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苯乙烯与D—120共聚物的性能研究 总被引:2,自引:0,他引:2
合成了侧基含有过氧键的苯乙烯-D-120共聚物(Poly(Sr-co-D-120)PSD)。用IR、GPC进行了表征。用DSC、GPC、TGA探讨了共聚物的热稳定性及分解机理,并对其就地增容PS/LDPE共混体系进行了初步研究。结果表明:共聚物中过氧键浓度越大,其起始分解温度越低,降解越严重,该共聚物可作为PE/PS共混体系的就地增容剂。 相似文献
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在计算机辅助下,应用Goldkey和PC-Gene程序,根据新报道的曼氏血吸虫谷胱甘肽S-转移酶Sm26/2的氨基酸序列,进行亲水性、柔韧性、可接近性、电荷分布和二级结构分析,预测出6个抗原肽,并用固相法进行了合成。经Dot-ELISA法测定,其中的2个对抗日本血吸虫免疫球蛋白多克隆抗体(抗-Si-IgG-PcAb)显示出较好的抗原性,1个对抗血吸虫表膜单克隆抗体(A6McAb)显示出较好的抗原性 相似文献
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从充分利用气相色谱/质谱(GC/MS)提供的信息来鉴定GC流出组分的目的出发,并以脂肪醇分析为例讨论了GC保留指数在MS谱图解析及MS鉴定结果的合理性检验方面的作用。总结了GC保留的同系物规律、极性规律、加和规律及异构物规律来指导MS谱图解析。提出了含氧化合物官能团相对于-CH2-质量数的保留指数附加贡献值辅助MS确定化合物的类别。同时采用了GC/MS中选择离子检测方法(SIM)在分子离子峰受噪音干扰或太弱以至完全未观测到时来进一步佐证其相对分子质量。 相似文献
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用多维色谱—稳定同位素稀释质谱联用技术测定酒中氨基甲酸乙酯 总被引:4,自引:0,他引:4
建立了一个用多维色谱/质谱方法(GC/GC/MS),结合同位素稀释技术(IDMS),测量酒中致癌物质-氨基甲酸乙酯(EC)的准确方法,主要步骤如下:向精确称取的样品中,加入精确称取为,以^13C,^15N标记的氨基甲酸乙酯(LEC)内标溶液,试样经调节,pH萃取,浓缩等化学前处理步骤后,进行GC/GC/CIMS测定。测量以GC/GC的中心切割技术排除复杂基体的干扰。以化学电离(CI)和选择性子检测 相似文献
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HPLC/CoPC修饰电极安培检测大鼠心肌线粒体中谷胱甘肽的研究 总被引:4,自引:0,他引:4
研究了钴酞菁修饰电极的修饰方法及其电化学性质。它可以催化氧化谷胱甘肽,降低GSH的过电位。以CoPC何尝修饰电极为工作电极的安培薄层化学检测器,与高压认相色谱联用,在工作电极电位为+0.8V时,GSH的浓度在3.0*10^-6mol/L-1.0*10^-3mol/L浓度范围内与峰电流呈良好的线性关系,线性相关系数为0.9991,检出限为1.0*10^-3mol/L浓度范围内与峰电流呈良好的线性关系 相似文献
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弹性体型聚氨酯和聚碳酸酯共混物的形态结构 总被引:1,自引:0,他引:1
用DSC、WAXD和SAXS研究了溶液共混的弹性体型聚氨酯(PU)/聚碳酸酯(PC)共混物的结构。结果表明,PU/PC为部分相容体系;共混过程中,溶剂DMF的诱导作用使PC形成结晶,其长周期与PU硬段形成微相的长周期相近 相似文献
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Mourey TH Leon JW Bennett JR Bryan TG Slater LA Balke ST 《Journal of chromatography. A》2007,1146(1):51-60
Nanogels are highly branched, swellable polymer structures with average diameters between 1 and 100nm. Size-exclusion chromatography (SEC) fractionates materials in this size range, and it is commonly used to measure nanogel molar mass distributions. For many nanogel applications, it may be more important to calculate the particle size distribution from the SEC data than it is to calculate the molar mass distribution. Other useful nanogel property distributions include particle shape, area, and volume, as well as polymer volume fraction per particle. All can be obtained from multi-detector SEC data with proper calibration and data analysis methods. This work develops the basic equations for calculating several of these differential and cumulative property distributions and applies them to SEC data from the analysis of polymeric nanogels. The methods are analogous to those used to calculate the more familiar SEC molar mass distributions. Calibration methods and characteristics of the distributions are discussed, and the effects of detector noise and mismatched concentration and molar mass sensitive detector signals are examined. 相似文献
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Monte Carlo simulations were conducted to estimate the elution curve of size exclusion chromatography (SEC). The present simulation can be applied to various types of branched polymers, as long as the kinetic mechanism of nonlinear polymer formation is given. We considered two types of detector systems, (1) a detector that measures the polymer concentration in the elution volume to determine the calibrated molecular weights, such as by using the differential refractive index detector (RI), and (2) a detector that determines the weight‐average molecular weight of polymers within the elution volume directly, such as a light scattering photometer (LS). For polydisperse star polymers, both detector systems tend to give a reasonable estimate of the true molecular weight distribution (MWD). On the other hand, for comb‐branched polymers, the RI detector underestimates the molecular weight of branched polymers significantly. The LS detector system improves the measured MWD, but still is not exact. The present simulation technique promises to establish various types of complicated reaction mechanisms for nonlinear polymer formation by using the SEC data quantitatively. In addition, the present technique could be used to reinvestigate a large amount of SEC data obtained up to the present to estimate the true MWD. 相似文献
