Analysis and application of NRD-guide excitors

In this paper, the NRD-guide excitors using a length of coaxial line which consists of a rectangle external conductor and a thin round inner conductor are presented, and the characteristics of the input impedances of LSE ₁₁ ^o mode and LSM ₁₁ ^o mode at the insertion points are analysed and calculated by using the method of the rector Green's function respectively. The computation results show that the mode excitors are able to improve the operating modes matching between NRD-guide and the quasi-TEM transmission line. The structures are suitable for fabrication LSE ₁₁ ^o mode oscillator and LSM ₁₁ ^o mode oscillator to compose millimeter wave NRD-guide integrated front ends. An example of an LSE ₁₁ ^o mode oscillator in Ka-band is given. Its oscillation frequency and output power could be easily adjusted by changing the parameters of the excitor.     

Steady-State Responses of NRD-Guide LSE/LSM Mode Oscillators in MM-Wave Bands

The analysis methods for the steady-state responses of the mm-wave band NRD-guide negative impedance oscillators based on nonlinear microwave autonomous circuits harmonic balanced method are presented in the paper in details. Firstly, the large-signal nonlinear lumped equivalent circuits of the Gunn diode are studied in mm-wave bands. Then, the performances of two kinds of NRD-guide autonomous circuits, the probe-exciting LSM ₁₁ ^o-mode oscillator and the LSE ₁₁ ^o-mode oscillator, are analyzed by the way of extracting the large-signal dynamic harmonic admittance (conductance) of the Gunn diode or directly configuring the harmonic balance equations for the oscillator. The input impedance of the exciting probe in the oscillator and the performances of the load-pulling and the local stability of the NRD-guide oscillator are also involved.     

Steady State Responses of NRD-Guide Crossbar Balanced Mixer in MM-Wave Band

The periodic and quasi-periodic steady states of the nonradiative dielectric waveguide (NRD-guide) crossbar single-balanced mixer excited by single tone or dual tones in mm-wave band are deeply researched in the paper. Based on the wideband dispersion characteristics, the mode self-contained property and the modes orthogonality and a series of modes excitation criterions of the NRD-guide, a novel mixer is designed and analyzed. Two important parameters, the local oscillator and incident wave inductive electromotive forces corresponding to the LSE/LSM mode-converter and LSM-mode probe respectively, are calculated firstly by using the wire-antenna theory and the moment method. According to the theorem of band-pass signal sampling, a kind of integrated and general quasi-periodical steady-state responses algorithm for the nonlinear microwave/mm-wave circuits excited by multiple tones, the inter-modulation balance method based on the multi-dimension discrete Fourier transformation (MDFT-IMB), is designed and then successfully applied to calculate the performances of the above NRD-guide mixer.     

The development of nonradiative dielectric waveguide transmitting front-end in Ka-band

The operating theory,design method and experimental results of the nonradiative dielectric waveguide (NRD-guide) transmitting front-end in millimeter wave band are related in details in this paper. As a kind of dielectric waveguide,the NRD-guide possesses fine transmission performances, and it can be used to fabricate the millimeter wave hyterodyne integrated circuits. The two kinds NRD-guide transmitting front-ends substantiated in the paper, the voltage controlling oscillator(VCO) and twin-Gunn-diode power-combiner,have very similar structures to each other and possess compact sizes, fine machinery and electric performances.For the VCO front-end in Ka-band, the frequency modulation band is greater than 150MHz, the output power is larger than 20mW.For the power-combiner, the output power is larger than 40mW,the combination efficiency is better than 90%,the frequency stabilization reaches 1.68×10^–5. Combined with the receiving front-end reported before,the transmitter and receiver can be composed to a dielectric waveguide R/T module to be applied in some millimeter wave sub-systems.     

