Oscillator strengths from line absorption in a high-temperature furnace—I. The (0,0) and (1,0) bands of the A2Σ+ - X2Πi transition in OH and OD

Quantitative high-resolution spectroscopy was applied to the (0,0) and (1,0) U.V. absorption bands of OH and OD. Known concentrations of OH and OD were prepared in a high-temperature furnace containing a 2:1 mixture of water vapor and oxygen. Band oscillator strengths at 1425 K for the OH (0,0), OH(1,0), OD (0,0) and OD (1,0) bands were 9.6 × 10^-4, 2.4 × 10^-4, 9.5 × 10^-4 and 2.6 × 10^-4 with a statistical and systematic uncertainty of about 20 per cent. The use of the OH or OD rotational intensity distribution with vibration-rotation correction factors to determine gas temperature was verified. The collision width of OH or OD lines in the furnace at a total pressure of 580 torr is about 0.14 cm^-1 at low J″ and appears to decrease at higher J″.     

Ne(I) spectral lines from a Ne-O2 d.c. glow discharge

Measurements have been made of intensities of the spectral lines emitted from an Ne-O₂ d.c. discharge with small discharge current (1–4 mA) under the following conditions: gas pressures of 2 and 3 torr and oxygen partial pressures (P₀₂) up to 0.1 torr. All of the Ne(I) line intensities observed decrease when O₂ is added. The Ne(I) λ5852 line (1s₂-2p₁) has been studied in detail as a representative example. The population density of the 2p₁ level of neon has been obtained from the intensity measurements as a function of P₀₂. The energy-distribution function of electrons has been determined using Druyvesteyn's method in order to calculate the population density for a corona model. The high-energy tail of the measured distribution function is markedly reduced when O₂ is added. It is shown that inelastic collisions of electrons with O₂ produce large energy losses for the electrons. These cause a decrease in population density of the 2p₁ level when O₂ is added. The population density of the 2p₁ level at a gas pressure of 2 torr is 1.2×10⁴ cm^-3 in pure neon and 5.2×10² cm^-3 in an Ne-O₂ mixture (P₀₂ = 0.01 torr). The electron densities and average electron energies are 3.5×10⁸ cm^-3 and 8.7 eV and 1.7×10⁸ cm^-3 and 5.3 eV, respectively, for the specified two cases.     

High resolution emission spectra of laser-excited molecular iodine as the excitation frequency is tuned through and away from resonance

We have studied the ΔJ = 2 rotationally shifted emission lines in the region of the strong absorption of molecular iodine which occurs within the 5145 Å argon ion laser line. We used an etalon tuned, single frequency argon ion laser with a linewidth of 20 MHz to excite the iodine emission and recorded the spectra of the rotational lines with Fabry-Perot spectrometers having resolutions up to 70 MHz (0.0023 cm^-1). To overcome Doppler linewidth limitations we took spectra of the emission at small angles to the exciting beam and found the lines to have widths less than our instrumental resolution and frequencies which accurately tuned with the incident laser frequency. We recorded the emission lines for laser frequencies in the absorption line center and out into the absorption wing. Our spectra show that the intensity of the emission lines follows the absorption line profile while the frequency of the emission lines is determined by the laser frequency; the intensity is maximum at the absorption line center, falling by 10⁴ as the laser frequency is moved off the line center, while the line position maintains a constant frequency shift from the laser frequency.     

EPR and Optical Absorption Study of Cr3+-Doped Dipotassium Tetrachloropalladate

X-band electron paramagnetic resonance (EPR) study of Cr³⁺-doped dipotassium tetrachloropalladate single crystal is done at liquid nitrogen temperature. EPR spectrum shows two sites. The spin-Hamiltonian parameters have been evaluated by employing hyperfine resonance lines observed in EPR spectra for different orientations of crystal in externally applied magnetic field. The values of spin-Hamiltonian and zero-field splitting (ZFS) parameters of Cr³⁺ ion-doped DTP for site I are: g _x  = 2.096 ± 0.002, g _y  = 2.167 ± 0.002, g _z  = 2.220 ± 0.002, D = (89 ± 2) × 10^?4 cm^?1, E = (16 ± 2) × 10^?4 cm^?1. EPR study indicates that Cr³⁺ ion enters the host lattice substitutionally replacing K⁺ ion and local site symmetry reduces to orthorhombic. Optical absorption spectra are recorded at room temperature. From the optical absorption study, the Racah parameters (B = 521 cm^?1, C = 2,861 cm^?1), cubic crystal field splitting parameter (Dq = 1,851 cm^?1) and nephelauxetic parameters (h = 2.06, k = 0.21) are determined. These parameters together with EPR data are used to discuss the nature of bonding in the crystal.     

