三维四向编织复合材料刚度和强度的理论预测

以单胞模型为基础,将三维四向编织复合材料中相同走向的纤维束视为单向复合材料,利用桥联模型确定了单向复合材料的柔度矩阵,再将具有不同材料主向的单向复合材料的刚度矩阵通过体积平均,得到了三维四向编织复合材料的总体刚度矩阵,从而得到其工程弹性常数．然后,以单向复合材料为基础,基于等应变假设和桥联模型,确定出材料内各组分（纤维束和基体）的细观应力分布,且对纤维束采用Hoffman失效准则,对基体采用Mises失效准则,预报了三维四向编织复合材料的拉伸强度．     

Influence of Modifiers on the Physicomechanical Properties of Sawdust-Polyethylene Composites

Polymer-wood composites based on recycled polyethylene (RPE) are investigated. Dispersed alder sawdust was utilized as a filler. To improve the compatibility between the nonpolar matrix and the polar wood fibers as a reinforcement, two types of modifiers were used, which differed in their chemical nature and mechanical interaction with the constituents of the composites. The modifiers of the first type (paraffin and OP) improved the dispersibility of sawdust (SD), and those of the second type (Exxelor 1015 and OREVAC) contained groups of maleic anhydride, which interacted with the OH-groups of SD. The effect of the modifiers on the moisture sorption by SD, the dispersibility of the filler in the matrix, and the strength characteristics (ultimate strengths and moduli in tension and bending) of dry and moist RPE–SD composites and on their moisture sorption is estimated. The best results were obtained for the composites modified with paraffin, which is due to the more efficient employment of the strength and rigidity of well-dispersed SD fibers. In their strength characteristics, the RPE-based composites investigated are comparable to composites based on low-density polyethylene.     

Influence of a Silica Aerogel Filler on the Mechanical,Thermal, and Physical Properties of Flax/Epoxy Composite

Mechanics of Composite Materials - The influence of Maerogel (MA) on the material properties of the flax fiber reinforced epoxy composites has been investigated. The composites were fabricated...     

Effect of nanofiller aspect ratio on the stress relaxation and creep response of toughened pom composites

Ternary composites composed of polyoxymethylene (POM), polyurethane (PU), and sodium fluorohectorite (FH) or sodium bentonite (BN) were produced by the melt compounding masterbatch (MB) technique. The related MB was produced by mixing the PU latex with water-swellable FH or BN. The dispersion of the nanofillers in the composites was studied by X-ray diffraction techniques. The crystallization of the POM-based systems was inspected by polarized optical microscopy (PLM). The stress relaxation and creep properties of the composites were determined in short-time stress relaxation and creep tests (creep at various temperatures), respectively. The POM/PU/FH composites produced by the MB technique outperformed the POM/PU blend and the POM/PU/BN system in respect to most of the stress relaxation and creep characteristics. This fact was attributed to the higher aspect ratio of FH compared with that of BN. The master curves (creep compliance vs. time) constructed by employing the time-temperature superposition principle showed that the Findley power law was fully applicable to the experimental results obtained.     

Anisotropy of elasticity of a composite with irregularly oriented anisometric filler particles

The effects of orientation and shape of filler particles on the elastic properties of composites have been analyzed. The elastic constants of a composite with irregularly oriented filler particles were calculated by using the method of orientational averaging of the properties of a representative structural element. The elastic constants of the structural element were found according to a known generalized Eshelby solution for a finite concentration of ellipsoidal inclusions. The diagrams of elasticity anisotropy for a transversely isotropic structural element and an orthotropic composite with irregularly oriented inclusions are presented. A quantitative estimate for the degree of anisotropy of elastic properties of composites is suggested. Data on the influence of shape anisometry of inclusions on the anisotropy coefficient of filled composites are also reported.     

