Suspended Particles Transport and Deposition in Saturated Granular Porous Medium: Particle Size Effects

An experimental study on the transport and deposition of suspended particles (SP) in a saturated porous medium (calibrated sand) was undertaken. The influence of the size distribution of the SP under different flow rates is explored. To achieve this objective, three populations with different particles size distributions were selected. The median diameter $d_{50}$ of these populations was 3.5, 9.5, and $18.3~\upmu \hbox {m}$ . To study the effect of polydispersivity, a fourth population noted “Mixture” ( $d_{50} = 17.4\; \upmu \hbox {m}$ ) obtained by mixing in equal proportion (volume) the populations 3.5 and $18.3\;\upmu \hbox {m}$ was also used. The SP transfer was compared to the dissolved tracer (DT) one. Short pulse was the technique used to perform the SP and the DT injection in a column filled with the porous medium. The breakthrough curves were competently described with the analytical solution of a convection–dispersion equation with first-order deposition kinetics. The results showed that the transport of the SP was less rapid than the transport of the DT whatever the flow velocity and the size distribution of the injected SP. The mean diameter of the recovered particles increases with flow rate. The longitudinal dispersion increases, respectively, with the increasing of the flow rates and the SP size distribution. The SP were more dispersive in the porous medium than the DT. The results further showed that the deposition kinetics depends strongly on the size of the particle transported and their distribution.     

Coupled Effects of Ionic Strength,Particle Size,and Flow Velocity on Transport and Deposition of Suspended Particles in Saturated Porous Media

In this study, the coupled effect of ionic strength, particle size, and flow velocity on transport and deposition of suspended particles (SP) in saturated sand was undertaken. Three polydispersive SP populations (silt particles with the median of 3.5, 9.5 and 18.3 \(\upmu \)m) were investigated using a pulse injection technique. High ionic strengths were used and vary from 0 to 600 mM (NaCl). Two high velocities were tested: 0.15 and 0.30 cm/s. Suspended particles recovery and deposition kinetics were strongly dependent on the solution chemistry, the hydrodynamics, and the suspended particles size, with greater deposition occurring for increasing ionic strength, lower flow velocity, and larger ratios of the median diameter of the SP to the median sand grain diameter. A shift between the extended Derjaguin–Landau–Verwey–Overbeek theory prediction (the particles and sand grain surfaces are considered chemically and topographically homogeneous) and the experimental results for certain ionic strength was observed. So, as reported in recent literature, effects of surface heterogeneities should be considered. The residence time of the non-captured particles is dependent on ionic strength and hydrodynamic. A relationship between the deposition kinetics, particle and grain sizes, flow velocity, and ionic strength is proposed.     

Analytical Solutions for Macrodispersion in a 3D Heterogeneous Porous Medium with Random Hydraulic Conductivity and Dispersivity

A stochastic analysis of macrodispersion for conservative solute transport in three-dimension (3D) heterogeneous statistically isotropic and anisotropic porous media when both hydraulic conductivity and local dispersivity are random is presented. Analytical expressions of macrodispersivity are derived using Laplace and Fourier transforms. The effects of various parameters such as ratio of transverse to longitudinal local dispersivity, correlation length ratio, correlation coefficient and direction of flow on asymptotic macrodispersion are studied. The behaviour of growth of macrodispersivity in preasymptotic stage is also shown in this paper. The variation in local dispersion coefficient causes change in transverse macrodispersivity. The consideration of random dispersivity along with random hydraulic conductivity indicates that the total dispersion is affected and important in the case when the hydraulic conductivity and dispersivity are correlated. It is observed that the pre-asymptotic behavior of the macrodispersivity is not sensitive to the choice of spectral density functions.     

Three-Dimensional Analytical Models for Virus Transport in Saturated Porous Media

Analytical models for virus transport in saturated, homogeneous porous media are developed. The models account for three-dimensional dispersion in a uniform flow field, and first-order inactivation of suspended and deposited viruses with different inactivation rate coefficients. Virus deposition onto solid particles is described by two different processes: nonequilibrium adsorption which is applicable to viruses behaving as solutes; and colloid filtration which is applicable to viruses behaving as colloids. The governing virus transport equations are solved analytically by employing Laplace/Fourier transform techniques. Instantaneous and continuous/periodic virus loadings from a point source are examined.     

