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1.
应用基于Ono-Kondo格子理论得到的通用吸附等温方程, 通过分析氢在不同温度下, 在沸石NaX、CaA、NaA和ZSM-5上的吸附数据, 确定了氢的最大单层吸附容量. 并引入维里吸附方程, 由第二维里吸附系数和圆柱孔的Lennard-Jones(12-6)势模型计算了氢与沸石微孔壁面的作用势. 结果表明, 通用吸附等温方程可较好地描述氢在沸石上的超临界吸附行为, 拟合所得的氢在沸石上的最大单层吸附容量与吸附剂相关, 而与吸附温度无关. 圆柱孔作用势模型计算所得的氢分子在沸石上的吸附作用势与吸附热相近. 氢分子间的作用力表现为吸引力. 相似文献
2.
The hydrogen adsorption properties and uptake capacities of the A, X and ZSM-5 types of zeolites were investigated at temperatures of 77, 195 and 293 K and pressures up to 7MPa, using a conventional volumetric adsorption apparatus. All hydrogen adsorption isotherms were basically type I, but the maximum in isotherm,a unique feature of supercritical adsorption, was observed at high pressures of 2-5 MPa at 77 K. The isosteric heats of adsorption were determined from the isotherms and the factors that influence their variations were discussed. Different types of zeolites exhibited remarkably different hydrogen uptake, based on both the framework structure and the nature of the cations present. The highest gravimetric storage capacity of 2.55wt% was obtained for NaX-type zeolite at 4 MPa and 77 K. In CaA, NaX and ZSM-5 types of zeolites,hydrogen uptakes were proportional to the specific surface areas, which were associated with the available void volumes of the zeolites. A threshold in hydrogen adsorption observed in NaA and KA was attributed to a pore blocking effect by large cations in KA. A ratio of the kinetic diameter of adsorbate to the effective opening diameter of zeolite was used to judge the blocking effect for physisorption. 相似文献
3.
用高真空重量法测定了NaX分子筛对不同吸附质NH3, H2O, C2H5OH等的吸附等温线, 用微孔体积填充理论对吸附等温线进行非线性拟合, 得到满意结果。表明该理论不但可扩展到以静电场为主的吸附体系, 还可适用于吸附温度高于吸附质临界温度的吸附体系。计算结果表明, NaX吸附不同吸附质测得的极限空腔体积基本相同, 且与结构分析得到的空腔体积一致, 进一步表明微孔体积填充理论对该体系的适用性。计算了各种吸附质的极限吸附量, 以及某填充度下的蚊分吸附热随着温度的变化趋势。可为固体吸附式制冷系统的设计与制造提供理论依据及有关掺数。 相似文献
4.
The ion exchange between60Co2+ ions contained in residual radioactive water and zeolites of the NaA, NaX and CaA types was studied. The more advanced retaining of60Co2+ ions occurs for the NaA zeolite with the higher exchange capacity, as compared to NaX. With the CaA zeolite, a very weak ion exchange with60Co2+ ions was observed. 相似文献
5.
The scope of this work is to carry out a systematic comparison of inverse gas chromatography (IGC) and microcalorimetry as tools for the study of the gas-phase adsorption of organic vapours (using hexane as model compound) on zeolitic materials (using different Mn, Co and Fe-exchanged NaX and CaA zeolites). Adsorption isotherms were recorded using both techniques in the temperature range of 150-250 degrees C, being observed that the shape of the isotherms obtained with the dynamic (IGC) and static (microcalorimetry) techniques was surprisingly similar in the pressure range at which both techniques are applicable (low surface coverages). Concerning to the measurement of the strength of the adsorption, calorimetric data provide two parameters related to the adsorption enthalpy: the initial differential heat and the isosteric adsorption enthalpy. A great coincidence was found between the last one and the adsorption enthalpy determined by IGC (4-20% of difference, depending on the studied material). The behaviour of the initial differential heat depends strongly on the studied material, being in some cases closely related to the other two parameters and temperature-independent (in the case on Mn-exchanged zeolites), whereas for the Co-CaA and Fe-CaA zeolites, it is temperature-dependent, being not correlated with the other parameters in this case. The main conclusion of this work is that IGC is an attractive alternative to the static microcalorimetric data for obtaining information on the adsorption of organic compounds on microporous materials. 相似文献
6.
