共查询到20条相似文献,搜索用时 15 毫秒
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《Journal of organometallic chemistry》1992,431(1):C21-C25
The molecular structure of di-μ-carbonyl-bis[carbonyl(η5-pentamethylcyclopentadienyl)ruthenium] (RuRu) has been determined by a single-crystal X-ray diffraction study (monoclinic, space group P21/n,a 979.90(9), b = 831.91(7), c = 1427.75(12) pm, β = 100.026(9)°, R = 0.018). In the solid state the complex exists solely as the trans-carbonyl bridged isomer. The RuRu bond length is 275.2(1) pm. 相似文献
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《Journal of organometallic chemistry》1991,408(2):C25-C29
Upon warming the reaction mixture of Ni(cdt), C2F4, and 2,6-iPr2Ph-dad in THF from −78°C to room temperature the red-violet complex (2,6-iPr2Ph-dad)Ni(C2F4) (1) is obtained. 1 reacts with ethene already at −78°C by coupling of the olefinic ligands with the nickel atom to form the blue nickelatetrafluoro-cyclopentane compound (2,6-iPr2Ph-dad)Ni(C2H4C2F4) (2). 相似文献
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《Journal of organometallic chemistry》1988,348(1):C12-C14
Pt(PPh3)2(C2H4) reacts with monofluoroacetylene to give the π-complex Pt(PPh3)2(FCCH), and with dichloroacetylene under oxidative addition to yield Pt(PPh3)2(Cl)(ClCCl), the structure of which was determined by X-ray crystallography. 相似文献
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《Journal of organometallic chemistry》1987,320(2):C11-C15
Upon reaction of Na[MeCp(CO)2MnSiR3] (1) (MeCp = η5-CH3C5H4) with Ph3PAuCl or (3-picoline)2PtCl2 (2) in the presence of moist 3-picoline the heteronuclear hydrido complexes MeCp(CO)2Mn(μ-H)AuPPh3 (3) or [MeCp(CO)2Mn(μ-H)]2Pt(3-picoline)2 (4) are obtained. In both complexes the hydride ligand bridges the two metals. 相似文献
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A. Kurtenacker 《Fresenius' Journal of Analytical Chemistry》1960,174(6):452
Ohne Zusammenfassung 相似文献
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《Journal of organometallic chemistry》1991,403(3):C29-C31
Dicarbonyl(η5-cyclopentadienyl)(diethylaminocarbyne)(tungsten reacts with dimethyl(methylthio)sulfonium tetrafluoroborate to form dicarbonyl(η5-cyclopentadienyl)[η2-diethylamino(methylthio)carbene]tungsten in high yields. 相似文献