An Analysis of Three-Phase Pore Occupancies and Relative Permeabilities in Porous Media with Variable Wettability

In three-phase flow, the macroscopic constitutive relations of capillary pressure and relative permeability as functions of saturation depend in a complex manner on the underlying pore occupancies. These three-phase pore occupancies depend in turn on the interfacial tensions, the pore sizes and the degree of wettability of the pores, as characterised by the cosines of the oil–water contact angles. In this work, a quasi-probabilistic approach is developed to determine three-phase pore occupancies in media where the degree of wettability varies from pore to pore. Given a set of fluid and rock properties, a simple but novel graphical representation is given of the sizes and oil–water contact angles underlying three-phase occupancies for every allowed combination of capillary pressures. The actual phase occupancies are then computed using the contact angle probability density function. Since a completely accessible porous medium is studied, saturations, capillary pressures, and relative permeabilities are uniquely related to the pore occupancies. In empirical models of three-phase relative permeability it is of central importance whether a phase relative permeability depends only on its own saturation and how this relates to the corresponding two-phase relative permeability (if at all). The new graphical representation of pore sizes and wettabilities clearly distinguishes all three-phase pore occupancies with respect to these saturation-dependencies. Different types of saturation-dependencies may occur, which are shown to appear in ternary saturation diagrams of iso-relative permeability curves as well, thus guiding empirical approaches. However, for many saturation combinations three-phase and two-phase relative permeabilities can not be linked. In view of the latter, the present model has been used to demonstrate an approach for three-phase flow modelling on the basis of the underlying pore-scale processes, in which three-phase relative permeabilities are computed only along the actual flow paths. This process-based approach is used to predict an efficient strategy for oil recovery by simultaneous water-alternating-gas (SWAG) injection.     

Effect of Network Topology on Relative Permeability

We consider the role of topology on drainage relative permeabilities derived from network models. We describe the topological properties of rock networks derived from a suite of tomographic images of Fontainbleau sandstone (Lindquist et al., 2000, J. Geophys. Res. 105B, 21508). All rock networks display a broad distribution of coordination number and the presence of long-range topological bonds. We show the importance of accurately reproducing sample topology when deriving relative permeability curves from the model networks. Comparisons between the relative permeability curves for the rock networks and those computed on a regular cubic lattice with identical geometric characteristics (pore and throat size distributions) show poor agreement. Relative permeabilities computed on regular lattices and on diluted lattices with a similar average coordination number to the rock networks also display poor agreement. We find that relative permeability curves computed on stochastic networks which honour the full coordination number distribution of the rock networks produce reasonable agreement with the rock networks. We show that random and regular lattices with the same coordination number distribution produce similar relative permeabilities and that the introduction of longer-range topological bonds has only a small effect. We show that relative permeabilities for networks exhibiting pore–throat size correlations and sizes up to the core-scale still exhibit a significant dependence on network topology. The results show the importance of incorporating realistic 3D topologies in network models for predicting multiphase flow properties.     

Three-Phase Capillary Pressure and Relative Permeability Relationships in Mixed-Wet Systems

A simple process-based model of three-phase displacement cycles for both spreading and non-spreading oils in a mixed-wet capillary bundle model is presented. All possible pore filling sequences are determined analytically and it is found that the number of pore occupancies that are permitted on physical grounds is actually quite restricted. For typical non-spreading gas/oil/water systems, only two important cases need to be considered to see all types of allowed qualitative behaviour for non-spreading oils. These two cases correspond to whether water or gas is the intermediate-wetting phase in oil-wet pores as determined by the corresponding contact angles, that is, cos ^o _gw > 0 or cos ^o _gw < 0, respectively. Analysis of the derived pore occupancies leads to the establishment of a number of relationships showing the phase dependencies of three-phase capillary pressures and relative permeabilities in mixed-wet systems. It is shown that different relationships hold in different regions of the ternary diagram and the morphology of these regions is discussed in terms of various rock/fluid properties. Up to three distinct phase-dependency regions may appear for a non-spreading oil and this reduces to two for a spreading oil. In each region, we find that only one phase may be specified as being the intermediate-wetting phase and it is only the relative permeability of this phase and the capillary pressure between the two remaining phases that depend upon more than one saturation. Given the simplicity of the model, a remarkable variety of behaviour is predicted. Moreover, the emergent three-phase saturation-dependency regions developed in this paper should prove useful in: (a) guiding improved empirical approaches of how two-phase data should be combined to obtain the corresponding three-phase capillary pressures and relative permeabilities; and (b) determining particular displacement sequences that require additional investigation using a more complete process-based 3D pore-scale network model.     

