Eigenfunction expansions for Schrödinger and Dirac operators with singular potentials

The spectral theory (eigenfunction expansion theorem) is developed for Schrödinger and Dirac operators with classes of potentials includingg exp(?μ∣x∣)/∣x∣² in the Schrödinger case andg exp(?μ∣x∣)/∣x∣ in the Dirac case.     

Transition energy and dipole oscillator strength of 1s23d-1s2 nf transitions for Sc18+ ion

The transition energies of the 1s²3d-1s² nf (4?n?9) transitions and fine structure splittings of 1s² nf (n?9) states for Sc¹⁸⁺ ion are calculated with the full-core plus correlation method. The quantum defect of 1s² nf series is determined by the single-channel quantum defect theory. The energies of any highly excited states with n?10 for this series can be reliably predicted using the quantum defect as function of energy. Three alternative forms of the dipole oscillator strengths for the 1s²3d-1s² nf (n?9) transitions of Sc¹⁸⁺ ion are calculated with the transition energies and wave functions obtained above. Combining the quantum defect theory with the discrete oscillator strengths, the discrete oscillator strengths for 1s²3d-1s² nf (n > 9) transitions and the oscillator strengths densities corresponding to the bound-free transitions are obtained.     

Scattering theory in the energy space for a class of non-linear wave equations

We study the asymptotic behaviour in time of the solutions and the theory of scattering in the energy space for the non-linear wave equation $$\square \varphi + f(\varphi ) = 0$$ in ? ⁿ ,n≧3. We prove the existence of the wave operators, asymptotic completeness for small initial data and, forn≧4, asymptotic completeness for arbitrarily large data. The assumptions onf cover the case wheref behaves slightly better than a single powerp=1+4/(n?2), both near zero and at infinity (see (1.5), (1.6) and (1.8)).     

Absolute intensities and pressure broadening coefficients measured at different temperatures for the 201II ← 000 band of 12C16O2 at 4978cm-1

Absolute line intensities and self-broadening coefficients have been measured at 197° and 294°K for the 201_II ← 000 band of ¹²C¹⁶O₂ at about 4978cm^-1. The vibration-rotation factor (F_VR), the purely vibrational transition moment (∣R(O)∣), and the integrated band intensity (S_band) are deduced from the measurements. The results are: F_VR(m)=1+(0.24±0.08)x10^-4m+(0.55+0.21)x10^-4m², ∣R(O)∣= (4.340±0.008x10^-3 debye, S_band=96372±190cm^-1km^-1atm^-1_STP. The results for self-broadening coefficients, as well as for individual vibration-rotation lines, are presented in the text.     

Ionic and electronic conduction of oxygen ion conductors in the Bi2O3−Y2O3 system

The ionic conduction of sintered samples of Bi₂O₃?Y₂O₃ containing 20–30 mol% Y₂O₃ has been investigated by means of ac conductivity experiments and EMF measurement of an oxygen concentration cell using the specimen tablet as electrolyte. Ac conductivity was measured at a frequency of 10 kHz under oxygen partial pressures ranging from 1 to 10^-21 atm. The results show that these materials possess high ionic conduction. The conductivities for samples containing 22.5–30 mol% Y₂O₃ are many times higher than those of stabilized zirconia-based solid electrolyte at corresponding temperatures. The ratio of E_meas./E_calc. of an oxygen concentration cell Pt∣O₂(air)∣Bi₂O₃?Y₂O₃∣O₂(pure oxygen)∣Pt is close to 1 which shows that the materials containing 22.5 to 30 mol% Y₂O₃ are nearly pure ionic conductors. The p-type conductivity is negligible at higher P_O2 values. The n-type conduction for a sample containing 27.5 mol% Y₂O₃ was investigated using the Coulomb titration technique in which the following cell was used: Pt Rh∣O₂(air)∣Bi₂O₃?Y₂O₃∣[O]_sn∣W.log P_é=-767000/T+665. P_é is equal to 2.6×10^-61 atm at 800°C. The n-type conductivity is also very small. Thus these materials are good oxygen ionic conductors.     

