高氧压合成产物La2CuO4+δ的相变研究

 本文采用超高氧压2.3 GPa合成方法，得到超导相含量大于30%的超导化合物La₂CuO_4+δ所采用的压力是目前所见报导中对La₂CuO₄化合物施加的最高氧压。湿化学方法测量给出过量氧含量δ=0.05±0.01，而TGA（氮气中）给出δ=0.143。高氧压合成产物经在空气中、不同温度下加热，然后淬火到室温，结果发现超导体在200~300 ℃的加热处理中存在着一个一级相变。经此相变后，超导体转变成反铁磁半导体。TGA及DSC证实了此相变的存在。该相变前后所联系的氧含量变化恰好为湿化学方法给出的结果，这部分与超导电性存在联系的过量氧，实际上引起了Cu²⁺向Cu^(2+2δ)+的转变。该结果强有力地排除了所谓“超氧化物”引起超导电性的可能性。     

取代亚胺中亚胺基15N NMR化学位移规律的研究

提出了计算苯甲醛亚胺、N-苯基亚胺、N-甲基亚胺、N-异丙基亚胺中亚胺基氮原子¹⁵N NMR化学位移的经验公式：δ_cal=δ_0n+Δα+Δβ+Δγ+c. 按亚胺基氮原子和碳原子上两类取代基的不同分别结合最小二乘法通过线性回归各得到5种取代基参数,计算结果分别以其化学位移数据为样本点作回归检验,置信度为99.5%,最大误差Δδ≤3.1,大约有95%的¹⁵N NMR化学位移计算值的计算误差小于3.0（相对误差小于0.3%）. 初步分析了芳香族亚胺苯环上对位取代基对亚胺基氮原子化学位移的影响.     

高温超导体低温、高压下的物理性质的研究

 在3~20 GPa压力范围内，测量了含氧量较低的YBa₂Cu₃O_7-δ（δ=0.46）单晶压力增强效应（dT_c/dp=4.9KGPa^-1）；YBa₂Cu₃O₇（T_c0=90 K）单晶在压力下临界电流密度随压力变化；外磁场H=30 kO_e时，T_c与磁场、压力关系；压力达16.5 GPa下，Bi₂Sr₂CaCu₂O_x单晶T_c(p)关系（dT_c/dp=-0.4 KGPa^-1）。发现Y系高温超导体的温度压力导数dT_c/dp与T_c0中间呈dT_c/dp=b-mT_c0线性关系（b、m为常数）。结合压力下Y系超导体结构相变和含氧量对T_c影响，分析这类超导体T_c有很强的正压力效应的原因。把实验结果同几种超导电性微观理论模型进行了分析和比较。     

MICROSCOPIC CALCULATION OF THE INERTIA IN HEAVY NUCLEI

A realistic calculation of the inertia for ²³⁶U fisson based on the linear response theory is presented, in which the single particle states are provided by Nilsson model. The dependence of the nuclear inertia M_δiδi on the collective variables δ₂, δ₄ is studied at the range of certain nuclear temperature (0—1 MeV). The pairing effect and the shell effect on the nuclear inertia are discussed. The calculated results show a very prominent structure at level crossing points and when acrossing the critical temperature.     

高温高压合成CeTbO3+δ的XPS研究

 经过高温高压合成的CeTbO_3+δ进行了XPS研究，发现在1.0 GPa下，Tb⁴⁺在~600 ℃开始转变成Tb³⁺，而Ce⁴⁺在~800 ℃开始向Ce³⁺转变。在1 000~1 200 ℃形成单相萤石结构化合物CeTbO_3+δ的Ce是以Ce³⁺、Ce⁴⁺混合价形式存在，Tb全部变成Tb³⁺。实验表明，用Ce_3d谱上~888 eV峰的峰位及其与882 eV峰的相对强度变化可以定性判断化合物中是否含有Ce³⁺。研究了高温高压合成的CeTbO_3+δ的稳定性随时间的变化问题。     

ON THE νi13/2PAIR IN EVEN Pt ISOTOPES

A systematic analysis on the νi_13/2 pair in the even Pt isotopes has been carefully done. Comparisons between the experimental data and Nilsson cranked model results with different parameters κ,μ show. 1)An improved κ,μ set, which can nicely fit the ¹⁸⁵Au data, seems also applicable in Pt isotopes too. 2)The νi_13/2 alignment only could not explain the big up-bend phenomenon in ¹⁸⁴Pt,πh_9/2 alignment must be taken into considevation as well. 3) Deviations between experimental data and theoretical calculations indicate that dimensional potential energy surface calculation of ε₂, ε₄ and γ, is needed.     

