Electrical conductivity and chemical diffusion coefficient measurements in single crystalline nickel oxide at high temperatures

Electrical conductivity measurements on nickel oxide have been performed at high temperatures (1273 K<T< 1673 K) and in partial pressures of oxygen ranging from Po₂ = 1.89 × 10^?4 atm to Po₂ = 1 atm. The $\text{po}{}_2{}^{\mathrm{<mtext>1</mtext><mtext>n</mtext>}}$ dependence of the conductivity decreases from about $\text{1}\text{4}$ for Po₂ = 1 atm to smaller values for lower partial pressures of oxygen. The activation enthalpy for conduction increases for decreasing oxygen partial pressures (from 22.5 kcal mol^?1 at Po₂ = 1 atm to 26.0 kcal mol^?1 for Po₂ = 1.89 × 10^?4 atm). This behaviour can be explained by the simultaneous presence of singly and doubly ionized nickel vacancies, with different energies of formation.Furthermore, chemical diffusion coefficient measurements have been performed in the same temperature range, using the conductivity technique, and leading to the result:

$\text{D}\text{?}\text{= 0.244 exp (?}\text{36,600}\text{RT}\text{) cm}{}^2\text{s}{}^{\mathrm{?1}}$

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Theory of hopping conduction in two-dimensional impurity band under strong magnetic field

It is shown that the low-temperature conductivity in two-dimensional impurity band of n-type inversion layer under strong magnetic field is $\text{σ}{}_{\mathrm{xx}}\text{(}\text{min}\text{)=σ}{}_0\text{exp}\text{[?(}\text{T}{}_0\text{T}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{]}$. Therefore the effective conductivity of inversion layer $\text{σ}{}_{\mathrm{<mtext>eff</mtext>}}\text{=}\text{σ}{}^2{}_{\mathrm{xy}}\text{σ}{}_{\mathrm{xx}}\text{(}\text{min}\text{)}$ at Shubnikov-de Haas conductivity minima may be very high at low temperature.     

Temperature variation of the magnetic cluster structures in an iron-nickel invar alloy

Small-angle scattering of long wavelength neutrons $\text{(λ = 6.42}\text{A}\text{?}\text{)}$ from an Fe₆₅Ni₃₅ single crystal has been measured with the applied magnetic field (6.2 kG) parallel and perpendicular to the scattering vector $\text{K}$ of the elastic scattering over the temperature range from 25 to 422°C (T_c = 227°C). The scattering cross sections due to the longitudinal spin fluctuation have been analyzed by means of Guinier's approximation $\text{(dσ/dω)}{}_0\text{exp}\text{(?κ}{}^2\text{R}{}_{\mathrm{<mtext>g</mtext>}}{}^2\text{3}\text{)}$, where the forward cross section (dσ/dω)₀ is proportional to n, which is the number of atoms in a paramagnetic cluster, and R_g is the radius of gyration of the cluster. The empirical relation between n and R_g is = 0.298 × R_g^2.34 to be compared with that calculated for a simple spherical cluster model n = 1.274 R_g³.     

A thermodynamic study of nonstoichiometric cerium dioxide

Thermogravimetric measurements were performed on nonstoichiometric CeO_2?x in the temperature range 750–1500°C and from oxygen pressures of 10^?2 to 10^?26 atm. From this data the deviation from stoichiometry x = x(T, P_o2) was determined. The thermodynamic quantities Δ$\text{H}$_o2 and Δ$\text{S}$_o2 were calculated in the region 0.001? x ? 0.3 and found to be independent of temperature.In the composition region 0.001< x < 0.006, the variation of Δ$\text{S}$_o2 with x is consistent with a defect model involving randomly distributed doubly ionized oxygen vacancies. The experimental dependence of x and σ (electrical conductivity) is shown to be consistent with this model as Δ$\text{H}$_o2 (≈ -10 eV) exhibits a slight dependence on x. It is postulated that the variation in Δ$\text{H}$_o2 may result from lattice parameter increases with x, while the defects remain essentially randomly distributed.In the composition region 0.006 < x < 0.1, x ∝ with 1 < n < 5, and in the region 0.1 < x < 0.3, x ∝ with n increasing rapidly with x to n? 30. This behavior is believed to result from increasing defect interaction with increasing departures from stoichiometry. It is interesting to note that the ordered phase observed by Bevan and Kordis between CeO_1·72 and CeO_1·70 was not observed in this study at temperatures between 1300° and 1500°C.     