Dielectronic recombination rate coefficients for Fe23+ ion

The dielectronic recombination rate coefficients are explicitly calculated for the Li-like ion Fe²³⁺, which recombines with the continuum electron to form Fe²²⁺. Both 1s²2s and 1s²2p initial states are treated for the temperature range 1～8 keV. The rate coefficients are obtained from a direct evaluation of the Auger and radiative transition probabilities which are calculated from nonrelativistic Hartree-Fock wave functions. The L-shell electron excitation with Δn≠0 is found to be the dominant transition, while the 2s→2p excitation with Δn = 0 contributes approx. 10–25% of the Δn≠0 value. The K-shell excitation effect is about 1～30% in the temperature range considered, and the cascade effect is estimated to be a reduction in the rate of about 14%.     

Excited states dynamics under high pressure in lanthanide-doped solids

Emission related to rare earth ions in solids takes place usually due to 4fⁿ→4fⁿ and 4fⁿ⁻¹5d¹→4fⁿ internal transitions. In the case of band to band excitation the effective energy transfer from the host to optically active impurity is required. Among other processes one of the possibilities is capturing of the electron at the excited state and the hole at the ground state of impurity.The latest results on high pressure investigations of luminescence related to Pr³⁺ and Eu²⁺ in different lattices are briefly reviewed. The influence of pressure on anomalous luminescence and 4fⁿ⁻¹5d¹→4fⁿ luminescence in BaSrF₂:Eu²⁺ and LiBaF₃:Eu²⁺ systems and Pr³⁺ 4fⁿ→4fⁿ emission quenching is presented and discussed. A theoretical model describing the impurity-trapped exciton as a system where a hole is localized at the impurity and an electron is captured by Coulomb potential at Rydberg-like states is developed. The results show the importance of local lattice relaxation for the creation of stable impurity-trapped exciton states. The ligands shifts create a potential barrier that controls the effect of mixing between the Rydberg-like electron and localized electron wave functions.     

On the scaling factors α(z) and δ(z)

We introduce a new method to determine the scaling factors α(z) and δ(z) for the period-doubling route to chaos in dissipative systems, exemplified by the one-dimensional mapping x_n+1=1−λ∣x_n∣^z. With the help of the Feigenbaum universal functions g(x) and h(x) we derive the inequality α^z−α<δ(z)<α^z, implying in particular that δ(z) remains finite (≲30) in the limit z → ∞.     

Multigap superconductivity in doped p-type cuprates

Andreev and tunneling spectroscopy studies of Bi₂Sr₂Ca _{n ? 1}Cu _n O_{2n + 4 + δ}, HgBa₂Ca _{n ? 1}Cu _n O_{2n + 2 + δ} and Tl₂Ba₂Ca _{n ? 1}Cu_{2n + 4 + δ} have shown that superconductivity in single-layer (n = 1) and two-layer (n = 2) phases has a single-gap character. Qualitatively different results were obtained for three-layer phases. In doped p-type Hg-1223, Bi-2223, and Tl-2223 samples two (or three) superconducting gaps were observed. The existence of multigap superconductivity in superconducting cuprates with n ≥ 3 is explained by a difference in doping levels of outer (OP) and internal (IP) CuO₂ planes.     

Measurement of the isospin amplitude ∣M012∣ in the reaction γn → ϱ0(pπ−) at 7.5 GeV

The cross-channel isospin amplitude $\text{∣M}{}_0{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{∣}$ is measured in the single reaction γn → ?⁰(pπ^?) at 7.5 GeV assuming the ?⁰ dominance model. A low-mass enhancement is found for $\text{∣M}{}_0{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{∣}{}^2$ in the range of m(pπ^?) of ～1.2 to ～1.7 GeV. The reaction strongly violates s-channel helicity conservation but is consistent with t-channel helicity conservation. The $\text{∣M}{}_0{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{∣}$ features are found to be very similar to those obtained in previous analyses of πp → π(Nπ) reactions.     

Semiclassical approximation and 1/n expansion in quantum-mechanical problems

The semiclassical approximation and the technique of 1/n expansion are used to calculate the eigenenergies and the wave functions for the radial Schrödinger equation. It is shown that the expressions that are asymptotically exact in the limit n=n _r+l+1 → ∞ and which describe the above eigenenergies and the asymptotic coefficients at the origin and at infinity ensure a satisfactory precision even for states characterized by modest values of the quantum numbers n _r and l, including the ground state.     