Normal modes of a probe field in the pulsed regime of electromagnetically induced transparency in a Λ-scheme of degenerate quantum transitions

The effect of separation of linearly polarized short probe pulses of electromagnetically induced transparency in the field of linearly polarized coupling radiation is modeled numerically. It is shown that the input-probe pulses polarized parallel or perpendicular to the input-probe field propagate in the medium without changing the state of their polarization. If the input-probe radiation is weak compared to the coupling radiation, then the probe field inside the medium is the sum of two independently propagating linearly polarized normal modes, which are excited by the projections of the input-probe pulse onto the direction of polarization of the coupling radiation and onto the perpendicular direction, respectively. The normal modes have the same phase velocities, but different velocities of their real envelopes. This circumstance leads to the rotation of the plane of polarization of the total probe field at short distances and to its separation into two pulses with mutually perpendicular directions of polarization at long distances. At a high intensity of the probe radiation, the input-probe pulse decays into pulses the planes of polarization of which are not mutually perpendicular. Under these conditions, it is impossible to represent the probe radiation as a sum of normal modes. The modeling is performed in the scheme of degenerate quantum transitions between states of levels ³ P ₀, ³ P ₁ ⁰, and ³ P ₂ of isotope ²⁰⁸Pb taking into account the Doppler broadening of spectral lines.     

Hydrothermal growth of ZnO on annealed electrodeposited titanate film: Influence of zinc nitrate and methenamine

Hydrothermal growth of hexagonal ZnO nanorods on the annealed titanate nanotube films is reported as a function of molar ratio of Zn(NO₃)₂ and methenamine (1:1-1:4). The molar ratio of 1:4 results in a dense and thinner rod in comparison with other molar ratios. Corn-like structures of the rods are believed to be due to the higher amine concentration. Raman peaks at 437 and 331 cm⁻¹ are assigned to E₂ and E_2H-E_2L modes. Near band gap edge and green photoluminescence emission indicates the structural and oxygen vacancy. O 1s peak is found built-up of sub-peaks at 530.62, 531.8 and 532.84 eV corresponding to O²⁻ on normal wurtzite structure and OH and oxygen vacancies of ZnO, respectively.     

A new type NRD-guide receiving front-end in Ka-band

A new type millimeter-wave receiving frond-end using NRD-guide as internal transmission line is presented in this paper. The receiving frond-end consists of a NRD-guide crossbar balanced mixer, a NRD-guide LSE mode local oscillator and two impedance-converters at two input ports of the mixer circuit. Firstly, the propagation characteristics of some transmission modes often used in NRD-guide are given, and the conditions which these modes are applied as the operating modes are discussed. Secondly, the principle of the balanced mixed which is regarded as the key circuit unit in the receiving frond-end is analysed by using vector Green's function, and the conversion loss of the mixer is computed with an equivalent circuit in Ka-band. And then, from the view of obtaining the optimum performances of the whole receiving frond-end, some methods of designing local oscillator are expound. Some experimental results of the receiving frond-end at Kaband are given in the paper lastly. Because the frond-end have the impedance matching and converting circuits, it possesses better electrical performance. The integrated frond-end which have compact size and excellent shock strength is suitable for varied millimeter-wave system.     

Nonlinear Frequency-Modulation Distortion Analysis for VCO Based on Harmonic Balance Method

The analysis methods for the steady-state responses of the voltage tuning negative resistance oscillator (voltage-controlling oscillator, VCO) by the microwave nonlinear autonomous circuit harmonic balance method in millimeter-wave bands are studied in the paper. Firstly, the quasi-periodic characteristic of the steady-state response of the VCO modulated by a periodic signal is proved. Then, on the bases of the harmonic balance analysis and the inter-modulation balance analysis, a novel method for obtaining the steady-state tuning performance and the nonlinear frequency-modulation distortion characteristic of the VCO is presented. The total analysis process is aimed to a kind of NRD-guide Gunn diode VCO. The large-signal lumped equivalent circuit model of the millimeter-wave P⁺N-junction varactor is also given for explaining the algorithm and the principle of the NRD-guide VCO.     