Three-dimensional free-surface suspended particles transport in the South Biscayne Bay,Florida

A three-dimensional, time-dependent free surface model has been developed which takes account of topographical and meterological parameters for application to suspended particles transport. This investigation of suspended particles transport is the most realistic in regard to treating the moving free-surface in computing the hydrodynamic field. A unique mass-conserving numerical model is used for solving the concentration equation by an explicit finite difference scheme. The paper presents a mathematical model which can be applied to surface water dispersion of particulates associated with dredging operations and land-fill. The effects of settling velocity and bottom bed deposition rate are compared and discussed.     

Experiments on Solute Transport in Aggregated Porous Media: Are Diffusions Within Aggregates and Hydrodynamic Dispersion Independent?

Two region models for solute transport in porous media assume that hydrodynamic dispersion in mobile water and solute diffusion within immobile water regions are independent. Experimental and theoretical results for transport through a macropore indicate that hydrodynamic dispersion and solute exchange are interdependent. Experiments were carried out to investigate this problem for a column packed with spherical porous aggregates. The effective diffusion coefficient of a tracer within the agreggates was determined from specific experiments. The dispersivity of the bed was determined from experiments carried out with a column filled with nonporous beads. We took advantage of the dependence of hydrodynamic dispersion on density ratios between the invading and displaced solutions to obtain a set of breakthrough curves corresponding to situations where the diffusion coefficient remains constant, whereas the dispersivity varies. Simulations reproduce correctly the experiments. Small discrepancies are noted that can be corrected either by increasing the dispersion coefficient or by fitting the external mass transfer coefficient. Increased dispersion coefficients probably reveal a modification of Taylor dispersion due to solute exchange. The fitted external mass transfer coefficients are close to the values obtained with classical correlations of the chemical engineering literature.     

Dispersion Stability and Transport of Nanohybrids through Porous Media

Single-walled carbon nanotube-silica nanohybrid particles are a very promising material that could be used for enhanced oil recovery because of their interfacial activity. To demonstrate the basic principle, aqueous nanohybrid particle dispersions were evaluated by looking at the effect of pH, surfactant, and polymer. The results showed that pH did not have significant effect on the dispersion stability of nanohybrid particles. Although surfactant could improve the dispersion stability, it reduced the interfacial activity of the nanohybrid particles, causing them to stay in the aqueous phase. The best nanohybrid particle dispersion stability was found upon polymer addition, where the dispersions were stable for more than a week even at low polymer concentration (50?ppm). One-dimensional sand-pack studies were performed to evaluate the flow of the nanohybrid particles through porous media. The results showed that most of the nanohybrid particles (>99%) could pass through a column packed with glass beads while a measurable fraction of the particles was retained in the column packed with crushed Berea. When the columns contained a residual saturation of decane, additional nanohybrid particles were retained at the oil/water interface in both glass beads and crushed Berea sand media. The sand pack studies showed that not only can the nanohybrid particles flow through porous media but also about half of the particles injected will go the O/W interface when the porous medium contains a residual saturation of hydrocarbon, where they could be used to support a catalytic conversion of components of the oil in reservoirs.     

Effects of Particle Size Non-Uniformity on Transport and Retention in Saturated Porous Media

Short-pulse injection experiments are investigated to study the effects of particle size non-uniformity on the transport and retention in saturated porous media. Monodisperse particles (3, 10, and 16 \(\upmu \hbox {m}\) latex microspheres) and polydisperse particles (containing 3, 10, and 16 latex microspheres) were explored. The obtained results suggest considering not only the particle sizes but also their polydispersivity (particle size non-uniformity) in transport and retention. Although, the density of the suspended particles is close to that of water, results reveal a slow transport of particles compared to the dissolved tracer whatever their size and flow velocity. The recovered particles in the mixture experiments show that the retention of large particles (10 and 16 \(\upmu \hbox {m}\)) enhances the retention of small ones (3 \(\upmu \hbox {m}\)). However, the straining of 10 and 16 \(\upmu \hbox {m}\) particles in “mixture experiments” is smaller than their straining in “monodisperse experiments”. A linear relationship summarizing the simultaneous effect of particle sizes and flow velocity on deposition kinetics coefficient is proposed.     

