Diode-pumped doubly passively Q-switched c-cut Nd:GdVO4 1.34 μm laser with V:YAG and Co:LMA saturable absorbers

By simultaneously using both V³⁺:YAG and Co:LMA saturable absorbers in the cavity, a diode-pumped doubly passively Q-switched c-cut Nd:GdVO₄ laser at 1.34 μm is demonstrated for the first time. The average output power, the pulse width and the pulse repetition rate have been measured. The experimental results show that the doubly passively Q-switched laser can generate shorter pulse width with higher peak power in comparison to the singly passively Q-switched laser only with V³⁺:YAG or Co:LMA saturable absorber. At the pump power 13 W, the pulse width has been compressed 83% and the peak power has been improved 15 times, respectively.     

CW and passive Q-switching of 1331-nm Nd:GGG laser with Co<Superscript>2+</Superscript>:LMA saturable absorber

In this paper, the output performances at 1331 nm in continuous-wave (CW) operation and the passive Q-switching regime of a Nd:Gd₃Ga₅O₁₂(Nd:GGG) laser crystal have been investigated under pumping with diode lasers. A maximum CW output power of 1.5 W was reached at an incident pump power of 7.5 W; the overall optical-to-optical efficiency and the slope efficiency with respect to the pump power were 21.5% and 19.4%, respectively. The passive Q-switching regime was achieved with Co²⁺:LaMgAl₁₁O₁₉ (Co²⁺:LMA) saturable absorber (SA) crystals. A maximum average output power of 183 mW was recorded with a Co²⁺:LMA SA with initial transmission T _i of 90%. The pulse energy was 18.7 μJ and the pulse duration was 26.1 ns, which correspond to a pulse peak power of 0.7 kW. With a Co²⁺:LMA SA with T _i=81%, the average power decreased to 131 mW. However, the pulse energy increased to 21.4 μJ, the pulse duration was 16.4 ns and the pulse peak power increased to 1.3 kW.     

Structure and phase composition of thin a-C:H films modified by Ag and Ti

The structure and phase composition of thin a-C:H and a-C:H〈M〉 films (M = Ag, Ti, or Ag + Ti) have been studied by Raman and X-ray photoelectron spectroscopy. The a-C:H〈M〉 films were prepared by ion-plasma magnetron sputtering of a combined target of graphite and metal in an Ar–CH₄ gas mixture. The Raman spectra of these films indicate that their structure is amorphous. The a-C:H〈Ag + Ti〉 films have a more graphitized structure in comparison with pure a-C:H films and films containing only one metal. It is established that carbon in the a-C:H〈Ag + Ti〉 films is in the sp ², sp ³, and C=O states, which are characteristic of the a-C:H, a-C:H〈Ag〉, and a-C:H〈Ti〉 films. In addition, there are also ether (–C–O–C–) or epoxy (?C?O–) carbon groups in the a-C:H〈Ag + Ti〉 films. It has been revealed that silver atoms in the a-C:H〈Ag〉 and a-C:H〈Ag + Ti〉 films form no chemical bonds with carbon, oxygen, and titanium. Titanium in the a-C:H〈Ti〉 and a-C:H〈Ag + Ti〉 films exists in the form of titanium IV oxide (TiO₂).     

Mössbauer spectrum of Baotite

Baotite Ba₄{(Ti, Nb, Fe)₈[Si₄O₁₂O₁₆}Cl is a four-membered ring silicate. Two sets of quadrupole doublets were obtained from the Mössbauer spectrum. The A doublet is caused by Fe³⁺ in the Ti?O octahedra (I.S.=0.389 mm/s, Q.S.=0.636 mm/s, Γ=0.602 mm/s, A/GSA=0.569), whereas the B doublet reflects Fe²⁺ in the octahedra (I.S.=1.029 mm/s, Q.S.=2.632 mm/s.). Fe³⁺/Fe²⁺=1.32. The spectrum indicates that: (1) both Fe³⁺ and Fe²⁺ are present in Baotite; (2) Fe³⁺ and Fe²⁺ exist as isomorphs in the Ti?O octahedra.     