Raman scattering from GaSxSe1-x

The non resonant Raman scattering spectra of GaSe, GaS and of eight different mixed crystals GaS_xSe_1-x are presented. The frequencies of some vibrational modes shift continuosly from GaSe to GaS indicating that the mixed crystals are homogeneous. The discontinuous shift of some other modes is explained either by the change of the stacking of the layers, or by a ‘two mode’ behaviour as previously observed in other types of mixed crystals. Moreover, local vibrational modes are observed.     

Hydrogen‐bonding interactions in fully deuterated α‐glycine at high pressures

Recent spectroscopic investigations of various amino acids report intriguing high‐pressure and low‐temperature behavior of NH₃⁺ groups and their influence on various hydrogen bonds in the system. In particular, the variation of the intensity of NH₃⁺ torsional mode at different temperatures and pressures has received much attention. We report here the first in situ Raman investigations of fully deuterated α‐glycine up to ∼20 GPa. The discontinuous changes in COO⁻ and ND₃⁺ modes across ∼3 GPa indicate subtle structural rearrangements in fully deuterated α‐glycine. The decrease in the intensity of ND₃⁺ torsional mode is found to be similar to that of undeuterated α‐glycine. The pressure‐induced stiffening of N D and CD₂ stretching modes are discussed in the context of changes in the hydrogen‐bonding interactions. Copyright © 2011 John Wiley & Sons, Ltd.     

Double Higgs production at the linear colliders and the probing of the Higgs self-coupling

We study double Higgs production in the e⁺e^? and γγ modes of the linear collider. It is also shown how one can probe the scalar potential in these reactions. We discuss the effective longitudinal W approximation in γγ processes and the W _LW_L luminosities in the two modes of a high-energy linear collider. A generalised non-linear gauge-fixing condition, which is particularly useful for tree-level calculations of electroweak processes for the laser induced collider, is presented. Its connection with the background-field approach to gauge fixing is given.     

Highly Sensitive ‘on–off’ Pyrene Based AIEgen for Selective Sensing of Copper (II) Ions in Aqueous Media

A Fluorescent chemosensor based on pyrene scaffold, 5-diethylamino-2-(pyren-1-yliminomethyl)-phenol (PDS) is synthesized using condensation method. It displays novel aggregation-induced emission (AIE) phenomena in its aggregated/solid state. The AIE characteristic of PDS is studied in CH₃CN/H₂O mixtures at different volume percentage of water and morphology of the aggregated particles are investigated by DLS and optical fluorescence microscopic study. The probe is aggregated into ordered one-dimensional (1-D) rod like microcrystals and exhibit high efficiency of solid-state emission with green colour. By taking advantage of its interesting AIE feature, the aggregated hydrosol has been utilized as ‘off–on’ type fluorescence switching chemosensor with superb selectivity and sensitivity towards Cu²⁺ions and the limit of detection (LOD) was calculated as low as 6.3 µM. A high Stern–Volmer quenching constant was estimated to be 2.88?×?10⁵ M^?1. The proposed chemosensor with AIE feature reveals a prospective view for the on-site visual recognition of Cu²⁺ ions in fluorescent paper strips and the synthesized probe is also exploited to find out the concentration of Cu²⁺ions in real water samples.

     

Intermixing during epitaxial growth and Mössbauer spectroscopy with probe layers

Mössbauer spectroscopy with ⁵⁷Fe (¹¹⁹Sn) probe layers is a useful method to study the local magnetic structures at buried interfaces. However interface alloying, which always exists in the real samples, have to be taken into account for accurate interpretation of experimental data. We developed an algorithm, which describes the interface intermixing in the multilayers. Substituting deposited atoms by atoms of substrate and floating of deposited atoms in the upper layers during epitaxial growth leads to the formation of asymmetric chemical and magnetic interfaces. This asymmetry in the M₁/M₂ superlattices can explain the difference between magnetic responses from M₁ on M₂ and M₂ on M₁ interfaces which were observed in experiments. Applying this intermixing model to the systems with probe layers located at different distances from the interfaces gives the natural explanation of hyperfine fields distributions on probe atoms and helps us clarify some discrepancies reported in the literature.     

