Electro-optical properties of doped anthracene films

Electroluminescence in anthracene doped with anthraquinone (10^?3 mole%) films are presented. Films are deposited at room temperature in a vacuum of 10^?5 torr. It is observed that at constant frequency the brightness/voltage relationship follows the relation $\text{B = B}{}_0\text{exp}\text{(?b/V}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}$. The results show that electroluminescent brightness increases linearly with frequency. At lower frequencies green electroluminescent (EL) emission and at higher frequencies blue EL emission is observed. Similar nature for I–V and brightness/voltage relationship are found in anthracene doped with 10^?4 mole% anthraquinone.     

Oscillator strengths in the Cameron system of carbon monoxide

Relative oscillator strengths in the Cameron system of CO(a³Π ← X¹Σ) have been observed in absorption for six bands (υ′ = 0–5, υ″ = 0) with the result, normalized to the absolute (0, 0) band measurement of Hasson and Nicholls, $\text{?}{}_{00}\text{= (1.62±0.07) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{10}\text{= (1.96±0.09) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{20}\text{= (1.41±0.04) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{\mathrm{3\; 0}}\text{= (0.72±0.03) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{40}\text{= (0.31±0.02) × 10}{}^{\mathrm{?7}}$, $\text{?}{}_{50}\text{= (0.14±0.01) × 10}{}^{\mathrm{?7}}$. The density of CO was modulated with a motor-driven vacuum valve and synchronous fluctuations (?1 per cent) in the transmitted intensity detected with a lock-in amplifier. Peak pressure in the 21 cm absorption cell was approximately 10 torr. A curve of growth analysis was used to correct saturation effects by less than 3 per cent.     

A study of the excited electronic states of 9-fluorenone

Some spectroscopic properties of the low-energy electronic states of 9-fluorenone have been examined. The spectra in paraffin matrices at 4.2°K show detailed vibrational spectra. Two fluorescence spectra are observed; a diffuse emission arises from 9-fluorenone crystals in the paraffin matrix, and a sharp emission is characteristic of the molecule. The sharp fluorescence is analyzed in terms of known a₁ vibrational fundamentals. The sharp absorption is a near mirror-image to the fluorescence, so Herzberg-Teller vibrations are not prominent. The polarization in the crystal spectrum allows this low-energy transition near 23 000 cm^?1 to be assigned ${}^1\text{B}{}_2\text{←}{}^1\text{A}{}_1$. Because there is no vibronic perturbation in fluorescence, and certainly no out-of-plane modes, a $\text{π}{}^1\text{← n}$ transition seen at about 26 000 cm^?1 is tentatively assigned ${}^1\text{B}{}_1\text{←}{}^1\text{A}{}_1$. Another sharp absorption system is seen at 31 000 cm^?1 in the paraffin matrices at 4.2°K (linewidth 6 cm^?1) but no fluorescence was detected. The polarized crystal spectrum indicated the assignment of this system and another very strong system at 40 000 cm^?1 to be ${}^1\text{B}{}_2\text{←}{}^1\text{A}{}_1$, while other systems at about 34 000 cm^?1 and 44 000 cm^?1 are ${}^1\text{A}{}_1\text{←}{}^1\text{A}{}_1$.The phosphorescence spectrum of pyrene-d₁₀ held in a single crystal of 9-fluorenone at 4.2°K has been recorded. No delayed fluorescence from the host crystal is observed at 4.2°K but is intense at 77°K. The energy difference between host and guest triplet levels is estimated to be about 900 cm^?1 allowing the lowest triplet state of 9-fluorenone to be placed at 17 800 cm^?1.     