Co2+:LMA crystal as saturable absorber for a diode-pumped passively Q-switched Nd:YVO4 laser at 1342 nm

We have demonstrated an efficient diode-pumped passively Q-switched Nd:YVO₄ laser at 1342 nm by using an uncoated Co²⁺:LaMgAl₁₁O₁₉ (Co²⁺:LMA) crystal as the saturable absorber. With the absorbed pump power of 11.7 W, the pulse width could be as low as 42 ns, with a corresponding average output power of 580 mW. At around 40 kHz repetition rate, the energy of a single Q-switched pulse was estimated to be about 14.5 μJ and the peak power was 346 W. The passive Q switching operation for the Co²⁺:LMA in different polarization states was also investigated. PACS 42.55.-f; 42.55.Xi; 42.60.Gd; 42.70.Mp     

Nd:LMA自锁模飞秒激光器腔结构最佳化设计

Nd:LMA晶体相对低的非线性折射率n₂,使得针对Ti:Sapphire自锁模激光器设计的腔,对Nd:LMA介质而言并没有提供足够的自幅度调制(SAM).为了在Nd:LMA激光器上实现自锁模,在腔内引入一个具有大的非线性系数n₂、快的响应时间的SF57介质,这样就使得激光腔的结构比较特殊.在这篇文章里利用ABCD传输矩阵对该激光器的结构从理论上进行了分析和计算,使腔结构达到了最佳化设计.     

Hyperfine structure and isotope shift measurements on 4d10 1S0 → 4d9 5p J=1 transitions in Pd I using deep-UV cw laser spectroscopy

The 4 d ^{10 1} S₀ ground-state transitions to the 4 d ⁹ 5 p configuration of palladium (Pd) have been studied. For this purpose, a tunable, single-mode, deep-UV cw laser has been built to generate the sum frequency of a frequency-doubled Ti:S laser with a second Ti:S laser. The produced wavelengths range from 244 to 276 nm. From the measured spectra the frequency splitting due to hyperfine structure and isotope shift, the hyperfine structure A and B constants and the lifetimes of the states have been extracted. Received 3 October 2001     

Doubly passively Q-switched laser with V<Superscript>3+</Superscript>:YAG and Co:LMA saturable absorbers

By using both V³⁺:YAG and Co:LMA saturable absorbers, a doubly passively Q-switched laser is realized for the first time. The shorter pulse with the higher peak power is generated in comparison to the singly passively Q-switched laser with V³⁺:YAG or Co:LMA saturable absorber. The experimental results shows that it is possible to obtain a shorter pulse with the higher peak power in a doubly passively Q-switched laser.     

Further EPR study of paramagnetic Cr3+ centers in KTiOPO4

Careful reanalysis of EPR spectra of Cr³⁺ ions in KTiOPO₄ has been carried out in order to resolve the weaker lines not considered in our previous study. Two additional centers denoted as C and D have now been identified and the respective spin Hamiltonian parameters have been determined. The reanalysis of the results for the centers A and B identified previously and those for the new centers C and D indicates that the centers A and C originate from Cr³⁺ ions at Ti(2) sites, whereas the centers B and D originate from Cr³⁺ ions at Ti(1) sites. Sixteen magnetically inequivalent Cr³⁺ sites are assigned to two crystallographically different titanium sites: Ti(1) and Ti(2). Possible charge compensation models for the two different centers arising from Cr³⁺ ions at each of the two Ti sites are also suggested.     

A comparative study of cationic distribution in the systems Li1+5XM1−XO3 and Li1+XM1−XM′ XO3 (M=Nb,M′=Ti; M=Ta,M′=Ti,Zr, Sn)

Abstract

A comparative ferroelectric and NMR studies of the systems Li_1+5X M_1?XO₃ and Li_1+XM_1?XM^′ _XO₃ (M=Nb, M′=Ti M = Ta; M′=Ti, Zr, Sn) have indicated that plot of T_C versus composition can be qualitatively explained on the basis of cationic distribution. The strong drop of T_C has been found in systems with all cations in octahedral sites, whereas little change of T_C was observed along the solid solutions with Li-ions in interstitial tetrahedral sites.     

