MgO:LiNb0.3与LiNb0.3质子交换光波导光学及结构特征的比较

利用退火的质子交换法在MgO:LiNbO.3和LiNbO.3两种材料上制作了光波导，得到了质子交换的扩散特性以及光波导折射率分布的退火规律．通过x射线衍射和OH-红外吸收谱方法研究了 MgO:LiNbO.3和LiNbO.3质子交换光波导的结构特征及其与退火参数的关系，对MgO :LiNbO.3和LiNbO.3光波导光学和结构特征的结果进行了分析和比较． 关键词： 退火质子交换光波导 晶格结构 x射线衍射 红外吸收     

Surface acoustic wave distribution and acousto-optic interaction in proton exchanged LiNbO3 waveguides

The efficiency of acoustooptic (AO) interaction in YZ-cut proton exchanged (PE) LiNbO₃ waveguides is theoretically analysed by determining the overlap between the optical and acoustic field distributions. The present analysis takes into account the perturbed SAW field distribution due to the presence of the PE layer on the LiNbO₃ substrate determined by the rigorous layered medium approach. The overlap is found to be significant upto very high acoustic frequencies of the order of 5 GHz, whereas in the earlier analysis by vonHelmolt and Schaffer [6] for diffused waveguides, it was shown that the overlap integral rolls down to nearly zero at this high frequency range.     

Second-order optical non-linearity of proton exchanged lithium tantalate waveguides

A detailed correlation between the fabrication conditions, crystallographic phase state of H_xLi_1-xTaO₃ waveguides and second-order optical non-linearity has been investigated by using reflected SHG measurements from the polished waveguide end face. The non-linearity, strongly reduced after the initial proton exchange, is found to be restored and even increased after annealing. However, this apparent increase in the non-linearity is accompanied by a strong degradation of the quality of the SHG reflected beam in the region of the initial as-exchanged waveguide due to beam scattering. The high temperature proton exchange technique has been shown to produce high-quality α-phase waveguides with essentially undegraded non-linear optical properties. There is no phase transition when the α-phase waveguides are fabricated by direct exchange. This phase presents the same crystalline structure as that of LiTaO₃ and maintains the excellent non-linear properties of the bulk material. The results obtained are important for the design, fabrication and optimization of guided-wave non-linear optical devices in LiTaO₃. Received: 21 May 2001 / Published online: 23 October 2001     

Comparison of the electro-optic coefficient r33 in well-defined phases of proton exchanged LiNbO3 waveguides

The electro-optic coefficient, r₃₃, of proton exchanged LiNbO₃ waveguides has been measured in well-defined phases of the exchanged layer. Namely, in two low index-jump α-phases, i.e. unannealed soft-exchanged (SPE) and annealed (APE) guides, and in two high index-jump phases, i.e. β₁ guides and, for comparison, ordinary proton exchanged (PE) guides (having a mixture of phases). The following values have been obtained (in pm/V): 22.1±0.6 for SPE; 20.9±0.7 for APE; 0.33±0.01 for β₁; and 0.76±0.04 for PE. Differences between these values are discussed in terms of the structure of the phase involved. Received: 18 May 2001 / Revised version: 22 August 2001 / Published online: 30 October 2001     

Ti:LiNbO3 optical waveguides

Various experiments on Ti diffused optical waveguides in LiNbO₃ have been carried out in order to determine precisely the character of the diffusion process. The required guide parameters and the effective mode indices could be controlled by adjusting only the diffusion time under fixed temperature and film thickness. Therefore the dependence of the guide characteristics on the diffusion time has been investigated in detail. On the basis of the data obtained, a two-stage diffusion model is proposed. In the first stage, the Ti diffusant profile is described by a erfc-function, and the second stage is characterized by a modified Gaussian form.     

Acoustic properties of proton exchanged LiNbO3 investigated by Brillouin scattering

The propagation of surface acoustic waves at microwave frequencies (10¹⁰ Hz) was studied on proton exchanged LiNbO₃ crystals by means of Brillouin scattering. The proton exchange causes a large velocity reduction for surface acoustic waves propagating in the x–y plane of ay-cut crystal as well as for longitudinal bulk acoustic waves travelling in the proton exchanged sub-surface region. The velocity reduction amounts to about 20% for both types of waves. The corresponding elastic constants are reduced even by about 40% since the density remains almost constant. This softening seems to involve both the shear and compressional elastic constants, but in an anisotropic way.Thus by proton exchange it is possible to build acoustic waveguides adjacent to the surface, similar to the construction of optical waveguides. By a lateral control of the proton exchange rate optical elements for ultrasonic waves, for example, acoustic lenses can be produced without deformation of the flat surface.The absorption of surface acoustic waves on proton exchanged surfaces is stronger than on pure LiNbO₃ indicating a novel absorption mechanism becoming active in the proton exchanged material.     