Evaluation of stochastic particle dispersion modeling in turbulent round jets

ODT (one-dimensional turbulence) simulations of particle-carrier gas interactions are performed in the jet flow configuration. Particles with different diameters are injected onto the centerline of a turbulent air jet. The particles are passive and do not impact the fluid phase. Their radial dispersion and axial velocities are obtained as functions of axial position. The time and length scales of the jet are varied through control of the jet exit velocity and nozzle diameter. Dispersion data at long times of flight for the nozzle diameter (7 mm), particle diameters (60 and 90 µm), and Reynolds numbers (10, 000–30, 000) are analyzed to obtain the Lagrangian particle dispersivity. Flow statistics of the ODT particle model are compared to experimental measurements. It is shown that the particle tracking method is capable of yielding Lagrangian prediction of the dispersive transport of particles in a round jet. In this paper, three particle-eddy interaction models (Type-I, -C, and -IC) are presented to examine the details of particle dispersion and particle-eddy interaction in jet flow.     

Effect of Slow and Fast Moving Liquid Zones on Solute Transport in Porous Media

A conceptual model is developed in this article that accounts for the effect of slow and fast moving liquid zones on solute transport in porous media. The liquid phase within the porous media is divided into three zones—immobile, slow moving, and fast moving. Slow moving liquids surround the solid particles in thin layers and have lower velocity in flow. Fast moving liquids have higher velocity and are not in contact with the solid particles. Solute mass transfer occurs between the slow and fast liquids, and the slow and immobile liquids. The immobile and slow moving liquids interact with the solid matrix in the media through the mechanism of sorption and desorption. Implicit finite-difference methods are used to solve the partial differential equations that describe the slow and fast movement of solute in the porous medium. The model was validated for a laboratory column experimental data. Sensitivity analyses were conducted to ascertain the effects of the model parameters on solute movement. The effect of each parameter on retardation of the solute movement was analyzed. It was observed that the maximum retardation of solute occurs when there is high adsorption coefficient, high mass transfer rates, and high volume of slow moving liquid in the porous media.     

方柱尾流流态对床面冲淤形态的影响

应用平面二维悬沙数学模型对方柱尾流区的泥沙输运及床面调整进行了数值模拟，并对重要物理参数做了分析说明。数值计算采用时间分裂一全隐式有限差分格式，流场的计算基于沿水深平均的RANS方程。通过系统的数值模拟，揭示了不同来流情况下，方柱尾流区的流态变化，及与之相应的床面变化规律，并对不同流态下的泥沙运动作了分析。计算结果表明在方柱尾流区，不同的流场流态对尾流区的床面调整有明显影响。流场较弱的情况下，尾流区中湍动强度相应较弱，此时悬浮泥沙由于流速减小而普遍落淤，床面应力的减小也致使床面冲刷量减小。随着流场强度的逐渐增大，尾流区中湍动强度相应增强，床面应力增大，同时湍流的强烈交换作用增强了对泥沙的输运作用，床面变化不再是简单的淤积状态，部分区域出现了冲刷。     

Graphite dust deposition in the HTR-10 steam generator

Graphite dust has an important effect on the safe operation of a high-temperature gas-cooled reactor (HTR). The present study analyzes temperature and flow field distributions in the HTR-10 steam generator. The temperature and flow field distributions are then used to study thermophoretic deposition and turbulent deposition. The results show that as the dust diameter increases, the thermophoretic deposition decreases, while the turbulent deposition first decreases and then increases. The thermophoretic deposition is higher at higher reactor powers, with turbulent deposition growing more rapidly at higher reactor power. For small particles, the thermophoretic deposition effect is greater than the turbulent deposition effect, while for large particles, the turbulent deposition effect is dominant.     

