共查询到18条相似文献,搜索用时 62 毫秒
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新型激光自倍频晶体Cr:Nd:GdCa4O(BO3)3 总被引:1,自引:0,他引:1
首次利用提拉法生长了优质铬离子敏化激光自倍频晶体Cr:Nd:GdCa4O(BO3)3(Cr:Nd:GdCOB),发现当铬离子和钕离子双掺时,由于协同效应使铬离子容易进入GdCOB晶体中,测量了Cr:Nd:GdCOB和Nd:GdCOB晶体的室温透过谱和荧光谱.Cr:Nd:GdCOB晶体在蓝紫外区比Nd:GdCOB晶体具有更强的吸收,适合于利用闪光灯泵浦.利用闪光灯泵浦分别对长度为7mm,沿最佳倍频方向(θ=66.8°,φ=132.6°)切割的Cr:Nd:GdCOB和Nd:GdCOB晶体进行自倍频实验.Cr:Nd:GdCOB的激发阈值为0.9J,而Nd:GdCOB的激发阈值为1.0J.在10J的输入能量时,Cr:Nd:GdCOB输出绿光能量为2.46mJ,而Nd:GdCOB输出绿光能量为1.96mJ,说明在该晶体中,铬离子对钕离子有很好的敏化作用. 相似文献
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新型AgGa1-xInxSe2晶体用于CO2激光倍频研究 总被引:1,自引:0,他引:1
本实验室用布里奇曼方法成功生长出有应用前景的新型四元非线性AgGa1-xInxSe2晶体,对晶体光学透过,红外低倍显微成像,反射损耗和吸收系数进行了研究和计算.基于纯AgGaSe2和AgInSe2的Sellmeier方程,用线性内插方法计算了不同In含量的AgGa1-xInxSe2在0.9~19μm的Sellmeier色散系数并建立了Sellmeier方程.计算和描绘了Ⅰ型相位匹配CO2激光二次谐波产生的调谐曲线,并标出我们的倍频实验数据.在近似非临界相位匹配条件下,进行了TEA CO2激光10.6μm在AgGa1-xInxSe2中的倍频实验研究,并与AgGaSe2进行了比较,测量的1#AgGa1-xInxSe2相位匹配角θ及相位匹配接收外角△θext·L分别为88.2°和7.7°·cm,AgGa1-xInxSe2的倍频效率比AgGaSe2高出近3倍. 相似文献
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采用熔盐顶部籽晶法从K2Mo3O10-B2O3助熔剂中生长出尺寸为20 mm的优质GdAl3(BO3)4(简称GAB)和Nd3+激活的自变频激光晶体.确定了GAB晶体的透光波长范围、折射率和倍频系数随波长的变化,结果表明其在整个透光范围内均可实现相位匹配.测定了Nd3+∶GAB晶体在室温下的偏振吸收、荧光光谱和荧光寿命,进行了光谱计算,测试了晶体的自变频激光性能,实现了紫外-可见光-红外-中红外多波段激光输出. 相似文献
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本文对新型非线性光学晶体Na3La9O3(BO3)8(NLBO)三倍频产生355 nm紫外纳秒激光的特性进行了研究。以重复频率10 kHz、脉冲宽度10 ns的高功率1 064 nm调Q激光器作为基频光源,采用I类相位匹配的LBO和NLBO晶体分别作为倍频晶体和三倍频晶体,获得平均输出功率152.5 mW的355 nm紫外纳秒激光输出,为目前采用NLBO晶体获得355 nm紫外激光的最高输出功率。本文还研究了NLBO晶体在实现三倍频最佳输出时晶体偏转角度随温度的变化规律,从实验角度对NLBO晶体在不同温度下的三倍频最佳相位匹配角度进行了修正。 相似文献
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X.N. Jiang D. Xu D.R. Yuan M.K. Lu S.Y. Guo G.H. Zhang X.L. Duan 《Crystal Research and Technology》2002,37(1):67-75
To get a better understanding of the growth of cadmium mercury thiocyanate (CMTC), a promising nonlinear optical crystal, we have investigated the structures of its growth solutions by using Raman spectra. It has been found that Hg(II) ions coordinate with SCN‐ through S atoms, forming the most stable complex of [Hg(SCN)4]2‐ in the solutions while Cd(II) ions bind to SCN‐ around Hg(II) through the other end N atom. Thereby, taking [Hg(SCN)4]2‐ anions as centers, a network structure of Cd(II)‐N‐C‐S‐Hg(II) is formed in the solutions as in the crystal lattice. It is notably that there are other complexes, mostly the Cd(SCN)n (n < 4) complexes, in the solutions. Therefore, the solution structure of CMTC is complicated, which is believed to contribute greatly to the difficulty of growing large single crystals. Based on the analysis of the solution structures, the reasonable growth units of CMTC are proposed. 相似文献
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X.L. Duan D.R. Yuan X.Q. Wang X.F. Cheng Z.H. Yang S.Y. Guo H.Q. Sun D. Xu M.K. Lu 《Crystal Research and Technology》2002,37(5):446-455
Cadmium mercury thiocyanate (CdHg(SCN)4, CMTC) and its two lewis base adducts: cadmium mercury thiocyanate dimethyl‐sulphoxide (CdHg(SCN)4(H6C2OS)2, CMTD) and cadmium mercury thiocyanate glycol monomethyl ether (CdHg(SCN)4(C3H8O2), CMTG) have been discovered as nonlinear optical (NLO) crystal materials. Their structural, optical and physicochemical properties were characterized by X‐ray powder diffraction (XRPD), infrared spectroscopy, vis/UV/NIR spectra and thermal analysis. It is discovered that their transparency cutoffs lie in the UV region and CMTD crystals possess the shortest cutoff wavelength among the three crystal materials. 相似文献