Fabrication and characterization of polyethylene terephatate optical waveguides

In this paper, the fabrication and characterization of polyethylene terephatate (PET) thin film integrated optical waveguide is presented. Dip-coating technique has been used to fabricate the optical waveguide using PET. Various waveguide properties, such as mode effective refractive index, optical loss, dispersion and waveguide thickness as a function of temperature of waveguides have been reported. The optical loss are found to be <1 dB cm^–1.     

Photoconductivity and photovoltaic behaviour of LiNbO3 and LiNbO3 waveguides at high optical intensities

The photoconductivity and photovoltaic currents of pure LiNbO₃ and proton exchanged waveguides in LiNbO₃ have been measured as a function of the optical intensity up to about several kW/cm² by the use of surface electrodes. For pure LiNbO₃ the observed dependences are a simple extrapolation of the well known low intensity behaviour. The photoconductivity of proton exchanged waveguides is considerably increased compared with pure LiNbO₃ and the curves are strongly nonlinear in the high intensity region. These results can explain, at least qualitatively, the previously observed characteristic time and intensity dependence of light-induced refractive index changes in this type of waveguides. Both the time and temperature behaviour of the dark conductivity of all proton exchanged waveguides give strong evidence of ionic charge transport in the proton exchanged region.     

Raman characterization of H:LiNbO3 waveguides

In this work we present polarized Raman measurements of z-cut multimode H:LiNbO₃ waveguides in the κ_i- and β_i-phase states. A spectrum with unexpected form and behaviour, originating from the layer at the very surface, was observed in samples with various degrees of Li–H substitution. Possible reasons for the presence of this strange spectrum are considered. Received: 16 May 2001 / Revised version: 7 August 2001 / Published online: 23 October 2001     

Characterization of LiNbO3 waveguides fabricated by proton exchange in water

Proton exchange of LiNbO₃ substrates has been achieved by immersing the samples in distilled water in sealed ampoules at temperatures between 190 °C and 300 °C. The samples have been studied by infrared spectra analysis, dark mode reflectivity and X-ray rocking curve diffraction. The results obtained show that exchange rates as high as with common acids (85%) are easily reached. The structure of the exchanged waveguides varies from the low index -phase to the high index -phases depending on the temperature and time length of the exchange process, as well as on the distilled water amount used. Optical waveguides made up of phases of high, sharp index jump (n_e0.12) as well as of low index jump and very low propagation losses (0.5 dB/cm) have been obtained and characterized. PACS 42.82.Et; 42.70.Mp     

c—切MgO：LiNbO3质子交换平板波导中切伦科夫倍频的理论分析

从耦合模方程出发,推导了切伦科夫倍频转换效率公式,并得出该效率主要是由交叠积分决定的结论;通过对交叠积分的计算找到了进一步提高该效率的有效方法;最后用Nd:YAG激光器进行了切伦科夫倍频实验,得到了接近1%的转换效率,增加包层折射率可以使该效率增加到1.3%,实验结果证实了理论分析.     

MgO:LiNbO_3与LiNbO_3质子交换光波导光学及结构特征的比较

利用退火的质子交换法在MgO :LiNbO3和LiNbO3两种材料上制作了光波导 ,得到了质子交换的扩散特性以及光波导折射率分布的退火规律 .通过x射线衍射和OH- 红外吸收谱方法研究了MgO :LiNbO3和LiNbO3质子交换光波导的结构特征及其与退火参数的关系 ,对MgO :LiNbO3和LiNbO3光波导光学和结构特征的结果进行了分析和比较     

Theoretical expression for change of extraordinary refractive index in annealed proton exchanged LiNbO3 optical waveguides

A general expression for the change in extraordinary refractive index of the annealed proton exchanged LiNbO₃ waveguide has been deduced. The expression deduced explains the experimental results of decrease in change of extraordinary refractive index with annealing. The effect of annealing time has also been incorporated following Cao's model (Cao, Ramaswamy, Srivastava, J. Lightwave Technol. 10 (1992) 1302–1313). The concentration profile of protons in the annealed waveguide has been deduced theoretically, which is consistent with the previous results. The spontaneous polarization has been considered as the central mechanism for change in extraordinary refractive index due to proton exchange with annealing.     