Preparation and characterization of ZnO nanorods from NaOH solutions with assisted electrical field

ZnO naorods on ZnO-coated seed substrates were fabricated by solution chemical method from Zn(NO₃)₂/NaOH under assisted electrical field. The working mechanism of electrical field was analyzed and the factors affecting the rod growth such as potential, precursor concentration and growth temperature were elucidated. The structural and optical properties are characterized by SEM, TEM, XRD, HRTEM and UV-vis. The results indicated that the nanorods have wurtzite structure without electrical field and are primarily of zincite structure under electrical field; when the electrical field is 1.1-1.3 V, not only the elevation of ion diffusion and adsorption lower the crystallite/solution interfacial energy and then the crystal nucleation barrier by increasing charge intensity, but also the production of H⁺ through oxidation of OH⁻ increases properly the degree of solution supersaturation near the substrate, and thus lowers the activation energy. Both the two processes do favor to rod growth. With increasing precursor concentration in this system, the average diameter and length of ZnO nanorods increase, leading to decreasing of optical transmittance. The maximum rod growth rate at given concentration of Zn²⁺ occurs at a specific temperature.     

Mode transition in magnetic pole enhanced inductively coupled argon plasmas

The electrical probe (Langmuir probe) diagnostics of different plasma parameters and operation regimes (E/H modes) of magnetic pole enhanced, inductively coupled (MaPE-ICP) argon plasmas are investigated. It is shown that uniform, high density (n _e ∼ 10¹² cm^-3) and low electron temperature (T _e ∼ 1.5 eV) plasma can be produced in low pressure argon discharges at a low power (100 W). It is found that an MaPE-ICP reactor operates in two different modes; capacitive (E mode) and inductive (H mode). No density jump or hysteresis are reported between these modes. The effect of pressure on transition power, where the mode changes from E to H mode at 20 sccm gas flow rate are studied and it is found that for all pressures tested (∼7.5 mTorr to 75 mTorr) the transition power remains same. In the inductive mode, the above plasma parameters show a smooth variation with increasing filling gas pressure at fixed power. The intensity of the emission line at 750.4 nm due to 2p ₁ → 1s ₂ (Paschen’s notation) transition, closely follows the variation of n _e with RF power and filling gas pressure. Measured electron energy probability function (EEPF) shows that electron occupation mostly changes in the high-energy tail, which enlightens close similarity of the 750.4 nm argon line to electron number density (n _e ). The behaviour of the electron energy probability function (EEPF) with regard to pressure and RF power in two operational modes is presented.     

Effects of tunneling coupling on plasmon modes in asymmetric double-quantum-well structures

The collective charge density excitations in asymmetric double-quantum-well (DQW) structures with different tunneling strengths are systematically studied. In particular, the damping properties of the plasmon modes in various tunneling strengths are investigated in detail. It is shown that plasmon modes in asymmetric DQW structures are quite different from those in symmetric DQW systems. In weak tunneling regime, an intra-subband mode ω _- with an acoustic-like dispersion relation which is damped in symmetric DQW structures arises and coexists with the optical-like mode ω ₊ while the inter-subband mode ω ₁₀ is highly damped. With the tunneling strength being increased, the ω ₁₀ branch gradually becomes undamped and emerges out of the (1-0) single-particle continuum, whereas the ω _- branch gradually approaches the (0-0) single-particle continuum. In intermediate coupling regime, these three branches of modes coexist undamped. In strong tunneling regime, ω _- enters the (0-0) single-particle continuum and becomes damped. Consequently, only the ω ₊ and ω ₁₀ modes exist in this regime. Received 10 July 2001 and Received in final form 17 September 2001     

57Fe and 119Sn probe M?ssbauer spectroscopy investigation of perovskite-type double manganite family CaCuxMn7?xO12 (x = 0, 0.15, 3)

