共查询到20条相似文献,搜索用时 15 毫秒
1.
Ves’kina N. A. Afon’kina S. R. Odinokov V. N. 《Russian Journal of Organic Chemistry》2011,47(11):1767-1771
The reduction of ponasterone A diacetonide with lithium in liquid ammonia stereospecifically led to 7,8β-dihydroanalogs of
5α- and 5β-epimers of ponasterone A and 7,8β-dihydro-6α-hydroxy derivative. 7,8β-Dihydroponasterone A, phytoecdysteroid from
the needles of Japanise yew Taxus cuspidata, and its 5α-epimer were synthesized. 相似文献
2.
Cycloadsurgenin, 20R,24 S-epoxycycloartan-6α,25-diol-3,16-dione, was partially synthesized in four steps from cyclosieversigenin. Side products with the structures 17E,24S-cycloart-17-en-6α,24,25-triol-3,16-dione and 17Z,24 S-cycloart-17-en-6α,24,25-triol-3,16-dione were obtained in addition to the desired product.
Presented at the 1st International Symposim on Edible Plant Resources and the Bioactive Ingredients, Xinjiang, China, July
25–27, 2008.
Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 591–595, November–December, 2008. 相似文献
3.
The lactone 20R-25-norcycloartan-3β,6α,16β-triol-20,24-olide was synthesized from cyclosiversigenin.
Presented at the 1st International Symposium on Edible Plant Resources and the Bioactive Ingredients, Xinjiang, China, July
25–27, 2008.
Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 324–327, May–June, 2009. 相似文献
4.
The structure of a sesquiterpene lactone germacranolide was defined as 1β,6β-dihydroxygermacr-4(5),10(14)-dien-8,12-olide and was the C6-epimer of (11R)-11,13-dihydrotatridin-B. 相似文献
5.
Markus Dobler James C. Anderson Mathias Juch Hans-Jürg Borschberg 《Helvetica chimica acta》1995,78(2):292-300
Synthetic (+)-makomakine ( 6 ) was transformed in six steps into (+)-17R,18R)-17,18-dihydrohobartine-17,18-diol ((+)- 5 ) with an overall yield of 38% (Scheme 2). This compound was shown to be identical with natural hobartinol, a monoterpene indole alkaloid from Aristotelia australasica, originally believed to be the (17S)-epimer 1 . At the same time, the synthesis of (+)- 5 delineates the hitherto unknown absolute configuration of this metabolite. 相似文献
6.
I. F. Makarevich S. N. Kovalenko T. D. Gusarova Yu. I. Gubin 《Chemistry of Natural Compounds》2009,45(1):40-44
Twelve compounds including secologanin, loganin, the aglycon of loganin, and a new iridoid called glucologanin were isolated
from fruit of common snowberry Symphoricarpos albus (L.) Blake. The structure of glucologanin was confirmed using PMR and mass spectroscopy and chemical transformations. 2′,3′,4′,6′,7-Penta-O-acetylloganin and 2′,3′,4′,6′-tetra-O-acetylloganin were synthesized.
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 37–40, January–February, 2009. 相似文献
7.
L. D. Popov I. N. Shcherbakov V. A. Kogan O. I. Kobeleva T. M. Valova V. A. Barachevsky A. I. Shienok L. S. Kol’tsova O. Yu. Os’kina N. L. Zaichenko 《Russian Chemical Bulletin》2009,58(5):974-977
New hybrid spirooxazine was synthesized from the 8′-amino-substituted spironaphtho-oxazine and 2-(p-tosylamino)benzaldehyde. Photochromism and the complex-forming ability toward Mg2+, Ba2+, La3+, and Tb3+ ions of the synthesized compound and initial 8′-amino-spironaphthooxazine were studied in comparison. The spectral kinetic
differences in the photochromism and complex formation of these compounds were revealed. 相似文献
8.