Scaling function for two-point correlations with long-range interactions to order 1/η

The two-point correlation function ? (q, ξ) is calculated in the critical region of momentum space q in terms of a suitable correlation lenght ξ, by means of perturbation expansion to order 1/n, for an n-vector system with long-range interactions decaying as $\text{|}\text{R}\text{/a|}{}^{\mathrm{?(d\; +\; \sigma )}}$, for $\text{|}\text{R}\text{/a|}\text{a}\text{?}\text{1}$, where a is the spacing on a d-dimensional lattice, σ < d < 2σ and 0 < σ ? 2 ? η_SR. The calculations are done in zero field for T ? T_c. Explicit expansions for long-range propagators are developed for $\text{σ « 1}$ and for the neighborhood of σ ? 2 ? η_SR, in terms of which a universal, cut-off independent scaling function is obtained over the whole range of $\text{x = |}\text{q}\text{| ξ}$, and it is shown that the amplitude of the correlation-length dependence of the susceptibility becomes a universal parameter. Both the exponents and the coefficients of the expansion for fixed q as $\text{(T ? T}{}_{\mathrm{<mtext>c</mtext>}}\text{)}\text{T}{}_{\mathrm{<mtext>c</mtext>}}\text{→0}$ are calculated explicitly. The former are shown to require the validity of the operator-product expansion and explicit logarithmic correction terms are obtained for $\text{d = d}{}^1\text{= 3σ/2}$. For these and other dimensionalities, the coefficients are shown to be finite functions of d and σ. The correction to the Ornstein-Zernike form is given explicitly, with non-integer powers of x that have finite coefficients.     

A Mössbauer study of amorphous Fe40Ni40B20

Amorphous Fe₄₀Ni₄₀B₂₀ (VITROVAC 0040) alloy has been investigated using ⁵⁷Fe Mössbauer Spectroscopy. The Curie temperature T_c is found to be well defined and is 695 ± 1 K. The quadrupole splitting just above T_c is 0.64 mm sec^?1. The crystallization temperature is 698 ± 2 K, close to but definitely above T_c. The average hyperfine field H_eff(T) of the glassy state shows a temperature dependence of $\text{H}{}_{\mathrm{<mtext>eff</mtext>}}\text{(0)[1 ? B}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{(T/T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{? C}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{(T/T}{}_{\mathrm{c}}\text{)}{}^{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{? …]}$ indicative of the existence of spin wave excitations. The values of $\text{B}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{C}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ are found to be 0.40 and 0.06, respectively, for T/T_c ? 0.72. At temperatures close to T_c, H_eff(T) varies as (1 ? T/T_c)^β where β is one of the critical exponents and its value is found to be 0.29 ± 0.02.     

Hopping conductivity in amorphous carbon films

The electrical resistivity of amorphous carbon films getter-sputtered at 95°K is well fitted between 300 and 20°K by the relation $\text{? = ?}{}_0\text{exp}\text{[(T}{}_0\text{/T)}{}^{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{]}$ with T₀ ? 7 × 10⁷K. This behavior suggests a hopping conductivity very similar to that found in other amorphous semiconductors.     

Time-dependent correlation functions of the transverse Ising chain at the critical magnetic field

We study the correlation function 〈σ₀^x(t)σ_n^x(0)〉 of the transverse Ising model in a critical field whose hamiltonian is $\text{1}\text{2}\text{Σ}{}_{\mathrm{l}}\text{{σ}{}_{\mathrm{l}}{}^{\mathrm{x}}\text{σ}{}_{\mathrm{l+1}}{}^{\mathrm{x}}\text{?σ}{}_{\mathrm{l}}{}^{\mathrm{z}}\text{}}$. At an arbitrary temperature T we relate the autocorrelation to a Fredholm determinant. Moreover at T = 0 the correlations are given by a Painlevé V function for all n. The long-time asymptotic behavior of this function is found and the connection problem is studied. This result contains oscillatory terms which are related to the density of states at the Brillouin zone boundary.     

Room temperature electrical conductivity of a highly two dimensional synthetic metal: AsF5-graphite

We report here studies at room temperature of the electrical conductivity of AsF₅-graphite, a lamellar intercalation compound. Compounds with composition C_8nAsF₅ have been synthesized where n is the stage. Preliminary measurements of basal plane electrical conductivities indicating values comparable with OFHC copper have been confirmed. Associated anisotropy ratios $\text{α ≡}\text{σ}{}_{\mathrm{<mtext>a</mtext>}}\text{σ}{}_{\mathrm{<mtext>c</mtext>}}\text{> 10}{}^6$ are observed for n ≤ 3. Data for both the a-axis and c-axis conductivities as a function of stage for low stage compounds is reported.     