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Quantitative evaluation of polymer composition across the SEC chromatogram can provide more accurate characterization of heterogeneous polymer samples for problem solving and for material specification. To this end Fourier-transform infrared spectroscopy (FTIR) with solvent-evaporation interfaces has become a very powerful detector for size-exclusion chromatography (SEC). The solvent-evaporation interface removes the mobile phase at the exit of the chromatograph and deposits the separated molecular sizes as polymer films on infrared transparent substrates. Quantitative interpretation of the FTIR spectra obtained from these films has recently been found to be best accomplished by using partial least squares. In this paper, polystyrene and poly(methylmethacrylate), alone, as blends, and a copolymer were analyzed in a SEC equipped with an evaporative interface. Molecular weight effects, wavelength selection, the effect of averaging spectra on results, and selection of the best data preprocessing method were investigated. General methods of evaluating these variables were developed to arrive at conditions for this particular "model" situation in order to provide a basis for the analysis of more complex polymers. 相似文献
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Composition determination of binary polymer mixtures by size exclusion chromatography with light scattering detection 总被引:1,自引:0,他引:1
<正>Base on the principle of absolute quantification of size exclusion chromatography(SEC),a light scattering(LS) detector coupled with a concentration detector(refractive index detector) is utilized to determine the compositions of complicated binary mixtures.A theoretical analysis predicts that the response factors for both LS and RI detectors are linear functions with the composition of any specified polymer mixtures in the binary polymer mixtures.Two pairs of complicated binary mixtures were used to test the theory mentioned in the present paper,and the experimental results show an excellent accordance with the theory. 相似文献
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《液相色谱法及相关技术杂志》2012,35(10):1911-1934
Abstract An on-line viscometer which measures the eluent pressure drop across a long capillary was developed for use in aqueous size exclusion chromatography (SEC). Intrinsic viscosities of several polymer standards were calculated from data collected by the viscometer. These viscosities agree well with the measurements made with a Ubbelohde four-bulb shear dilution viscometer. The on-line viscometer becomes more sensitive as polymer hydro-dynamic volume increases. Therefore, it can be more effective than a refractive index detector for SEC analysis of high molecular weight, water soluble polymers. 相似文献
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Timo F. Beskers Thorsten Hofe Manfred Wilhelm 《Macromolecular rapid communications》2012,33(20):1747-1752
The determination of molecular weight and correlated chemical composition is of major interest for the advanced analysis of copolymers, blends, or unknown samples. In this work, we present a new way of online coupling IR spectroscopy and SEC to achieve a chemically sensitive, universally applicable SEC detector. Our method overcomes the limitations of existing spectroscopy–SEC combinations. We solved the major problems, like huge intensity of solvent signals (polymer concentration in detector <1 g L−1) and short measuring time (<30 s), by recording the IR spectra with fully optimized sensitivity and by following mathematical solvent suppression. The measuring time for a certain S/N was reduced in several optimization steps by a factor of more than 70 000. The resulting sensitivity allows online coupled IR–SEC measurements. 相似文献