Algebraic study of a class of relativistic wave equations

First-order relativistic wave equations are considered whose irreducible matrix coefficients satisfy the simplest (except for the Dirac algebra) unique mass condition, (β · p)³ = p²(β · p), which is also sufficient to guarantee causality in a minimally coupled external electromagnetic field. All of the associated representations of SL(2, ©) are classified and studied up to and including those which are the direct sum of four irreducible components, (n, m), with either n or m less than two. A large number of families of representations are found which permit the algebraic condition to be satisfied. These are tabulated according to whether a Hermitian choice for β⁰ is possible and their spin content is given. If a unique spin is described, then the only possible representations are

$\text{(1) (}\text{n}\text{,0) ⊕ (}\text{n}\text{? 1/2, 1/2)}$

$\text{(2) (}\text{n}\text{,0) ⊕ (}\text{n}\text{+ 1/2, 1/2)}$

$\text{(3) (}\text{n}\text{+ 1/2, 1/2) ⊕ (}\text{n}\text{,0) ⊕ (}\text{n}\text{? 1/2, 1/2)}$

$\text{(4) (1,0) ⊕ (1/2, 1/2) ⊕ (0,1)}$

and their conjugates. If, in addition, the representation is assumed to be self-conjugate, then only the Dirac and Petiau-Duffin-Kemmer equations survive.     

Oscillatory behaviour of ultrasonic attenuation in KH2PO4 near the phase transition temperature

Oscillations in ultrasonic attenuation have been observed in KH₂PO₄ near the ferroelectric phase transition temperature for longitudinal ultrasonic wave propagation along the polarization axis. Oscillations are present both above and below the transition temperature; the periods of oscillations are different in the two phases for the same ultrasonic frequency and the same ∣T ? T_c∣. The temperature dependence of the oscillations shows that they are due to the phase transition.     

On the specific features and transformation of the band structure of mercury-based HTSC compounds

A systematic analysis of the temperature dependences of the thermopower S(T) for different phases of the HgBa₂Ca _n?1Cu _n O_2n+2+δ family (n=1, 2, 3) at different doping levels is performed in the framework of a narrow-band phenomenological model. Quantitative estimates of the main parameters of the band responsible for conduction in the normal phase of HgBa₂Ca _n?1Cu _n O_2n+2+δ are given for optimally doped samples. The character of the variation in these parameters with an increasing number n of the copper-oxygen layers is discussed. A trend toward broadening of the conduction band with increasing n is revealed, which can be due to the increase of the density-of-states (DOS) peak near the Fermi level with an increasing number of the CuO₂ layers responsible for the formation of the conduction band. It is found that an increase in the number n leads to an increase in the fraction of localized carriers in the band owing to a more defective structure observed in the more complex phases of HgBa₂Ca _n?1Cu _n O_2n+2+δ. The variations in the band-structure parameters in going from under-to overdoped compositions in the HgBa₂Ca _n?1Cu _n O_2n+2+δ family are also discussed.     

Comparative analysis of multi-wave mixing and measurements of the higher-order nonlinearities in resonant media

The features of degenerate multi-wave mixing in resonant media (dye solutions) have been studied theoretically and experimentally. It has been demonstrated that thermal nonlinearity due to the induced absorption from the excited level contributes significantly to the efficiency of four-wave mixing, but results in lower efficiency of higher-order interactions. The measurement results obtained for the energy efficiency of four-, six- and eight-wave mixing enable calculations of the third-, fifth- and seventh-order nonlinear optical susceptibilities, respectively. Experimentally, the method proposed for measurements of the higher-order nonlinearities has been realized with the use of the multi-wave mixing at second harmonic λ = 532 nm of monopulse YAG:Nd³⁺ laser radiation in a Rhodamine 6G dye solution. The ratios ∣χ⁽⁵⁾∣/∣χ⁽³⁾∣ and ∣χ⁽⁷⁾∣/∣χ⁽⁵⁾∣ are determined to be of the order of 10⁻⁵ cm³/erg.     