Particle motion and turbulence in dense two-phase flows

Measurements of particle mean and r.m.s. velocity were obtained by laser-Doppler anemometry in a descending solid-liquid turbulent flow in a vertical pipe with volumetric concentrations of suspended spherical particles of 270 μm mean diameter in the range 0.1–14%. Similar measurements were obtained in the flow downstream of an axisymmetric baffle of 50% area blockage placed in the pipe with volumetric concentrations of 310 μm particles up to 8% and of 665 μm particles up to 2%. In order to enable measurements in high particle concentrations without blockage of the laser beams the refractive index of the particles was matched to that of the carrier fluid.

The results show that the particle mean velocity profiles become more uniform and the particle r.m.s. velocity decreases with increasing concentration in both flow cases. The particle mean velocity in the pipe flow also decreases with concentration and the relative velocity, the difference between the particle velocity and the fluid velocity in single-phase flow, decreases with increasing Reynolds number. The length of the recirculation region downstream of the baffle was shorter than in single-phase flow by 11 and 24% for particle concentrations of 4 and 8%, respectively. The particle mean velocities were hardly affected by size for concentrations up fo 2%, but the r.m.s. velocities were lower with the larger particles.     

Effects of Flow Velocity and Nonionic Surfactant on Colloid Straining in Saturated Porous Media Under Unfavorable Conditions

Knowledge of colloid straining mechanism in porous media is of importance for protecting groundwater from being contaminated by biocolloids (e.g., bacteria and protozoa) and by contaminants whose transport can be facilitated by mobile particles. This study examined effects of flow velocity on colloid straining in porous media under unfavorable chemical conditions. Saturated column experiments were conducted using glass beads as collector and a $3\,\mu \text{ m}$ carboxylate-modified polystyrene latex microsphere as model colloid. To unambiguously examine colloid straining mechanisms, attachment was minimized by extensively cleaning the collectors and adopting deionized water as solution. Results show that increasing flow velocity decreases colloid straining under unfavorable chemical conditions, in agreement with to theoretical finding in literature. This study additionally examined effects of nonionic surfactant (Triton X-100) on colloid straining in porous media under unfavorable chemical conditions. Results show that the addition of Triton X-100 decreases colloid straining and the decrease is enhanced by increasing the concentration of Triton X-100.     

Geometric and Hydrodynamic Characteristics of Three-dimensional Saturated Prefractal Porous Media Determined with Lattice Boltzmann Modeling

Fractal and prefractal geometric models have substantial potential for contributing to the analysis of flow and transport in porous media such as soils and reservoir rocks. In this study, geometric and hydrodynamic parameters of saturated 3D mass and pore–solid prefractal porous media were characterized using the lattice Boltzmann model (LBM). The percolation thresholds of the 3D prefractal porous media were inversely correlated with the fraction of micro-pore clusters and estimated as 0.36 and 0.30 for mass and pore–solid prefractal porous media, respectively. The intrinsic permeability and the dispersivity of the 3D pore–solid prefractals were larger than those of the 3D mass prefractals, presumably because of the occurrence of larger solid and pore cluster sizes in the former. The intrinsic permeability and dispersivity of both types of structure increased with increasing porosity, indicating a positive relationship between permeability and dispersivity, which is at odds with laboratory data and current theory. This discrepancy may be related to limitations of the convection dispersion equation at the relatively high porosity values employed in the present study.     

饱和砂土中泥浆渗透的变形-渗流-扩散耦合计算模型

传统的泥浆渗透计算中没有考虑土体变形和浆液流速的影响.根据泥浆颗粒的质量守恒定律推导了耦合流速的浓度扩散方程,并通过在浓度方程中引入沉积系数进一步计算得到沉积颗粒的质量;同时,以沉积量作为耦合项对毕奥固结方程中的水量连续方程进行了修正,在此基础上建立了变形-渗流-扩散耦合的控制方程及其变分原理. 采用有限单元法求解基本方程,运用了时间增量法与直接迭代法,并利用一维试验验证计算方法的可靠性,并与赫齐格的经典模型的计算结果进行了比较,结果表明,本文建立的模型的计算结果可以较好地预测各组试验中颗粒的沉积规律,且吻合程度优于仅考虑颗粒对流和扩散的传统计算方法. 最后,将泥浆在槽壁中的渗透简化为二维问题并进行了计算,计算结果与工程认识相符合,泥浆的沉积填充效应随深度的增加而增大,施工时需要严格控制浅层作业段的机械垂直度;成槽机的下斗抓挖时机可以根据地层填充的致密程度进行计算,对现场施工具有一定的指导意义.      