The effect of CNT modification on the mechanical properties of polyimide composites with and without MoS<Subscript>2</Subscript>

The aim of this work was to investigate the effect of surface modification of carbon nanotubes (CNTs) on the mechanical properties of polyimide (PI) composites with and without MoS₂. A three-phase system of CNT/PI/ MoS₂ laminates were fabricated with an extrusion-grade PI to produce CNT-reinforced laminates with MoS₂ volume fractions of 1–5%. The tensile and impact properties of CNT/PI composites and CNT/PI/MoS₂ laminates were also measured and compared. Results showed that the introduction of CNTs as reinforcing additives improved the tensile properties of the composites, but worsened their impact properties. Furthermore, the addition of MoS₂ increased the impact strength of the CNT/PI composites greatly. The optimum contents of CNT and MoS₂ have been found.     

Long- and short-term creep of polyoxymethylene/polyurethane/alumina ternary composites by comparison

Ternary composites consisting of polyoxymethylene, polyurethane (PU), and boehmite alumina were produced by melt blending with and with out latex precompounding. The latex precompounding served to predisperse the alumina particles. The related advanced masterbatch (MBa) was produced by mixing the PU latex with the water-dispersible boehmite alumina. The dispersion of alumina and rubber particles was studied by using the scanning electron micros copy. The creep properties of the composites were determined from results of long- and short-term creep tests (per formed at various temperatures). The composites produced by the MBa technique out performed those made by direct melt compounding with respect to most of creep characteristics. The Findley power law was found to be fairly applicable to the experimental results obtained. Master curves (strain vs. time) were also constructed by employing the time-temperature super position principle.     

Multifibre polymer composites: Prediction of deformation and thermophysical properties

Conclusions A theoretical and experimental investigation was carried out to examine the possibilities of a structural approach for prediction of elastic constants, creep functions and thermophysical characteristics of hybrid polymer composites reinforced with anisotropic fibres of several types. The theoretical solutions were obtained by generalizing the self-consistent method for the case of a three phase model. The effects of brittle fibre breakdown under tension in the direction of reinforcement of a unidirectional hybrid composite were studied under conditions of a short-term loading and a long-term creep. It has been shown that a creep of viscoelastic fibres plays a principal role in creep of the hybrid composite. It is just this creep that significantly increases the fibre damage during creep of the composite.A variant of the solution has been proposed for predicting the thermorheologically complex behavior of hybrid composites containing not only elastic but also viscoelastic thermorheologically simple components with different temperature-time shift factors. The peculiarities of thermal expansion of hybrid composites and the possibilities for a purposeful control of thermal expansion coefficients by hybridization were studied. The considered thermal interval included a region of transition of the polymer matrix from a glass state into a viscoelastic one.The control tests were performed for specimens of organic/glass, organic/carbon, glass/carbon and organic/boron polymer composites with different ratios of fibre volume contents. On the whole, the obtained accuracy of predicting the characteristics of the examined hybrid composites may be considered as acceptable for engineering applications.Published in Mekhanika Kompozitnykh Materialov, Vol. 30, No. 3, pp. 299–313, May–June, 1994.     

Physicomechanical properties of composites from recycled polyethylene and linen yarn production wastes

The possibilities of utilizing wastes of linen thread production (chaffs, spinning and roving losses) in recycled polyolefin composites have been investigated. The wastes were mixed with recycled polyethylenes (produced from domestic and industrial film production wastes). The physicomechanical properties (tensile strength, bending and tensile moduli, and water resistance) and the fluidity (melt flow-behavior index) for systems with a different filler content are estimated. Almost all the composite materials obtained have satisfactory fluidity (melt flow-behavior index is not lower than 0.07–0.15 dg/min). For all types of the composites, a slight increase in tensile strength and a considerable increase (3–7 times) in bending and tensile moduli were observed. The water resistance of the composites decreased with an increase in the filler content. The modification of filled systems with diisocyanates (diphenylmethane diisocyanate) improved the useful properties and water resistance of all the composites investigated.     

