正弦波导高频特性分析

对一种全金属慢波系统—–正弦波导的高频特性进行了理论分析.在用一系列相连矩形阶梯逼近余弦槽的基础上,对慢波结构进行了合理的区域划分,获得了各区域的场表达式.考虑槽区的高次驻波项,采用场匹配和导纳匹配相结合的方法,导出色散方程和耦合阻抗表达式.以应用于220 GHz行波管的正弦波导为例进行高频特性的数值求解,理论计算值与全三维电磁软件CST-MWS的仿真值符合良好.在此基础上,详细分析了尺寸参数变化对正弦波导高频特性的影响.     

纳米TiO2叶片状阵列电极的制备及其在染料敏化太阳电池中电子的输运性能

在低温条件下采用定向刻蚀技术, 对金属Ti片表面用H₂O₂溶液进行刻蚀氧化, 制备了垂直生长的纳米TiO₂叶片状阵列薄膜电极. 通过X射线衍射分析表明, 纳米TiO₂叶片状阵列薄膜经500 ℃下烧结1 h后, 从无定型转变为锐钛矿相. 场发射扫描电子显微镜观察表明: 在80 ℃下的H₂O₂溶液刻蚀氧化, 经1 d制备得到的是Ti片表面垂直生长的叶片状阵列, 其形貌均匀且完整地 关键词： 2')" href="#">纳米TiO₂ 叶片状阵列电极 染料敏化太阳电池 电子传输     

The space-time-averaging procedure and modeling of the RF discharge

An approach to modeling RF discharges and the ensuing analysis of fast electron and ion motions for the case of electrode sheaths in the high-pressure RF discharge is discussed. Time-averaging over fast electron motions with the applied voltage frequency gives analytic expressions for the average electric field and average ionization density. The resulting relatively simple equations for the ion density profile describe drift, diffusion, ionization, and recombination processes. The simple scaling rules, the approximate expressions for the density profile in various regions, the sheath length, the ion density at the plasma-sheath boundary, and the dimensionless criteria for various discharge regimes can be deduced. For the non-self-sustained discharge, it is demonstrated that the ion drag towards the electrode and the diffusion results in significant lowering of the ion density in the sheath compared with the positive column at not too high a pressure. The analytic transition criterion from α to γ forms of the self-sustained discharge is obtained. The numerical solution of the averaged ion equations yields the results which nearly coincide with the results of full-scale modeling     

Electrode effects in lithium conducting oxyfluorophosphate glasses

The ac impedance of the lithium oxyfluorophosphate glasses has been studied as function of frequency and temperature in the range 100 Hz–13 MHz and 25–250°C. Three different electrode materials namely, silver, graphite and lithium have been used. The equivalent circuits have been derived from the complex plane analysis. MacDonald's model for perfectly blocking electrodes suggests the presence of a pure double layer capacitance to act at the interface but does not explain the observed depression of the electrode semicircle. Huggins and coworkers' empirical equation fits the experimental data correctly giving a frequency dependent interface impedance. Equivalent circuit parameters for the blocking electrodes (silver and graphite) have been calculated at different temperatures.     

Characteristics of an Electric Dipole in a Plane Waveguide with an Inhomogeneous Filling in the Long-Line Approximation

Within the framework of the long-line approximation, we obtain the expressions for the current distribution, input impedance, and admittance of a nonsymmetric thin electric dipole whose ends are connected to perfectly conducting walls of a plane waveguide filled by an inhomogeneous dielectric. The use of this approximation allows one to qualitatively interpret the results of rigorous solution of the problem of the effect of the medium inhomogeneity on the radiation characteristics of the antenna.     

Impedance characteristics of three-phase electrodes on solid electrolytes

Previously obtained theoretical expressions for the impedance associated with the diffusion of neutral species through a permeable electrode and along the electrode/electrolyte interface are discussed as they apply to gas electrodes on solid electrolytes. A new result, describing diffusion under circular electrode contacts, is obtained. Representative impedance-plane, admittance-plane and Bode-type plots are given for each theoretical model. The effects of rate-controlling adsorption-desorption exchange with the gas phase are considered, as is the applicability of the idealized theoretical models to irregular electrodes.     

Excitation of a cylindrical cavity by a helical current and an axial electron beam current

The explicit expressions (in the Vainshtein and Markov forms) are derived for the excitation of a cylindrical cavity with perfectly conducting walls and with impedance end faces. Excitation of a cylindrical cavity and a cylindrical waveguide with a preset nonuniform axial electron-beam current and a helical current with a variable pitch, which is excited by a concentrated voltage source and is loaded by a preset pointlike matched load, is considered. For the helical current, the integro-differential equation is formulated. The traveling-wave tube (TWT) is simulated in the preset beam current approximation taking into account the nonuniform winding of the spiral coil, nonuniform electron beam, and losses.     