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X.N. Jiang D. Xu D.L. Sun D.R. Yuan M.K. Lu S.Y. Gou X.L. Yu 《Crystal Research and Technology》2002,37(1):43-49
New growth phenomena ‐ direct incorporation of aggregates have been observed on the {110} faces of cadmium mercury thiocyanate CdHg(SCN)4 crystals by atomic force microscopy. These aggregates grow in two forms: some directly cover up the steps and forms new growth layers; while others are just incorporated at the step edges. These aggregates, which are mostly oriented along [111] direction, are formed by small columnar structural units. The aggregates have the similar structure of CdHg(SCN)4 crystals and greatly vary in nature with the variation of solution supersaturation σ and growth time t. With the increase of σ the aggregates become larger, consistent with the variation of growth units dimension with the supersaturation; and with the increase of growth time the aggregates become more structurally substantial. These observations have led to a new understanding about the crystal growth. 相似文献
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X.N. Jiang D. Xu D.R. Yuan D.L. Sun M.K. Lu G.H. Zhang S.Y. Guo 《Crystal Research and Technology》2001,36(6):601-608
Growth mechanisms and defect formations on {110} faces of cadmium mercury thiocyanate crystals grown at 30°C (σ=0.24) were investigated by using atomic force microscopy (AFM). It was found that, under this condition, spiral dislocation controlled mechanism and 2D nucleation mechanism operates simultaneously and equally during growth, which is completely different from the traditional 2D nucleation and dislocation source controlled mechanisms. A number of 2D nucleus are formed at the large step terraces generated by dislocation sources, leading to the unequal growth rates of the elementary steps and thereby “step bunches” arecaused. Various defects are formed under this growth condition, which is assumed to result from the incongruence between the steps generated by different sources. A new kind of 2D defect, corresponding to one growth layer in height, was observed for the first time. 相似文献
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Investigation on the Aqueous Solution for Growth of Bimetallic Thiocyanate Complex Crystal Materials
X.L. Duan D. R. Yuan X. Q. Wang S. Y. Guo J. G. Zhang D. Xu M. K. Lu 《Crystal Research and Technology》2002,37(10):1066-1074
The stability of cadmium mercury thiocyanate (CMTC) crystal growth solution was mainly discussed. The effects of temperature, pH value, time and KCl concentration on CMTC crystal growth were investigated. The effects of pH value and KCl concentration on crystallization habit of CMTC were also studied. The results show that when pH value ranges from 2.5 to 3.8, the solution is relatively stable, under the condition of pH ≤ 2.0 or pH ≥ 4.0, the solution has poor stability and some powder appears. The solution becomes unstable at high temperatures. When the concentration of KCl is more than 27% there has not generated CMTC crystal in the solution, a new kind of material produced from solution. The pH value and KCl concentration affect crystalline morphology of CMTC crystal. 相似文献