Creep of Heat-Resistant Composites of an Oxide-Fiber/Ni-Matrix Family

A creep model of a composite with a creeping matrix and initially continuous elastic brittle fibers is developed. The model accounts for the fiber fragmentation in the stage of unsteady creep of the composite, which ends with a steady-state creep, where a minimum possible average length of the fiber is achieved. The model makes it possible to analyze the creep rate of the composite in relation to such parameters of its structure as the statistic characteristics of the fiber strength, the creep characteristics of the matrix, and the strength of the fiber-matrix interface, the latter being of fundamental importance. A comparison between the calculation results and the experimental ones obtained on composites with a Ni-matrix and monocrystalline and eutectic oxide fibers as well as on sapphire fiber/TiAl-matrix composites shows that the model is applicable to the computer simulation of the creep behavior of heat-resistant composites and to the optimization of the structure of such composites. By combining the experimental data with calculation results, it is possible to evaluate the heat resistance of composites and the potential of oxide-fiber/Ni-matrix composites. The composite specimens obtained and tested to date reveal their high creep resistance up to a temperature of 1150°C. The maximum operating temperature of the composites can be considerably raised by strengthening the fiber-matrix interface.     

Processing,structure, and mechanical properties of alumina-nanofilled polystyrene composites

Binary composites composed of polystyrene (PS) and a synthetic boehmite alumina were produced by using the water-mediated melt compounding (WMC) and direct melt compounding (DMC) techniques. The alumina particles were dispersed in water at ambient temperature. The aqueous alumina suspension was injected into molten PS in a twin-screw extruder to prepare reinforced polymer composites. The dispersion of the alumina was studied by transmission and scanning electron microcopy techniques (TEM and SEM, respectively). The mechanical and thermomechanical properties of the composites were determined by employing a dynamic-mechanical thermal analysis (DMTA) and short-time creep and uniaxial static tensile tests. It was found that the direct melt compounding of the alumina with PS resulted in microcomposites, whereas the water-mediated melt compounding technique gave rise to nanocomposites. The incorporation of alumina into the PS nanocomposites increased their stiffness, tensile strength, and creep resistance. However, the elongation of the PS nanocomposites at break was smaller than that of the PS microcomposites.     

Creep of orthogonally reinforced spherofibrous composites

Models of composites with three-dimensional structure, a proposed problem solving method, and Rabotnov's creep operators were used assuming purely elastic deformation of the composite along the orientation of the fibers to determine the viscoelastic properties of composites on inclined surfaces in a three-dimensional stressed state. The formulas used in viscoelasticity theory in the elastic region of component deformation lead to results in satisfactory accord with the reported experimental elastic properties of composites with three-dimensional structure.A. A. Blagonravov Mechanical Engineering Institute, Russian Academy of Sciences, Moscow. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 6, pp. 780–786, November–December, 1996.     

Mechanical properties of henequen fibre/epoxy resin composites

By using surface-treated and untreated henequen fibres and an epoxy resin, composites were made by compression moulding, and their mechanical properties and failure modes were determined experimentally in tension, bending, and impact loading. The results obtained show that the treatment of fibre surface does not improve the bond between the fibres and the resin matrix, and the general mechanical properties of the composites are similar.     

Physicomechanical properties of composites from recycled polyethylene and linen yarn production wastes

The possibilities of utilizing wastes of linen thread production (chaffs, spinning and roving losses) in recycled polyolefin composites have been investigated. The wastes were mixed with recycled polyethylenes (produced from domestic and industrial film production wastes). The physicomechanical properties (tensile strength, bending and tensile moduli, and water resistance) and the fluidity (melt flow-behavior index) for systems with a different filler content are estimated. Almost all the composite materials obtained have satisfactory fluidity (melt flow-behavior index is not lower than 0.07–0.15 dg/min). For all types of the composites, a slight increase in tensile strength and a considerable increase (3–7 times) in bending and tensile moduli were observed. The water resistance of the composites decreased with an increase in the filler content. The modification of filled systems with diisocyanates (diphenylmethane diisocyanate) improved the useful properties and water resistance of all the composites investigated.Translated from Mekhanika Kompozitnykh Materialov, Vol. 35, No. 2, pp. 199–210, March–April, 1999.     

