共查询到20条相似文献,搜索用时 15 毫秒
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三价铬离子水解聚合作用的研究 VII.反丁烯二酸存在下高铬浓度区水解产物的pqr分析 总被引:1,自引:0,他引:1
本文报道用静置平衡pH法研究在较高的铬浓度(CA=0.01, 0.015,0.02mol.dm^-^3)存在下,Cr^3^+在水溶液中的状态,用Newton-Raphson法和非线性Gauss-Newton法进行优化处理,自编成LEMIT程序、用此程序在电子计算机上对铬配合物HPMqAr的组成进行pqr分析,求得粒子的最佳组成为[CrOH]^2^+,[Cr~OH]^5^+,[Cr(OH)A]和[Cr~2(OH)A]^3^+.用此程序同时计算30个数据点,求得各粒子的水解常数,拟合结果良好,说明LEMIT程序能用于复杂体系的计算。 相似文献
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Summary A procedure is described for the determination of 0.2–3.5 mg of the diphenyliodonium cation by extraction of its hexathiocyanatoferrate(III) Complex from slightly acidic solution into 1,2-dichloroethane. Absorbance measurements are made directly on the organic extract at 485 nm. Beer's law is not obeyed and a calibration curve must be used.
Part VI: Mikrochim. Acta [Wien]1967, 564. The work reported in this paper forms part of a thesis submitted byAnthony J. Bowd to the Faculty of Science of the University of London in partial fulfilment of the requirements for the degree of Doctor of Philosophy. 相似文献
Zusammenfassung Ein Verfahren für die Bestimmung von 0,2 bis 3,5 mg Diphenyljodoniumkation durch Extraktion seines Hexathiocyanatoferrat(III)-komplexes aus sehwach saurer Lösung mit 1,2-Dichloräthan wurde beschrieben. Die Absorption des organischen Extraktes wurde unmittelbar bei 485 nm gemessen. Das Beersche Gesetz ist nicht anwendbar, weshalb man eine Eichkurve verwenden muß.
Part VI: Mikrochim. Acta [Wien]1967, 564. The work reported in this paper forms part of a thesis submitted byAnthony J. Bowd to the Faculty of Science of the University of London in partial fulfilment of the requirements for the degree of Doctor of Philosophy. 相似文献
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E. Campaigne H. R. Burton C. D. Blanton S. W. Schneller 《Journal of heterocyclic chemistry》1971,8(1):65-72
Ring closure of ylidenemalononitrile adducts has been extended to the syntheses of isomeric sulfur heterocycles. The malononitrile derivatives of thiochromanone, thiochromone and iso-thiochromanone have been synthesized, and results of the acidic ring closure experiments on these compounds are reported. The thiochromanone adducts gave an interesting disproportionation reaction, and experiments designed to support the proposed route are presented. 相似文献
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