Co SiO2颗粒膜的巨磁电阻效应

测量了Ｃｕ Ａｌ混合粉末经过不同时间球磨后的２７Ａｌ核磁共振（ＮＭＲ）谱,分析了２７ＡｌＮＭＲ谱的特征参量随球磨时间的变化．根据２７ＡｌＮＭＲ谱所提供的信息,研究了Ｃｕ Ａｌ混合粉末机械合金化反应的微观过程．Ｃｕ Ａｌ混合粉末的２７ＡｌＫｎｉｇｈｔ位移随球磨时间的增加而减小．对于Ｃｕ Ａｌ混合粉末,球磨不仅改变了２７Ａｌ附近的化学短程序,而且也直接地影响了２７Ａｌ的外层电子态,后者使传导电子的ｓ态成分减小．实验结果表明,Ｃｕ Ａｌ混合粉末在球磨过程中发生了真正的合金化反应;经过９０ｈ球磨完成了合金化反应; 关键词：     

Co SiO2颗粒膜的巨磁电阻效应

采用离子束溅射方法在玻璃基片上制备了一系列的Co－SiO\-2颗 粒膜样品,并对样品的巨磁电阻效应进行了研究.在Co35(SiO\-2)65(体积 百分比)颗粒膜样品中,观测到室温下近4%的巨磁电阻效应.研究了不同基片温度对巨磁电 阻效应的影响并发现,随着基片温度的升高样品的巨磁电阻效应下降.根据样品的电阻率温度关系曲线分析,在铁磁金属- 非磁绝缘介质颗粒膜中,除了电子自旋相关隧穿效应外, 可能还存在其他的导电机制. 关键词：     

不同过渡层上Co/Cu/Co三明治结构的巨磁电阻效应研究

通过对不同过渡层上Co(5.5nm)/Cu(3.5nm)/Co(5.5nm)三明治结构的研究,发现过渡层的磁性及过渡层诱导的三明治晶格结构对材料的巨磁电阻效应有重要影响.反铁磁Cr过渡层由于和相邻铁磁Co层之间存在着反铁磁耦合,可以获得6％以上的巨磁电阻值,但它同时使材料的矫顽力较大,因此磁灵敏度不高.Ni和Ti过渡层上Co/Cu/Co三明治结构,由于形成了强的（111）织构,其巨磁电阻值也达到5％以上.磁性材料Ni过度层还使三明治结构材料的矫顽力大为下降,从而显著提高了材料的磁灵敏度. 关键词：     

La1-xCaxMnO3的巨磁电阻效应

通过测量La_2/3Ca_1/3MnO₃，La_0.6Ca_0.4MnO₃单相多晶样品的磁电阻、电阻与温度的依赖关系，发现在La_1-xCa_xMnO₃体系中随x的变化，其磁电阻峰和电阻峰都发生了位移．作者认为体系中Mn⁴⁺含量是受Ca含量调制的，正是Mn⁴⁺含量的变化，导致磁性 关键词：     

Fe-Al2O3颗粒膜的隧道巨磁电阻效应

对射频共溅射法制备的Fe-Al₂O₃颗粒膜的隧道巨磁电阻效应进行了研究.当Fe体积百分比为45%时,样品的室温磁电阻的变化率(MR)在1T的平行膜面的磁场下可达4.4%.磁测量表明在室温时样品呈超顺磁态.另外,从MR随温度的变化关系曲线可以看出,当温度低于50K时,MR随着温度的下降而显著增加,MR在20K时达到14.9%,4.2K时可达26%,大大超过理论的预期值,这可能与低温下由库仑抑制效应引起的自旋相关隧穿的高阶效应有关.     

纳米材料中的巨磁电阻效应

纳米材料是指三维空间尺度中至少有一维处于纳米量级的材料,通常为１—１００ｎｍ,如纳米微粒,纳米线、管,纳米薄膜或其组合材料,近年来纳米材料中的巨磁电阻效应颇受人们青睐,本文将重点介绍颗粒膜,颗粒合金薄带,非连续多层膜,颗粒—薄膜混合型膜以及磁性隧道结的巨磁电阻效应。     

纳米材料中的巨磁电阻效应

纳米材料是指三维空间尺度中至少有一维处于纳米量级的材料，通常为１—１００ｎｍ，如纳米微粒，纳米线、管，纳米薄膜或其组合材料，近年来纳米材料中的巨磁电阻效应颇受人们青睐，本文将重点介绍颗粒膜，颗粒合金薄带，非连续多层膜，颗粒—薄膜混合型膜以及磁性隧道结的巨磁电阻效应。     

退火对Co35(SiO2)65颗粒膜巨磁电阻效应的影响

采用多靶离子束溅射镀膜机制备了一系列不同退火温度的Co₃₅(SiO₂)₆₅（体积百分数）颗粒膜样品,发现样品的巨磁电阻效应随着退火温度T_a的升高而单调下降.应用磁力显微镜对样品的磁结构进行了观测,发现随着退火温度的升高,近邻的Co颗粒的磁矩倾向于平行排列,形成磁畴结构,从而导致Co₃₅(SiO₂)₆₅颗粒膜巨磁电阻效应单调下降. 关键词：     

Co掺杂对铁磁金属La0.8Sr0.2MnO3磁电阻影响机理

通过对La_0.8Sr_0.2Mn_1-yCo_yO₃(y≤02)饱和磁矩和输运的测量,研究了Co对La_0.8Sr_0.2MnO₃的磁电阻影响机制.结果表明,在La_0.8Sr_0.2Mn_1-yCo_yO₃（y≤02）中Co³⁺离子是低自旋态.由于Mn³⁺—O—Co³⁺—O—Mn³⁺类型的磁交换与Mn³⁺-Mn⁴⁺离子间双交换作用相比较弱,Curie温度T_C附近的磁电阻随着Co掺杂量的增加而降低.与此相反,由于Co²⁺离子与e_g巡游电子的反铁磁交换耦合作用,低温区间的磁电阻随着Co掺杂量的增加而升高. 关键词： 低自旋 磁电阻 磁交换作用     

