Ag/Si(111)-(7X7) Heteroepitaxy—STM Experiment and KMC Simulations

Heteroepitaxial growth of Ag on Si(111)-(7X7) surface at various conditions was experimentally studied by scanning tunneling microscopy. A growth model based on experiments was used for kinetic Monte Carlo (KMC) simulations. The simulations of nucleation and island growth at low coverage and fitting experimental data provided basic growth parameters. Further growth—formation of a discontinuous transition film (wetting layer)—was implemented into the basic model. The suggested growth mechanism was successfully tested using the KMC simulations. The choice of experiments, the role of minimizing processes and parameters in the model, and efficiency of the used approach is demonstrated and discussed.     

Diffusion of Au atoms and (5×2) phase formation on the Si(111) (7×7) surface

In this article we investigate the complex 1D mesoscopic model of adatom diffusion and the evolution of an ordered phase on the substrate surface. The analysis of the theoretical model is compared with the experimental results of the spreading of Au adatoms on Si(111)-(7×7) surface. The steady state solutions and their stability conditions are determined within the concept of the traveling-wave solution. It is shown that the formation of the ordered phase (5×2) and the difference in the diffusion of Au on (7×7) and on (5×2) structure results in a sharp edge of diffusion front which corresponds to the coverage of a saturated (5×2) phase. This edge moves linearly in time and α can be determined by experiment. The system of model equations enables the damped waves solution or temporary evolution of two steps.     

Patterns in Ge cluster growth on clean and oxidized Si(111)-(7 × 7) surfaces

Ge atoms have been deposited on domain-patterned clean Si(111)-(7 × 7) and oxidized Si(111)-(7 × 7) surfaces. Clustering of Ge from the deposited Ge adatoms on these two kinds of surfaces shows contrasting patterns. On the clean Si surface, clustering predominantly occurs on domain boundaries, which include step edges on two sides. This leaves small domains denuded. Ge diffusion length has been estimated from the size of these denuded domains. For large domains, additional clustering is observed within the domains. For the oxidized Si surface, the pattern formation is in sharp contrast with that for the clean Si surface. In this case the domain boundaries remain relatively empty and there is strong clustering within the domains leading to the formation of dense Ge nanoislands within the domains. This contrasting pattern formation has been explained via a reaction diffusion model.     

The S(E) factor of7Li(p, γ)8Be and consequences for S(E) extrapolation in7Be(p, γ0)8B

Excitation functions and forward-backward anisotropies have been measured for the⁷Li(p, )⁸Be capture reaction over the proton energy rangeE _p =100 to 1500 keV, using a 4 summing crystal and Ge(Li) detectors, respectively. The data show at all energies the presence of El and M1 capture amplitudes arising from the direct capture (DC) process and theE _R =441 and 1030 keV resonances, respectively. Due to the observed DC process, the present data increase significantly the reaction rates (up to a factor of 110) compared to values given in the compilation. The data and their analyses remove the recent criticism on DC model calculations, which had implied a significant reduction in the extrapolated S(E) factor for⁷Be(p,)B and thus in the predicted flux of high-energy solar neutrinos; thus, the solar neutrino problem is still with us.Supported in part by the Deutsche Forschungsgemeinschaft (Ro429/21-3 and Ro429/21-4) and the German-Hungarian Collaboration (X238.6 and OTKA3808)     

Non-Abelian Vortices,Super Yang–Mills Theory and Spin(7)-Instantons

We consider a complex vector bundle E{\mathcal{E}} endowed with a connection A{\mathcal{A}} over the eight-dimensional manifold \mathbbR²×G/H{\mathbb{R}^2\times G/H}, where G/H = SU(3)/U(1) × U(1) is a homogeneous space provided with a never-integrable almost-complex structure and a family of SU(3)-structures. We establish an equivalence between G-invariant solutions A{\mathcal{A}} of the Spin(7)-instanton equations on \mathbbR²×G/H{\mathbb{R}^2\times G/H} and general solutions of non-Abelian coupled vortex equations on \mathbbR²{\mathbb{R}^2}. These vortices are BPS solitons in a d = 4 gauge theory obtained from N = 1{\mathcal{N} =1} supersymmetric Yang–Mills theory in ten dimensions compactified on the coset space G/H with an SU(3)-structure. The novelty of the obtained vortex equations lies in the fact that Higgs fields, defining morphisms of vector bundles over \mathbbR²{\mathbb{R}^2}, are not holomorphic in the generic case. Finally, we introduce BPS vortex equations in N = 4{\mathcal{N} =4} super Yang–Mills theory and show that they have the same feature.     

Direct evidence for Ge preferential growth at steps and out-of-phase boundaries of (7 × 7) domains on Si(111) in solid phase epitaxy

Ge solid phase epitaxy on a Si(111) surface has been directly observed by secondary electron surface microscopy which is based on scanning electron microscopy. Ge island formation initially occurs at steps and out-of-phase boundaries of (7 × 7) domains. These results confirm the origin of previously reported mesh patterns of Ge islands grown on Si(111).     