Gas Condensate Relative Permeability for Well Calculations

This paper addresses several issues related to the modeling and experimental design of relative permeabilities used for simulating gas condensate well deliverability. Based on the properties of compositional flow equations, we make use of the fact that relative permeability ratio k _rg/k _ro is a purely thermodynamic variable, replacing saturation, when flow is steady-state. The key relation defining steady-state flow in gas condensate wells is relative permeability k _rg as a function of k _rg/k _ro. Consequently, determination of saturation and k _r as a function of saturation is not important for this specific calculation. Once the k _rg=f(k _rg/k _ro) relationship is experimentally established and correlated with capillary number (N _c), accurate modeling of condensate blockage is possible. A generalized model is developed for relative permeability as the function of k _rg/k _ro and capillary number. This model enables us to link the immiscible or rock curves with miscible or 'straight-line curves by a transition function dependent on the capillary number. This model is also extended to the case of high-rate, inertial gas flow within the steady-state condensate blockage regionand locally at the wellbore. We have paid particular attention to the effect of hysteresis on the relation k _rg=f(k _rg/k _ro), based on our observation that many repeated cycles of partial/complete imbibition and drainage occur in the near-well region during the life of a gas condensate well. Finally, the composite effect of condensate blockage is handled using a Muskat pseudopressure model, where relative permeabilities are corrected for the positive effect of capillary number dependence and the negative effect of inertial high velocity flow. Special steady-state experimental procedures have been developed to measure k _rg as a function of k _rg/k _ro and N _c. Saturations, though they can be measured, are not necessary. An approach for fitting steady-state gas condensate relative permeability data has been developed and used for modeling relative permeability curves.     

A Parametric Model for Predicting Relative Permeability-Saturation-Capillary Pressure Relationships of Oil–Water Systems in Porous Media with Mixed Wettability

A parametric two-phase, oil–water relative permeability/capillary pressure model for petroleum engineering and environmental applications is developed for porous media in which the smaller pores are strongly water-wet and the larger pores tend to be intermediate- or oil-wet. A saturation index, which can vary from 0 to 1, is used to distinguish those pores that are strongly water-wet from those that have intermediate- or oil-wet characteristics. The capillary pressure submodel is capable of describing main-drainage and hysteretic saturation-path saturations for positive and negative oil–water capillary pressures. At high oil–water capillary pressures, an asymptote is approached as the water saturation approaches the residual water saturation. At low oil–water capillary pressures (i.e. negative), another asymptote is approached as the oil saturation approaches the residual oil saturation. Hysteresis in capillary pressure relations, including water entrapment, is modeled. Relative permeabilities are predicted using parameters that describe main-drainage capillary pressure relations and accounting for how water and oil are distributed throughout the pore spaces of a porous medium with mixed wettability. The capillary pressure submodel is tested against published experimental data, and an example of how to use the relative permeability/capillary pressure model for a hypothetical saturation-path scenario involving several imbibition and drainage paths is given. Features of the model are also explained. Results suggest that the proposed model is capable of predicting relative permeability/capillary pressure characteristics of porous media mixed wettability.     

Relative Permeabilities for Strictly Hyperbolic Models of Three-Phase Flow in Porous Media

Traditional mathematical models of multiphase flow in porous media use a straightforward extension of Darcys equation. The key element of these models is the appropriate formulation of the relative permeability functions. It is well known that for one-dimensional flow of three immiscible incompressible fluids, when capillarity is neglected, most relative permeability models used today give rise to regions in the saturation space with elliptic behavior (the so-called elliptic regions). We believe that this behavior is not physical, but rather the result of an incomplete mathematical model. In this paper we identify necessary conditions that must be satisfied by the relative permeability functions, so that the system of equations describing three-phase flow is strictly hyperbolic everywhere in the saturation triangle. These conditions seem to be in good agreement with pore-scale physics and experimental data.     

