Temperature Effects in the Raman Spectrum of Solid Orthocarborane

Abstract

Variable temperature studies of the laser Raman spectrum of solid orthocarborane indicate a change in the line widths of the peaks in the observed frequency region from 745 cm^?1 to 815 cm^?1. A marked change in the line width of the 807 cm^?1 peak around 4°C confirms recently observed anomalies in the NMR spectrum at this temperature.     

Antiferromagnetic resonance in Bi2CuO4

Magnetic resonance of the low-frequency spin-wave branch in the Bi₂CuO₄ antiferromagnet with an easy-plane anisotropy has been studied. Angular, frequency, and temperature dependences of the position and width of the antiferromagnetic resonance (AFMR) line have been measured. Our measurements combined with earlier data [H. Ochta, K. Yoshida, T. Matsuya, T. Nanba, M. Motokawa, K. Yamada, Y. Endon, and S. Hosoya, J. Phys. Soc. Jpn. 61, 2921 (1992); E. W. Ong, G. H. Kwei, R. A. Robinson, B. L. Ramakrishna, and R. B. von Dreele, Phys. Rev. B 42, 4255 (1990) [ have allowed us to determine anisotropy constants of this material and to account for the unusual character of its static susceptibility anisotropy. The AFMR line shifts to the high-field side and broadens in a temperature range of 10–15 K, and the cause of this has remained unclear. In the low-temperature range the line shows a hysteresis corresponding to a static field magnitude several times as large as the spin-flop field. The position and width of the AFMR line depend sensitively on the sample preparation technique. Zh. éksp. Teor. Fiz. 113, 2244–2255 (June 1998)     

Dependence of the intrinsic line width of surface states on the wave vector: The Cu(111) and Ag(111) surfaces

The dependence of the intrinsic line width Γ of electron and hole states due to inelastic scattering on the wave vector k _∥ in the occupied surface state and the first image potential state on the Cu(111) and Ag(111) surfaces has been calculated using the GW approximation, which simulates the self-energy of the quasiparticles by the product of the Greens’s function and the dynamically screened Coulomb potential. Different contributions to the relaxation of electron and hole excitations have been analyzed. It has been demonstrated that, for both surfaces, the main channel of relaxation of holes in the occupied surface states is intraband scattering and that, for electrons in the image potential states, the interband transitions play a decisive role. A sharp decrease in the intrinsic line width of the hole state with an increase in k _∥ is caused by a decrease in the number of final states, whereas an increase in Γ of the image potential state is predominantly determined by an increase of its overlap with bulk states.     

Detection of a scatter target over a randomly rough surface by using the angular correlation function in a finite-element approach

Abstract

It is known that the angular correlation function of scattered fields from a randomly rough surface has a conspicuous enhancement on the memory line, and becomes much smaller away from the line. The finite-element method is employed to solve the problem of scattering from a scatter target situated over a randomly rough surface. Numerical results show that the width of the angular correlation function becomes broadened owing to the presence of the target. It can be used to detect the presence of a target placed over the rough surface.     

Lattice damage and Al-metal precipitation in 2.5 MeV-electron-irradiated AlH3

AlH₃ powder was bombarded with energetic electrons at 20 K and at room temperature and investigated by EPR, NMR, X-ray diffractometry, and microwave dielectric-constant measurements. The EPR spectra of the irradiated powder and of a selected single crystal cuboid of mm edge show a complex asymmetric line centered at g = 2.009, with a Curie-like temperature dependence, attributed to radiation-induced color centers and/or their agglomerates. At the same time, the grains, which have become shiny black after irradiation, exhibit an increase of both the real and the imaginary part of . ²⁷Al-NMR spectra of the irradiated powder present a Knight-shifted line at 1600(50) ppm, close to the position of bulk metallic Al, and corresponding to a concentration of c(Al) . In addition, the main hydride line differs from that before irradiation, demonstrating an alteration of environmental symmetry. The irradiation induces also a change in shape and width of the ¹H-NMR line, another indication of symmetry change in the lattice. Finally, a refined X-ray single-crystal structure analysis of the irradiated cuboid indicates a change of structure from trigonal R -3 c to R -3, with a loss of mirror symmetry for the two Al sites caused by the introduction of Al-defects in the vicinity of one of them. Received: 20 October 1997 / Revised: 24 December 1997 / Accepted: 30 January 1998     

Critical behavior of electron spin resonance in La0.8Sr0.2MnO3 — a material with colossal magnetoresistance

High-frequency absorption in the colossal magnetoresistance material La_0.8Sr_0.2MnO₃ is investigated near the critical temperature in a magnetic field. The temperature dependences of the width, position, and intensity of the ESR line are studied in the near-critical region. Pis’fma Zh. éksp. Teor. Fiz. 67, No. 12, 1000–1004 (25 June 1998)     