Dongmin Shen Martin Bülow Flor Siperstein Maximilian Engelhard Alan L. Myers 《Adsorption》2000,6(4):275-286
Experimental measurements of heats of adsorption published in the literature are often in disagreement; differences of 10–20% are common. The three most widely used experimental methods are: (1) differentiation of adsorption isotherms at constant loading; (2) measurement of adsorption isosteres; (3) calorimetry. Results from these methods were compared for the systems nitrogen on CaA, oxygen on CaA, and carbon dioxide on NaX. Although the same materials and similar degassing procedures were used for all experiments, calorimetric heats are about 2 kJ/mol higher than the heats from isoteric measurements. Additional experiments are needed to bring these methods into exact agreement. 相似文献
7.
采用两步晶化和氨基酸辅助的协同合成策略, 制备了具有高产率(89%)和高结晶度(微孔体积为0.30 cm 3/g)的多级孔NaX分子筛. 利用X射线粉末衍射、 扫描电子显微镜、 透射电子显微镜和氮气吸附等技术, 考察了两步晶化和氨基酸加入量对NaX分子筛的形貌、 相对结晶度和产率的影响. 实验结果表明, 两步晶化有利于多级孔结构的产生, 氨基酸的引入有助于提高分子筛相对结晶度和产率. 与传统方法合成的NaX分子筛相比, 该合成策略制备的多级孔NaX分子筛展现出更优异的CO2吸附性能, 在273 K和100 kPa条件下, 其CO2吸附量达到154.2 cm 3/g, 而传统NaX分子筛的CO2吸附量为147.6 cm 3/g. 该合成策略为绿色且高效制备高质量的多级孔分子筛提供了新思路. 相似文献
8.
A. M. Voloshchuk V. A. Gorlov T. A. Moskovskaya L. S. Reifman V. N. Chechevichkin A. A. Yurkevich 《Russian Chemical Bulletin》1990,39(6):1097-1100
The use of the method of densitometry of light passing through a layer of zeolite crystals permits determining the limiting stage of diffusion during adsorption by zeolites. Diffusion in transport pores and external heat exchange play the basic role in adsorption of benzene by NaX zeolite, while diffusion in crystals is the determining mechanism of transport in adsorption of water by NaA and NaX zeolites. The diffusion coefficients of water in NaX zeolite have an order of magnitude of 10–17 m2/sec and increase with an increase in the degree of filling. An explanation for the anomalous behavior of the kinetic adsorption curve for brief times of adsorption of water by zeolite is proposed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1224–1228, June, 1990. 相似文献
9.
The kinetics of the adsorption of ethane-hydrogen mixtures at low pressures (5–20 Torr) on the zeolites LiLSX and CaA are studied by diffuse reflectance IR spectroscopy. The adsorption of ethane mixed with hydrogen on the granulated zeolites is two orders of magnitude slower than the adsorption of pure ethane. Comparison of the adsorption kinetics of ethane-hydrogen mixtures on granulated samples and thin pellets shows that the transport of ethane into the microcrystals of the granular zeolites is retarded primarily by the counter-diffusion of ethane and hydrogen in the intercrystallite pores. 相似文献
10.
Adsorption of supercritical carbon dioxide on two kinds of zeolites with identical chemical composition but different pore structure (NaA and NaX) was studied using the Gibbs ensemble Monte Carlo simulation. The model frameworks for the two zeolites with SiAl ratio being unity have been chosen as the solid structures in the simulation. The adsorption behaviors of supercritical CO2 on the NaA and NaX zeolites, based on the adsorption isotherms and isosteric heats of adsorption, were discussed in detail and were compared with the available experimental results. A good agreement between the simulated and experimental results is obtained for both the adsorbed amount and the bulk phase density. The intermediate configurational snapshots and the radial distribution functions between zeolite and adsorbed CO2 molecules were collected in order to investigate the preferable adsorption locations and the confined structure behavior of CO2. The structure behaviors of the adsorbed CO2 molecules show various performances, as compared with the bulk phase, due to the confined effect in the zeolite pores. 相似文献
11.