Semi-inclusive scaling for largepT events

We consider semi-inclusive reactions of the type p + p → (particle with large p_T) + n charged particles + neutrals, and propose the following scaling law

$\text{E}\text{d}{}^3\text{σ}{}_{\mathrm{n}}\text{d}{}^3\text{p}\text{=}\text{1}\text{(}\text{s}\text{)}{}^{\mathrm{k+1}}\text{H}{}^{\mathrm{2p}}\text{T}\text{s}\text{,}\text{n}\text{s}$

for the distribution function of the large-p_T particle produced in association with n charged particles. This scaling rule is shown to be consistent with present information on single-particle spectra and average associated multiplicities at large p_T. Also, we show that if the associated multiplicity were to continue to increase linearly with p_T, then moments of the multiplicity distribution would increase like powers of s.     

Absorption spectra of Ni2+ in (NH4)2Mg(SO4)2·6H2O and Co2+ in Na2Zn(SO4)2·4H2O

Optical absorption spectra of Ni²⁺ in (NH₄)₂Mg(SO₄)₂·6H₂O and Co²⁺ in Na₂Zn(SO₄)₂·4H₂O single crystals have been studied at room and liquid nitrogen temperatures. From the nature and position of the observed bands, a successful interpretation could be made assuming octahedral symmetry for both the ions in the crystals. The splitting observed for ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band in Ni²⁺ and ${}^4\text{T}{}_{\mathrm{2g}}\text{(F)}$ band in Co²⁺ at liquid nitrogen temperature have been explained as due to spin-orbit interaction. The extra band observed at 16,325 cm^-1 in the case of Ni²⁺ at low temperature has been interpreted to be the superposition of vibrational mode of SO^2-₄ radical on ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band. The observed band positions in both the crystals have been fitted with four parameters B, C, Dq and ζ.     

s- and p-wave neutron spectroscopy: Part VII. Widths of Neutron Resonances

Neutron reduced widths Γ_n⁰ and Γ_n¹ are reported for about 200 resonances observed in neutron total cross sections of Ca^{40, 44}, Ti⁴⁸, Cr^{50, 52, 54}, Fe^{54, 56}, Ni^{58, 60}, Sr⁸⁸, Y⁸⁹, Sn¹²⁴, Te¹³⁰, Ba^{136, 138}, and Pb^{206, 207, 208}, in the energy region 1 to 200 ^kev. Average parameters $\text{Γ}{}_{\mathrm{n}}{}^0$, $\text{Γ}{}_{\mathrm{n}}{}^0\text{D}$, and $\text{Γ}{}_{\mathrm{n}}{}^{\mathrm{(1)}}\text{D}$ have been derived and the Wigner distribution for local spacings and the Porter-Thomas distribution for reduced widths are verified for the resonances in the even-even nuclei Ca⁴⁰, Fe⁵⁶, Ni⁵⁸, and Ni⁶⁰. A simple method of area analysis which is less tedious and time consuming than the method reported before in Part III is also described.     

Hopping conduction in the Landau level tails in GaAs-AlxGa1-xAs heterostructures at low temperatures

We have investigated the temperature dependence of the transverse conductivity σ_xx in the two-dimensional Shubnikov—de Haas oscillation minima in GaAs-Al_xGa_1-xAs heterostructures at temperatures between 10mK and 1 K. We found that for σ_xx ? σ_xx (max), where σ_xx (max) is the conductivity in the corresponding oscillation maxima, the results agree qualitatively with a theory recently published by Ono, predicting $\text{σ}{}_{\mathrm{xx}}\text{∝ (1/T) exp - (T}{}_0\text{/T)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, but are not consistent with the estimated T₀-values.     

ESR of Ni doped amorphous chalcogenide semiconductors

ESR signals with g = 2.08 and 2.13 due to Ni were observed for evaporated (Ge_0.32Se_0.32Te_0.32As_0.4) 100_-xNi_x and $\text{(Ge}{}_{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}\text{Se}{}_{\mathrm{<mtext>2</mtext><mtext>3</mtext>}}\text{100}{}_{\mathrm{-x}}\text{Ni}{}_{\mathrm{x}}$ films respectively. The large increase of the electrical conductivity by the addition of Ni is discussed in connection with the ESR signal. Bulk glasses prepared by melt-quenching are also investigated for comparison.     