Interaction of optical phonons with anisotropic imperfections

Inelastic (Raman) light scattering by phonons interacting with anisotropic imperfections is investigated. Three different kind of disorder-induced defects (point, linear and planar) have been considered. The optical phonon width and line shape are found to depend importantly on the dimension of the imperfections. There is a close correspondence between the scale of the imperfection and the phonon line shape observed in the Raman scattering experiments. The dependence of the phonon frequency shift and width on the defect concentrations is calculated, and the critical concentrations at which the optical phonon can no longer be observed are determined. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 12, 817–822 (25 December 1997) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Power broadening of a diffusion resonance

We derive an expression in terms of cylinder functions for the shape of a nonlinear resonance in a two-level system with a rapidly decaying level. We show that when the natural linewidth is negligible, the square of the total width is the sum of squares of the power and diffusion widths. The traditional variational approximation yields a correct value for the full width at half maximum, but distorts the line profile. We derive a formula for the absorbed power as a function of the incident wave intensity for comparable power and diffusion broadening. The formula is found to be valid for a power width that is small or large compared to the diffusion width, and in a new intermediate domain where homogeneous saturation becomes inhomogeneous. Zh. éksp. Teor. Fiz. 113, 1632–1648 (May 1998)     

Diode laser spectroscopic measurement and impact theoretical analysis of collision broadening of acetylene band transitions

A near infrared diode laser spectrometer has been used for measurement of line shapes of the rotational transitions of the () overtone-combination band of acetylene perturbed by oxygen and air. Pressure-broadening coefficients and line strength parameters are extracted from least squares fitting of the spectra with Voigt profiles. A detailed calculation of pressure-broadening coefficients for the self, nitrogen and oxygen broadening cases has been performed by using semi-classical impact theory based on quadrupolar and dispersion interactions. The relative importance of the intermolecular interactions has been investigated and it is found that for these weak interaction cases dispersive terms have a dominant role in line broadening. This is more pronounced for the O₂-broadening case. We have included all the non-resonant terms till convergence is achieved. The cutoff parameter b₀ of the Anderson procedure has been determined separately for each non-resonant process. In order to include the orientation effect of the molecules at the moment of collision we have considered an average kinetic collision diameter which sets the lower limit of b₀. This improves the result considerably and the calculated values are close to the observed results. The J-dependence of the half width is also reported and shows decrease for large J-values. Received 24 November 1999     

Effect of dispersion of orthorhombic anisotropy fields on the ferromagnetic resonance linewidth in iron garnet films

The effect of the dispersion of anisotropy fields on the width of the ferromagnetic resonance line is calculated in films with orthorhombic anisotropy. The results of the calculation, based on a model of linear variation of the anisotropy fields with thickness and on the assumption of additivity of the different contributions to the resulting linewidth, are in good agreement with experimental results. Zh. Tekh. Fiz. 67, 131–134 (August 1997)     

Pressure induced effects in forsixrite monitored by ESR

Summary

Chromium doped single crystals of Forsterite where investigated directly under the influence of uniaxial pressure in situ by ESR. The two Cr³⁺ centres M₁ and M₂ exhibit distinct response to the action of pressure on the crystal as a whole. The pressure effects are manifested in remarkable changes of the line width of the fine structure transitions. Uniaxial pressure in the MPa range induces nearly symmetrical distribution of distortions of the coordination polyhedra of the Cr³⁺ centres accompanied by reorientation effects.     

Spin-spin and spin-lattice relaxation of nitrogen in electron irradiated and annealed synthetic diamond

Transient nutation ESR spectroscopy has been used to study the broadening of isolated lines in the triplet of P1 nitrogen centers in disperse synthetic diamond bombarded by electrons and annealed at 670–1070 K. On the basis of measurements of the spin-spin relaxation time, it was established that at nitrogen concentrations up to 1.2×10¹⁹ cm⁻³ the homogeneous line width is caused by dipole interaction between the nitrogen atoms and exchange interactions make no contribution. Fiz. Tverd. Tela (St. Petersburg) 40, 1235–1237 (July 1998)     

Exchange interactions of excitons localized at opposite interfaces in type-II GaAs/AlAs superlattices: Optically detected magnetic resonance and level anticrossing

Two types of excitons, localized at opposite interfaces and characterized by different magnitudes of the exchange interactions at the same radiation energies, are simultaneously in type-II GaAs/AlAs superlattices. It is shown that the additional long-wavelength luminescence line in superlattices grown with growth interruptions after the GaAs layers is due to the recombination of an exciton localized at an inverted interface in regions where the quantum-well width is increased by one monolayer. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 10, 701–706 (25 November 1996)     