CaCu _x Mn_7−x O₁₂ (x = 0, 0.15, 3) manganites were studied by ⁵⁷Fe and ¹¹⁹Sn probe M?ssbauer spectroscopy. It was established that the ⁵⁷Fe and ¹¹⁹Sn probe cations are stabilized in the octahedral positions of the manganite structures by substituting the manganese cations. The magnetic and structure phase transition temperatures of CaMn₇O₁₂ and CaCu_0.15Mn_6.85O₁₂ manganites fell upon the introduction of ⁵⁷Fe probe cations into their structures. It was concluded that intrasublattice Mn⁴⁺-O-Mn⁴⁺ exchange interactions play a noticeable role in the formation of the magnetic structure of CaCu₃Mn₄O₁₂ manganite.     

Results of irradiating aluminum and homogeneous alloy YMn2 by 23 MeV γ-quanta in a molecular deuterium atmosphere at 2 kbar pressure

Specimens of a number of metal were placed successively along the length in a deuterium high-pressure chamber of the “finger type” (DHPC-FT). The specimens were: two aluminum rods, a copper rod, two YMn₂ alloy specimens, and stainless steel. The molecular deuterium pressure in the DHPC-FT chamber was 2 kbar. The specimens were irradiated by braking γ-quanta with boundary energy 23 MeV. After irradiation, all specimens were investigated on scanning electron microscopes (SEM) with electron probe X-ray microelement analysis (XMA). Considerable changes in the structure of the surfaces and elemental composition of the measured aluminum, destruction of the homogeneous YMn₂ alloy specimen, and the “formation of monocrystalline specimens” of the YMn₂ type and structures resembling manganese-based “crystals” were observed. A phenomenological explanation of the observed phenomena and effects based on nuclear reactions is proposed with consideration of certain new approaches, which are examined.     

Single-mode optical waveguides fabricated in LiNbO3 by multienergy C implantations

Single-mode waveguides in LiNbO₃ are demonstrated by use of prism coupling method. The waveguides are fabricated by three different energies and single energy C²⁺ implantations at the equal total doses, respectively. Dark modes and propagation loss are measured by use of prism coupling and moving fiber methods, respectively. Damages produced by implantation are measured by RBS/channeling technique. The waveguide structures are investigated in two different implantation cases. The results of analysis indicate that the heavy ion-implanted waveguides are still defined by synergetic characteristics from both the raised-index region and the low-index barrier. The broadened barrier from multienergy implantation is demonstrated to play a significant role in reducing propagation loss.     

Engineering the Internal Structure of Magnetic Silica Nanoparticles by Thermal Control

Calcination of hydrated iron salts in the pores of both spherical and rod‐shaped mesoporous silica nanoparticles (NPs) changes the internal structure from an ordered 2D hexagonal structure into a smaller number of large voids in the particles with sizes ranging from large hollow cores down to ten nanometer voids. The voids only form when the heating rate is rapid at a rate of 30 °C min^?1. The sizes of the voids are controlled reproducibly by the final calcination temperature; as the temperature is decreased the number of voids decreases as their size increases. The phase of the iron oxide NPs is α‐Fe₂O₃ when annealed at 500 °C, and Fe₃O₄ when annealed at lower temperatures. The water molecules in the hydrated iron (III) chloride precursor salts appear to play important roles by hydrolyzing Si? O? Si bonding, and the resulting silanol is mobile enough to affect the reconstruction into the framed hollow structures at high temperature. Along with hexahydrates, trivalent Fe³⁺ ions are assumed to contribute to the structure disruption of mesoporous silica by replacing tetrahedral Si⁴⁺ ions and making Fe? O? Si bonding. Volume fraction tomography images generated from transmission electron microscopy (TEM) images enable precise visualization of the structures. These results provide a controllable method of engineering the internal shapes in silica matrices containing superparamagnetic NPs.