FTIR studies of zeolite matrix effects on the properties of palladium clusters confined in the supercages of NaX and NaY 总被引:1,自引:0,他引:1
Palladium clusters have been synthesized by the "ship-in-a-bottle" approach in the supercages of NaX and NaY faujasite zeolites. In comparison with CO adsorbed on a bulk Pd electrode, the same molecule adsorbed on the Pd clusters electrodes evoked an enhanced IR absorption (EIRA). The enhancement factors have been determined to be about 38 and 51 in NaX and NaY, respectively. IR band centers of linear-bonded CO, bridge-bonded CO, and multi-bonded CO in NaX are measured, respectively, 12, 14, and 11 cm(-1) lower than those of the corresponding adsorption modes in NaY. The adsorption of CO and the oxidation of adsorbed CO in NaX matrix are faster than that in NaY matrix. These results suggest that part of the Pd2+ ions in NaX are located in sites III and III' that are near the 12-ring window of the supercage of zeolite, which lead to the formation of small Pd clusters. The present study is of significant importance in exploring the dependence of catalyst properties on structures, as well as in understanding and predicting the locations and properties of metal clusters in zeolites. 相似文献
12.
The diffusion-limited adsorption of individual ethane or of ethane from mixtures with hydrogen by thin pellets of NaA, CaA
and LiLSX zeolites or by thick layers of granulated zeolites was studied at room temperature. The rates of adsorption were
monitored by development of the bands from the symmetry forbidden C–H stretching vibrations that were not observed for gaseous
molecules. Diffusivity of individual ethane in the micropores of the thin NaA pellet obtained by this method is equal to 6
⋅ 10−16 m2/s. This value agrees well with that one previously reported in literature. For adsorption of pure ethane in the larger primary
micro pores of CaA or LiLSX only the lower limits of diffusivities were estimated. Diffusion-limited adsorption of ethane
from mixtures with hydrogen by the thicker layers of granulated zeolites is much slower and is limited by counterdiffusion
inside much larger channels between the zeolite granules. Estimation of diffusion coefficients of such counterdiffusion indicated
that they are by two orders of magnitude lower than those for diffusion in gaseous mixtures of similar composition.
This paper is dedicated to the memory of Professor Wolfgang Schirmer. 相似文献
13.
A study has been made of the temperature dependence of deformation of CaA, CaX, and LaX zeolites when krypton or xenon is adsorbed, and also the deformation of activated carbon when dimethyl ether is adsorbed. It has been shown that the volume compressibility and the standard chemical potential of the adsorbate in a vacancy solution, within the interval of temperatures and pressures that were investigated, can be considered as linear functions of temperature. In this case, knowledge of the temperature dependence of sorptive deformation offers a means for calculating sorptive deformation curves for other temperatures.Institute of Physical Chemistry, Russian Academy of Sciences, 117915 Moscow. Institute of Petrochemical Synthesis, Russian Academy of Sciences. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 23–28, January, 1992. 相似文献
14.
Inverse gas chromatography (IGC) has been used to examine the adsorption of organo-sulfur compounds on various zeolites. Results obtained were used to explain the behaviour of these materials as adsorbents for ultra-deep desulfurisation of fuels. The model compounds chosen were thiophene and 2,5-dimethylthiophene, with zeolite adsorbents NaX, HX, NaY and HY. Zeolite NaY showed the largest adsorption capacity. Adsorption isotherms in the gas phase are not representative of saturation adsorption in the liquid phase. However, the heat of adsorption and the specific interaction parameter were found to be well correlated to the strength and the selectivity of adsorption in the liquid phase by the different zeolites. The main conclusion of this work is that IGC is a useful tool for preliminary comparison of different adsorbents for the removal of sulfur compounds from fuels. 相似文献
15.