Grating-Stabilized External Cavity Diode Lasers for Raman Spectroscopy—A Review

Abstract: Conventional Raman techniques require a continuous-wave laser with stabilized wavelength, narrow line width, and sufficient output power. Due to their miniature size and low cost, diode lasers are good choice as light sources for Raman spectroscopy, especially when compact and portable instruments are needed. However, a solitary multimode diode laser has certain drawbacks that limit its use for Raman application. To circumvent these drawbacks, an external cavity can be coupled to the active gain medium of the diode to enhance the laser performance. A grating-based external cavity allows the laser to operate in a single longitudinal mode with greatly reduced line width and stabilized wavelength. This article examines the fundamentals of semiconductor lasers to show the necessity of operating diode lasers in an external cavity for Raman applications. Two feedback grating-based external cavity diode laser (ECDL) designs, viz. Littrow and Littman-Metcalf configurations, are explained. Historic and recent progress in the development of ECDL devices is reported. An updated summary of ECDL-equipped Raman systems applied to fields such as in vivo biomedical studies and in situ process/quality control is provided. Topics on mode-hop-free continuous scanning, wavelength stabilization, and dealing with ambient conditions are discussed.     

Luminescence of excitons in slightly asymmetric double quantum wells

We report the first studies of exciton luminescence spectra from asymmetric double quantum wells (DQWs) of very similar width. The DQWs were of GaAs/AlGaAs and the differences in widths of the coupled wells were one or two monolayers. The coupled direct and indirect exciton states anticross with a resonance splitting of 1.33 meV. An additional luminescence line appearing at low temperatures is identified as a localized indirect exciton. Fiz. Tverd. Tela (St. Petersburg) 39, 735–739 (April 1997)     

Zur Untersuchung von Versetzungen mit Hilfe der magnetischen Kernresonanz

The line width of the nmr signal is obtained for a statistical distribution of distances and orientations of dislocations as a function of the dislocation density. The quadrupolar part of the line width increases proportional to the root of the dislocation density in the case of first order distortion but is proportional to the dislocation density itself in the case of second order distortion. The total line width passes through a maximum within the range of first order distortion and approaches the value of the undistorted central line which arises from magnetic dipole interaction when the dislocation density becomes sufficiently large. The intensity decay of the nmr signal connected with this line width behaviour will also be presented. In the range of second order distortion the total line width is determined by the constant dipole interaction and the quadrupole interaction of the central line which depends on the dislocation density. Under the assumption of a Gaussian distribution for the line shape a simple expression for this width can be obtained. The calculations are checked for the case of first order distortion by measurements on the Na²³ and Cl³⁵ nmr signals of NaCl single crystals and for the case of second order distortion by measurements on the J¹²⁷ signal of KJ single crystals.     

Emission from a slab of resonant two-level atoms induced by a delta-pulse excitation

Using eigenmode analysis I calculate in the linear regime the emission characteristics from a slab of two-level resonant atoms excited by a delta-pulse propagating normal to the surface of the slab. I show that the qualitative features of the emitted spectra in the forward and backward directions to be different from each other; I also find the effects of the total linewidth of the resonance line and of the deviation in the spatial periodicity of the initial atomic polarization from k ₀, where k ₀ = ω₀/c and ω₀ is the two level resonant frequency, on the spectra. The dominant spatial mode of the system is identified as the key parameter for determining the forward emission spectral width.     

Cooperative population dynamics of an ensemble of Λ atoms in a bichromatic field

Equations are derived which describe the dynamics of three-level atoms with a Λ level scheme, interacting with two coherent resonance fields under conditions such that cooperative relaxation predominates over incoherent spontaneous emission. A numerical calculation of the temporal dynamics of the values of the atomic populations is performed. It is shown that coherent population trapping in the presence of cooperative decay is possible. The quantities characterizing this phenomenon are calculated—the width of the black line and the transition time to coherent trapping in this scheme. Zh. Tekh. Fiz. 68, 19–24 (June 1998)     

MC model of Auger spectra from highly charged ion beam surface interaction

Abstract

A Monte Carlo code is described which simulates angle resolved Auger electron energy spectra from highly charged ion surface interaction. The combined effect of the Doppler spread of laboratory emission energy and electron scattering by the solid, together with the broad inherent line width, is found to have considerable influence on the spectral lines. As a new feature, low or high energy shoulders can appear. By comparison between simulated and measured spectra information on the kinematic and electronic state of the projectile ions in the moment of electron emission can be extracted. The standard method of spectrum analysis, which is based on the assumption of direct escape of the electrons, is evaluated with respect to the simulated spectra.     

Observation of a hybridization gap in cyclotron resonance spectra of semimetallic InAs/GaSb quantum wells

Splitting of the cyclotron resonance (CR) line is observed in the electron CR spectra of InAs/GaSb heterostructures containing tunneling-coupled electron and hole layers. This splitting is interpreted to be a manifestation of a hybridization gap arising as a result of anticrossing of the Landau levels of electrons and holes when their wave functions overlap. The energy splitting of the CR lines is correlated with the magnitude of the overlap and agrees with theoretical estimates of the hybridization gap width. Pis’ma Zh. éksp. Teor. Fiz. 69, No. 4, 313–317 (25 February 1999)