二维Rh-C60聚合相的制备和表征

 利用高压合成装置在6 GPa压力、700 ℃温度条件下合成了二维C₆₀聚合相,并用X射线衍射（XRD）和高分辨核磁共振（NMR）等方法对样品进行了表征。XRD分析结果表明,C₆₀分子在高温高压下发生了聚合反应,晶体结构由面心立方结构变为菱形结构,通过［2+2］加环反应在邻近分子间形成sp³杂化共价键。¹³C核磁共振魔角谱 （¹³C MAS NMR）在δ145和δ72处出现了两个共振峰,其中在δ145附近的峰展宽并有两个边带。δ145附近的峰的展宽与分裂主要是由于C₆₀分子上出现了不等价的sp²杂化碳和高温高压条件下产生的结构无序,边带的形成说明了其结构的各向异性;位置为δ72附近的峰证明了聚合物内C₆₀分子之间出现了sp³杂化键。     

BaF2 Scintillator Coupling with a Low-pressure Multistep Avalanche Chamber

We studied the properties of a UV light sensitive low-pressure multistep avalanche chamber containing pure TMAE vapour.The gain of two chambers with different constructure at various temperatures is measured.With pure TMAE vapour at 40°C the gain of one chamber was 4×10⁵,the time resolution was 4.1ns.Coupling the chamber with a 2×2×2.4cm³ BaF₂ scintillator we successfully observed the signal of ¹³⁷Cs γ-ray of 0.661MeV.     

Study on Irradiation Damage of Bi-Doped PbWO4 Crystal

The luminescence and point defects of pure lead tungstate crystals (PbWO₄) and Bismuth (Bi) doping crystal (PbWO₄:Bi)grown by modified Bridgman method are studied. It is found that irradiation results in the great change of the transmission and X-ray excited emission after γ-ray irradiation about 4 Mrad dose. The defects in PbWO₄ crystal have been studied by means of positron annihilation lifetime and X-ray photoelectron spectra. The results show that Bi dopant suppresses the concentrations of positron capture centers and low-valent oxygen ions.After γ-ray irradiation,in the pure crystal the concentration of lead vacancy (V_Pb) is decreased and that of low-valent oxygen increased; on the contrary,in Bi dopant crystal the concentrations of positron capture centers increased and that of low-valent oxygen ions suppressed. It is tentatively proposed that Bi³⁺ dopants would mainly occupy the sites of lead vacancies resulted from Pb volatilization. And irradiation changes the chemical valence of Bi element,which is Bi³⁺→Bi⁵⁺.The Bi⁵⁺ will replace the lattice W⁶⁺ ions and it will cause some (WO₄)^2－ replaced by (BiO₃+V_O)^－.     

因瓦合金纳米微粉的恒磁导率及其压力、频率特性和压力相变

 以Fe-30wt%Ni合金片为母合金，用蒸发冷凝法制备了三种粗细不同的纳米微粒。经透射电镜和X光衍射物相分析，微粒成分与母合金一致。5T、5H和3K粉的平均粒度分别为13.6、27和40 mm。在室温和43~28个不同的流体静压力（0.000 1~2.205 GPa）下测量了它们的磁化曲线、磁导率曲线和起始磁化曲线。结果表明：（1）在H＝(20－132)(1000/4π)A/m范围内Fe-30Ni合金三种纳米粉均具有恒磁导率。（2）三种纳米粉恒磁导率随静水压的变化规律如下：μ_r＝3.83+0.253p-0.022 1p²-0.007 22p³（5T粉）；μ_r＝3.93+1.20p-1.97p²+1.52p³-0.510p⁴+0.059 9p⁵（5H粉）；μ_r＝5.96-0.276p+0.107p²-0.045 9p³（3K粉）。前两者随压力增加而升高。后者随压力增加而下降。（3）γ-α马氏体相变明显存在于5T、5H粉中，而3K粉中未见到。（4）Fe-30Ni合金片的μ_i从200kHz至2 MHz已下降一个数量级，而其纳米粉μ_i的频率范围高于300 MHz，增大两个数量级以上。     