An Analytical Solution Evaluating Steady-State Plumes of Sequentially Reactive Contaminants

A steady state version of an analytical solution of the reactive flow and transport problem is derived. This solution allows a better understanding of the steady-state plume characteristics, and allows the prediction of the effectiveness of natural attenuation of sequentially reactive contaminants. The sequential reactions are assumed to be first order. Using spatial moments as compact information of plume characteristics, the total mass, plume centroids, and extents of each contaminant plume are derived as functions of dispersivity, velocity, and reaction rates. The steady-state plume centroids and extents are independent of stoichiometric coefficients. The solution is demonstrated for a four-species sequentially reactive transport in a one-dimensional column. The extension to three dimensions is easily made and does not change the basic functions.     

Mechanisms of Particle Transport Acceleration in Porous Media

Experimental data show that the groundwater transport of radionuclides in porous media is frequently facilitated when accompanied with colloid particles. This is usually explained by the size exclusion mechanism which implies that the particles move through the largest pores where the flow velocity is higher. We call attention to three other mechanisms which influence the colloid particle motion, while determining both the probable transport facilitation and retardation. First of all, it is shown that the transport facilitation may be significantly reduced and even transformed into a retardation due to the growth of the effective suspension viscosity (a friction-limited facilitation). Secondly, we will show that the transport of particles through the largest pores can be retarded due to a reduced connectivity of the large-pore cluster (a percolation-breakup retardation). Thirdly, we highlight the Fermi mechanism of acceleration known in statistical physics which is based on the elastic collisions between particles. All three effects are analyzed in terms of the velocity enhancement factor, by using statistical models of porous media in the form of a capillary bundle and a 3D capillary network. Optimal and critical regimes of velocity enhancement are quantified. Estimations show that for realistic parameters, the maximal facilitation of colloid transport is close to the experimentally observed data.     

各向同性湍流内颗粒碰撞率的直接模拟研究

对 Re_{\lambda } 约为51均匀各向同性湍流内 St_{k}(=\tau_{p}/\tau_{k}) 为 0 ~10.0 的 有限惯性颗粒的碰撞行为进行了直接数值模拟，以研究湍流对有限惯性 颗粒碰撞的影响. 结果表明，具有一定惯性颗粒的湍流碰撞率完全不同于零惯性的轻颗粒 (St_{k}=0) 和可忽略湍流作用的重颗粒 (St{k} \to \infty) , 其变化趋势极其复杂： 在Stk为 0~1.0 之间，颗粒的碰撞率随 St 的增加而近乎线性地剧烈增长，在 Stk≈1.0 3.0(对应的StE=τp/Te≈0.5)附近，颗粒碰撞率出现两个峰值，在Stk>3.0以后，颗粒的碰撞率随惯性增 大而逐渐趋向于重颗粒极限；在峰值处，有限惯性颗粒的平均碰撞率的峰值较轻颗粒增强了 30倍左右. 为进一步分析湍流作用下颗粒碰撞率的影响因素，分别使用可能发生碰撞 的颗粒对的径向分布函数和径向相对速度来量化颗粒的局部富集效应和湍流掺混效应，表明 St_{k} \approx 1.0 时局部富集效应最为强烈，使得颗粒的碰撞率出现第1个峰值； 湍流掺混效应则随着颗粒Stk的增大而渐近增大；局部富集和湍流掺混联合作用的结果， 使得颗粒碰撞率在 St_{k} \approx 3.0 附近出现另一个峰值.