Toward the theory of a loop antenna in an anisotropic plasma

We consider the problem of determining the current distribution along a loop antenna consisting of an infinitely thin perfectly conducting strip coiled into a ring. The antenna is immersed in an anisotropic plasma medium perpendicular to the external magnetic field and is excited by a given EMF. Primary attention is focused on the frequency band in which the excitation of electrostatic waves is possible. The problem is reduced to solving a system of integral equations with logarithmic and singular kernels. Using the solution of these equations, we found expressions for the antenna current distribution and input impedance. The analysis of these expressions is presented. Radiophysical Research Institute, Lobachevsky State University, Nizhny Novgorod, Russia. Translated from izvestiya Vysshikh Uchbnykh Zavedenii, Radiofizika, Vol. 41, No. 3, pp. 358–373, March, 1998.     

Zur kernmagnetischen Relaxation in Mehrbereichsystemen mit endlicher räumlicher Ausdehnung

General equations, describing the nuclear spin relaxation behaviour in heterogeneous systems, consisting of regions with different relaxation times and diffusion coefficients, are presented. For a special two region system, by means of analogue computing technique the influence of both diffusivity and height of the barriers between the regions on total relaxation is studied. It is shown, that using appropriate expressions for the mean lifetimes of the nuclei in the regions, the relaxation function of total magnetisation may be approximated by the formulae of ZIMMERMAN and BRITTIN . These relations may be used for a rough estimation of diffusivity in the systems under consideration.     

Bounded diffusion in solid solution electrode powder compacts. Part I. The interfacial impedance of a solid solution electrode (MxSSE) in contact with a m+-ion conducting electrolyte

The transient and ac electrical response of electrochemical systems containing a solid solution electrode is derived using Laplace transform methods. First, the operational impedance of the electrolyte/solid solution electrode interface is derived, for both asymmetrical and symmetrical cell systems. From the operational impedance the current, voltage and ac impedance response is calculated. By combination of semi-infinite and bounded diffusive behaviour, both the chemical diffusion coefficient of the inserted ions and the thermodynamic factor (? ln a/? ln c) can be obtained from kinetic data only.     

Anomalous diffusion and memory effects on the impedance spectroscopy for finite-length situations

The contribution of ions to the electrical impedance of an electrolytic cell limited by perfect blocking electrodes is determined by considering the role of the anomalous diffusion process and memory effects. Analytical solutions for fractional diffusion equations together with Poisson's equation relating the effective electric field to the net charge density are found. This procedure allows the construction of general expressions for the electrochemical impedance satisfying the Kramers-Kronig relations when the diffusion of ions in the cell is characterized by the usual, as well as by anomalous, behavior.     

Some aspects of polarization in ionic crystals with electrode reactions

Space charge polarization involving an electrode reaction with surface adsorption is examined. As recently demonstrated by Lányi, the presence of such a process may be represented using a complex, frequency-dependent rate constant. Lányi's rate constant is shown to be normally a special case of a more general complex rate constant following from earlier work of Armstrong and others on electrode reactions with an adsorbed intermediate species. An exact expression, based on earlier work of one of the authors, is given for the impedance of a uni-univalent extrinsic-conduction system with mobile charges of only a single sign and for which the electrode processes involve such adsorbed intermediate species. Conditions are then found which reduce the exact results to the approximate expressions for series capacitance and resistance derived by Lányi for his special case of calcium-doped NaCl. These conditions are well satisfied for his specific choices of parameter values. Curves showing the exact frequency response of various series and parallel quantities are presented, together with complex impedance plane results. Finally, it is shown how under conditions that include the range of usual experimental interest the entire space-charge, electron reaction/adsorption system can be well represented by a simple equivalent circuit of frequency-independent elements.     

Co-electrolysis of CO2 and H2O in solid oxide cells: Performance and durability

This study examines the initial performance and durability of a solid oxide cell applied for co-electrolysis of CO₂ and H₂O. Such a cell, when powered by renewable/nuclear energy, could be used to recycle CO₂ into sustainable hydrocarbon fuels. Polarization curves and electrochemical impedance spectroscopy were employed to characterize the initial performance and to break down the cell resistance into the resistance for the specific processes occurring during operation. Transformation of the impedance data to the distribution of relaxation times (DRT) and comparison of measurements taken under systematically varied test conditions enabled clear visual identification of five electrode processes that contribute to the cell resistance. The processes could be assigned to each electrode and to gas concentration effects by examining their dependence on gas composition changes and temperature.This study also introduces the use of the DRT to study cell degradation without relying on a model. The durability was tested at consecutively higher current densities (and corresponding overpotentials). By analyzing the impedance spectra before and after each segment, it was found that at low current density operation (− 0.25 A/cm² segment) degradation at the Ni/YSZ electrode was dominant, whereas at higher current densities (− 0.5 A/cm² and − 1.0 A/cm²), the Ni/YSZ electrode continued to degrade but the serial resistance and degradation at the LSM/YSZ electrode began to also play a major role in the total loss in cell performance. This suggests different degradation mechanisms for high and low current density operation.     