Two-electron,one-photon transitions in nickel

The two emission lines, Kα₁α₃^h and Kα₂α₃^h resulting from the two-electron transitions $\text{1s}{}^{\mathrm{?2}}\text{→ 2s}{}^{\mathrm{?1}}\text{2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$ and $\text{1s}{}^{\mathrm{?2}}\text{→ 2s}{}^{\mathrm{?1}}\text{2p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$ were resolved for elemental nickel. Their measured energies agree well with calculations. Their relative intensity $\text{I(Kα}{}_1\text{α}{}_3{}^{\mathrm{h}}\text{)/I(Kα}{}_2\text{α}{}_3{}^{\mathrm{h}}\text{) ≈}\text{3}\text{4}$ and their intensity relative to that of the Kα diagram lines is about 10^?4. This is some 10⁴ times larger than both theoretical results and the results of ion-atom collision experiments.     

A measurement of the Ω− lifetime

In an experiment at the CERN-SPS charged-hyperon beam, a sample of $\text{2500 Ω}{}^{\mathrm{?}}\text{→ ΛK}{}^{\mathrm{?}}$ decays has been collected at Ω^? momenta of 98.5 and 115 GeV/c. The Ω^? lifetime is found to be $\text{τ}{}_{\mathrm{\Omega }}\text{= (0.822 ± 0.028) × 10}{}^{\mathrm{?10}}\text{s}$.     

Molecular Rydberg transitions: Cyanogen chloride

The electronic absorption spectrum of cyanogen chloride has been investigated in the range 2200-1250 Å. The first s-Rydberg transitions, $\text{X}\text{?}{}^1\text{Σ}{}^{\mathrm{+}}\text{→}{}^3\text{Π}{}_1$ and $\text{X}\text{?}{}^1\text{Σ}{}^{\mathrm{+}}\text{→}{}^1\text{Π}{}_1$ have been assigned, and analyzed to yield exchange and spin-orbit coupling parameters. The relative intensities of these two transitions have been shown to accord with an intermediate coupling situation. The $\text{π → π}{}^1$ intravalence excitations, leading to ^1.3(Σ^?, Δ and Σ⁺) states, have been discussed. It has been shown that one or both of the ¹Σ^? and ¹Δ states have bent geometries and that the ¹Σ⁺ state is located (tentatively) at 79 755 cm^?1. Two $\text{σ → π}{}^1\text{π → σ}{}^1$ states have been assigned, one at 56 340 cm^?1, the other at 74 450 cm^?1. The latter assignment is tentative, being largely based on observed vibronic interferences between the $\text{X}\text{?}{}^1\text{Σ}{}^{\mathrm{+}}\text{→}{}^1\text{Π}{}_1$ transition and the 74 450 cm^?1 transition. A considerable amount of vibrational oscillator strength and quantum defect data is presented.     

Predissociation and Λ-doubling in the even-parity Rydberg states of the nitrogen molecule

Predissociations in the y¹Π_g and $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ Rydberg states of N₂ (configurations $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{4pσ}$ and $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{3pπ}$, respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c^? or case cⁱ predissociation. Λ doubling in the y state, attributed to interactions with the $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state and with another, ¹Σ⁺, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ state, here labeled x′, is obtained. It is concluded that the predissociation in the Π⁺ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a ${}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state dissociating to ${}^4\text{S +}{}^2\text{P}$ atoms: combined, however, with perturbation of the y state by the k¹Π_g Rydberg state (configuration $\text{3σ}{}_{\mathrm{g}}{}^{\mathrm{?1}}\text{4dπ}$), whose Π⁺ levels are completely predissociated.     

Ultraviolet absorption spectra of Zn2 and Cd2 in solid argon and krypton at 10 K

Zinc and cadmium atoms have been condensed with argon and krypton at 10 K. The most intense absorption is due to the ${}^1\text{P}{}_1\text{←}{}^1\text{S}{}_0$ atomic transition, and a weak band is due to the ${}^3\text{P}{}_1\text{←}{}^1\text{S}{}_0$ atomic absorption. Structured absorptions at 252 and 254 nm in solid argon and krypton with vibrational spacings of 140-120 cm^?1 are due to the ${}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{←}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ transition of Zn₂. Similar 273 and 277 nm absorptions with 110-90 cm^?1 vibrational spacings are due to Cd₂ in solid argon and krypton, respectively.     