Ag离子注入非晶SiO2的光学吸收、拉曼谱和透射电镜研究

能量为200keV的Ag离子，以1×10¹⁶，5×10¹⁶，1×10¹⁷ cm^-2的剂量分别注入到非晶SiO₂玻璃，光学吸收谱显示：注入剂量为1×10¹⁶ cm^-2的样品的光吸收谱为洛伦兹曲线，与Mie理论模拟的曲线形状一致；注入剂量较大的5×10¹⁶，1×10¹⁷ cm^-2的谱线共振吸收增强，峰位红移并出现伴峰. 透射电镜观察分析表明，注入剂量不同的样品中形成的纳米颗粒的大小、形状、分布都不同，注入剂量较大的还会产生明显的表面溅射效应，这些因素都会影响共振吸收的峰形、峰位和峰强. 当注入剂量达到1×10¹⁷ cm^-2时，Ag纳米颗粒内部可能还形成了杂质团簇. 关键词： 离子注入 纳米颗粒 共振吸收 红移     

Stark broadening of lines from multiply-charged carbon ions in a high-density arc plasma

Profiles of C(III) and C(IV) lines emitted in the VUV and visible regions from a pulsed arc (N_e=1.5×10¹⁸ cm^-3, T_e=5.3×10⁴K) have been measured with time resolution. The experimental results are in satisfactory agreement with the predictions of electron impact theory for (3-3) and (3-4) transitions for which the energy separation between the upper level and the nearest perturbing level is smaller than the electron thermal energy. For lines from (2-2) transitions for which the plasma is optically thick, damping constants determined experimentally agree with theoretical values within a factor of two.     

Raman-gain,linewidth, and effectiveg-value with spin-flip-Raman scattering in inSb

In this paper we report on measurements of spin-flip-Raman gain inn-InSb as a function of the magnetic field. The measurements were carried out at temperatures of 1.8 K and 4.2 K and at a carrier concentration of 1.35×10¹⁵ cm^?3. The Raman cross sections obtained from these results, e.g. 1.25×10^?20 cm²/sr at a magnetic field of 10 kG and a pump frequency of 1884.35 cm^?1, agree very well with those theoretically predicted by Wherrett and Wolland. Furthermore, these measurements yield line shapes and linewidths of the spontaneous scattering (100–1500 MHz) and allow the determination of the effectiveg-value with an accuracy known from ESR-investigations. These results are discussed in terms of already published theoretical investigations.     

Ground state and singlet excited state of laser dye DCM: Dipole moments and solvent induced spectral shifts

The solvent-induced shifts of the absorption and emission spectra of 4-dicyanomethylene-2-methyl-6-p-dimethyl-amino-styryl- 4H-pyran (DCM) have been studied in a variety of solvents. The absorption spectrum of its first singlet excited state has been determined in methanolic solution (λ_max=455nm , ϵ_max=6.2×10⁴ 1 mol^-1 cm^-1).     

Application of 940 nm high-power DFB lasers for line-broadening measurements at normal pressure using a robust and compact setup

High-power distributed-feedback (DFB) lasers for the wavelength range near 940 nm (i.e. about 10,600 cm⁻¹) were used for line-broadening measurements of individual rotational-vibrational absorption lines of water vapour at atmospheric pressure using a minimalist set-up. The laser has a maximum output power larger than 500 mW. Over the whole power range from threshold to maximum power, it operates in single mode operation with a tuning range of 4.7 nm, i.e. 50 cm⁻¹, at 20°C. With an emission line-width ≤2 MHz (0.66×10⁻⁴ cm⁻¹), the device is well suited for high-resolution spectroscopy.     

Crystalline structure and optical spectroscopy of Er3+-doped KGd(WO4)2 single crystals

4 )₂ single crystals doped with Er³⁺ have been grown by the flux top-seeded-solution growth method. The crystallographic structure of the lattice has been refined, being the lattice constants a=10.652(4), b=10.374(6), c=7.582(2) Å, β=130.80(2)°. The refractive index dispersion of the host has been measured in the 350–1500 nm range. The optical absorption and photoluminescence properties of Er³⁺ have been characterised in the 5–300 K temperature range. At 5 K, the absorption and emission bands show the (2J+1)/2 multiplet splittings expected for the C₂ symmetry site of Er in the Gd site. The energy positions and halfwidths of the 72 sublevels observed have been tabulated as well as the cross sections of the different multiplets. Six emission band sets have been observed under excitation of the ⁴F_7/2 multiplet. The Judd–Ofelt (JO) parameters of Er³⁺ in KGW have been calculated: Ω₂=8.90×10^-20 cm², Ω₄=0.96×10^-20 cm², Ω₆=0.82×10^-20 cm². Lifetimes of the ⁴S_3/2, ⁴F_9/2, and ⁴I_11/2 multiplets have been measured in the 5–300 K range of temperature and compared with those calculated from the JO theory. A reduction of the ⁴S_3/2 and ⁴I_11/2 measured lifetimes with increasing erbium concentration has been observed, moreover the presence of multiphonon non-radiative processes is inferred from the temperature dependence of the lifetimes. Received: 15 December 1997/Revised version: 10 July 1998     