DISCOVERY OF MULTIPLE,COLLECTIVE BAND STRUCTURES IN NUCLEI WITH A=60—80

Recent studies of levels in even-even ^68,70,72Ge,^70,72,74Se,^74,76,78,80Kr and ⁶⁵Ga and ⁷⁴Br have led to the discovery of a wide variety of different collective band structures.These include bands built on near spherical ground states and excited more well de-formed shapes that may include triaxial shapes,rotation-aligned bands built on thesame orbital （g_（9/2））² for both protons and neutrons,RAL negative parity bands witheven and odd spins,and ΔI=1 γ-type vibrational bands in even-even nuclei.As recent as 1974,a survey of the energy level in the even-even Ge and Se iso-topes^[1] revealed little was known above a spin of 4⁺ （see for examples Figs.1 and 2 of Ref.1）.With the exception of the unusally low-lying excited 0⁺ states in ^70,72Ge,first discovered in ⁷²Ge in 1948 at Vanderbilt^[2],the theoretical treatment of thesenuclei was limited primarily to some variation of the vibrational model.However,very recently there has been a surge of information on nuclei in this region that hasrevealed fascinating new features and also provided new insight into the excited 0^+’states.Particularly striking are the multiple,independent and highly collective bandstructures which we have discovered in our in-beam γ-ray spectroscopy studies fol-lowing heavy-ion induced reaction.Evidence for and the theoretical understandingof the richness of the collective band structures that are found in our studies of^68,70,72Ge （Refs.3—6）,^70,72,74Se （Refs.7—13） and ^74,76,78,80Kr （Refs.14—18）,as illustratedby the at least seven different bands found in our studies of the levels of ⁶⁸Ge ⁷⁴Se,and ⁷⁶Kr （Figs.1—3）,are described in this paper.These multiple structures includethe following:a) coexistence of ground bands built on near-spherical shapes andexcited bands with larger deformation built on O^+′ band heads;b) bands with 8⁺ band heads interpreted as rotation-aligned,RAL,bands built on both neutron and/orproton （g_（9/2））² quasiparticle configurations coexisting with the ground-state band;c)RAL neutron and proton odd-parity bands formed from coupling of a g_{（9/2 ）}quasipar-ticle and a p_（1/2）,p_（3/2） or f_（5/2）,quasiparticle with the core;d) ΔI=1 even-parity bands,which are best characterized as gamma-vibrational bands;and e) additional bandswhose nature are presently not known.     

水绿矾的状态方程和高压熔化

 用阻抗匹配法和压电探针技术测量了初始密度为1.714 g/cm³（孔隙率α=ρ₀/ρ₀₀=1.898/1.714=1.107）的水绿矾（FeSO₄·7H₂O）的冲击压缩线,发现其在0～100 GPa范围内存在两个明显相区：含有部分熔融的低压相和完全熔化的高压相。在两个相区内,冲击波速度D和波后粒子速度u可分别描述为：D=0.59+2.06u（u<3.12 km/s）和D=3.18+1.223u（u≥3.12 km/s）。从冲击压缩数据出发,用欧拉有限应变理论得到了其等熵状态方程。其熔化方程可用p_m(GPa) =0.159(T_m(K)/1000)^6.3371+0.69来近似描述。     

双稀土氧化物LnEuO3的Mossbauer效应研究

 本文首次利用高温高压方法合成了双稀土氧化物LaEuO₃、PrEuO₃、NdEuO₃和SmEuO₃。此外，还合成了CeEuO_3.5。X射线衍射分析表明LaEuO₃属A型（六方）结构，PrEuO₃、NdEuO₃和SmEuO₃属B型（单斜）结构，CeEuO_3.5属F型（萤石）结构。室温下用¹⁵¹Eu的21.6 eV γ射线测量了它们的Mossbauer谱，观察到了¹⁵¹Eu同质异能移位和四极劈裂强烈地依赖于Eu离子配位体体积而呈线性关系。超精细相互作用的这种体积效应，主要原因是由于Eu离子5s壳层的重叠畸变所引起。     

Role of bismuth precursor in crystallization of SrBi2Ta2O9 thin films

Crystallization of SrBi₂Ta₂O₉ (SBT) thin films was studied as a function of viscosity of bismuth precursor and baking temperature, in order to fabricate capacitors with improved ferroelectric properties. SBT thin films were deposited on to Pt substrates using a chemical solution deposition (CSD) technique. Post-deposition anneal at 750 °C for 1 h in oxygen atmosphere revealed a significant influence of baking temperature and the viscosity of bismuth precursor on the microstructure and the ferroelectric properties of SBT thin films. A high baking temperature (350 °C) and a low viscosity of bismuth precursor (8 cp) yielded larger amounts of Bi₂O₃ secondary phase, smaller SBT grains (104 nm), and lower remanent polarization (P_r=2.0 7c/cm²). Additionally, these films exhibited a very high rate of ageing (>45% reduction in P_r after 7 days). A modified CSD process is suggested, which could suppress the formation of Bi₂O₃ secondary phase. Films fabricated using modified CSD technique exhibited a much larger grain size of 165 nm, higher P_r of 7.2 7c/cm², and significantly improved ageing characteristics (<1% reduction in P_r after 7 days). A qualitative model to describe the ageing in SBT-based capacitors is also suggested.     

Phenomenological Scaling of Rapidity Dependence for Anisotropic Flows in 25 MeV/nucleon Ca＋Ca by Quantum Molecular Dynamics Model

Anisotropic flows （v1, v2, v3 and v4） of light fragments up to the mass number 4 as a function of rapidity are studied for 25 MeV/nucleon ^40Ca ＋ ^40Ca at large impact parameters by a quantum molecular dynamics model. A phenomenological scaling behaviour of rapidity dependent flow parameters vn （n = 1, 2, 3 and 4） is found as a function of mass number plus a constant term, which may arise from the interplay of collective and random motions. In addition, v4/v2^2 keeps to be almost independent of rapidity and remains a rough constant of 1/2 for all light fragments.     