The rotational analysis of the 1Π-X 1Σ+ system at 649.5 nanometers of zirconium oxide

A red-degraded band head, normally badly overlapped by the gamma system, $\text{A}{}^3\text{Φ}\text{- X′}{}^3\text{Δ}$, of zirconium oxide, appears in emission spectra of zirconium arcs and in absorption spectra of S-type stars and of frozen rare gas matrices containing zirconium. The emission band has been examined at high-resolution with the aid of separated zirconium isotopes. Identification of the band as 0-0 of a ${}^1\text{Π}\text{- X}{}^1\text{Σ}{}^{\mathrm{+}}$ system of zirconium oxide is confirmed by rotational analysis where the following constants (cm^?1) are obtained for ⁹⁰Zr¹⁶O:

$\text{B}{}_0\text{′(R,P) = 0.40142 D}{}_0\text{′(R,P) = 3.51 × 10}{}^{\mathrm{?7}}$

$\text{B}{}_0\text{′(Q) = 0.40166 D}{}_0\text{′(Q) =3.52 × 10}{}^{\mathrm{?7}}$

$\text{B}{}_0\text{″ = 0.42263 D}{}_0\text{″ =3.19 × 10}{}^{\mathrm{?7}}$

$\text{ν}{}_0\text{= 15383.81s}$

The Λ-type doubling in the ¹Π state and the question of whether $\text{X}{}^1\text{Σ}{}^{\mathrm{+}}$ or $\text{X′}{}^3\text{Δ}$ is the true ground state of ZrO are discussed.     

Study of the photon spectrum in the decay KS0→π+π−γ

The branching ratio $\text{Λ(}\text{K}{}_{\mathrm{<mtext>S</mtext>}}{}^0\text{→π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{γ)}\text{Λ(}\text{K}{}_{\mathrm{<mtext>S</mtext>}}{}^0\text{→π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{)}$ has been determined to be (2.68±0.15)×10^?3 for photon energies $\text{E}{}_{\mathrm{\gamma }}{}^1$ greater than 50 MeV in the K_S⁰ rest frame. The decay K_S⁰→π⁺π^?γ is found to be dominated by the internal bremsstrahlung transition. The branching rato of a possible direct transition is found to be less than 0.06 × 10^?3 at 90% confidence level for $\text{E}{}_{\mathrm{\gamma }}{}^1\text{> 50}\text{MeV}$.     

Multiphonon relaxation rate from pumped level to upper laser level in YAG:Nd

The rise time of the near-infrared fluorescence intensity has been measured in YAG:Nd³⁺ at room temperature under the excitation by 10 ns duration pulses at 514.5 nm using a time-correlated single photon counting method. The result reveals that the relaxation rate from the pumped level (${}^2\text{K}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ + ${}^2\text{G}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ + ${}^4\text{G}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{)}$ to the upper level laser level $\text{(}{}^4\text{F}{}_{\mathrm{<mtext>sol3</mtext><mtext>2</mtext>}}\text{)}$ is larger than 10⁸s^?1, which is in contrast with the previously reported values of (1.6 ～ 2) × 10⁶s^?1. An experiment to search for the visible emission in YAG:Nd³⁺ gives support to the present value.     

Measurement and interpretation of the 1-0 band of 14N16O at 1900 cm−1

The wavenumbers of the vibration rotation band lines of ¹⁴N¹⁶O are reported for the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ subbands of the 1-0 transition in the infrared. The full set of spectroscopic constants for this band has been determined by direct approach using the analysis of Zare, Schmeltekopf, Harrop, and Albritton. In addition to the band origin ν₀ and the B, D, H constants for the lower and upper vibrational levels, the following spin-orbit coupling constants have been derived: $\text{A}\text{?}{}_0\text{= 123.02772 ± 0.00011}$ and $\text{A}\text{?}{}_1\text{= 122.78248 ± 0.00011}$ (in cm^?1). Apparent centrifugal corrections to these constants have been determined and the values obtained for them are $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>0</mtext>}}\text{= (0.347573 ± 0.00051) × 10}{}^{\mathrm{?3}}$ and $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>1</mtext>}}\text{= (0.337135 ± 0.00050) × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$. Λ-Type doubling constants evaluated by using both grating and tunable laser data are also reported.     