Infrared absorptivity of the 9.6 μm ozone band as a function of spectral resolution and abundance

The i.r. absorptivity of the R-branch maximum (9.48 μm) of gaseous ozone was determined at 25°C as a function of spectral resolution and absorbance a/a total pressure of 735 torr of dry air. Ozone samples produced by a high voltage discharge in oxygen, and measured accurately by either a pressure or volume change, were spectroscopically measured in a 57741. environmental chamber at paths up to 69.17 m. A linear relation between spectral slit (Δv) and the ratio of the absorbances (R_v/p) of the observed absorption minimum between the R and Q branches to the absorption maximum of the R-branch was found for cm^-1 < Δv < 10cm^-1 and for absorption up to 48%. The i.r. absorptivity varied approx. 20% (from 3.9 to 4.8 cm^-1 STP) over the range of values for R_v/p studied. Absorptivity was weakly dependent on ozone abundance (w) for w?0.03 cm STP.     

Electrical conduction mechanism and carrier trapping in β-metal free phthalocyanine single crystals

The dark electrical conductivity of β-metal free phthalocyanine single crystals has been investigated over the temperature range 273–600°K, at a reduced pressure of 10^?7 torr. The results obtained are in accordance with the model proposed by Barbe and Westgate[5] for this material, in which the energy gap between the top of the valence band and the bottom of the conduction band is determined to be 2·00 eV. At temperatures below about 410°K, the conduction process is consistent with the presence of an electron trapping level located 0·32 eV below the conduction band edge, with a density of 7×10¹⁶ cm^?3, and a donor level of density 2×10⁷ cm^?3 at the same energy. Above about 410°K, there is evidence to suggest that the conduction process is intrinsic.     

Infrared absorption in In-doped degenerate Hg1−xCdxTe

The infrared absorption spectra, including absorption edge spectra and below-gap absorption spectra, were investigated both experimentally and theoretically for an In-doped degenerate HgCdTe sample with an electron concentration N_e = 7.0 × 10¹⁷ cm^-3 for wavelengths 7 μm<L<17 μm at the temperatures 77 K <T< 300 K. The possibility of applying free-carrier absorption theory developed for InSb to HgCdTe is discussed. It is concluded that the virtual crystal approximation works fairly well for HgCdTe and that the two-mode Callen effective charge should be used in the calculation of free-carrier absorption coefficients to account for the two-mode character of the optical phonons of HgCdTe. Good agreement between theory and experiment in the below-gap absorption spectra was obtained. The concentration of ionized impurities was found to be N_imp=3.4 × 10¹⁸ cm^-3. A good account of the behaviour of absorption edge in the light of Burstein-Moss effect has also been given.     

Influence of collisions and pulse intensity on multiple photon absorption in SF6

Using a pyroelectric detector, the multiple photon absorption (MPA) of the SF₆ molecule in a wide range of pressures (10^-3 -1 torr) has been studied. The significant role of collisions in MPA has been shown. The fraction of molecules excited under essentially collisionless conditions has been defined. It is shown that under collisionless excitation of SF₆ (p < 10^-2 torr) at energy fluences E < 10^-1 J/cm² the intensity of the laser pulse plays the essential role, while in presence of collisions MPA is determined mainly by the energy fluence in the pulse.     

ESR of V3+ in zinc oxide single crystals

Electron spin resonance has been investigated in zinc oxide single crystals containing vanadium. Several groups of ordinary and forbidden transitions can be observed. The experimental results are interpreted with the aid of the spin Hamiltonian, for which the following parameters were determined:g∥=1.945; ⊥=1.937; ¦D¦=750×10^?4 cm^?1, ¦A¦=68 × 10^?4 cm^?1; ¦B ¦=93×10^?4 cm^?1; ¦A?P¦=65×10^?4cm^?1.     