Effects of Relative Permeability History Dependence on Two-Phase Flow in Porous Media

Hysteresis phenomena in multi-phase flow in porous media has been recognized by many researchers and widely believed to have significant effects on the flow. In an attempt to account for these effects, a theoretical model for history-dependent relative permeabilities is considered. This model is incorporated into 1-D two-phase nondiffusive flow system and the corresponding flow is predicted. Flow history is observed to have a notable impact on the saturation profile and fluids breakthrough.     

Relative Permeability Estimation for Rich Gas-Condensate Reservoirs

This study addresses relative permeability prediction from well test data for low permeability, rich gas-condensate systems. Characteristic of these systems are high velocities and large pressure gradients within the near wellbore region. Within this region the relative permeabilties are rate sensitive and non-Darcy effects can be important. This study combines both the non-linear (in velocity) terms into a single effective relative permeability term. Effective relative permeabilities are estimated through non-linear regression with both synthetic and field data. Results show that a two-parameter simplified correlation is adequate for representing effective relative permeability. These parameters can be obtained by matching well test data. Mechanical skin was needed to match field data considered in this study. Non-Darcy effects can decrease the flowing bottom-hole pressures by about 480 kPa in high rate gas-condensate well tests. A well test design is proposed from which gas and condensate relative permeabilities can be estimated.     

Predictive Pore-Scale Modeling of Single and Multiphase Flow

We show how to predict flow properties for a variety of rocks using pore-scale modeling with geologically realistic networks. The pore space is represented by a topologically disordered lattice of pores connected by throats that have angular cross-sections. We successfully predict single-phase non-Newtonian rheology, and two and three-phase relative permeability for water-wet media. The pore size distribution of the network can be tuned to match capillary pressure data when a network representation of the system of interest is unavailable. The aim of this work is not simply to match experiments, but to use easily acquired data to estimate difficult to measure properties and to predict trends in data for different rock types or displacement sequences.     

Positive Effect of Flow Velocity on Gas–Condensate Relative Permeability: Network Modelling and Comparison with Experimental Results

Positive velocity dependency of relative permeability of gas–condensate systems, which has been observed in many different core experiments, is now well acknowledged. The above behaviour, which is due to two-phase flow coupling in condensing systems at low interfacial tension (IFT) conditions, was simulated using a 3D pore network model. The steady-dynamic bond network model developed for this purpose was also equipped with a novel anchoring technique, which was based on the equivalent hydraulic length concept adopted from fluid flow through pipes. The available rock data on the co-ordination number, capillary pressure, absolute permeability, porosity and one set of measured relative permeability curves were utilised to anchor the capillary, volumetric and flow characteristics of the constructed network model to those properties of the real core sample. Then the model was used to predict the effective permeability values at other IFT and velocity levels. There is a reasonable quantitative agreement between the predicted and measured relative permeability values affected by the coupling rate effect.     

Estimation of Dynamic Relative Permeability and Capillary Pressure from Countercurrent Imbibition Experiments

Direct laboratory measurements of in situ water-phase saturation history are used to estimate relative permeability and capillary pressure functions. The magnitude of so-called nonequilibrium effects during spontaneous imbibition is quantified and, if significant, these effects are incorporated within the estimation technique. The primary constraint employed is that curves must increase or decrease monotonically; otherwise, no predetermined functionality is assumed. The technique is demonstrated using water saturation profile histories obtained for diatomite (a low-permeability and high-porosity rock). Results indicate that nonequilibrium effects detected at laboratory scale in low-permeability rocks influence the estimation of unsteady-state relative permeability and capillary pressure.     

Relative Permeability Analysis of Tube Bundle Models

The analytical solution for calculating two-phase immiscible flow through a bundle of parallel capillary tubes of uniform diametral probability distribution is developed and employed to calculate the relative permeabilities of both phases. Also, expressions for calculating two-phase flow through bundles of serial tubes (tubes in which the diameter varies along the direction of flow) are obtained and utilized to study relative permeability characteristics using a lognormal tube diameter distribution. The effect of viscosity ratio on conventional relative permeability was investigated and it was found to have a significant effect for both the parallel and serial tube models. General agreement was observed between trends of relative permeability ratios found in this work and those from experimental results of Singhal et al. (1976) using porous media consisting of mixtures of Teflon powder and glass beads. It was concluded that neglecting the difference between the average pressure of the non-wetting phase and the average pressure of the wetting phase (the macro-scale capillary pressure) – a necessary assumption underlying the popular analysis methods of Johnson et al. (1959) and Jones and Roszelle (1978) – was responsible for the disparity in the relative permeability curves for various viscosity ratios. The methods therefore do not account for non-local viscous effects when applied to tube bundle models. It was contended that average pressure differences between two immiscible phases can arise from either capillary interfaces (micro-scale capillary pressures) or due to disparate pressure gradients that are maintained for a flow of two fluids of viscosity ratio that is different from unity.     