I. S. Levina L. E. Kulikova E. V. Shulishov I. P. Klimenko A. V. Kamernitskii Yu. V. Tomilov 《Russian Chemical Bulletin》2006,55(11):2119-2121
4′,4′-Dimethyl[16α,17α]spiropentanopregn-4-ene-3,20-dione was synthesized. The addition of diazo-2,2-dimethylcyclopropane
generated from N-(2,2-dimethylcyclopropyl)-N-nitrosourea to 16,17-didehydropregnenolone acetate occurs regio-and stereospecifically to give 3β-acetoxy-1′,1′-dimethyl-20-oxopregn-5-ene-[16α,17α;7′,6′]-4′,
5′-diazaspiro[2.4]-hept-4′-ene in high yield. Its thermolysis affords a spiropentane-containing steroid, which is transformed
into the target diketone. The anti position of the gem-dimethyl group in the fused spiropentane fragment is evident from the X-ray diffraction study of the final product.
Dedicated to Academician O. M. Nefedov on the occasion of his 75th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2040–2042, November, 2006. 相似文献
9.
A. G. Korepin P. V. Galkin E. K. Perepelkina N. M. Glushakova I. L. Eremenko L. T. Eremenko 《Russian Chemical Bulletin》2009,58(10):2103-2108
Nitration of N-(ω-acylamino0-β,β-dinitroalkyl)tetrahydro-1,3-oxazines and N-(ω-acylamino-β,β-dinitroalkyl)oxazolidines resulted in O-nitrates bearing amide, dinitromethylene, and nitroamine groups.
It was found that nitration can be accompanied by N-hydroxymethylation of the amide group. Three nitrates synthesized were
tested for, and exhibited good level of, cardioprotection. 相似文献
10.
E. A. Khamidullina A. S. Gromova V. I. Litskii A. L. Vereshchagin A. A. Semenov M. F. Larin 《Chemistry of Natural Compounds》1989,25(4):441-447
Four new cycloartane glycosides have been isolated from a methanolic extract ofThalictrum squarrosum Stephan ex Willd.: squarroside A1 (I) — (21R, 22S, 23R)-3β-(β-D-glucopyranosyloxy)-21α-methoxy-21,23-epoxycycloart-24-ene-22β,30-diol,
C30H60O10; squarroside A2 (II) — the (21S)-epimer of compound (I); squarroside B1 (III) (21R, 22S, 23R)-3gb-[O-α-L-rhamnopyranosyl-(1
→ 6)-β-D-glucopyranosyloxy]-21α-methoxy-21,23-epoxycycloart-24-ene-22β,30-diol, C43H70O14; and squarroside B2 (IV) — the (21S)-epimer of compound (III). The proposed structures were determined on the basis of1H and13C NMR spectroscopy, FAB mass spectrometry, and chemical transformations.
Irkutsk Institute of Organic Chemistry, Siberian Branch, USSR Academy of Sciences. Translated from Khimiya Prirodnykh Soedinenii,
No. 4, pp. 516–523, July–August, 1989. 相似文献
11.
M. I. Merlani L. Sh. Amiranashvili N. I. Men’shova E. P. Kemertelidze 《Chemistry of Natural Compounds》2007,43(1):97-99
5α-Androstan-3β,17β-diol (3b-adiol), a known inhibitor of prostate cancer cell growth, was synthesized from tigogenin. Its structure was confirmed
by NMR and IR spectroscopy and mass spectroscopy.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 81–82, January–February, 2007. 相似文献
12.
I. M. Chung Mohd Ali A. Ahmad C. Y. Yu K. H. Ma J. G. Gwag Y. J. Park 《Chemistry of Natural Compounds》2005,41(6):650-653
One new compound 3,7,11,15,19-pentamethyl-9α,10α,11α,17α,18α-pentahydroxy-n-tetracosan-1-oxy-p-hydroxycaffeoate (oryzaterpenyl
caffeoate) (1), together with three known fatty acids linoleic acid, stearic acid and myristic acid were isolated and identified from the
rice grain of Oryza sativa. The structure of the new compound was elucidated by 1D and 2D NMR spectroscopic techniques (1H-1HCOSY, 1H-13C HETCOR) aided by EI-MS, and IR spectra.
__________
Published in Khimiya Prirodnykh Soedinenii, No. 6, pp. 535–537, November–December, 2005. 相似文献
13.