Doubly passively Q-switched and mode-locked laser with V<Superscript>3+</Superscript>:YAG and Co:LMA saturable absorbers

By using both V³⁺:YAG and Co:LMA saturable absorbers, an xenon-lamp-pumped doubly passively Q-switched and mode-locked (QML) Nd:YAG laser at 1.3 μm in a straight cavity is realized for the first time. The modulation depth of QML pulse has nearly reached 100%. The experimental results shows that the doubly passively Q-switched and mode-locked (QML) laser can generate shorter Q-switch envelope pulse with higher average peak power in comparison to the singly passively QML laser with V³⁺:YAG or Co:LMA saturable absorber.     

Effect of pressure and interstitial atoms on magnetic properties of LuFe11Ti Intermetallics

Magnetisation and magnetocrystalline anisotropy of the LuFe₁₁Ti intermetallics have been studied under pressure up to 1.2 GPa in temperatures from 5 K to 350 K using a miniature CuBe pressure cell and a SQUID magnetometer. A decrease of Fe-moment under pressure is compatible with the increase of Fe-moment in hydride and nitride of LuFe₁₁Ti. A complex dependence of magnetocrystalline anisotropy on volume of the elementary crystal cell of LuFe₁₁Ti and its hydride and nitride has been observed.     

Austauschwechselwirkungen,Intrabandschwingungen und Ti3+-Kristallfeldaufspaltung in dotiertem Al2O3

The absorption spectra of ruby with various Cr concentrations have been studied in the wavelength region between 50 μ and 1 mm at liquid helium and nitrogen temperatures. At liquid helium temperatures two strong absorptions have been found at 37.7 and 106 cm^?1 and weak absorptions at 18.8, 30.7, 33.2 and 43.0 cm^?1. These lines depend on the Cr concentration and vanish at N₂ temperatures. The two strong absorptions have also been observed in Al₂O₃ crystals doped with Ti or V. Sapphire did not show any of these absorptions. The origin of the two strong absorptions in Al₂O₃ crystals doped with Ti, V or Cr are discussed by consideration of magnetic dipole transitions of exchange coupled Cr³⁺ - pairs, the crystal field splitting of Ti³⁺ impurities and impurity — induced lattice modes. The weak absorption lines, on the other hand, may be assigned to transitions between the exchange levels of the second-nearest and fourth-nearest Cr³⁺ pairs if one makes use of the data obtained from the EPR and fluorescence spectra. For the second-nearest Cr³⁺ pairs group theory of the exchange interaction predicts transitions withΔS=2, whereas for the fourth-nearest neighbours no restriction forΔS exists.     

Investigation of formation mechanism of Ti3SiC2 by high pressure and high-temperature synthesis

ABSTRACT

In this paper, synthesis of titanium silicon carbide (Ti₃SiC₂) under high pressure and high-temperature condition has been investigated by using the reactant systems Ti/Si/C, Ti/SiC/TiC, Ti/SiC/C and Ti/TiC/Si. Results reveal that Ti/TiC/Si is unsuited to the synthesis of Ti₃SiC₂ under a high pressure of 2.0?GPa, while an elemental mixture of Ti/Si/C is applicable. By the addition of Al, Ti₃SiC₂ with 95.8?wt% purity was obtained from elemental mixture with a large excess of silicon. The optimum experimental parameters were determined as Ti/Si/Al/C having the molar ratio of 3:1.5:0.5:1.9, holding at 2.0?GPa and 1300?°C for 60?min.     

Gap levels of Ti<Superscript>3+</Superscript> on Nb or Li sites in LiNbO<Subscript>3</Subscript>:(Mg):Ti crystals and their effect on charge transfer processes

The Ti dopant occupying Li or Nb sites and the charge transfer processes induced by thermochemical reduction and optical bleaching treatments have been investigated in LiNbO₃ systems using optical absorption and EPR. The Ti³⁺ centers, built preferentially at Nb sites in heavily Mg-codoped crystals, are shown to have absorption bands at 1.62±0.08 eV and 2.65±0.25 eV, which are similar or slightly redshifted compared to Ti³⁺ centers at Li sites in LiNbO₃:Ti crystals. The Ti_Nb^4+/3+ gap level plays an important role in the trapping of electron-polarons in LiNbO₃, double-doped with Mg and Ti; in particular, an enhanced optical detrapping sensitivity for pumping in the 1.3–2.8 eV range is observed, which may be relevant for applications in integrated optics. Evidence indicating the possible existence of bipolarons involving the Ti dopant is presented. PACS 77.84.Dy; 71.55.Ht; 71.38.-Mx; 78.40.Ha; 76.30.Fc     