Giant magnetoresistance in Y0.9La0.1Mn6Sn6 compound

Magnetic transitions and magnetoresistance effect of the HfFe_6Ge_6-type Y_{0.9}La_{0.1}Mn_6Sn_6 compound have been investigated in the temperature range of 5－380K. The sample displays antiferromagnetic behaviour in the whole temperature range below Néel temperature T_N=309K. The metamagnetic transition from antiferromagnetism to ferromagnetism can be induced by an applied field. The metamagnetic transition field decreases monotonically from 2T at 5K to 0.4T at 300K. The giant magnetoresistance effect is observed with the metamagnetic behaviour, such as -10.4% at 245K under a field of 5T.     

Low energy sputtering of neutral Cu2 molecules

The ratios of relative yields of neutral sputtered Cu₂ molecules to neutral sputtered Cu atoms were found to be linearly proportional to the sputtering yield of Cu, from a Cu target under bombardment by Ar⁺ ions (energy 50–90 eV), as determined by secondary neutral mass spectrometry.     

Structural evolution of Co clusters on Cu90Co10 upon annealing

A granular alloy, composed of cobalt embedded in a copper matrix, was studied by using EXAFS and magnetotransport measurements as function of annealing parameters (temperature and annealing time). The results suggest that different annealing routes can reach the same final state. For annealing temperatures up to 450°C, the results indicate the coalescence of cobalt atoms, resulting in magnetic particles with increasing size. On the other hand, the annealing at 500°C shows a rapid formation of cobalt particles and then the re-dissolution of cobalt atoms in the copper matrix.     

Magnetoresistance near the metal-insulator transition of Cd0.99Mn0.01Se

At 0.5 ≤ T ≤ 4.2 K samples of Cd_0.99Mn_0.01Se which are near the metal-insulator transition exhibit a large positive magnetoresistance (MR) in fields H ∽ 10 k0e. The effect is accompanied by an increase in the Hall coefficient and a decrease in the Hall mobility. At the lowest temperatures and for fields well above 10 k0e a small negative MR is observed. The positive MR is tentatively attributed to an increase in the screening radius r_s, which leads to enhanced Coulomb-potential fluctuations.     

Giant Magnetoresistance in La0.67Ca0.33MnO3/Alq3/Co Sandwiched-Structure Organic Spin Valves

La_0.67Ca_0.33MnO₃/Alq₃/Co sandwiched-structure organic spin valves are fabricated by vacuum thermal evaporation method. A giant magnetoresistance (GMR) of 14% is observed at low temperature 100K. At 30K, the magnetoresistance can increase to 50%. The large GMR of the device is attributed to the high spin polarization and low conductivity of the La_0.67Ca_0.33MnO₃ contact. The magnetoresistance ΔR/R and the coercive field of the Co electrode depend strongly on temperature. The large high-field magnetoresistance reported on La_0.67Sr_0.33MnO₃/Alq₃/Co organic spin valves [Nature 427 (2004) 821] is not observed in our La_0.67Ca_0.33MnO₃/Alq₂/Co organic spin valves.     

新型钙钛矿铜氧材料Sr8 CaRe3 Cu4 O24的亚铁磁和轨道有序性质

用密度泛函理论和格林函数方法研究了新型钙钛矿铜氧材料Sr8CaRe3Cu44O24的电子结构和磁性性质.所得结果与实验符合得很好,表明这种材料是绝缘体,每个元胞有1.0μB的磁矩.磁矩主要在Cu原子上,相邻Cu原子上的磁矩反平行排列.非磁的Re原子使得Cu上的d轨道有序排列,这导致这种材料有很高的居里温度(TC≈440K).基于密度泛函的结果,用海森伯模型描述了材料的电子自旋自由度,并用格林函数方法研究了材料有限温度下的磁性行为,所得结果和实验一致,表明自旋为1和自旋为1/2磁矩交错排列的海森伯模型可很好地描述这种材料的磁性性质.     

Magnetic properties for the Cu2MnSnSe4 and Cu2FeSnSe4 compounds

Magnetic susceptibility χ measurements in the range from 2 to 300 K were carried out on samples of the Cu₂FeSnSe₄ and Cu₂MnSnSe₄ compounds. It was found that Cu₂FeSnSe₄ was antiferromagnetic showing ideal Curie-Weiss behavior with a Néel temperature T_N of about 19 K and Curie-Weiss temperature θ=−200 K, while for Cu₂MnSnSe₄ the behavior was spin-glass with a freezing temperature T_f of about 22 K and Curie-Weiss temperature θ=−25 K. The spin-glass order parameter q(T), determined from the susceptibility data, was found to be in agreement with the prediction of conventional spin-glass theory.     

Double exchange model for RuSr2(Eu,Gd)Cu2O8

We propose a double exchange model to describe the RuO₂ planes of RuSr₂(Eu,Gd)Cu₂O₈. The Ru⁺⁵ ions are described by localized spins, and additional electrons provided by the superconducting CuO₂ planes are coupled ferromagnetically to them by Hund rules coupling. We calculate the spin structure factor, magnetic susceptibility and magnetization as a function of magnetic field and temperature, using a Monte Carlo algorithm in which the Ru⁺⁵ spins are treated as classical. Several experiments which seemed in contradiction with one another are explained by the theory.