Simulation of refractive index profiles for titanium indiffused lithium niobate channel waveguides

A generally applicable method to simulate the two-dimensional profiles of Ti-concentration and refractive index of Ti:LiNbO₃, waveguides is presented. The influence of the fabricational parameters on the refractive index profiles has been studied in detail. The model parameters are extracted from the available experimental data. The computed values of surface refractive index change agree closely with the experimental results. The model is also extended for coupled waveguides.     

Modelling of optical amplification in Er/Yb co-doped LiNbO3 waveguides

The optical amplification of LiNbO₃:Er³⁺/Yb³⁺ channel waveguides has been modelled in the small signal regime using the overlapping integrals method and the rate-equation formalism. It has been found that Yb³⁺ -sensitisation improves the pump efficiency at 980 nm and a higher gain is achievable in the high power-limit compared to singly-doped LiNbO₃:Er³⁺ amplifiers.     

Temperature effects in proton exchanged LiNbO<Subscript>3</Subscript> waveguides

Temperature effects on single, homogeneous phases of proton exchanged LiNbO₃ waveguides have been studied. The refractive index of -phase guides on z-cut and x-cut congruent substrates monotonically increases with temperature, the thermo-optical coefficient being similar to that of the substrate. In ₂-phases on z-cut congruent substrates and in ₁-phases on z-cut and x-cut congruent and quasi-stoichiometric substrates, the thermo-optical coefficient is smaller than that of the substrate below 60 °C and higher above this temperature. A rather similar effect has been observed in ₁-phases on z-cut and x-cut congruent substrates in the linear expansion coefficient. The microscopic origin of the phase transition is not known for the moment. PACS Provide PACS codes please.     

Effects of a lossy thin plasma-film on metal-diffused LiNbO3 optical waveguides

I intend to investigate the effects of different kinds of partially reflecting metal film (plasma layer) on the wave characteristics of a stratified titanium-diffused LiNbO₃ optical waveguide. The mode number, the equivalent indices, the extinction coefficients, the field distributions and the powers carried in each layer are given as a function of the free-space wavelength, of the diffusion parameters, and of the opticc-axis orientation. Of course, the power of TM-like hybrid waves flows in opposite directions in the plasma and the other regions.For ac-axis varying in the transverse plane, the ith-order hybrid mode is rather complicated in the guide with an aluminum layer. There, in fact, the field mapping can be seen as an overlap of a TE _i with a TM _i+1, mode because of a sudden transformation of the TM₀ mode into a superficial plasma wave (SPW). On the contrary, with a silver layer, the hybrid field is a simple combination of a TE _i with a TM _i mode with no SPW growing.The guide losses assume the lowest values (1 dB/cm) for an Ag layer which is the prime candidate for making electro-optical or acoustic-optical devices. On the other hand, the nickel film causes the highest losses (66 dB/cm).     

Low-loss, damage-resistant optical waveguides in Zn-diffused LiNbO3 by a two-step procedure

In the present work the fabrication of high-quality LiNbO₃ waveguides, based on Zn diffusion from vapor phase using a two-step diffusion process, has been demonstrated. The optical waveguides fabricated using this method have low propagation losses (less than 0.5 dB/cm measured at 633 nm), as a consequence of the high surface quality obtained. High photorefractive damage resistance is reported, and it has been related to the Zn incorporation into the LiNbO₃ crystals. Additional advantages of this waveguide fabrication method due to the low temperature of the process (<900 °C) are to prevent Li out-diffusion and to preserve ferroelectric domain structures. Received: 2 March 2000 / Accepted: 21 June 2000 / Published online: 13 September 2000     

Dependences of the refractive indices on the proton concentration in H:LiNbO3 waveguides

Proton-exchanged optical waveguides in lithium niobate crystals exhibit a rich variety of structures and phases. It is established that seven H_xLi_1−x NbO₃ crystalline phases with a lithium niobate structure may form under various conditions of proton exchange and post-exchange annealing. A method is proposed to determine the proton concentration in the various phases identified. Relationships are established between the structural parameters, the proton concentration, and the ordinary and extraordinary refractive indices of various H_xLi_1−x NbO₃ crystalline phases. The results can explain various optical phenomena observed in proton-exchanged waveguides and permit prediction of the characteristics of light-guide structures. Zh. Tekh. Fiz. 69, 47–57 (March 1999)