Study of very neutron deficient nuclei 178Pt and 181Au

The ¹⁷⁸Pt and ¹⁸¹Au nuclei have been studied with the (230 MeV) ⁴⁶Ti +¹⁴²Nd fusion-evaporation reaction; γ-rays, evaporated particles and recoiling nuclei have been detected by the γ-array GASP + the Si ball ISIS + the recoil mass spectrometer RMS. The newly observed structures in ¹⁷⁸Pt and ¹⁸¹Au are most probably built on the proton and quasi-proton h_9/2 and i_13/2 configurations. Received: 2 January 1998 / Revised version: 27 May 1998     

Electronic structure studies of Mg0.95Mn0.05Fe2−2xTi2xO4 (0x0.8)

The electronic structure of Mg_0.95Mn_0.05Fe_2−2xTi_2xO₄ (0x0.8) compound is investigated using near edge X-ray absorption fine structure, (NEXAFS) spectroscopy measurements, carried out at O K, Fe and Ti L_3,2-edges at room temperature. The O K-edge spectra indicate that the Fe 3d orbitals have been considerably modified and a new spectral feature start dominating in the pre-edge region at higher Ti doping. The Fe 2p NEXAFS spectra exhibit a mixed valent Fe²⁺/Fe³⁺ states apart from the conversion of Fe³⁺ to Fe²⁺ with the substitution of Ti ions. The Ti L_3,2-edge spectra indicate that Ti ions remain unchanged at 4+ state. These variations in the host electronic structure due to Ti substitution are consistent with the dielectric and transport properties of the material.     

Mössbauer investigation of temperature transformations in bacterial ferrihydrite

Ferrihydrite nanoparticles formed as a result of the microorganism activity have been studied using Mössbauer spectroscopy, X-ray powder diffraction analysis, and X-ray fluorescence analysis. Three positions of trivalent iron with nonoverlapping ranges of quadrupole splittings have been revealed in bacterial ferrihydrite: QS{Fe³⁺(1)} = 0.49–0.83 mm/s, QS{Fe³⁺(2)} = 0.84–1.10 mm/s, and QS{Fe³⁺(3)} = 1.25–1.73 mm/s. It has been experimentally demonstrated that the Fe³⁺(3) positions are the centers of nucleation of the hematite phase in the course of heat treatment.     

Synthesis and characterization of mixed-valence barium titanates

A single-crystal barium oxotitanate(III, IV) of approximate composition , containing mixed-valence Ti, was grown from a borate flux. The crystal structure was identified as hollandite type by single-crystal X-ray diffractometry. Electron-energy-loss spectroscopy of Ti L 2,3 and O K edges was used to determine chemical shifts related to the presence of mixed-valence Ti in the crystal. Comparison of Ti L 2,3 and O K energy-loss near-edge structure (ELNES) of with those obtained from a K 1.54 Mg 0.77 Ti 7.23 O 16 single crystal with hollandite structure, containing only Ti 4+ , revealed a shift in the Ti L 2,3 edge by 0.4-0.5 eV towards lower energy losses whereas only slight intensity variations without a detectable energy shift of the edge onset occur at the O K ELNES. In addition, valence-specific multiplet structures of the Ti L 23 ELNES are used as valence fingerprints. The observed fine structures of O K and Ti L 2,3 edges can be used to interpret coordination and bonding in related compounds.     

全固化自锁模飞秒Ti:S激光器实验研究

首次在国内系统报道了以腔内LBO倍频Nd:YVO₄激光器为泵浦源的全固化自锁模飞秒钛宝石激光器的实验结果.设计了一种热不敏腔内LBO倍频线性折叠腔结构,获得到了25.5%的光转换效率,泵浦功率为22W时得到了5.6W的基模绿光输出功率;以该激光器为泵浦源,在线性Z型腔的基础上,使用了一种能够通过改变腔内凹面聚焦镜折叠角消除象散的方法,直接由钛宝石激光器得到了脉冲宽度为22fs、功率为300mW的光脉冲.整个激光系统稳定性好,噪音明显低于Ar³⁺激光器的泵浦情况.