Si(111)-(7×7)表面上Ge量子点的自组织生长

用扫描隧道显微镜研究了Si(111)(7×7)表面上Ge量子点的自组织生长.室温下用固相外延法在硅基底上沉积亚单层的Ge,然后在适当的温度下退火可以聚集形成有序的Ge量子点.由于Ge在Si(111)(7×7)表面选择性的吸附而形成有序的Ge量子点. 关键词： 锗 硅 扫描隧道显微镜 自组织生长     

10~(-7)安积分电路

在核物理实验中,往往需要测知离子流的电量与离子流强度。比较简便的方法是用积分电路来测量电量,同时可指示离子流强度。本文所介绍的是一个实用的积分电路,其中包括直流放大,触发电路,计数电路及稳定电源等。离子流的强度由仪器上电流表指出,电量由机械记数器的数字来表示。     

Si(111)7×7结构模型的稳定性研究

本文基于有相互作用的结构件的概念,对Si(111)7×7结构模型的稳定性进行研究。利用紧束缚法,计算了各种结构件的形成能及其相互作用能。由这些结构件可灵活地构成各种大单胞的表面结构并对其进行总能计算,而避免了大工作量的计算。对Si(111)5×5和7×7DAS模型,我们得到其表面能分别为-0.467eV和-0.477eV,与Qian和Chadi的结果很接近。并指出,Harrison提出的7×7吸附原子模型和Binnig等人提出的7×7吸附原子-空位模型都是不稳定的。     

Adsorption of Perylene on Si(111)(7×7)

We investigate the adsorption of organic molecular semiconductor perylene on(7 × 7) reconstructed Si(111)surface by ultraviolet photoemission spectroscopy.It is observed that seven features that derive from the organic material are located at 0.71,2.24,4.0,5.9,7.46,8.65 and 9.95 eV in binding energy.The theoretical calculation results reveal the most stable adsorption geometry of organic molecule perylene on Si(111)(7 × 7) substrates is at the beginning of deposition.     

1993年(第7卷)主题索引

理论研究和数值模拟高加载率条件!:LY12铝合金损伤断裂现象的研究·············································…… .....................................·..·..·.……~·一“…王泽平黄风雷丁傲侠教铝、铜、铅压力熔化曲线的研究·············································……郑伟涛张瑞林Thomas一Fermi模峨的相对论修正·············································,····…     

Femtosecond dynamics and transport of optically excited electrons in epitaxial Cu films on Si(111)-7×7

Time-resolved two-photon photoemission spectroscopy is used to study ultrafast electron dynamics of epitaxial Cu films grown in situ on a Si(111)-7×7 substrate with 6 to 44 nm thickness. For excitation with femtosecond laser pulses at h=2.35 eV a pronounced increase of the electron relaxation rates is observed with increasing film thickness and even further in comparison to bulk data. This is attributed to an enhanced energy dissipation in thicker films due to transport of excited carriers into the bulk. PACS 73.50.Gr; 73.90.+f; 78.47.+p; 79.60.-i     

Microscopic calculation of the 3He(α,γ)7Be and 3H(α,γ)7Li capture cross sections using realistic interactions

The radiative capture cross sections for the 3He(α,γ)7Be and 3H(α,γ)7Li reactions are calculated in the fully microscopic fermionic molecular dynamics approach using a realistic effective interaction that reproduces the nucleon-nucleon scattering data. At large distances bound and scattering states are described by antisymmetrized products of 4He and 3He/3H ground states. At short distances the many-body Hilbert space is extended with additional many-body wave functions needed to represent polarized clusters and shell-model-like configurations. Properties of the bound states are described well, as are the scattering phase shifts. The calculated S factor for the 3He(α,γ)7Be reaction agrees very well with recent experimental data in both absolute normalization and energy dependence. In the case of the 3H(α,γ)7Li reaction the calculated S factor is larger than available experimental data by about 15%.     

Breakup of 8B and the 7Be(p, γ)8B reaction

The calculated rate of events in some of the existing solar neutrino detectors is directly proportional to the rate of the ⁷Be(p, γ)⁸B reaction measured in the laboratory at low energies. However, the low-energy cross sections of this reaction are quite uncertain as various measurements differ from each other by 30–40%. The Coulomb dissociation process which reverses the radiative capture by the dissociation of ⁸B in the Coulomb field of a target, provides an alternate way of accessing this reaction. While this method has several advantages (like large breakup cross sections and flexibility in the kinematics), the difficulties arise from the possible interference by the nuclear interactions, uncertainties in the contributions of the various multipoles and the higher order effects, which should be considered carefully. We review the progress made so far in the experimental measurements and theoretical analysis of the breakup of ⁸B and discuss the current status of the low-energy cross sections (or the astrophysical S-factor) of the ⁷Be(p, γ)⁸B reaction extracted therefrom. The future directions of the experimental and theoretical investigations are also suggested. Work supported by EPSRC, UK, grant nos J/95867 and L/94574.     