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Dawen Kou Gerald ManiusShangdong Zhan Hitesh P. Chokshi 《Journal of chromatography. A》2009,1216(28):5424-5428
A technique of using size exclusion chromatography (SEC) with the Corona charged aerosol detector (CAD) was developed and evaluated in comparison with refractive index (RI) and evaporative light scattering detection (ELSD) for fast screening of polyethylene glycol (PEG), a polymer used in preparing pegylated pharmaceutical compounds. These detection techniques were used in the analysis of multiple lots of PEG reagents. CAD was found to provide more accurate impurity and polydispersity profiles of PEG reagents that better differentiate their quality, while RI was not suitable for this application due to its low sensitivity and ELSD led to underestimation of the impurity and polydispersity. The accuracy of polydispersity determination by SEC-CAD was validated against a commercial reference standard of known polydispersity. The SEC-CAD technique and the observed differences between the three detectors can also be applied to polymer analysis in general. 相似文献
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One‐pot synthesis of soluble and fluorescent aliphatic hyperbranched poly(amide‐imide) with solvent‐dependent emission
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Rong‐Rong Wang Jun‐Jie Yan Run‐Lin Yang Dong‐Hui Pan Wen Li Yu‐Ping Xu Li‐Zhen Wang Xin‐Yu Wang Min Yang 《Journal of polymer science. Part A, Polymer chemistry》2017,55(12):2053-2060
Aliphatic hyperbranched poly(amide‐imide) was facilely prepared by employing a functional thiolactone‐maleimide monomer. Highly efficient, selective and quantitative properties of amine‐maleimide Michael addition and aminolysis of a thiolactone guaranteed the generation of an ABB' thiol‐yne intermediate without side products, followed by consecutive thiol‐yne click reaction in one‐pot. The hyperbranched structure of the poly(amide‐imide) was confirmed by NMR spectroscopy and triple‐detector GPC/SEC analysis. Additionally, due to the presence of aminosuccinimide fluorophores and intrinsic physical property of hyperbranched polymers, this aliphatic hyperbranched poly(amide‐imide) possessed solvent‐dependent emission and presented good solubility in various organic solvents. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 2053–2060 相似文献
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A novel data processing method for a hyphenated technique, size exclusion chromatography/matrix-assisted laser desorption/ionization-mass spectrometry (SEC/MALDI-MS), has been proposed to determine accurate molecular weight distributions on the basis of the individual oligomer species of a polymer. This method is based on the concept that the individual peak intensities of MALDI mass spectrum observed for every SEC fraction with narrow molecular weight distribution could be adjusted to the quantified values to reveal the accurate molecular weight distribution using the signal intensity of the corresponding fraction on the SEC chromatogram observed with a refractive index detector. At first, the theory of the proposed date processing is described in detail. Then, experimental verification of the method is described. This was performed through the characterization of mixtures of three kinds of monodispersed polystyrene reference materials (weight average molecular weight = ca. 6000, 10000, and 18000) as model samples. An accurate trimodal molecular weight distribution for the individual oligomer species of the sample was obtained without any influence of the chromatographic band broadening observed in the original SEC chromatogram. Moreover, the method for depicting the elution profiles of individual oligomer species during SEC separation was also obtained as a "mass chromatogram" using the data processing procedure. 相似文献