of Debye form, not Lifschitz, at low temperatures.Supported by the Swiss National Science Foundation.On leave of absence from the Institute de Fisica, University of São Paulo, Brazil.     

On the effects on a Landau-type system for an atom with no permanent electric dipole moment due to a Coulomb-type potential

We analyse the bound states for a Landau-type system for an atom with no permanent electric dipole moment subject to a Coulomb-type potential. By comparing the energy levels for bound states of the system with the Landau quantization for an atom with no permanent electric dipole moment (Furtado et al., 2006), we show that the energy levels of the Landau-type system are modified, where the degeneracy of the energy levels is broken. Another quantum effect investigated is a dependence of the angular frequency of the system on the quantum numbers associated with the radial modes and the angular momentum. As examples, we obtain the angular frequency and the energy levels associated with the ground state and the first excited state of the system.     

Effect of quasiparticle renormalization on the localization of the excitations of a one-dimensional Bose-Einstein condensate in a random potential

We investigate the effects of renormalization on the localization of the quasiparticle excitations of one-dimensional Bose-Einstein condensate in a random potential. Starting with a set of linearized equations of motion for the phases of superfluid grains coupled by Josephson interactions, we use mode-counting techniques to calculate the inverse localization length for large (10⁸) arrays. Employing distributions for the interaction parameters that are the same as the initial (pre-renormalization) distributions used by Gurarie et al. (Phys. Rev. Lett. 101 (2008) 170407), we compare the initial-interaction results for the localization length with those obtained using renormalization group techniques.     

Effect of external Gaussian random field on phonon spectrum of linear atomic chains

We present the theoretical study of the effect of external random field characterized by a Gaussian probability distribution function on the continuous phonon spectrum of one-dimensional (1D) chain, based on the Jacobian matrix method. The cumulative effect of the random field and simple isotopic defect is studied analytically and numerically. The Gaussian random field removes a square-root divergence appearing in the phonon spectrum of ideal 1D chain. The impurity phonon DOS shows strong dependence on the variance and the mean of the random field and exhibits very different behavior from the non-random case: the continuous spectrum is expanded and the δ-peak, describing discrete impurity vibrations in the non-random chain with the impurity, falls into a continuous zone.     

Two-dimensional potential energy function for internal rotation in 1,2-dihydroxybenzenes

We have obtained an analytical expression for the two-dimensional potential energy function for internal rotation in 1,2-dihydroxybenzenes, allowing us to use perturbation theory methods to calculate and interpret the torsional spectra of these compounds. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 133–136, January–February, 2006.     

One-body potential theory of molecules and solids modified semiempirically for electron correlation

The study of Cordero, March and Alonso (CMA) for four spherical atoms, Be, Ne, Mg and Ar, semiempirically fine-tunes the Hartree-Fock (HF) ground-state electron density by inserting the experimentally determined ionization potentials. The present Letter, first of all, relates this approach to the very recent work of Bartlett ‘towards an exact correlated orbital theory for electrons’. Both methods relax the requirement of standard DFT that a one-body potential shall generate the exact ground-state density, though both work with high quality approximations. Unlike DFT, the CMA theory uses a modified HF non-local potential. It is finally stressed that this potential generates also an idempotent Dirac density matrix. The CMA approach is thereby demonstrated to relate, albeit approximately, to the DFT exchange-correlation potential.     

On the asymmetry of a random walk in the presence of a field

Any ensemble of random walks with symmetric transition probabilities will have symmetric properties. However, any single realization of such a random walk may be asymmetric. In an earlier paper, Weiss and Weissman developed a measure of asymmetry and applied it to random walks in the absence of a field, showing that the degree of asymmetry (in the diffusion limit) is independent of time and that the most probable degree of asymmetry corresponds to the maximum possible. We show in the present paper how the presence of a symmetric field can change this result, both in making the degree of asymmetry depend on time, and driving the random walk toward a more symmetric state.     

Averaged electron Green function and CDW pinning in one-dimensional random potential

The averaged retarded electron Green functionG ⁺(,k) in 1d disordered metal is calculated using the Berezinsky diagram technique. Using the Gorkov's theory it is shown, that the substitution of inG ⁺ (,k) by the square of the external frequency atk=0 gives the dependence of Fröhlich conductivity _F(). This dependence describes the impurity pinning of CDW in 1d disordered metals. The good agreement of this dependence with experimental data Zeller et al. about _F() in quasi-1d conductor KCP is found     

The Strength of First and Second Order Phase Transitions from Partition Function Zeroes

We present a numerical technique employing the density of partition function zeroes (i) to distinguish between phase transitions of first and higher order, (ii) to examine the crossover between such phase transitions and (iii) to measure the strength of first and second order phase transitions in the form of latent heat and critical exponents. These techniques are demonstrated in applications to a number of models for which zeroes are available.     

Phonon density of states of ann-component alloy

We have generalized the coherent potential approximation (CPA) of Tripathi and Behera to the case of ann-component alloy. It is seen that then-component CPA density of states reproduces the binary, ternary quartenary alloys etc when the appropriate limits are adopted.     

Spectral density of mixtures of random density matrices for qubits

We derive the spectral density of the equiprobable mixture of two random density matrices of a two-level quantum system. We also work out the spectral density of mixture under the so-called quantum addition rule. We use the spectral densities to calculate the average entropy of mixtures of random density matrices, and show that the average entropy of the arithmetic-mean-state of n qubit density matrices randomly chosen from the Hilbert–Schmidt ensemble is never decreasing with the number n. We also get the exact value of the average squared fidelity. Some conjectures and open problems related to von Neumann entropy are also proposed.