Radiative decays and quark content of f 0(980) and φ(1020)

The quark structure of φ(1020) and f ₀(980) is studied on the basis of data on the radiative decays φ(1020) → γπ ⁰, γη, γη′, γ a ₀(980), γ f ₀(980) and f ₀(980) → γγ. The partial widths are calculated under the assumption that all the mesons under consideration are $\bar qq$ states: φ(1020) is a dominantly $s\bar s$ state ( $\eta ' = n\bar nsin\theta + s\bar scos\theta $ component contributes not more than 1%); η, η′, and π ⁰ are standard $q\bar q$ states, $\eta = n\bar ncos\theta - s\bar ssin\theta $ and $\eta ' = n\bar nsin\theta + s\bar scos\theta $ with θ?37°; and f ₀(980) is a e5 meson with the flavor wave function $n\bar ncos\varphi + s\bar ssin\varphi $ . The transition φ → γπ ⁰ specifies the admixture of the $n\bar n$ component in the φ meson: it is on the order of 0.5%. We argue that this order of $n\bar n$ value does not contradict data on the decay φ(1020) → γ a ₀(980). The partial widths calculated for the decays φ → γη, γη? are in reasonable agreement with experimental data. The measured branching-ratio value Br(φ→γf ₀(980))=(3.4±0.4 _?0.5 ^+1.5 ×10^?4) requires 25°≤|?|≤90°. For the decay f ₀(980) → γγ, the agreement with data, Γ(f ₀(980) → γγ)=0.28 _?0.13 ^+0.09 keV, is attained at either ?=85°±8° or ?=?46°±8°. A simultaneous analysis of the decays φ(1020) → γ f ₀(980) and f ₀(980) → γγ favors the solution with the negative mixing angle of ?=?48°±6°, setting f ₀(980) very close to the flavor octet (? _octet=±54.7°).     

Atmospheric chemistry of HFE-7000 (i-C3F7OCH3) and isofluoro-propyl formate (i-C3F7OC(O)H): reactions with OH radicals,atmospheric lifetime and fate of alkoxy radical (i-C3F7OCH2O•) – a DFT study

ABSTRACT

The mechanism of hydrogen abstraction reaction between HFE-7000 (i-C₃F₇OCH₃) and OH radicals using M06-2X functional in conjunction with 6-31+G(d,p) basis set is investigated. The pre-reactive and post-reactive complexes from intrinsic reaction coordinate calculations are validated at entrance and exit channels, respectively. The standard enthalpies of formation for the species and bond dissociation energy for C–H bond are also estimated. The rate constants of the titled reactions over the temperature range of 250–450 K are reported. The OH-driven atmospheric life time of i-HFE-7000 is computed to be 3.19 years. The atmospheric fate of the alkoxy radical (i-C₃F₇OCH₂O^?) is also explored here for the first time. Three prominent plausible decomposition channels including oxidation are considered in detail. The thermochemical data reveal that reaction with O₂ is the dominant path for the decomposition of i-C₃F₇OCH₂O^? radical. Moreover, rate constant for the OH-initiated hydrogen abstraction of isofluoro-propyl formate (i-C₃F₇OC(O)H) is also reported.     

Line Positions and Intensities in the 2nu(2)/nu(4) Vibrational System of (14)NH(3) near 5-7 µm

Line positions and intensities belonging to the vibrational system 2nu(2)/nu(4) of ammonia (14)NH(3) are measured and analyzed between 1200 and 2200 cm(-1) in order to improve the molecular database. For this, laboratory spectra are obtained at 0.006 and 0.011 cm(-1) unapodized resolution and with 4% precisions for the intensities using Fourier transform spectrometers located at the Kitt Peak National Observatory and the Jet Propulsion Laboratory. The observed data contain transitions of the nu(4) fundamental band near 1626.276(1) and 1627.375(2) cm(-1) (for s and a inversion upper states, respectively) and the 2nu(2) overtone band near 1597.470(3) and 1882.179(5) cm(-1) (for s and a inversion states, respectively). A total of 2345 lines with J' 相似文献   

A straight domain boundary of single-atom width on a Si(111)-(7 × 7) surface

Using scanning tunneling microscopy (STM), we have observed an antiphase domain boundary of single-atom width on a Si(111)-(7 × 7) surface. The extra row of adatoms forming the boundary lies on the unfaulted half of the 7 × 7 unit cell, in agreement with total energy calculations using the first-principles self-consistent pseudofunction method. The filled-state STM image shows a missing interior adatom on the unfaulted half, in agreement with calculations of the partial density of states of an adatom surrounded by three rest-atoms.