16.
Levin PP Costa SM Lopes JM Serralha FN Ribeiro FR 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2000,56(9):1745-1757
The ground-state and transient absorption, prompt and delayed fluorescence of tetraphenylporphyrin (TPP) adsorbed onto the external surface of different zeolites was monitored using diffuse-reflectance steady-state and laser flash photolysis. The delayed fluorescence (DF) of TPP detected in the presence of O2 is attributed to the energy transfer from 3TPP to 3O2 to form 1O2 and subsequent energy transfer from 1O2 to some other 3TPP within the organised molecular ensembles on the zeolite surface. The spectroscopic and kinetic parameters, namely the yield of DF (2-20% relative to prompt fluorescence), depend on the zeolite properties: the observed differences were correlated with the acid-base properties of the two zeolite series studied in this work (KA, NaA, CaA) and (NaA, NaX, NaY). 相似文献
17.
NaA, NaX and NaZSM-5 zeolites were prepared by using silica extracted from rice hull ash as a raw material, and they were investigated for CO2 adsorption performance as an adsorbent in order to solve the problem of suppressing the global warming. Three zeolites were synthesized by hydrothermal methods with seed technology, and a series of characterization methods, including XRD, FTIR, nitrogen adsorption-desorption and SEM, were used to demonstrate their advantages compared to traditional hydrothermal methods. The maximum equilibrium adsorption capacity of NaA-RS, NaX-RS and NaZSM-5-RS was 1.46, 3.12 and 2.20 mmol/g at 0 °C and 101.3 kPa, respectively. The CO2 and N2 adsorption isotherms recorded at different temperatures were perfectly fitted by the Dual-site Langmuir model. The CO2/N2 selectivity and Henry's law constants were calculated to demonstrate that the samples have a stronger affinity for CO2, especially at low pressures. The isosteric heat of CO2 and N2 adsorption of the three zeolites was calculated, which was indicated that they were in an excellent potential for adsorption and separation of CO2 in industrial flue gas. 相似文献
18.
以高岭土为原料合成沸石分子筛的相变规律 总被引:5,自引:0,他引:5
以天然粘土矿物高岭土为原料, 采用水热晶化法合成了NaX, NaP和SOD三类沸石. 利用XRD、 静态饱和水吸附等测试手段详细考察了晶化温度、 初始反应混合物的碱浓度对沸石结晶的影响. 通过实验研究得到了三类沸石的结晶相区和结晶变化规律, 并优化出最佳合成工艺条件和相转变规律. 相似文献
19.
A statistical thermodynamic treatment of adsorption on zeolites assuming quasiindependent sites has been applied to methane adsorption on the zeolite NaX and the carbon adsorbent PAU-10 from polyvinylidenechloride in the pressure range 0.1–107 Pa and 120–410 K. The relation between the isosteric adsorption heats and the magnitude of adsorption at different temperatures was calculated for both adsorption systems. A sharp decrease in these heats was observed at high adsorption values up to and in the supercritical temperature range.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 974–978, May, 1990.The authors would like to thank V. A. Bakaev for discussions about this work. 相似文献
20.
M. Jaroniec A. Dabrowski G. Nowakowski H. Herden W. D. Einicke R. Schöllner 《Journal of inclusion phenomena and macrocyclic chemistry》1985,3(1):85-93
The isotherm equation for adsorption of binary liquid mixtures of nonelectrolytes, involving differences in molecular sizes of components and quasi-Gaussian energy distribution of adsorption sites, is used to describe the excess adsorption data for 1-olefin/n-paraffin liquid mixtures on NaX and NaY zeolites at 293 K. This equation gives a good representation of the above adsorption data. Analysis of these data showed that the heterogeneity parameter is slightly dependent on the difference in molecular sizes of both components. 相似文献