A measurement of the lifetimes of Ξ0 and Λ hyperons

The mean lifetimes of the Λ and Ξ⁰ hyperons have been measured in a short neutral beam at the CERN Proton Synchrotron. Λ and Ξ⁰ decays have been identified by measuring their decay products in a magnetic spectrometer and in a lead glass hodoscope. The experimental results, based on 53 000 Λ decays and 6300 Ξ⁰ decays are

From the result for τ_Ξ⁰ together with existing data on τ_Ξ^? we obtain a violation of the $\text{ΔI =}\text{1}\text{2}$ rule in non-leptonic Ξ decays.     

On the mobility of a very pure semiconductor including the low impurity concentration limit

The low temperature mobility μ limited by charged impurities is calculated by solving the equation for the relaxation rate previously derived. The calculated μ behaves like $\text{μ = 2.03 κ}{}^2\text{(k}{}_{\mathrm{B}}\text{T)}{}^{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{e}{}^{\mathrm{?3}}\text{z}{}^{\mathrm{?2}}\text{n}{}_{\mathrm{s}}{}^{\mathrm{?1}}\text{m}{}^{\mathrm{<mtext>1</mtext><mtext>?1</mtext><mtext>2</mtext>}}$ In $\text{[38.2κ}{}^2\text{m}{}^{\mathrm{<mtext>1</mtext><mtext>1</mtext><mtext>2</mtext>}}\text{(k}{}_{\mathrm{B}}\text{T)}{}^{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{/z}{}^2\text{e}{}^4\text{h}\text{?}\text{n}{}_{\mathrm{s}}\text{]}$ for lowest concentrations n_s<10¹¹cm^?3 for Ge and

$\text{μ = 0.360}\text{h}\text{?}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{κ(k}{}_{\mathrm{B}}\text{T)}{}^{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{(ze)}{}^{\mathrm{?1}}\text{n}{}_{\mathrm{s}}{}^{\mathrm{<mtext>?1</mtext><mtext>2</mtext>}}\text{m}{}^{\mathrm{<mtext>1</mtext><mtext>?3</mtext><mtext>4</mtext>}}$

for intermediate concentrations n_s ～ 10¹²?10¹⁴cm^?3.     

A new 5.0 ns isomer in 144Eu

A new 9^? isomeric state having a 5.0 ns half-life has been observed in ¹⁴⁴Eu following the ¹⁴⁴Sm(α, p3n) reactions at 50 MeV. The new isomer most likely has a $\text{(π}\text{g}{}^{\mathrm{?1}}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{v}\text{h}{}^{\mathrm{?1}}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}\text{)}{}_9{}^{\mathrm{?}}$ configuration.     

The reactions K−p → K1− + nucleon at 3.13 and 3.3 GeV/c

Results are presented of a 12 event/μb bubble-chamber experiment; the reactions discussed in detail are $\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^1\text{(890)}{}^{\mathrm{?}}\text{p, K}{}^1\text{(1420)}{}^{\mathrm{?}}\text{p and K}{}^1\text{(890)}{}^{\mathrm{?}}\text{Δ}{}^{\mathrm{+}}$.The K¹ (890)^?p channel is dominated by the forward peak. The suggestion of flattering at cos θ = 1 is more pronounced in $\text{(?}{}_{11}\text{+ ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$; which is mainly natural-parity exchange. Pseudoscalar exchange contributes to $\text{?}{}_{00}{}^{\mathrm{J}}\text{d}\text{σ}\text{d}\text{t}$; this is more sharply peaked in t. The value of $\text{(?}{}_{11}\text{? ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$ is somewhat larger than the upper limit from the dominant natural-parity exchange. There is significant structure in $\text{?}{}_{00}{}^{\mathrm{H}}\text{d}\text{σ}\text{d}\text{t}\text{at}\text{t ≈ ?0.6 (}\text{GeV}\text{/c)}{}^2$.The K¹ (1420)^?p channel is much more pronounced at 3.3 GeV/c than at 3.13 GeV/c, but is not markedly peripheral. The width of the K¹ (1420) in the 3.3 GeV/c data is 42 ± 12 MeV/c².The cross section for $\text{K}{}^{\mathrm{1?}}\text{Δ}{}^{\mathrm{+}}$ agrees with that expected from $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^1\text{Δ}$, assuming a single t-channel exchange. Our measured density matrix elements are consistent with a strong pseudoscalar exchange.     