Line intensities of methane in the 2700–2862-cm−1 region

Individual strengths and wavenumbers of 2080 methane absorption lines have been measured between 2700 and 2862 cm^?1 at an average resolution of 0.023 cm^?1 using a grating spectrometer. The results include all lines with strengths greater than 3 × 10^?5 cm^?2 atm^?1 observable at 296 K with a maximum path of 32 m and a pressure of 4 Torr.     

Deep levels in gallium arsenide by capacitance methods

The three capacitance methods, i.e., TSCAP, PHCAP, and transient capacitance measurements, are applied to determine electronic properties of deep levels inn-GaAs. In the boat-grown wafer detected are the 0.30 eV electron trap withN _T =3.6×10¹⁶ cm^?3 andS _n =2.4×10^?15 cm², and the 0.75 eV electron trap withN _T =2.0×10¹⁶ cm^?3 andS _n =1.2×10^?14 cm². In the epitaxial wafer, the 0.45 eV hole trap is detected withN _T >1.5×10¹³ cm^?3 andS _p =1.4×10^?14 cm² as well as the 0.75 eV electron trap withN _T =2.4×10¹³ cm^?3.     

室温下1.3μm附近CO2的高灵敏度半导体激光吸收光谱

用DFB（分布反馈）半导体激光器结合波长调制吸收光谱技术观测了CO2在1.31μm附近的泛频吸收光谱，并获得的相应的光谱参数（如：谱线位置，谱线强度以及自加宽系数），同时发现了15条弱的新谱线。在665 Pa压力下，本实验可探测的最弱谱线是2.25163′10-27 cm-1/(molecule×cm-2)，相应的吸收是3.88′10-8。     

A quantum cascade laser-based optical feedback cavity-enhanced absorption spectrometer for the simultaneous measurement of CH4 and N2O in air

Optical feedback cavity-enhanced absorption spectroscopy (OF CEAS) has been demonstrated with a thermoelectrically cooled continuous wave distributed feedback quantum cascade laser (QCL) operating at wavelengths around 7.84 μm. The QCL is coupled to an optical cavity which creates an absorption pathlength greater than 1000 m. The experimental design allows optical feedback of infra-red light, resonant within the cavity, to the QCL, which initiates self-locking at each TEM₀₀ cavity mode frequency excited. The QCL linewidth is narrowed to below the mode linewidth, greatly increasing the efficiency of injection of light into the cavity. At the frequency of each longitudinal cavity mode, the absorption coefficient of an intracavity sample is obtained from the transmission at the mode maximum, measured with a thermoelectrically cooled detector: spectral line profiles of CH₄ and N₂O in ambient air were recorded simultaneously and with a resolution of 0.01386 cm^?1. A minimum detectable absorption coefficient of 5.5×10^?8 cm^?1 was demonstrated after an averaging time of 1 s for this completely thermoelectrically cooled system. The bandwidth-normalised limit for a single cavity mode is 5.6×10^?9 cm^?1?Hz^?1/2 (1σ).     

EPR, Optical Absorption and Superposition Model Study of Fe3+-Doped Ammonium Dihydrogen Phosphate Single Crystals

X-band electron paramagnetic resonance (EPR) studies are carried out on Fe³⁺ ions doped in ammonium dihydrogen phosphate (ADP) single crystals at room temperature. The crystal field and spin Hamiltonian parameters are evaluated from the resonance lines obtained at different angular rotations. The obtained values of spin Hamiltonian and zero-field parameters of the Fe³⁺ ion in ADP are: g = 1.994 ± 0.002, |D| = (220 ± 5) × 10^?4 cm^?1 and a = (640 ± 5) × 10^?4 cm^?1. On the basis of EPR data, the site symmetry of the Fe³⁺ ion in the crystal is discussed. The Fe³⁺ ion enters the lattice substitutionally replacing the NH₄ ⁺ sites. The optical absorption of the crystal is also studied at room temperature in the wavelength range of 195–925 nm. The energy values of different orbital levels are calculated. The observed bands are assigned as transitions from the ⁶ A _1g (S) ground state to various excited quartet levels of the Fe³⁺ ion in a cubic crystalline field. From the observed band positions, Racah interelectronic repulsion parameters (B and C), cubic crystal field splitting parameter (D _q ) and Trees correction are calculated. There values are: B = 970, C = 1,923, D _q  = 1,380 cm^?1 and α = 90 cm^?1, respectively. On the basis of EPR and optical data, the nature of bonding in the crystal is discussed. The zero-field splitting (ZFS) parameters are also determined theoretically using B _kq parameters estimated from the superposition model. The values of ZFS parameters thus obtained are |D| = (213 ± 5) × 10^?4 cm^?1 and |E| = (21 ± 5) × 10^?4 cm^?1.