Thermoluminescence in systems not subject to the usual approximations for first and second order kinetics

The properties of thermoluminescence (TL) glow curves have been studied in systems, containing one or more glow peaks, not restricted to the assumptions used to derive the usual first and second order glow peak kinetic expressions. If retrapping is negligible first order glow peaks are obtained whose peak temperature and shape are independent of other factors such as initial trapped charge concentrations. If retrapping occurs, glow peaks are obtained that are, in most cases, only approximated by first or second order kinetics. Also, in these cases the peak temperature, shape, relative intensity and other glow curve characteristics depend strongly on initial trapped charge concentrations, recombination and retrapping cross sections and other factors.     

Mechanical quality factor of high-overtone bulk acoustic resonator

Mechanical quality factor Qm is a key characteristic parameter of High-overtone bulk acoustic resonator(HBAR). The effects of structure parameter(thickness) and perfor?mance parameters(characteristic impedance and mechanical attenuation factor) of substrate,piezoelectric film and electrode constituting HBAR on Qm are carried out. The relationships between Qm and these parameters are obtained by a lumped parameter equivalent circuit instead of distributed parameter equivalent circuit near the resonance frequency, and the an?alytical expressions oi Qm are given. The results show that Qm increases non-monotonically with the continuous increase of the substrate thickness for HBAR with certain piezoelectric film thickness, and it approaches to the substrate material mechanical quality factor as the substrate thickness is large. Qm decreases wavily with the continuous increase of the piezoelectric film thickness for HBAR with certain substrate thickness. Sapphire and YAG with low mechanical loss are appropriate as the substrate to get a larger Qm- The electrode loss must be considered since it can reduce Qm- Compared with Au electrode, A1 electrode with lower loss can obtain higher Qm when the appropriate electrode thickness is selected. In addition, Qm decreases with the increase of frequency. These results provide the theoretical basis for optimizing the parameters of HBAR and show that trade-oflFs between Qm and must be considered in the design because their changes are often inconsistent.     

电化学阻抗谱在本科实验教学中的应用

电化学阻抗谱是常用的一种电化学测试技术,该方法具有频率范围广、对体系扰动小的特点,是研究电极过程动力学、电极表面现象以及测定固体电解质导电率的重要工具。本文以固体氧化物燃料电池的电化学阻抗谱的测试为例设计了一套在线分析电化学阻抗的应用课程。介绍了电化学阻抗谱的原理,数据采集方法和数据处理方法,阐述了电化学阻抗谱技术在本科实验教学中的可行性和重要性。     

肖特基钙钛矿太阳电池结构设计与优化

有机-无机杂化钙钛矿材料有高吸收系数、低廉的制作成本以及较为简单的制备工艺,在近年来表现出良好的发展前景.本文采用wx-AMPS模拟软件对平面结构钙钛矿太阳电池和肖特基钙钛矿太阳电池进行建模仿真对比,从理论上分析无载流子传输层的肖特基钙钛矿太阳电池的优势.结果显示,器件两侧电极功函数和吸收层的能带分布是提高太阳电池效率的关键.在对电极使用Au(功函数为5.1 eV)的前提下,透明导电电极功函数为3.8 eV,可以得到肖特基钙钛矿太阳电池转换效率为17.93%.对器件模型吸收层进行优化,通过寻找合适的掺杂浓度,抑制缺陷密度,确定合适的厚度,可以获得理想的转换效率(20.01%),是平面异质结结构(理论转换效率31%)的63.84%.肖特基钙钛矿太阳电池在简单的器件结构下可以获得优异的光电性能,具有较好的应用潜力.     

Measurement of electrode overpotentials for direct hydrocarbon conversion fuel cells

Cathodic and anodic overpotentials were measured using current interruption and AC impedance spectroscopy for two separate solid oxide fuel cells (SOFCs). The fuel cells used yttria-stabilized zirconia (YSZ) as the electrolyte, strontium-doped lanthanum manganite (LSM) as the cathode, and a porous YSZ layer impregnated with copper and ceria as the anode. The Cu/CeO₂/YSZ anode is active for the direct conversion of hydrocarbon fuels. Overpotentials measured using both current interruption and impedance spectroscopy for the fuel cell operating at 700 °C on both hydrogen and n-butane fuels are reported. In addition to providing the first electrode overpotential measurements for direct conversion fuel cells with Cu-based anodes, the results demonstrate that there may be significant uncertainties in measurements of electrode overpotentials for systems where there is a large difference between the characteristic frequencies of the anode and cathode processes and/or complex electrode kinetics.     

A simplified model of mouth radiation impedance closed by mask cavity

Acoustic radiation impedance of the mouth is an important parameter when the vocal tract is modelled by the equivalent electrical circuit. If the vocal tract is closed by a cavity, as when the speaker wears some kind of mask, total impedance acoustically loading the vocal tract becomes serial connection of the mouth radiation impedance and the mask impedance. In that case the mouth radiation impedance has to be changed compared to free field conditions. This paper introduces a simplified approach to the modelling of that change by an appropriate reduction coefficient. The analysis based on an experiment preformed by measurement in the vocal tract physical model accompanied with analytical estimation has shown that the value of such reduction coefficient is 0.5. The results reveal that for a vocal tract closed with mask cavity the change in mouth radiation impedance introduced in an equivalent electrical circuit can be approximated by the value for free field radiation decreased by about 50%.