High Spin States and Shape Coexistence in 134Ce

high spin states in ¹³⁴Ce nucleus have been studied by using the heavy–ion induced reaction ¹²²Sn(¹⁶O,4n) carried out at china institute of atomic energy. the early level scheme has been extended with spin up to 22. however,our result is different from that in a recent publication,and the magnetic rotation bands reported there have not been confirmed. our observed level structures may be interpreted as shape coexistence. the 10+ state at the backbending with h_11/2 quasineutron configuration has an oblate deformation with an asymmetry parameter γ≈–60°(lund convention),and the 10+ isomer is a yrast trap of prolate deformation with γ≈–120°,whereas the other signature partner bands with h_11/2 and g_7/2 proton configuration probably have a prolate deformation with γ≈0°.     

Sol-gel法制备Er3+-Yb3+共掺杂Al2O3粉末光致发光特性

采用异丙醇铝[Al(OC₃H₇)₃]为前驱体,溶胶-凝胶(Sol-gel)法制备Er³⁺-Yb³⁺共掺杂Al₂O₃粉末.实验结果表明:900 ℃烧结的粉末为固溶Er³⁺、Yb³⁺的γ-(Al,Er,Yb)₂O₃相和少量θ-(Al,Er,Yb)₂O₃相的混合物.Er³⁺-Yb³⁺共掺杂Al₂O₃粉末具有中心波长为1.533 μm的光致发光(PL)特性.1 mol % Er³⁺和1 mol% Yb³⁺共掺杂的Al₂O₃粉末的PL强度较1 mol % Er³⁺掺杂提高2倍,半峰宽从53 nm增加到63 nm.随泵浦功率的提高,PL强度呈线性增加后渐呈饱和趋势.     

高温高压下CeTbO3合成过程中电阻的动态测试研究

 在0.5 GPa、4.0 GPa的压力下，从室温到800 ℃的温度范围内测量了氧化物CeTbO₃、单稀土氧化物Tb₄O₇、CeO₂和摩尔比维4∶1配比的混合物CeO₂+Tb₄O₇等的电阻随温度变化关系。对这四种物质均反映出电阻随温度增加而减小的半导体特征。在压力维0.5 GPa，温度高于600 ℃时发现了混合物CeO₂+Tb₄O₇、氧化物Tb₄O₇中电阻变化的起伏。X射线衍射谱表明，对应这一电阻变化，在结构上出现了变化。结果分析表明，这一变化与Tb⁴⁺→Tb³⁺的价态变化密切相联。     

四态叠加多模叠加态光场|Ψe(4),Ⅲ〉q的等阶N次方Y压缩

根据量子力学的线性叠加原理,构造了由多模偶相干态与多模虚偶相干态组成的第Ⅲ种四态叠加多模叠加态光场态|Ψ_e⁽⁴⁾,Ⅲ〉_q的等阶N次方Y压缩特性.结果发现:1) 当压缩阶数N=4m,(m=1,2,3,…)时,态|Ψ_e⁽⁴⁾,Ⅲ〉_q恒处于等阶数N-Y最小测不准态;2) 当压缩阶数N=4m′+2,(m′=0,1,2,…)时,在(θ₁-θ₂),q,R_j,r₁,r₂等取不同的组合定值下,态|Ψ_e⁽⁴⁾,Ⅲ〉_q可分别呈现出等阶N次方Y压缩效应与"半相干态"效应;3) 当压缩阶数N为奇数时,在(θ₁-θ₂),q,R_j,r₁,r₂等取不同的组合定值下,态|Ψ_e⁽⁴⁾,Ⅲ〉_q可呈现出等阶N次方Y压缩效应.     

Study of 1/2[660](πi13/2) Rotation Band in 179Au

High-spin states in ¹⁷⁹Au have been studied experimentally using the ¹⁴⁹Sm(³⁵Cl,5n) heavy-ion fusion-evaporation reaction at beam energies of 164—180MeV. Measurements of γ-ray excitation functions, X-γ coincidences and γ-γ-t coincidences were performed with 13 BGO(AC)HPGe and 3 LOAX detectors. Based on these measurements, a rotational band built on the 1/2[660](πi_13/2) Nilsson state has been established for the first time, and this band has been assigned to ¹⁷⁹Au according to the systematic of level structure in odd-A Au nuclei. Properties of the 1/2[660](πi_13/2) band in odd-A Au nuclei are discussed with an emphasis on the band-head energy while changing the neutron number.