Scaling violation,the Callan Gross relation,and color excitation in electroproduction

The Callan-Gross relation is shown to be consistent with MIT-SLAC data for $\text{σ}{}_{\mathrm{<mtext>L</mtext>}}\text{(Q}{}^2\text{)}\text{σ}{}_{\mathrm{<mtext>T</mtext>}}\text{(Q}{}^2\text{)}$ for x ? 0.33 in deep inelastic eN scattering, despite the fact that these data are taken in the large Q² region where F₁ and F₂ individually exhibit scaling violation. Comparison is made with asymptotic freedom predictions, and color excitation is proposed to explain large values of $\text{σ}{}_{\mathrm{<mtext>L</mtext>}}\text{σ}{}_{\mathrm{<mtext>T</mtext>}}$ at small x.     

Intensities and pressure-broadened widths of CO2 R-branch lines at 15 μm from tunable laser measurements

Intensities and half-widths of individual lines, over the temperature range 200–325°K in the 15 μm bands of ¹²C¹⁶O₂, have been determined with a tunable diode laser spectrometer. Measurements were made on pure CO₂ and on dilute CO₂-in-N₂ mixtures on the R-branches of the 01¹0-00⁰0 and 02²0-01¹0 transitions. Intensities are approximately equal to those listed in the AFGL compilation. The pressure-broadened half-widths follow the general relationship $\text{b}{}_{\mathrm{L}}{}^0\text{(T) = b}{}_{\mathrm{L}}{}^0\text{(T}{}_0\text{) [}\text{T}{}_0\text{T}\text{]}{}^{\mathrm{n}}$ where n varies considerably from line to line but is always greater than $\text{1}\text{2}$.     

Measurement of the νμ and νμ nucleon charged-current total cross sections,and the ratio of νμ neutron to νμ proton charged-current total cross sections

The total ν_μ and $\text{ν}{}_{\mathrm{\mu }}$ nucleon charged-current cross sections have been measured in BEBC filled with deuterium and exposed to the wide-band neutrino and antineutrino beams at the CERN-SPS. Assuming a linear energy dependence for the cross sections, σ = aE(?_ν, we obtained the coefficients , where the quoted error is mainly systematic. The ratio of the cross sections is $\text{σ}{}_{\mathrm{<mtext>\nu </mtext><mtext>N</mtext>}}\text{/σ}{}_{\mathrm{<mtext>\nu </mtext><mtext>N</mtext>}}\text{= 0.53 ± 0.03}$.We also determined the ratio of the charged-current cross section for neutrino interactions on neutrons and protons R = σ_νn/σ_νp = 2.10 ± 0.08 (statistical) ±0.22 (sysetmatic). The dependence of R on the variables x, y and E_ν is discussed.     

Effects of composition on the upper critical field of V-Ga

Measurements of the temperature dependence of the upper critical field, H_c2(T), for a series of V_100?xGa_x materials are presented for 20.5 ≤ × ≤ 29.6. Fits of the data to conventional theory for a paramagnetically limited, dirty, type II superconductor show: 1) a maximum in T_c and H_c2(0) for x ? 25; 2) a constant ( for x ≤ 25; 3) a slowly increasing value of λ_so with increasing x up to x ～ 25; and 4) good agreement with stoichiometric ordered and thermally disordered V₃Ga. Above $\text{x ? 25}$ broader transitions are observed. For x = 25, T_c = 15.3 K, (, λ_so = 0.3 and H_c2(0) = 23.4 tesla. The effects of inclusion of strong-coupling in the theory are discussed briefly.     

Anisotropic conductivity in a channel-structured superionic conductor: Li2Ti3O7

From measurements on single crystals of Li₂Ti₃O₇, the conductivity is determined to be predominately ionic with an anisotropy of $\text{σ}{}_{\mathrm{b}}\text{σ}{}_{\mathrm{a}}\text{≈4}$ and $\text{σ}{}_{\mathrm{c}}\text{σ}{}_{\mathrm{b}}\text{≈7}$. This anisotropy is significant but is not sufficient to classify this channel-structured ramsdellite material as a one-dimensional conductor. A conduction path through the ramsdellite crystal structure consistent with the determined anisotropy is presented.