Environmental degradation of carbon nanotube-modified composite laminates: a study of electrical resistivity

The environmental durability of carbon nanotube (CNT)-modified carbon-fibre-reinforced polymers (CFRPs) is investigated. The key problem of these new-generation composites is the modification of their polymer matrix with nanoscaled fillers. It was recently demonstrated that the damage tolerance of these materials, as manifested by their fracture toughness, impact properties, and fatigue life, can be improved by adding CNTs at weight fractions as low as 0.5%. This improvement is mainly attributed to the incorporation of an additional interfacial area between the CNTs and the matrix, which is active at the nanoscale. However, this additional interface could have a negative effect on the environmental durability of the aforementioned systems, since it is well known that the moisture absorption ability of a matrix is enhanced by the presence of multiple interfaces, which serve as an ingress route to water. To examine this problem, CNT-modified CFRPs were exposed to hydrothermal loadings. At specified intervals, the composites were weighted, and the water uptake vs. time was recorded for both the modified and a reference systems. The electrical conductivity of the composites was registered at the same time intervals. After the environmental exposure, the interlaminar shear properties of the conditioned composite systems were measured and compared with those of unmodified composites, as well as with the shear properties of unexposed laminates. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 45, No. 1, pp. 31–48, January–February, 2009.     

具有非均匀界面相的颗粒和纤维增强复合材料弹性静力学问题的解析解

通过将以位移表示的平衡方程转化为黎卡提方程,得到了具有非均匀界面相的颗粒和纤维增强复合材料非均匀界面相内弹性场的解析解·　所得的解析解是弹性模量呈幂次方变化的非均匀界面相解的通用形式·　任意给定1个幂指数,可以得到具有非均匀界面相的颗粒和纤维增强复合材料体积模量的解析表达式·　通过改变幂指数及幂次方项的系数,此解析解可适用于具有多种不同性质的非均匀界面相·　结果表明:界面相模量和厚度对复合材料模量有很大的影响,当界面相存在时,粒子将出现一种"尺寸效应"·     

Influence of Nanoceramics on the Properties of Polytetrafluoroethylene

The influence of nanometer particles of ceramics on the formation and wear of polymer composites based on polytetrafluorethylene is investigated. The factors allowing one to improve the operational characteristics of the composites being developed are established.     

Effect of a dispersed filler on the modulus of elasticity of composites in the glassy state

An expression is proposed for predicting the reinforcement of composites by a dispersed filler in both the rubbery and glassy states with allowance for the internal thermal stresses in the polymer matrix. It is shown that by varying the plasticizer concentration in composites based on polyvinyl chloride it is possible to regulate the thermal stresses in the polymer matrix. The time-stress and time-concentration superposition principles are shown to be applicable to the dependence of the relative modulus of elasticity on filler concentration for glassy composites.     

Influence of nano-SiO<Subscript>2</Subscript> and carbon fibers on the mechanical properties of POM composites

Polyoxymethylene/carbon fiber(POM/CF)composites containing nano-SiO₂ were prepared, and their mechanical properties were investigated. At a content of 1-5 vol.%, the nano-SiO₂ exerted an obvious reinforcing effect on POM, leading to an increase in the elastic modulus and stiffness of the composites.     

Investigation of the three-dimensional micromechanical behavior of woven-fabric composites

A three-dimensional representative volume-element model is presented to study the micromechanical behavior of woven-fabric composites. The effects of the fiber undulation zone and the fiber braid angle on the elastic modulus of the composites are taken into account in the unit cell. Based on isostrain and isostress assumptions, a standard homogenization procedure is used to calculate the effective elastic properties of woven-fabric composites, and all the final stiffness components are expressed in an explicit form. The results obtained by the model considered agree with published experimental results very well. The relationship between the geometric parameters, such as fiber width, thickness, volume fraction, etc., and the macromechanical behavior of the composites can be obtained by this model. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 2, pp. 209–220, April–May, 2006.