Charmed baryon pair production in e+e− annihilation

Cross sections for charmed baryon pair production near threshold in e⁺e^? annihilation are calculated using pole-dominated form factors modified to take intoccount continuum effects. When the C₀⁺$\text{C}$₀^? production cross section is normalized with the help of data for $\text{e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{→}\text{p}\text{X}$ it is found that the total charmed baryon production cross $\text{(}\text{C}{}_0\text{C}{}_0\text{,}\text{C}{}_1\text{C}{}_1\text{,}\text{C}{}_1\text{C}{}_1{}^1\text{+}\text{C}{}_1{}^1\text{C}{}_1\text{,}\text{C}{}_1{}^1\text{C}{}_1{}^1\text{)}$ reaches a peak value of approximately 2.7 nb at √s = 5 GeV.     

Study of the three-proton three-neutron-hole nucleus 208At

Levels in ²⁰⁸At were populated in the ²⁰⁹Bi(α, 5n) reaction, and the subsequent radiation was studied using γ-spectroscopic methods including γ-ray excitation function and angular distribution, γγ(t) coincidence and γt measurements, as well as measurements of conversion electrons. The excited spectrum of ²⁰⁸At is found to consist of two almost disconnected parts which are proposed to originate from seniority-three proton and neutron cascades. Two isometric states are observed. A $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 45 ± 2}\text{ns}$ state at 1090 keV is proposed to have the main configuration and J^π = 10^?. A high-spin isomer with $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 1.5 ± 0.2 μs at 2276}\text{keV}$ is assigned to be the state. Shell-model arguments are used to assign configurations to most of the observed levels. Transition rates are discussed.     

Infrared diode laser spectroscopy of the NS radical

The v = 1 ← 0 vibration-rotation bands of the NS radical in the $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ electronic states were observed by using a tunable diode laser. From the least-squares analysis the band origins were determined to be 1204.2755(12) and 1204.0892(19) cm^?1, respectively, for $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$. The rotational and centrifugal distortion constants and the internuclear distance in the X²Π electronic state were obtained as follows: B_e = 0.775549(10) cm^?1, D_e = 0.00000129(33) cm^?1, and $\text{r}{}_{\mathrm{e}}\text{= 1.49403(4)}\text{A}\text{?}$, with three standard deviations indicated in parentheses.     

Lifetimes and g-factors of the 6− and 7− isomers in 66Ga and 68Ga

The 6^? and 7^? isomeric states in ⁶⁶Ga and ⁶⁸Ga at 1440.9 and 1229.6 keV, respectively, have been populated with the (¹³C, 2np) and (¹⁵N, n2p) reactions on natural Fe. The half-lives of these states have been measured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 57.3 ± 1.2}\text{ns}$ and $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 64 ± 2}\text{ns}$. Using previous data on the hyperfine field of Ga in Fe, the g-factors of these states have been determined by means of the TDPAD method. The results are $\text{g(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 0.129 ± 0.003}$ and $\text{g(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 0.105 ± 0.003}$. These values are in very good agreement with the independent particle model if one assumes the and configurations and uses the empirical proton and neutron g-factors from odd-A neighboring nuclei instead of the Schmidt values. The large disagreements with experiment when Schmidt values are used show that core polarization effects are important in these nuclei.