Asymptotic behavior of Mayer cluster sums for the one-dimensional Ising model

The properties of the high-field polynomialsL _n (u) for the one-dimensional spin 1/2 Ising model are investigated. [The polynomialsL _n (u) are essentially lattice gas analogues of the Mayer cluster integralsb _n (T) for a continuum gas.] It is shown thatu ^?1 L _n (u) can be expressed in terms of a shifted Jacobi polynomial of degreen?1. From this result it follows thatu ^?1 L _n (u); n=1, 2,... is a set of orthogonal polynomials in the interval (0, 1) with a weight functionω(u)=u, andu ^?1 L _n (u) hasn?1 simple zerosu _n (v); v=1, 2,...,n?1 which all lie in the interval 0<u<1. Next the detailed behavior ofL _n (u) asn→∞ is studied. In particular, various asymptotic expansions forL _n (u) are derived which areuniformly valid in the intervalsu<0, 0<u<1, andu>1. These expansions are then used to analyze the asymptotic properties of the zeros {u _n (v); v=1, 2,...,n?1}. It is found that $$\begin{array}{*{20}c} {u_n (v) \sim \tfrac{1}{4}({{j_{1,v} } \mathord{\left/ {\vphantom {{j_{1,v} } n}} \right. \kern-\nulldelimiterspace} n})^2 [1 - ({{j_{1,v}^2 } \mathord{\left/ {\vphantom {{j_{1,v}^2 } {12}}} \right. \kern-\nulldelimiterspace} {12}})n^{ - 1} + ({{j_{1,v}^2 } \mathord{\left/ {\vphantom {{j_{1,v}^2 } {700)( - 3 + 2j_{1,v}^2 )n^{ - 4} }}} \right. \kern-\nulldelimiterspace} {700)( - 3 + 2j_{1,v}^2 )n^{ - 4} }}} \\ { + ({{j_{1,v}^2 } \mathord{\left/ {\vphantom {{j_{1,v}^2 } {20160)(40 + 4j_{1,v}^2 - j_{1,v}^4 }}} \right. \kern-\nulldelimiterspace} {20160)(40 + 4j_{1,v}^2 - j_{1,v}^4 }})n^{ - 6} + \cdot \cdot \cdot ]} \\ {u_n (n - v) \sim 1 - ({{j_{0,v}^2 } \mathord{\left/ {\vphantom {{j_{0,v}^2 } 4}} \right. \kern-\nulldelimiterspace} 4})n^{ - 2} + ({{j_{0,v}^2 } \mathord{\left/ {\vphantom {{j_{0,v}^2 } {48)( - 2 + j_{0,v}^2 )n^{ - 4} }}} \right. \kern-\nulldelimiterspace} {48)( - 2 + j_{0,v}^2 )n^{ - 4} }}} \\ { + ({{j_{0,v}^2 } \mathord{\left/ {\vphantom {{j_{0,v}^2 } {2880)(2 + 9j_{0,v}^2 - 2j_{0,v}^4 )n^{ - 6} + \cdot \cdot \cdot }}} \right. \kern-\nulldelimiterspace} {2880)(2 + 9j_{0,v}^2 - 2j_{0,v}^4 )n^{ - 6} + \cdot \cdot \cdot }}} \\ \end{array} $$ asn→∞v fixed, wherej _k,v denotes thevth zero of the Bessel functionJ _k(^z)     

An−1(1) reflection K-matrices

We investigate the possible regular solutions of the boundary Yang–Baxter equation for the vertex models associated with the A_n−1⁽¹⁾ affine Lie algebra. We have classified them in two classes of solutions. The first class consists of n(n−1)/2 K-matrix solutions with three free parameters. The second class are solutions that depend on the parity of n. For n odd there exist n reflection K-matrices with 2+[n/2] free parameters. It turns out that for n even there exist n/2 K-matrices with 2+n/2 free parameters and n/2 K-matrices with 1+n/2 free parameters.     

Three-body continuum structure and response functions of halo nuclei (I): 6He

Three-body scattering states of the Borromean two-neutron halo nuclei are explored in a core + n + n model using the method of hyperspherical harmonics. We analyse the continuum structure (the properties of the continuum wave functions) separately from the continuum response (the magnitudes of one-step transitions from the ground state to the continuum). Predictions are made for the positions and strengths of the isoscalar monopole, electric dipole and quadrupole excitations, as well as for nuclear inelastic and charge-exchange response functions, for the ⁶He nucleus. The known 2⁺ resonance in ⁶He is reproduced. We find 1⁻ strength concentrations at lower energies in the proximity of the three-body threshold, and predict new 2⁺, 1⁺ (and possibly 0⁺) resonances at slightly higher energies in ⁶He.