Numerical Investigations of the Steady State Relative Permeability of a Simplified Porous Medium

The purpose of this paper is to investigate, by flow simulations in a uniform pore-space geometry, how the co and countercurrent steady state relative permeabilities depend on the following parameters: phase saturation, wettability, driving force and viscosity ratio. The main results are as follows: (i) with few exceptions, relative permeabilities are convex functions of saturation; (ii) the cocurrent relative permeabilities increase while the countercurrent ones decrease with the driving force; (iii) with one exception, phase 2 relative permeabilities decrease and phase 1 relative permeabilities increase with the viscosity ratio M=₁/₂; (iv) the countercurrent relative permeabilities are always less than the cocurrent ones, the difference being partly due to the opposing effect of the viscous coupling, and partly to different levels of capillary forces; (v) the pore-level saturation distribution, and hence the size of the viscous coupling, can be very different between the cocurrent and the countercurrent cases so that it is in general incorrect to estimate the full mobility tensor from cocurrent and countercurrent steady state experiments, as suggested by Bentsen and Manai (1993).(Now at AS Norske Shell, Norway.) e-mail:     

液滴撞击具有浸润性分布的倾斜固壁铺展行为的格子Boltzmann研究

采用基于单组分多相伪势模型的格子Boltzmann方法,模拟了三维液滴撞击左右两侧浸润性不同的倾斜固壁的铺展过程,获得了液滴在壁面两侧的铺展因子、相对铺展宽度、相对高度和液滴运动速度随时间的变化情况,研究了壁面浸润性分布和壁面倾斜角度对液滴铺展过程的影响．结果表明,液滴在倾斜壁面的铺展过程受到重力和表面力的综合作用,重力影响液滴的铺展和沿壁面向下的滑动,壁面浸润性分布影响液滴向壁面亲水侧横向移动．     

Behavior of Nonaqueous Phase Liquids in Fractured Porous Media under Two‐Phase Flow Conditions

After dense nonaqueous phase liquids (DNAPLs) travel downward through the subsurface, they typically come to rest on fractured bedrock or tight clay layers, which become additional pathways for DNAPL migration. DNAPLs trapped in fractures are continuous sources of groundwater contamination. To decide whether they can be left in place to dissolve or volatilize, or must be removed with active treatment, the movement of DNAPLs in fractured media must be understood at a fundamental level. This work presents numerical simulations of the movements of DNAPLs in naturally fractured media under twophase flow conditions. The flow is modeled using a multiphase network flow model, used to develop predictive capabilities for DNAPL flow in fractures. Capillary pressure–saturation–relative permeability curves are developed for twophase flow in fractures. Comparisons are made between the behavior in crystalline, almost impermeable rocks (e.g. granite) and more permeable rocks like sandstone, to understand the effects of the rock matrix on the displacement of the DNAPLs in the fracture. For capillarydominated flow, displacements occur as a sequence of jumps, as the invading phase overcomes the capillary pressure at downgradient apertures. Preferential channels for the displacement of nonaqueous phase are formed due to high fracture aperture in some regions.     

Relative Permeability Analysis of Tube Bundle Models,Including Capillary Pressure