P. Kh. Yuldashev B. Tashkhodzhaev K. K. Turgunov M. M. Mirzaeva 《Chemistry of Natural Compounds》2011,46(6):924-928
The bisindole compound 2β,16α,2′β,16′β(H)-tetrahydronordihydrotoxiferine consisting of two diastereoisomeric deoxytetrahydronorfluorocurarine moieties was isolated
from the reduction mixture of the alkaloid norfluorocurarine. 16-Deformyl-2,16,17,20-tetrahydro-20,21-dehydronorfluorocurarine
was produced by dehydrogenation of norfluorocurarine; N(β)-methyldihydrodefluorocurarine, by hydrogenation of fluorocurarine. The structures of the synthesized compounds were established
by x-ray structure analyses. The configurations of the asymmetric centers in 2β,16α,2′β,16′β(H)-tetrahydronordihydrotoxiferine were determined as 2S,3S,7R,15S,16R,2′S,3′S,7′R,15′S,16′S. Inversion to the R-configuration at the C15 center was observed in N(β)-methyldihydrodefluorocurarine whereas the configurations 3S and 7R were retained. Atom C2 adopted the S-configuration in 16-deformyl-2,16,17,20-tetrahydro-20,21-dehydronorfluorocurarine. 相似文献
14.
The structure of a new cycloartane-type triterpene glycoside, cyclomacroside E, which was isolated from roots of Astragalus macropus Bunge (Leguminosae), was established as 3-O-α-L-rhamnopyranoside,24-O[(β-D-xylopyranosyl)(1→2)-β-D-xylopyranoside]-24R-cycloartan-1α,3β,7β,24,25-pentaol. 相似文献
15.
A new triterpene glycoside of the cycloartane series that was called askendoside H was isolated from roots of Astragalus taschkendicus
Bunge (Leguminosae). Its structure was elucidated based on chemical transformations and spectral data. Askendoside H was a
bisdesmoside of cycloorbigenin C, 23R,24Rcycloartan-3β,6α,16β,23,24,25-hexaol 3-O-[(α-L-arabinopyranosyl)(1 → 2)-β-D-xylopyranoside] 23-O-βD-glucopyranoside. 相似文献
16.
The structure of the new cycloartane glycoside cyclomacroside D, which was isolated from Astragalus macropus Bunge (Leguminosae) and is 24R-cycloartan-1α,3β,7β,24,25-pentaol 3-O-α-L-rhamnopyranoside–24-O-β-D-xylopyranoside, was proved.
Presented at the 7th International Symposium on the Chemistry of Natural Compounds (SCNC, Tashkent, Uzbekistan, October 16–18,
2007).
Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 48–50, January–February, 2009. 相似文献
17.
A new triterpene cycloartane glycoside called askendoside K was isolated from roots of Astragalus taschkendicus Bunge (Leguminosae). The structure of this glycoside was established using chemical and biochemical transformations and spectral
data. Askendoside K was a bisdesmoside of cycloorbigenin C and had the structure 23R,24R-cycloartan-3β,6α,16β,23,24,25-hexaol 3-O-[(α-L-arabinopyranosyl)(1 → 2)-β-D-xylopyranoside],23-O-[(β-D-glucuronopyranosyl)(1 → 2)-β-D-glucopyranoside]. 相似文献
18.
The structure of the new cycloartane glycoside cyclomacroside B that was isolated from Astragalus macropus Bunge (Leguminosae) was shown to be 1,7-di-O-acetyl-24R-cycloartan-1α,3β,7β,24,25-pentaol 3-O-α-Lrhamnopyranoside-24-O-β-D-xylopyranoside. 相似文献
19.
The structure of the novel cycloartane triterpene glycoside cyclomacroside A, which was isolated from Astragalus macropus Bunge (Leguminosae) roots, was determined as 3-O-α-L-rhamnopyranoside-24,25-isopropylidenedioxy-24R-cylcoartan-1α,3β,7β-triol. 相似文献
20.
A. B. Serov V. G. Kartsev Yu. A. Aleksandrov F. M. Dolgushin 《Russian Chemical Bulletin》2005,54(10):2432-2436
A series of 6a′,7′,8′,9′-tetrahydrospiro[indoline-3,7′-pyrrolo[1,2-a]quinoline]-2-one derivatives were synthesized by the 1,3-dipolar cycloaddition reaction. The regio-and stereoselectivity
of the reaction were established by X-ray diffraction study.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2357–2361, October, 2005. 相似文献