The analytical equations for calculating two-phase flow, including local capillary pressures, are developed for the bundle of parallel capillary tubes model. The flow equations that are derived were used to calculate dynamic immiscible displacements of oil by water under the constraint of a constant overall pressure drop across the tube bundle. Expressions for averaged fluid pressure gradients and total flow rates are developed, and relative permeabilities are calculated directly from the two-phase form of Darcy's law. The effects of pressure drop and viscosity ratio on the relative permeabilities are discussed. Capillary pressure as a function of water saturation was delineated for several cases and compared to a steady-state mercury-injection drainage type of capillary pressure profile. The bundle of serial tubes model (a model containing tubes whose diameters change randomly at periodic intervals along the direction of flow), including local Young-Laplace capillary pressures, was analyzed with respect to obtaining relative permeabilities and macroscopic capillary pressures. Relative permeabilities for the bundle of parallel tubes model were seen to be significantly affected by altering the overall pressure drop and the viscosity ratio; relative permeabilities for the bundle of serial tubes were seen to be relatively insensitive to viscosity ratio and pressure, and were consistently X-like in profile. This work also considers the standard Leverett (1941) type of capillary pressure versus saturation profile, where drainage of a wetting phase is completed in a step-wise steady fashion; it was delineated for both tube bundle models. Although the expected increase in capillary pressure at low wetting-phase saturation was produced, comparison of the primary-drainage capillary pressure curves with the pseudo-capillary pressure profiles, that are computed directly using the averaged pressures during the displacements, revealed inconsistencies between the two definitions of capillary pressure.     

多孔介质渗透率的一种新分形模型

多孔介质的渗流特性是油气藏工程、地下水资源利用、高放废物深地质处置等实际工程领域的热门研究问题．基于分形理论及多孔介质由一束面积大小不等的椭圆形毛细管组成的假设,本文建立了流体在分形多孔介质中渗流时的绝对渗透率及相对渗透率的分形渗透率模型．结果表明,绝对渗透率是最大和最小孔隙面积、分形维数、形状因子ε的函数,且当ε =1时,本文模型可以简化成Yu与Cheng模型;而非饱和多孔介质的相对渗透率与饱和度和多孔介质微结构参数有关．将本文提出的渗透率分形模型预测与实验测量数据及其他模型结果进行对比,显示它们整体吻合很好．     

Pore-scale Simulation of Water Alternate Gas Injection

We use a three-dimensional mixed-wet random network model representing Berea sandstone to compute displacement paths and relative permeabilities for water alternating gas (WAG) flooding. First we reproduce cycles of water and gas injection observed in previously published experimental studies. We predict the measured oil, water and gas relative permeabilities accurately. We discuss the hysteresis trends in the water and gas relative permeabilities and compare the behavior of water-wet and oil-wet media. We interpret the results in terms of pore-scale displacements. In water-wet media the water relative permeability is lower during water injection in the presence of gas due to an increase in oil/water capillary pressure that causes a decrease in wetting layer conductance. The gas relative permeability is higher for displacement cycles after first gas injection at high gas saturation due to cooperative pore filling, but lower at low saturation due to trapping. In oil-wet media, the water relative permeability remains low until water-filled elements span the system at which point the relative permeability increases rapidly. The gas relative permeability is lower in the presence of water than oil because it is no longer the most non-wetting phase.     

Electrical Resistivity Index in Multiphase Flow through Porous Media

The simultaneous flow of two phases through a three-dimensional porous medium is calculated by means of a Lattice-Boltzmann algorithm. The time-dependent phase configurations can be derived and also macroscopic quantities such as the relative permeabilities. When one phase only is supposed to be conductive, the Laplace equation which governs electrical conduction can be solved in each phase configuration; an instantaneous value of the macroscopic conductivity is obtained and it is averaged over many configurations. The influence of saturation on the resistivity index is studied for six different samples and two viscosity ratios. The saturation exponent is systematically determined. The numerical results are also compared to other possible models and also to experimental results; finally, they are discussed and criticized.     

Micromodel Observation of the Role of Oil Layers in Three-Phase Flow

We have studied the flow of a non-aqueous phase liquid (NAPL, or oil), water and air at the pore scale using a micromodel. The pore space pattern from a photomicrograph of a two-dimensional section through a Berea sandstone was etched onto a silicon wafer. The sizes of the pores in the micromodel are in the range 3–30,m and are the same as observed in the rock from which the image was taken. We conducted three-phase displacement experiments at low capillary numbers (in the order of 10^-7) to observe the presence of predicted displacement mechanisms at the pore scale. We observed stable oil layers between the wetting phase (water) and the non-wetting phase (gas) for the water–decane–air system, which has a negative equilibrium spreading coefficient, as well as four different types of double displacements where one fluid displaces another that displaces a third. Double imbibition and double drainage are readily observed, but the existence of an oil layer surrounding the gas phase makes the other double displacement combinations very unlikely.